1. Amalgam - An alloy that is formed by reacting mercury with silver, copper, and tin, and which may also contain palladium, zinc a. Irregular, spherical, lathe cut b. Silver-tin alloys are quite brittle and difficult to blend uniformly unless a small amount of copper is substituted for silver. c. zinc in an amalgam alloy is to act as a deoxidizer, which is an oxygen scavenger that minimizes the formation of oxides of other elements in the amalgam alloys during melting. d. Ag3Sn (γ phase), Cu3Sn (ε phase), Silver-Mercury (gamma I), Tin-Mercury (gamma II) e. High copper amalgams- 11.8% by weight. f. Creep- Creep rate has been found to correlate with marginal breakdown of conventional lowcopper amalgams; that is, the higher the amount of creep, the greater is the degree of marginal deterioration. Creep causes the amalgam to flow over time such that unsupported amalgam protrudes at the margin of the restoration. Because of low tensile strength and the onset of corrosion, the protruded segment of amalgam fractures and leaves a ditch around the margin g. If the amalgam is properly inserted, leakage decreases as the restoration ages in the mouth. This may be caused by corrosion products that form in the interface between the tooth and the filling, 2. Composite a. Components i. Resin Matrix – monomer, initiator, inhibitors, pigments ii. Inorganic Filler- glass, quartz, silica 1. Macrofillers (10-50um), Microfiller (40-50nm), Hybrid (both macro and micro), nano composite (nanomers- 0.02-0.07nm and nanoclusters 0.6-1.4nm) 2. Similar performance of nanocomposites and microhybrids iii. Coupling Agent b. Flowable Composites i. Similar particle sizes to hybrids, lower viscosity, inferior mechanical properties c. Incremental vs Bulk Fill i. Incremental- shrinkage stress ii. Bulk Fill- less porosity 1. Depth of cure increased by translucency, additional photo initiator d. Beveling- does not improve clinical or esthetic success. 3. Bonding Agents a. Generations i. 4th- 3 step etch and rinse ii. 5th – 2 step etch and rinse iii. 6th – 2 step self etch, 1 step self etch (mix) iv. 7th – on step self etch (no mix) b. Etch and Rinse- good enamel etch, but sensitive to dentin wetness after rinse i. 37% phosphoric etch, Primer (HEMA, GPDM, PAMM), Adhesive (Bis-GMA) c. Self Etch- good dentin conditioning (etch and prime infiltrate same depth of dentin simultaneously), no rinse so no dentin wetness sensitivity, but may require refrigeration and lower bonding strength to enamel. i. Acidic Monomers – MDP, Di-HEMA-Phosphare ii. Crosslinking Monomers (Bis-GMA, UDMA) iii. Solvent (water) d. Universal - may be used as self-etch (SE) adhesives, etch-and-rinse (ER) adhesives, or as SE adhesives on dentin and ER adhesives on enamel (a technique commonly referred to as “selective enamel etching”) 4. Caries a. Diagnosis- visual inspection deemed sufficient alone for caries detection b. ADA Caries Classification i. Sound ii. Initial- mild decalcification, only noticeable after drying, E1-D1 iii. Moderate- Visible enamel breakdown or signs of dentin demineralization, D2 iv. Severe- cavitation with dentin exposure 5. CAMBRA- identify cause and risk factors of caries and correct cause and risk factors, not drill and fill a. Fluoride- evidence is in favor of fluoride application every 3-6 month for children 0-18 years old. Expert opinion suggests use in adults b. Pit and Fissure Sealants – 76% reduction in caries rate, minimize progression of occlusal caries, work better than fluoride for pit and fissure caires c. CHX- evidence shows chx/thymol varnish every 3 months can reduce incidence of root caries. Use of CHX varnish alone or in combination with fluoride for caries prevention is NOT recommended. d. Xylitol- evidence is of low quality to suggest xylitol can prevent caries e. ACP- evidence suggests that ACP can be used to augment flouoride in caries prevention. f. Minimally Invasive Tx i. Non-invasive (remineralization) tx better than control for avoiding invasive treatment ii. Micro-invasive (pit and fissure sealant) better than non-invasive for preventin invasive iii. Pit and fissure sealants effective at preventing invasive treatment but often require retreatment more often than remineralization or PRRs iv. Teeth with caries and sealants 1. Sealed teeth show no caries progression 2. Unsealed teeth show caries progression g. Partial Caries Removal- success is equivalent to complete caries removal, success depends on adequate seal, can reduce pulpal exposure by 98% h. Pulp capping Agents- Dycal, MTA, Biodentine, Theracal