Phenomenological Transport laws Lecture # 1 CHEN 300 – FALL 2018 Introduction Fluid mechanics: The science that deals with the behavior of fluids at rest (fluid statics) or in motion (fluid dynamics), and the interaction of fluids with solids or other fluids at the boundaries. 2 Introduction Fluid mechanics: The science that deals with the behavior of fluids at rest (fluid statics) or in motion (fluid dynamics), and the interaction of fluids with solids or other fluids at the boundaries. 3 What is a Fluid? 4 What is a Fluid? • Basically: a Gas or a Liquid. • Technically: a fluid is defined in terms of how it responds to an applied force (Shear Stress). 5 What is Shear Stress? • Stress: Force per unit area. • Normal stress: The normal component of a force acting on a surface per unit area. (Pressure) • Shear stress: The tangential component of a force acting on a surface per unit area. • Strain: Response of a system to an applied stress. The normal stress and shear stress at the surface of a fluid element. For fluids at rest, the shear stress is zero and pressure is the only normal stress. 6 Fluid vs Solid response to Shear Stress 𝑦 𝑥 • Consider two parallel plates with a ‘material’ between them. 7 Fluid vs Solid response to Shear Stress 𝑦 𝑥 • Consider two parallel plates. • Bottom plate is fixed. • Material sticks to bottom plate (no slip). 8 Fluid vs Solid response to Shear Stress 𝑦 𝑥 • Consider two parallel plates. • Bottom plate is fixed. • Top plate is subject to a tangential force Fx in the x direction. 𝑭𝒙 9 Fluid vs Solid response to Shear Stress 𝑦 𝑥 𝑭𝒙 • Consider two parallel plates. • Bottom plate is fixed. • Top plate is subject to a tangential force Fx in the x direction. Contact Area (𝑨𝒚 ) Shear stress: The tangential component of a force acting on a surface per unit area. 𝝉𝒚𝒙 𝑭𝒙 = 𝑨𝒚 10 Fluid vs Solid response to Shear Stress 𝑦 𝑥 𝑭𝒙 • Consider two parallel plates. • Bottom plate is fixed. • Top plate is subject to a tangential force Fx in the x direction. Contact Area (𝑨𝒚 ) Shear stress: The tangential component of a force acting on a surface per unit area. Shear Strain: Response of a system to an applied stress. 𝝉𝒚𝒙 𝑭𝒙 = 𝑨𝒚 𝜸𝒚𝒙 11 Fluid vs Solid response to Shear Stress 𝑦 𝑥 Shear Strain: Response of a system to an applied stress. Case #1: The material is perfectly rigid (e.g. a brick). → Solid 𝑭𝒙 Brick • No deformation. ∴ 𝜸𝒚𝒙 = 𝟎 12 Fluid vs Solid response to Shear Stress 𝑦 𝑥 𝑭𝒙 Shear Strain: Response of a system to an applied stress. Case #2: The material is linearly elastic (e.g. rubber). → Solid • Will deform by an angle α. • The degree of deformation depends on the material properties. • Stress- Strain Relationship through the Shear Modulus. 𝜶 Rubber ∴ 𝜸𝒚𝒙 = 𝜶 𝝉𝒚𝒙 = 𝑮𝜸𝒚𝒙 13 Fluid vs Solid response to Shear Stress 𝑦 𝑥 𝑭𝒙 Shear Strain: Response of a system to an applied stress. Fluid Case #3: The material is a Liquid. → Fluid Will deform continuously under the influence of a shear stress. i.e. Flow 14 Fluid vs Solid response to Shear Stress 𝑦 𝑥 𝑭𝒙 Shear Strain: Response of a system to an applied stress. Fluid Case #3: The material is a Liquid. → Fluid Will deform continuously under the influence of a shear stress. i.e. Flow Resistance to flow is defined as the viscosity of the Fluid. 𝝉𝒚𝒙 𝒅𝜸𝒚𝒙 =𝝁 𝒅𝒕 15 Viscosity Resistance to flow is defined as the viscosity of the Fluid. Shear Stress 𝝉𝒚𝒙 𝒅𝜸𝒚𝒙 =𝝁 𝒅𝒕 Rate of Shear Strain Viscosity 16 Viscosity Resistance to flow is defined as the viscosity of the Fluid. Shear Stress 𝝉𝒚𝒙 𝒅𝜸𝒚𝒙 =𝝁 𝒅𝒕 Rate of Shear Strain Viscosity Lower Viscosity 17 Viscosity Resistance to flow is defined as the viscosity of the Fluid. Shear Stress 𝝉𝒚𝒙 𝒅𝜸𝒚𝒙 =𝝁 𝒅𝒕 Rate of Shear Strain Viscosity Lower Viscosity Higher Viscosity 18 Types of Flows -1 Viscous vs Inviscid Flows • Viscous Flow: Flow in which the frictional effects are significant. Almost all flows of practical interest in Chemical Engineering are Viscous Flows. • Inviscid Flow: The flow of an ideal fluid that is assumed to have no or negligible viscosity. Extensively used as a simplifying assumption to solve complex fluid dynamics problems. 19 Types of Flows -2 External vs Internal Flows • External Flow: Flow of an unbounded fluid over a surface. Example: Fluid flow around a sphere. • Internal Flow: The fluid is completely bounded by solid surfaces. Example: Fluid flow inside a pipe or duct. 20 Types of Flows -2 External vs Internal Flows • External Flow: Flow of an unbounded fluid over a surface. Example: Fluid flow around a sphere. • Internal Flow: The fluid is completely bounded by solid surfaces. Example: Fluid flow inside a pipe or duct. External flow around a sphere. 21 Types of Flows -3 Compressible vs Incompressible Flows Defined by Density of Fluid Density: Mass per unit Volume (e.g., @ 20 oC, 1 atm) Water Mercury Air rwater rHg rair = 1000 kg/m3 = 13,500 kg/m3 = 1.22 kg/m3 22 Types of Flows -3 Compressible vs Incompressible Flows • Incompressible Flow: the density does not change during fluid motion (constant density). 𝒊. 𝒆. 𝝏𝝆 𝝏𝝆 𝝏𝝆 , , =𝟎 𝝏𝒙 𝝏𝒚 𝝏𝒛 • Compressible Flow: Flow exhibits significant changes in fluid density. Density increases Density decreases 23 Types of Flows -3 Compressible vs Incompressible Flows • Incompressible Flow: the density does not change during fluid motion (constant density). • General criteria used to define incompressible flow: 𝒊. 𝒆. 𝝏𝝆 𝝏𝝆 𝝏𝝆 = 𝟎 𝒐𝒇 𝒇𝒍𝒖𝒊𝒅 𝒖 , 𝝏𝒚 ,𝑺𝒑𝒆𝒆𝒅 𝝏𝒙 𝝏𝒛 • Mach Number: 𝑴𝒂 = = 𝒄 𝑺𝒑𝒆𝒆𝒅 𝒐𝒇 𝒔𝒐𝒖𝒏𝒅 • Compressible Flow: Flow exhibits significant changes in fluid density. 𝑰𝒇 𝑴𝒂 < 𝟎. 𝟑 Density increases ⟹ 𝑪𝒐𝒎𝒑𝒓𝒆𝒔𝒔𝒊𝒃𝒍𝒆 Density decreases 24 Types of Flows -4 Laminar vs Turbulent Laminar flow: The highly ordered fluid motion characterized by smooth layers of fluid Turbulent flow: The highly disordered fluid motion that typically occurs at high velocities and is characterized by velocity fluctuations. 25