EEE 209 Lecture-3 Ref: Principles of Electronic Materials & Devices by S.O. Kasap (4th edition)- Chapter 4 & B.G. Streetman (Chapter 3) Fermi Distribution Takes into account Pauli exclusion principle. EF is the Fermi energy level → energy at which f(E)=0.5 for T>0 Density of states Number of allowed states per unit energy per unit volume → density of states For 3D materials Density of carriers If the band starts at Ec then Density of electrons Physical Source of holes Intrinsic Material Pure material If one of the Si valence electrons is broken away from its position in the bonding structure such that it becomes free to move about in the lattice, a conduction electron is created and a broken bond (hole) is left behind. At equilibrium Extrinsic Materials Doped materials → a common technique for altering the conductivity of materials. N-type dopants As, P, Sb n type materials A small amount of thermal energy enables this extra electron to overcome its coulombic binding to the impurity atom and be donated to the lattice as a whole. Thermal energy N type dopants are also called donors p type materials P type dopants B, Al, In p type materials With a small amount of thermal energy, this incomplete bond can be transferred to other atoms as the bonding electrons exchange positions. P type dopants B, Al, In Thermal energy p type dopants are also called acceptors