See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/312490665 Semiconductor Equipment Safety Standards Working Paper · January 2017 DOI: 10.13140/RG.2.2.35008.74243 CITATIONS READS 0 20,638 1 author: Nikola Zlatanov Applied Materials 44 PUBLICATIONS 52 CITATIONS SEE PROFILE Some of the authors of this publication are also working on these related projects: AC Power Distribution Systems and Standards View project Lasers and laser applications View project All content following this page was uploaded by Nikola Zlatanov on 17 January 2017. The user has requested enhancement of the downloaded file. Semiconductor Equipment Safety Standards Nikola Zlatanov* Introduction Technical operations such as those performed in semiconductor and photovoltaic device fabrication have inherent risks. For example, the equipment employed in these industries may operate at high temperatures, under vacuum conditions and can employ high electrical voltage/ currents and/or extremely hazardous, often pyrophoric and frequently corrosive chemicals. The failure of a critical system component with any of these system characteristics can produce unsafe conditions that can lead to severe injury or death of the operators, not to mention catastrophic damage to costly equipment. Other industrial settings have similar or greater levels of risk. Operational safety is thus of paramount importance in industrial semiconductor and other chemical processing systems. Because of this, a great deal of effort has been expended over the past decades into efforts to establish reliable metrics for the prediction of safe operational conditions for process equipment and to implement designs that meet the acceptable risk level without compromising costs and programmability. Operational safety is of paramount importance in OEM designs and the question of hard-wired safety solutions vs. programmable hardware-based safety solutions must be considered for these designs. In the past, safety engineers have typically resolved this question in favor of hard-wired interlocks in which the logic was wired directly onto the PCB. As an example, consider the semiconductor industry. Semi S2, the Safety Guideline for Semiconductor Manufacturing Equipment, is often cited as the “gold standard” of interlock safety and it recommends the use of electro-mechanical components for safety interlocks. However, it is commonly overlooked that the Semi S2 guidance also permits the use of solid state devices in a safety system, as long as they can be proven to be safe (cf. S2-93 SEMATECH Application Guide). The question confronting OEMs thus becomes: are operational safety solutions achieved through the use of programmable hardware-based interlocks as safe, or indeed more safe than hard-wired solutions. Since it is often the case that safety is best implemented using hard coded safety in one instance while another is more suited to programmable hardware safety, solution providers must offer safety interlocks in the form of both hardware based, and programmable hardware-based interlock safety boards. Knowing that both options exist, with the required level of safety criteria, is beneficial to the engineer who needs to make a decision about their safety solution. Predicting System Safety Mean Time Between Failures (MTBF) has been used as a metric for the prediction of a system’s ability to operate reliably. MTBF is described analytically by the following relationships: where λi = failure rate of i system component and n = number of components in the system. If the failure rate is expressed as “per hour” then the MTBF is in hours. Unfortunately, while MTBF is an excellent overall metric for assessing system reliability, it is not a metric that is specific for evaluating system safety. The problem with using MTBF as a safety metric is characterized in the following discussion: In any attempt to predict the safety characteristics of a given system, the most important failure rate is that associated with dangerous failures rather than the overall rate of failure of the system, 1 as is the case for MTBF. Therefore, in evaluating safety, λ needs to be subdivided into the components that reflect the impact of the type of failure on the system safety (i.e.): λ = λS + λDD + λDU λ = the rate of safe failures having no impact on safety (The system may cease function but no safety issue will exist); λDD = the rate of dangerous failures that are detected by the system safety design (Hence the system safety design can avoid a safety issue); λ DU = the rate of dangerous failures that are not detected by the system safety design (Such failures may cause a safety issue). Using these definitions, it can be seen that two systems having the same MTBF value can differ significantly in terms of the λDU value. Thus, serious inequalities in the safety of such systems are not predictable using just the MTBF metric. More reliable concepts for the prediction of system safety have emerged in recent years. Specifically, the concept of Safety Integrity Levels (SILs) has evolved for the design of safety critical systems such as those employed in the chemical and semiconductor process industries. Developed over the last two decades, the SIL concept has emerged from efforts to improve the safety of such systems. The concept has been developed with the purpose of moving away from the consideration of safety as an either/or characteristic of a system. Rather than considering a system as “safe” or “unsafe”, the SIL concept views safety as a continuous spectrum with a system’s position on the spectrum directly related to the level of risk of entering an unsafe state. Risk definition and analysis becomes a critical exercise in the development of safe systems. SIL 4 On Demand Mode of Operation (Probability of failure to perform its design function on demand) ≥ 10-5 to < 10-4 Number of Treated Demands 1-α = 0.99 1-α = 0.95 4.6 x 105 3 x 105 High Demand or Continuous Mode of (Probability of a dangerous failure per hour) -9 ≥ 10 to < 10-8 Hours of Operation in Total 1−α = 0.99 1-α = 0.95 4.6 x 109 3 x 109 3 ≥ 10-4 to < 10-3 4.6 x 104 3 x 104 ≥ 10-8 to < 10-7 4.6 x 108 3 x 108 2 ≥ 10-3 to < 10-2 4.6 x 103 3 x 103 ≥ 10-7 to < 10-6 4.6 x 107 3 x 107 1 ≥ 10-2 to < 10-1 4.6 x 102 3 x 102 ≥ 10-6 to < 10-5 4.6 x 106 3 x 106 The dominance of electronic control systems and integrated electronic circuitry in modern process technology, coupled with the vastly improved reliability of electronic components, has prompted the development of the international safety standard: IEC61508, “Functional Safety of Electrical/ Electronic/Programmable Electronic Safety-related Systems”. This standard codifies the requirements for the use and design of electronic and programmable safety functional systems and is commonly used as a method of proving that system safety is at a level sufficient for Semi S2 compliance and certification. Developed using the SIL concept, IEC61508 requires that risk analysis for “each determined hazardous event” be performed for each functional system within the Equipment Under Control (EUC) to establish functional safety in the entire system. IEC61508 defines risk as a function of the likelihood of an event and the severity of the consequences of that event. The system is considered safe if the risk can be acceptably reduced by applying either electronic circuits and programmable components or the traditional combination of traces and relays. IEC61508 defines four distinct Safety Integrity Levels; Safety Integrity Level 1 (SIL1) is the lowest level and Safety Integrity Level 4 (SIL4) the highest. Under IEC61508, safety systems are sorted into two categories: Continuous (high demand) Mode and On (low) Demand Mode. For example, in a car the braking system constitutes a functional safety system that works in Continuous Mode. The system must be ready to work at all times. On the other hand, the air-bag system is an On Demand functional safety system. It is needed very rarely and preferably never. But when it is needed, it must work. User configurable safety interlocks, such as those being addressed in this paper, are On Demand functional safety systems. In On Demand systems, 2 the accident rate is defined as a combination of the frequency of demands and the probability that the function will fail on demand (PFD). In Continuous Mode systems, the accident rate is the MTBF. Table 1 shows how the SIL levels are defined for On Demand and Continuous Mode safety functional systems. The PFD or Probability of Failure on Demand metric determines the SIL category (1-4) of the system. For example, in Table 1 above, a PFD value in the range 10-4 to 10-3 (e.g. SIL3 for On Demand Mode of Operation) means that for one out of 1000 to 10,000 demands most of the systems will fail. The lower the PFD number, the better the SIL. The relation between SIL and PFD is taken from the IEC 61508 standard. Electro-mechanical Interlocking devices When a machine or plant has to be equipped with a movable guard, the question that arises for the design engineer is: how is the position of this mobile safety device monitored? On the one hand the regulations in standards must be observed here. Of prime relevance here is the Machinery Directive 2006/42/EC, Annex 1 (see Section 1.4 - Required characteristics of guards and protective devices) as well as the A standard ISO 12100 (see Section 6.3.3) and - very important – the standard ISO 14119 "Safety of machinery - Interlocking devices associated with guards - Principles for design and selection". At the same time the selection and design of a protective device and its interlocking device must be considered under technical and economic aspects. The manipulation of protective devices must also be considered, as this forms part of the man/machine interface. The new ISO 14119:2013 was released at the end of 2013 and supersedes the previous version, ISO 14119 (1998-05) and the German DIN EN 1088. It is a “B2” standard in accordance with ISO 12100. The standard deals with the selection of interlocking devices. But it also provides advice on their design and assessment, and is therefore an aid to mechanical engineers wishing to design their own interlocking device. "Interlocking" and "guard locking" Unfortunately, the much used term "interlocking device" is not self-explanatory. The definition can already be found in the Type A standard ISO 12100 (Section 3.28.1), and has now been adopted unchanged in ISO 14119 (Section 3.1). According to this definition, an "interlocking device" or "interlock" is a "mechanical, electrical or other type of device, the purpose of which is to prevent the operation of hazardous machine functions under specified conditions" (generally as long as the guard has not closed). When this formal definition is translated into everyday language, an interlocking device is therefore a position switch, proximity switch, guard locking etc. on a protective device, which has the effect of enabling the machine controller to react to the position of a guard. With some interlocking devices which use a position switch with separate actuator, the separate actuator can be restrained so that the associated guard can only be opened under certain conditions, such as when the machine stops. A device which enables such a function is called a guard locking device or guard locking. In everyday language, one would probably describe this locking of the guard as "interlocking" rather than the link between the position of a guard and the machine controller. In cases of doubt, it is therefore advisable to ask what is precisely meant by the term "interlocking": "interlocking" within the meaning of the EC Machinery Directive and the corresponding European standards or "guard locking" as meant in the sense described above? This confusing terminology of interlocking/guard locking is not only a problem in English, but also in German (Verriegeln/Zuhalten) and in French (verrouillagel interverroui/lage). Fig 1: Example of an interlocking device 1) guard 2) Interlocking device 3) Actuator 4) Position switch 5) Actuating system 6) Output system a) Direction of opening 3 Fig 2: Principles of Type 1, Type 2, Type 3 and Type 4 interlocking devices. a) Type 1 interlocking device (actuated using uncoded cam, guard closed); b) Type 2 interlocking device (actuated using encoded tongue, guard not closed); c) Type 3 or 4 interlocking device (uncoded or encoded, non-contact actuated, guard closed). 1) movable guard 2) interlocking device 3) actuating element: a cam; b tongue; c RFID, reflector, surface 4) position switch 5) actuating system 6) output system Four basic designs For the first time "ISO 14119" (referred to below as standard) provides an illustration specifically according to the definition in Section 3.1, and which makes it easier to understand the definition and the various components of an interlocking device. The main component of an interlocking device is the position switch, which itself is divided into an actuating system and output system. The actuating element is the part connected to the movable guard. It can be provided by the user or be supplied by the manufacturer of the position switch. The classification of interlocking devices into various types is primarily made according to the actuation principle and then according to the encoding of the actuating element. Type 1 • Mechanically actuated through physical contact, i.e. using force; • "Uncoded actuating element”. This design is the classic position switch as shown in Figure 1. Type 1 switches have diverse uses, not least because the actuating element can be configured by the user himself. Due to the many possible designs of the actuating element, this is described as uncoded. Type 2 • Mechanically actuated through physical contact, i.e. using force; • "Encoded actuating element". In DIN EN 1088 this model is called "Interlocking device with separate actuator". It has long been known in Germany as a "category 2 switch" and more recently as a "type 2 switch". The latter name has now also found its way into the international standard and has even been extended to include types 3 and 4. Type 2 switches are characterized by very safe actuation whilst also being relatively easy to 4 "circumvent". This fact has already been addressed by A1 (Amendment 1) to DIN EN 1088, and the new standard also devotes an entire section to reducing the circumvention potential. Type 3 • Non-contact actuation, i.e. without physical contact; • "Uncoded actuating element". In this design, the actuating element and the actuating system are separated from each other. On approaching (guard closed), they switch the enable to start the machine. A counterpart (actuator) is required, but in the case of proximity switches with safety function, can be a metal flag for example. Type 4 • Non-contact actuation, i.e. without physical contact; • "Encoded actuating element". In the case of Type 4 switches, the actuating element and the actuating system are separated from each other. On approaching (guard closed), they switch the enable to tart the machine. The actuating element is encoded; a counterpart to the sensor (actuator) is required. Table 1 of the standard provides an overview of the design types and refers to the examples in Annexes A to E. Examples of actuating principle Mechanical Contact, force Examples of actuating elements Uncoded Cam profile Encoded Abbreviation Type 1 Linear cam A.2, A.4 Hinge A.3 Tongue (actuator key) Type 2 Key transfer system Non-Contact Inductive Uncoded Suitable ferrous material Magnetic Magnet, electromagnet Capacitive Every suitable object Ultrasound Every suitable object Optical Every suitable object Magnetic Encoded Examples* A.1 Encoded magnet B.1 B.2 Type 3 C Type 4 D.1 RFID Encoded RFID transponder D.2 Optical Optically encoded transponder - Table 1: Overview of the interlocking devices. * Examples of devices in Annex A through D of the standard Encoded actuating elements The term "uncoded actuating element" (Type 1 and 3) or "encoded actuating element" (Type 2 and 4) are used in conjunction with the design types. Without a precise definition, misunderstandings frequently arise about the meaning of "encoded" in this connection. Sometimes a Type 2 position switch is described as "encoded" if its interlocking device can only be actuated using the (always identical) supplied actuating element. However, there are also ranges of actuating elements which have several thousand variations. The probability that an identically encoded actuating element is available and that the interlocking device can be circumvented with it is extremely small. The standard creates clarity here too by defining three encoding levels: low, medium and high. Thus a "low level encoded actuator" is one which has between 1 and 9 encoding possibilities. The number of possibilities for a medium encoding level is between 10 and 1,000; more than 1,000 possibilities correspond to a high encoding level. A mechanical actuating element which, while having a specific shape, is always manufactured in its thousands in the identical shape, is classified as being a low level encoded actuator. 5 Similarly, a magnetic actuator element is classed as encoded (at a low level) as soon as a specific rather than a standard commercial magnet or simple metal flag is required for actuation. Reference is made to a high encoding level for non-contact acting RFID-based interlocking devices, for which an almost infinite number of encoding variations are available. Interlocking devices with guard locking function As can be seen from the heading, this product is an interlocking device which has been supplemented by a guard locking mechanism so as to keep a movable guard closed during a hazardous machine function (e.g. where dangerous stopping movements take longer). A separate status detection, which detects the position of the guard locking device, and generates a corresponding output signal which is used for control purposes, is a component of a guard locking device. The guard locking device can be an integral part of the interlocking device or a separate unit. The link to enable the machine (guard "closed" and "locked") must be guaranteed. As with electromechanical interlocking devices with guard locking function, one way of achieving this is by means of series connection or using the design measure of an integrated fail-safe locking mechanism. The design here ensures that an enable to start the machine can only be given when the protective device is closed and the guard locking is safely meshed. Since there are now several interlocking devices with guard locking functions on the market which contain a large number of potential-free contacts, the question for design engineers is, what are the right contacts to integrate in the safety circuit. The familiar symbol for positively driven contacts from IEC 60947-5-1, Annex K is available here: The standard has a new symbol for monitoring the guard locking of guard locking elements: This symbol identifies the contacts that the design engineer must integrate in the safety circuit of the controller in order to receive the message "protective device is closed". This does not apply in the case of interlocking devices with guard locking and electronic evaluation. The safe enabling outputs are realized by monitored outputs, usually transistor outputs (AOPD) here. Modes of operation and functions of guard locking An interlocking device with guard locking function, can be designed in a number of manifestations. For example, it can be released or actuated using different types of actuation: • Power-released • Released by spring force • Power-released, power-actuated • Power-actuated. However, the standard points out explicitly that when using guard locking that operates according to the principle of spring force release or energy actuation, the guard locking will be released during a power failure and that longer stopping times of machinery can arise and represent a hazard. Access to a danger zone, e.g. before a movement stops, would then be possible. This should be taken into account during the risk assessment, and additional measures may be required. 6 Fig 3: Actuation of a panic handle to leave a protected area New in the standard: interlocking devices with electromagnetic guard locking The interlocking device with electromagnetic guard locking has been newly adopted in ISO 14119. In this case an electromagnet keeps the protective device closed. Mechanical locking mechanisms are not present. The prerequisite for using such systems, however, is that the electromagnetic force is safely monitored in order to ensure that the defined guard locking force of the magnet is always achieved. If this is not the case, the interlocking device must not enable the machine start. As such a simple electromagnet is not suitable for such tasks. The advantage of these systems is that their smooth surfaces can be cleaned more easily. Compared to conventional systems, there are no openings to support the locking bolt, and no components or modules protrude on the moving part of the protective device. One disadvantage of the electromagnetic guard locking is that high locking forces with correspondingly high continuous current must be purchased. Release of interlocking devices with guard locking There may be a number of different reasons why an interlocking device which is currently kept closed should be released contrary to the command given by the machine controller. The standard defines three new terms on this subject for the first time: Emergency release This is the manual release of the guard locking without tools from outside the protected area. It is intended for freeing trapped persons or for fire-fighting, in other words in situations requiring fast action and where other risks are present in addition to those risks presented by the machine. Auxiliary release As with the emergency re lease, the manual release is effected from outside the protected area, but with the help of a tool or key. It is intended for interventions where speed is not of the essence, such as for a repair, when the guard locking cannot be released by the controller as a result of a fault. This is the manual release of the guard locking without tools from inside the protected area. Frequently, a kind of "escape route actuator/panic handle" is used here for simple actuation in the case of an escape. Selection of interlocking devices The new standard bears the title "Principles for the design and selection of interlocking devices". It is therefore directed at two, sometimes very different, target groups, namely the manufacturer of interlocking devices and the design engineer who is deploying them on his products. This ambivalence does not make the standard any easier to read. However, it does ensure that the specifications for manufacturer and user are to some extent consistent. 7 Section 6 of the standard offers help in the selection of a suitable interlocking device. "The following criteria must be taken into consideration when selecting or designing an interlocking device: • • • • • • • The conditions and the intended use of the machinery (see ISO 12100) The dangers arising on the machinery (see ISO 12100) The severity of the possible injury (see ISO 12100) The stopping time of the entire system and the access time The probability of a failure of the interlocking device The required Performance Level PL (see ISO 13 849-1) or Safety Integrity Level SIL (see IEC 62061) of the safety function Consideration of dynamic forces such as "bouncing back", especially to be considered for guard locking However, other criteria may also play a role depending on the application. One of the most important factors for selection is the question of whether the stopping time of the overall system is greater than the time required to reach the danger zone. If this question is answered in the affirmative, an interlocking device with guard locking must be selected. The flow diagram in the standard (see Figure 4) is designed to help come to a quick decision about which type of interlocking device is needed. Irrespective of the technology, a sufficiently high locking force on the guard locking device must be selected relative to the application. The informative Annex I in the standard is helpful here. The selection and specification of a suitable interlocking device with guard locking are the task of a Type C standard or a mechanical engineer. As a rule, the selection is made by a mechanical engineer. The device must, however, be selected in such a way that it can resist the anticipated forces in the application. Dynamic effects, such as "bouncing back", when a protective device is closed quickly and can rebound, must also be taken into consideration. Fig 4: Determination of the need for a locking interlock device If the anticipated impact forces are greater than the forces that can be withstood by the selected device, measures must be taken to reduce or prevent these forces. Attenuators such as shock absorbers represent a solution here. 8 Non-contact interlocking devices In addition to the familiar and proven electromechanical interlocking devices with positively driven contacts, ever more non-contact interlocking devices are available and in use. The advantages of such systems are clear to see. They are as follows: • Specially suitable for removable protective devices • Compact and have no external moving parts • Little vulnerability to dust and liquids • Easy to keep clean • Encoded • Tolerant to misalignment of the guard • Free of wear and tear. The new standard ISO 14119 has described these products and incorporated them in the informative Annexes C and D (see Figure 6, Type 3 and Type 4). The requirements of a non-contact interlocking device are described in the product standard IEC 60947-5-3. This standard deals with proximity switches under fault conditions, but does not deal with the subject of manipulation in detail. For this reason, the issue is dealt with thoroughly in ISO 14119 (see below). NB: In the past, an interlocking device was also implemented using commercially available proximity switches, and this is possible under ISO 14119. The EMC requirements are being made more stringent with the revision of product standard IEC 60947-5-3, however. With the introduction of IEC 61326-3-1 IEC 60947-5-3, it will become difficult to comply with the requirements of this product standard, which is also required under ISO 14119, using common inductive proximity switches. Fig 5: Method to determine the possible incentive to tamper with interlocking devices and the requisite measures to be taken by the manufacturer 9 Type 3 or Type 4 interlocking devices can be used to compensate for problems which can arise during the use of Type 1 or Type 2 interlocking devices. When considering possible manipulation and the resultant required measures, interlocking devices equipped with RFID technology are suitable, for example. Manipulation of interlocking devices In addition to selecting interlocking devices that comply with standards, it is also necessary to consider their design and/or integration in processes in terms of possible manipulation. There is a chapter in the standard for this. It is entitled "The use of design to minimize the opportunities for circumvention of interlocking devices". The background to this includes the BGIA manipulation study from 2006, which established a strong accumulation of manipulation on machine tools. Amendment 1/2007 of DIN EN 1088 described design requirements aimed at circumvention opportunities; these have been incorporated in the latest ISO 14119. Section 7 of the standard deals with this subject. The background is the requirement from the A standard ISO 12100, Section 1.4. "Requirements on protective devices'', and in particular Section 1.4.1.2 "General requirements''. Guards and protective devices other than a guard • must be built strongly • must not be capable of being easily circumvented or rendered ineffective The basis for considerations to prevent opportunities for circumvention is a tiered concept based on the tiered concept in ISO 12100: • Basic measures, such as securely affixing the interlocking device, protection from external influences and loosening of the fastening, compliance with tolerances etc., encoding of actuators on interlocking devices (Type 2 and Type 4 devices), use of electromechanical switchgear with positively driven contacts etc. • Establishing whether a manipulation incentive exists. The informative annex in the standard offers a procedure in the form of a tabular evaluation as suggestion, together with a further, completed table as example. This enables the possible incentive to manipulate every protective device, depending on the operating mode, to be checked and documented and for corresponding countermeasures to be specified where applicable. This systematic approach is also suitable as a component of the technical file. Application of additional measures to minimize the opportunities for circumventing interlocking devices (design check) Additional measures must be taken if the risk of circumvention in a reasonably foreseeable manner still exists after implementing the above mentioned measures. For such cases, the standard contains a diagrammatic representation of the method to determine possible incentives and the measures that machine manufacturers are required to take. It furthermore indicates additional measures which are designed to at least make the circumvention of interlocking devices more difficult. Additional measures Essentially measures of a design nature are addressed here: • Accessibility to the interlocking device • Attaching out of reach • Cordons or screening • Attaching in a concealed position • Avoidance of alternative actuation using available objects • encoded actuators with low encoding level • encoded actuators with high encoding level • Avoidance of removal or changing the position • Use of non-detachable fastenings. This primarily refers to Type 2 switch actuators. • Integration of a circumvention monitoring in the Controller • Status monitoring • Periodic inspections • Use of an additional position sensing and plausibility check. 10 Table 3 in the normative part of the standard lists the measures to be carried out when the measures described in Figure 5 fail to produce the desired result. In some cases alternative measures are proposed; in others extremely restrictive measures are demanded or recommended. It is not always possible to implement the measures described above effectively or in a cost-neutral manner. Therefore in many cases it makes sense to deploy products directly that have been produced with a high encoding level. These are now supplied as electromechanical interlocking devices (Type 2 switches - see Figure 7), as interlocking device with guard locking (see Figure 8) or as electronic safety sensors with integrated RFID technology. Interface to the controller Interlocking devices are safety-related parts of the control system of a machine (SRP/CS in accordance with ISO 13849-1) or a subsystem of a safety-related part of an electrical control system (SRECS in accordance with IEC 62061) and must correspond to the requirements of the above standards. In their technical data and depending on the characteristics of their product, the manufacturers of interlocking devices generally specify the requisite safety- related parameters (B10d, PFH etc.). An interlocking device with a required PLr = e under ISO 13849-1 or SIL 3 under IEC 62061 demands a minimum fault tolerance of 1 (e.g. two Type 1 interlocking devices), because faults cannot normally be ruled out. Fault exclusions are possible, however. ISO 13849-2 provides information on this in the informative annexes (see article "Validation of control systems in accordance with ISO 13849-2" on Page 169). For example, the following is supplemented in Annex D of ISO 13849-2 (Safety-related parts of control systems: Validation) under Table D8 (Faults and fault exclusions – Switches - Electromechanical Position Switches): "For PLe, no fault exclusion is permissible for mechanical (e.g. the mechanical connection between switch and contact elements) and electrical aspects. In this case redundancy is necessary." The conclusion from this is that a position switch or guard locking can be sufficient for applications in PLr = d. Monitoring the locked position A further aspect which has been described in detail for the first time in the standard is the monitoring of the locked position of guard locking. This additional safety function guarantees that a machine can only be set in motion if: • the safety device is closed; and • the guard locking device keeps the protective device closed. This safety function must be executed according to the risk analysis. All parts of the devices used to unlock/lock the signal are counted as safety-related parts of the control system. The question here is: does the guard locking also need to be performed redundantly in the case of a required PL= e or PL= d? The standard answers this question in its final version: a fault exclusion in PL e and in PL d is possible on the mechanical components of the guard locking, with the prerequisite that the requirements of guard locking which are similarly described in the standard are complied with. It means it is sufficient for applications in accordance with PL e to have just one guard locking and a further redundantly arranged position switch. ISO 14119 does not only result in an adjustment to technical progress through the consideration of new principles of operation for interlocking devices, it also provides practical hints on the design of protective devices and addresses the fact that protective devices are being repeatedly manipulated in practice. As such, probability is also being increasingly incorporated in the world of machine safety standards in this application area too. The standard was published at the end of 2013 and has transitional period of 18 months. Design engineers should be ready to be guided by the specifications and recommendations in ISO 14119. Standards Structure ISO and IEC have already established an overwhelming number of standards. Constantly adding and updating these standards to keep pace with daily product improvements is not possible. 11 However, classifying standards (ISO/IEC Guide 51) by type and using different types of standards in combination allows them to be applied to most up-to-date machinery. Three-tier Structure of International Safety Standards Type A: Fundamental safety standards applicable to all machinery. Type A standards deal with basic concepts, principles for design, and general aspects. (Type A standards are positioned on the top of the international safety standard pyramid, or they deal with one safety aspect.) Type B: Standards applicable to a wide range of machinery. Type B is divided into two categories: B1: Specific safety aspects (i.e., safety distances, surface temperature, and noise) B2: Safety related devices (i.e., two-hand controls, interlocking devices, pressure-sensitive devices, and guards) Type C: Detailed standards applicable to a specific machine or a particular group of machines. 12 Type A • ISO12100 along with ISO9000, the international standard for quality, and ISO14000 the international standard for the environment, ISO12100 Series formally became the international standard for safety of machinery in 2001. • ISO 14121 (Safety of machinery - Principles of risk assessment) is a typical Type A standard referred to by ISO12100. Type B • ISO13849-1: (Safety of machinery - Safety-related parts of control systems- part 1: General principles for design). It was developed based on EN954-1, and defines safety-related requirements for each category in accordance with ISO14121 (risk assessment). • ISO13850: (Safety of Machinery - Emergency stop - Principles for design). It defines functional requirements and design principles for stopping machinery in an emergency. It states that the emergency stop function has the top priority over all other operation modes and that its effectiveness cannot be overruled by any accidental operational command. It also states that electrical devices such as emergency stop switches must conform to IEC60204-1 (Electrical Equipment of Machines) • ISO13852: (Safety of machinery - Safety distances to prevent danger zones being reached by the upper limbs.) It defines safe distances to prevent the operator from reaching a dangerous zone. • ISO14119: (Safety of machinery - Interlocking devices associated with guards - Principles for design and selection) It defines the selection of safety switches to be used for guards. • EN954-1: Same as ISO13849-1. However, EN954-1 refers to EN1050, instead of ISO14121. • EN1088 : Same as ISO14119 • IEC60204-1: (Safety of Machinery - Electrical equipment of industrial machines - Part 1: General requirements). It defines requirements for electrical systems of machines. • IEC60079 series Explosion proof electrical devices. This Standard is comprised of many parts including general requirements. • IEC60947-5-1: (Low-voltage switch gear and control gear. Part 5: Control circuit devices and switching elements - Section one: Electromechanical control circuit devices). IEC6024-1 requires that low voltage switching gear conform to IEC60947-5-1. • IEC60947-5-5: (Low-voltage switch gear and control gear - part 5-5: Control circuit devices and switching elements - Electrical emergency stop device with mechanical latching function) It defines mechanical requirements (latching function, button colors, shapes, etc.) and electrical requirements (direct positive opening action function, etc.) Type C • ISO10218: (Manipulating industrial robots - Safety) 13 Compressed Gas Safety Compressed gas cylinders can present a variety of hazards due to their pressure and /or contents. All compressed gases used at UGA must be ordered through the Purchasing Department. In addition to the standard required work practices for inert gases, hazardous gases may require additional controls and work practices including, but not limited to, the use of gas cabinets, gas monitors, emergency shutoffs, proper equipment design, leak testing procedures, and the use of air supplying respirators for certain highly toxic gases. The ESD can be contacted for assistance with these requirements and to provide assistance with the safe design of equipment which involves the use of hazardous gases. It is the objective if this policy to ensure that employees handling compressed gases properly handle, store, and use them according to OSHA, DOT and other regulatory requirements. Students, regardless of status, are not to handle compressed gases unless under the direct supervision of a faculty or staff member. References: 29 CFR 1910.101, 102, 103, 104, 252, 253; 49 CFR 171 – 179; 14 CFR part 103; Compressed Gas Association Pamphlets, C-6-1968 and C-8-1962 Compressed Gas Use Applications Class 1 Application - Use of Inert Gases - Gases which are non-flammable and non-toxic, but which may cause asphyxiation due to displacement of oxygen in poorly ventilated spaces Class 2 Application - Use of Flammable, Low Toxicity - Gases which are flammable (at a concentration in air of 13% by volume or have a flammable range wider than 13% by volume), but act as non-toxic, simple asphyxiants (e.g. Hydrogen, methane) Class 3 Application - Use of Pyrophoric Gases and Liquids - Gases or liquids which spontaneously ignite on contact with air at a temperature of 130 F or below. Class 4 Application - Use of Corrosive, Toxic, and Highly Toxic Gases - Gases which may cause acute or chronic health effects at relatively low concentrations in air. (See Appendix A of Gas Monitoring Program for additional details on this definition and examples) Class 5 Application - Use of Compressed Gases in Fume Hoods Use of Cryogenic Liquids - Use of liquids with a boiling point below -238 F (-150 C). Use of Fuel Gases for Welding, Cutting, Brazing - Use of oxygen and fuel gases (e.g. propane, acetylene) for gas welding and cutting applications. Engineering Controls / Design Considerations This includes a listing of typical engineering controls, referenced in the list above. In some cases, the National Building Code may require additional controls. Additional controls or changes from the controls listed below may be appropriate for a particular application or experiment. The controls appropriate for each operation will be identified through the hazard review process. 1. Gas Cabinets -With the exception of cylinders containing a non-toxic, flammable gas, and cylinders used in fume hood applications, hazardous gas cylinders must be housed in gas cylinder cabinets. These cabinets must be equipped with sprinkler protection, and must be constructed and ventilated according to applicable building code requirements. These requirements include, for instance, but are not limited to, the need to provide 200 fpm air flow at the cabinet window. 2. Interlocks - In addition to automatic shutoff of gas flow due to loss of power or ventilation (described below), it will often be appropriate for an automatic shutdown of gas flow due to conditions such as high system pressure, high gas delivery pressure, loss of vacuum, loss of cooling, or other conditions identified through the hazard review process. 3. Emergency Off - Where gases are used in gas cabinets, the emergency off buttons should be located at the lab doorway. Activation of this button will cause pneumatic valves to shut, stopping gas flow. This button should kill electrical power to hazardous lab equipment as well. 4. Equipment Enclosures and Ventilation - Experimental apparatus using hazardous gases should be contained in an enclosed and exhausted enclosure (i.e., a laboratory hood). These enclosures must be connected to the exhaust ventilation system. Ventilation rates must be sized to allow for 100 fpm of air 14 flow through the largest open enclosure door. Mass flow controllers carrying hazardous gases must be housed in a separate ventilated enclosure (or in an enclosed compartment of a larger tool enclosure) so that 100 fpm exhaust flow is available at the largest open door to the enclosure. All components should be readily accessible for maintenance. 5. Smoke Detection - All labs using hazardous gases will have a smoke detector which is connected to the building alarm system. In certain cases, it may be necessary to interlock smoke detector activation with the shutdown of hazardous gas flow. 6. Sprinkler Protection - Where hazardous gases are contained in gas cabinets, sprinkler protection should be provided to the interior of the gas cabinet. In some cases, this protection is required by code. Sprinkler protection is recommended in all labs using hazardous materials. 7. Emergency Power - Emergency power is recommended to power exhaust fans connected to hazardous gas enclosures. In certain cases, this protection is required. 8. Pneumatic Shutoff Valves - All corrosive, toxic, flammable, and pyrophoric gases will contain a normally closed pneumatic shutoff valve, rated for at least full cylinder pressure, and located immediately downstream of the cylinder valve. This valve will shut in the event of power failure, remote actuation of an emergency off button (see this topic), or other appropriate conditions such as hazardous gas alarm activation. 9. Scrubbers - When hazardous waste gases are generated, it is often advisable to treat/react these gases prior to exhaust from the building. This may involve the use of bubblers in a fume hood or sophisticated units for larger scale hazardous gas processes. Note that in some cases (e.g. minimal volumes of hazardous gases produced) scrubbers may be not necessary or even unadvisable. Where scrubbers are used, they need to be carefully reviewed as part of the hazard review. Maintenance requirements and procedures need to be clearly understood and followed. 10. Vacuum Pumps - Vacuum pumps used for hazardous gases need to be carefully selected. Depending on the gases being pumped, special precautions may be necessary. For processes where pyrophoric gases are used, pumps need to be continuously purged with nitrogen, with loss of nitrogen flow causing the pyrophoric gas supply valves to close. Pumps used for oxygen service will need to be prepared for this services which includes the elimination of hydrocarbon oils for use due to flammability concerns. In some cases, such as the use of highly toxic gases, vacuum pumps will need to be housed in a ventilated enclosure. 11. Flow Restrictors - A means to limit hazardous gas flow rates to just over maximum flow needed must be installed immediately downstream of each hazardous gas cylinder. For small scale experiments, such as fume hood use, a needle valve is sufficient. For large cylinders a flow restricting orifice, installed by the gas supplier in the cylinder valve or installed in the gas purge panel is required. 12. Ventilation Alarms - All ducts connected to enclosures used to exhaust hazardous compressed gas cylinders or gas carrying components must be connected to a ventilation alarm. Typically, activation of this alarm will cause pneumatic gas supply shutoff valves to close. 13. Eyewash and Showers - A safety shower or eyewash with a wand is required to be present in areas where corrosive gases are used or stored. 14. Purge Panels - Where corrosive, pyrophoric, or toxic gases are in use, the gas installation must include means to adequately purge the area between the cylinder valve and the regulator with an inert gas prior to breaking these connections for maintenance or cylinder change. Inert gases used for this purpose must be used solely for this purpose and not connected to other apparatus. Failure to adequately purge cylinders can result in lack of ability to close the cylinder valve or "regulator creep" which allows full cylinder pressure to be transferred to the low pressure side of the regulator. Review the requirements listed in Purge Panels for your existing or planned installation. 15. Gas Monitors - See Gas Monitoring Program for a complete description of University gas monitoring requirements. 15 16. Piping and Fittings - All gas piping must be compatible with the gases used and capable of withstanding full cylinder pressure. For example, Tygon tubing should never be used with hazardous gases or low hazard gases unless one end is open to atmosphere. Fittings should be selected based on the service needs. Face seal or welding fittings should be used for hazardous gas service wherever possible. All gauges and components subject to leakages which carry hazardous gases must be contained in an exhausted enclosure. 17. Hardware - Never lubricate, modify, force, or tamper with a cylinder valve. Use the appropriate regulator on each gas cylinder. Adaptors or homemade modifications can be dangerous. Assure all components of the experimental apparatus that can handle full cylinder pressure or are otherwise protected. Oil or grease on the high-pressure side of an oxygen, chlorine, or other cylinder of an oxidizing agent can lead to an explosion. Whenever back siphoning of chemicals into the cylinder might be a problem, use multiple traps or check valves. Work Practices and Procedures - Hazardous Gases 1. Hazard Review - A hazard assessment is required for the following processes involving the use of hazardous gases: a. New or relocated equipment using a toxic, corrosive, or pyrophoric gas (contact 515-6860). b. New or relocated equipment using a flammable gas in a non-standard application (Contact 515-6860). Analytical equipment fuel gases, welding, cutting, brazing, and small scale use in fume hoods are considered standard applications. c. Existing gas installations should be self-inspected by the work area supervisor or Principal Investigator. Please contact ESD for assistance with this review. d. Existing installations using hazardous gases which are considered to present a significant risk or show design deficiencies will have a hazard review conducted at the discretion of the ESD. 2. Training - All persons handling or using cylinders must have basic training. Review of the information contained in this section, review of any additional information in the written safety plan for the work area, and hands-on assistance by an experienced gas user will meet this minimum requirement. Additional compressed gas safety training can be obtained through the ESD. 3. Hazard Information - The gas user must be thoroughly familiar with the properties of each gas they are using. A review of a good quality SDS is necessary. (See the SDS section of the ESD Home Page). 4. Ordering - All gas cylinders used on main campus may only be ordered and received through Central Stores. This allows for leak testing of highly toxic gases prior to delivery to your building. It also is the mechanism for inventory of gases used at the University. 5. Receiving - Be sure the cylinder tag (don't rely on cylinder stenciling or color coding) indicates the gas that has ordered. Hazardous gases (flammable, pyrophoric, toxic, corrosive) must be transported directly from the shipper to the end use location. No staging of hazardous gases is permitted. Low hazard gases (e.g. inert gases, Oxygen, Freon) may be stored temporarily in designated locations which provide means for securing cylinders with chains or straps. 6. Leak Testing - Toxic, corrosive, and pyrophoric gases must be leak tested at the following intervals; receiving, installation, disconnect/shipping. Highly toxic gases are leak tested by Environmental Health and Safety personnel prior to delivery to the user. The end user is responsible for other leak test intervals. It is important that toxic gases be leak tested prior to removal from their exhausted enclosures and subsequent transport. 7. Storage -- For short term experiments using hazardous gases, always select the smallest returnable cylinder available. Non-returnable cylinders are strongly discouraged. If non-returnable cylinders must be used, you must have a way to treat the remaining contents of the cylinder so that the cylinder valve can be removed prior to disposal. In cases where the gas will be used over an extended period of time (several months to more than one year), you should order a gas quantity that will last for three to six 16 months. Corrosive gases should be returned to the gas supplier within one year to avoid regulator and cylinder valve problems due to corrosion. In storage, restrain cylinders of all sizes by straps, chains, or a suitable stand to prevent them from falling. Segregate full cylinders of low hazard gases from "empty" cylinders awaiting return to the vendor. Assure hazardous gas cylinders are constantly stored in a suitable exhausted enclosure as described in Engineering Controls. Do not expose cylinders to temperatures higher than about 50 C. Some small cylinders, such as lecture bottles and cylinders of highly toxic gases, are not fitted with rupture devices and may explode if exposed to high temperatures. Never place cylinders where they may become part of an electric circuit. Avoid areas that are damp or subject to other corrosive materials. Do not store flammables and oxidizers together. Keep cylinders in storage upright, secure, and interlocked into a compact group. Protect cylinders stored outside from standing water by providing proper drainage. Where outdoors storage is necessary, an overhead cover is necessary to avoid sunlight and rain. 8. Transporting Cylinders - Hazardous gas cylinders must be transported directly from the gas supplier to the end user storage location, unless an exhausted and approved "staging" area has been constructed. Cylinders must never be transported without valve protection caps in place. Never move a cylinder with a regulator attached! . Cylinders larger than lecture bottle size should be chained or strapped to a wheeled cart during transport to ensure stability. Transportation of cylinders must be done only by trained personnel using approved trucks. Handle cylinders of compressed gases with the respect that high-energy sources deserve. 9. Shipping - Promptly remove the regulators from empty cylinders, leak test hazardous gases, and replace the protective caps at once. Mark the cylinder "MT". Never bleed a cylinder completely empty. Leave a slight pressure to keep contaminants out. Toxic, corrosive, and pyrophoric gases must remain in their exhausted enclosures until shipped back to the supplier. Cylinders used at UGa main campus may only be shipped through arrangements with Central Stores. 10. Changing Cylinders - Special procedures are required for changing toxic, corrosive, and pyrophoric gases and liquids. A proper cylinder purge panel is needed for high hazard gases, along with an adequate purge procedure. Persons changing gas cylinders requiring SCBA must work with a partner who is identically equipped. 11. Changing Pump Oil - Hazardous gases may be absorbed into vacuum pump oils. Personnel performing vacuum pump oil changes on pumps used with highly toxic gases must use SCBA for pump oil change. Hot pump oil should be allowed to cool prior to c hanging. 12. Other Equipment Maintenance Considerations - Consider equipment maintenance needs in advance. a. Consider reaction byproducts (e.g. use proper skin and eye protection when cleaning process chambers or vacuum pumps). "Low hazard" gases such as Freon will generate chlorine and fluorine decomposition products. Be sure to LOCK OUT upstream gas lines leading to equipment prepared for maintenance. Compressed gases are a hazardous energy source requiring lockout procedure. Be sure to adequately purge lines following lockout procedures and before beginning maintenance. 13. General Work Practices - Never use a cylinder that cannot be identified positively. Do not use compressed gas or compressed air to blow away dust or dirt (unless specifically equipped with a 30 psi or less diffuser for this application as used in machine shops). Flying dust and debris, as well as high pressure air itself, can cause significant injury. When not in use, close cylinder valves. The main cylinder valve should be tightly closed, but needle valves should only be finger tight to avoid ruining the valve and/or valve stem. 14. Emergency Procedures - Leaking cylinders should not be removed from their exhausted enclosures. Actuate remote emergency gas shutoff valve/button, if present. (Installed highly toxic gases, if properly installed, will have flow limiting devices and/or automatic cylinder shutoff valves in place to limit and shutoff the gas supply.) Close the main cylinder valve if a leak is stopped or slow, hazardous gases are contained in their enclosure, and it is clearly safe to approach. Do not extinguish a flame involving a highly combustible gas 17 until the source of gas has been shut off, otherwise, it can reignite, causing an explosion. Cylinders leaking at the cylinder valve should be reported to Campus Police (this should be reported as a "nonemergency" if the cylinder and gas are contained in an exhausted enclosure). If a hazardous gas is released into an unexhausted enclosure and the gas supply cannot be promptly cutoff, actuate the emergency evacuation procedure in your area and contact Campus Police. This procedure will also be initiated automatically if gas monitors trigger the building evacuation alarm. The Superfund Amendments and Re-authorization Act of 1986 (SARA Title III) states that releases of extremely hazardous substances must be reported to EPA. Accidental discharge of cylinder contents will be promptly reported to the ESD which will make reports to EPA. Cylinders found to be leaking upon gas delivery should not be accepted from the gas supplier. Fume Hood Use of Compressed Gases Hazardous gas use in fume hoods is appropriate under the following conditions: 1. The experimental apparatus fed by the hazardous gas is located inside the same hood. 2. The experimental apparatus is appropriate to be stored in the hood. 3. The experiment involves low gas pressure and flow rates 4. The experiment will be attended. 5. The engineering controls used for the hazardous gas in the fume hood provide equivalent safety to a gas cabinet installation. Since fume hood face velocities provide insufficient protection against pressurized gas leaks, special care must be taken when hazardous gases are used in fume hoods. The following is required for fume hood applications: 1. The smallest possible cylinder should be used for the experiment (a six-month bottle supply for routine use gases is appropriate, while smaller cylinder supplies are suggested for short term use). Make an effort to obtain gas cylinders in returnable bottles. Order bottles with the lowest cylinder pressure possible. 2. Use a flow restricting orifice or needle valve to restrict flow to only that needed for the experiment. 3. Toxic and corrosive gases must be used with a normally-closed pneumatic shutoff valve, located immediately downstream of the cylinder regulator, which closes with exhaust loss or power failure. This valve should be fed from a pneumatic air (or nitrogen) supply valve, located at the entrance to the lab. Activation of this quarter turn valve, causes the pneumatic cylinder valve to close in the event of an emergency. The air supply to the pneumatic shutoff valve should also be connected to a three-way electric solenoid that fails open on power loss, bleeding air from the pneumatic supply line, and closing the valve. A static pressure alarm, monitoring the hood exhaust duct, will be interlocked to the pneumatic shutoff valve. 4. Where determined necessary, run reactive or toxic gases through a suitable scrubbing media, then directly into the exhaust hood plenum (scrubber output hose should be placed into the exhaust slot). 5. Place the cylinder in rear of the hood. High pressure leaks can readily escape the hood and capture is best in the rear of the hood. 6. Assure all components in experiment can withstand full bottle pressure or incorporate pressure relief (run relief line into a hood slot) 7. All gas lines connected to the hazardous gas source, including purge lines and gas supply lines, must be completely contained inside of the hood. 18 Use of Fuel Gases for Welding and Cutting OSHA lists requirements for oxygen-fuel gas welding and cutting in 29 CFR 1910 .253. Cylinder handling precautions, materials of construction, and additional requirements are listed. This information should be reviewed by persons who will be using acetylene, oxygen, and other fuel gases or those who are designing facilities and equipment for this purpose. Please see the Personal Protective Equipment section of this manual for information on eye protection for welding and cutting operations. Be sure that all fuel gases are shut off at the cylinder valve after each use. Cryogenic Liquids Cryogenic liquids, as with all gases used at the University, must be ordered through Central Stores. Only inert gases are permitted at the University in portable cryogenic containers. Liquid oxygen, liquid hydrogen or other flammable or toxic cryogenic liquids are not permitted. Where appropriate, exterior tanks of liquid oxygen, used as a source of gaseous oxygen, may be installed by qualified individuals. All cryogenic liquids should be used with caution due to the potential for skin or eye damage due to the low temperature, and the hazards associated with pressure buildups in enclosed piping or containers. Portable containers should only be used where there is sufficient ventilation. Do not place containers in a closet or other enclosed space where there is no ventilation supply to the area. The buildup of inert gas in such an area could generate an oxygen deficient atmosphere. A full-face shield, loose fitting cryogenic handling gloves, apron, and cuffless slacks are the recommended equipment for transferring cryogenic fluids. Special vacuum jacket containers with loose fitting lids should be used to handle small quantities. Vacuum jacketed containers provided by the gas supplier will have overpressure relief devices in place. When plumbing cryogenic liquids, it is very important to include a pressure relief valve between any two shutoff valves. Also, any space where cryogenic fluids may accumulate (consider leakage into enclosed equipment as well) must be protected by overpressure relief devices. Tremendous pressures can be obtained in enclosed spaces as the liquid converts to gas. For example, one cubic centimeter of liquid nitrogen will expand to 700 times this volume as it converts (warms) to its gaseous state. Lines carrying liquid should be well insulated. Containers to be filled with cryogenic liquids should be filled slowly to avoid splashing. Cryogenic containers showing evidence of loss of vacuum in their outer jacket (ice buildup on the outside of the container) should not be accepted from the gas supplier. If already on a site, please contact Central Stores to obtain a replacement. Contact with air (or gases with a higher boiling point) will can cause an ice plug in a cryogenic container. Should ice plugs be noted, please contact Campus Police to obtain assistance. Constructing Equipment to be used with Hazardous Gases The ESD has additional guidelines and resources available to assist in the design of equipment which will be used with hazardous gases. Please contact ESD early in the planning stage of the project. Flammable, Oxidizing and Other Pressurized Gases Gas Cylinders I. The following guidelines shall be followed by all personnel using or storing pressurized gases. A. All personnel who will be working in areas where compressed gases are used or stored shall receive instruction regarding the safe handling of cylinders, the use of appropriate personal protective equipment, and the steps to be taken in the event of a leak or fire in an adjacent area. B. Do not remove any labels or other form of identification from any gas cylinder. C. Know how to detect the presence of leaks from any gas cylinder in your work area. Of particular importance are flammable and toxic gases. Contact ESD at 2-5801 in the event of a cylinder or valve leak. 19 Gas cylinder storage and labeling A. When receiving a gas cylinder do not accept it until the following items are verified: 1. the contents are identified either by labels or stencils, 2. it contains the appropriate DOT label, 3. it contains a valve protection cap (if so designed). B. Store gas cylinders in a well-ventilated area away from direct heat. All cylinders must be stored in an upright position secured to a sturdy permanent structure to prevent the cylinder from falling or being knocked over. Place protective caps on those cylinders which are not in use. All cylinders should be anchored individually. C. Gases should be stored in accordance with their physical and chemical properties. See individual material safety data sheets (MSDS) for specifics with regards to this information. D. Close valves on empty gas cylinders and mark them empty. Empty cylinders should be removed from the lab as soon as possible. Store empty and full gas cylinders separately. Cylinders are considered empty if their pressure is less than 25 psig. All cylinders will be considered full that are not properly identified. E. Store flammable gases away from oxidizing gases. F. Do not store gas cylinders near elevators, ventilating systems, or other openings through which gas may spread to other parts of the building should a leak occur. Do not store cylinders where there is a risk of dropping them or having heavy objects fall on them. G. Cylinders containing gases that are corrosive to cylinders or cylinder valves or that may become unstable while stored in the cylinder shall have a maximum retention period of six months, unless a shorter period is otherwise specified by the manufacturer. H. Cylinders of all gases having a health hazard rating of 3 or 4 (refer to the MSDS for rating) must be kept in a continuous mechanically ventilated storage hood or other continuous mechanically ventilated enclosure. There must be no more than three cylinders within the hood or other ventilated enclosure. Contact ESD for answers to questions regarding the storage of cylinders in continuous mechanically ventilated enclosures/storage hoods. I. The maximum volume size of a cylinder of a gas with a health hazard rating of three or four stored in a laboratory work area shall be limited to 0.1 cubic feet. Cylinders of a gas with a health hazard rating of three or four stored in a laboratory work area shall be limited to no more than three maximum size cylinders or an equivalent volume (0.3 cubic feet) of smaller sized cylinders. J. The maximum volume size of a flammable or oxidizing gas cylinder stored in a laboratory work area shall be limited to two cubic feet. Cylinders of flammable and/or oxidizing gases stored in a laboratory work area shall be limited to no more than six maximum sized cylinders or an equivalent volume (12 cubic feet) of smaller sized cylinders. K. The maximum volume size of a liquefied flammable gas cylinder stored in a laboratory work area shall be limited to 0.6 cubic feet. Cylinders of liquefied flammable gas stored in a laboratory work area shall be limited to no more than three maximum sized cylinders or an equivalent volume (1.8 cubic feet) of smaller size cylinders. L. Gas cylinders shall not be retained for more than ten years. Small, disposable, empty, lecture cylinders may be discarded in the lab trash after the valve stem has been removed. Small disposable lecture cylinders that are not empty may either be returned to the supplier or disposed of by a licensed gas cylinder disposal company. ESD shall be consulted prior to disposing of a cylinder using the preceding methods. Non-disposable cylinders must be returned to the supplier. M. Cylinders and other containers stored outdoors shall be stored off the ground on a raised concrete pad and within a covered non-combustible rack. They shall not be stored where they are at risk of dropping, having heavy objects dropped on them or being struck by a vehicle. 20 Proper handling of gas cylinders A. Always open cylinder valves slowly. Never force the valve open. If the valve cannot be opened by the wheel or small wrench provided, return the gas cylinder. To shut down a system, close the cylinder valve and relieve the pressure from the entire system through a hose that is not being used. B. Never interchange regulators and hose lines among different types of gases. C. Always turn off cylinders from the main stem valve (not the regulator). Turn off cylinders slowly. D. Suitable equipment must be available for moving cylinders and other portable containers. Hand trucks must be equipped with a clamp or chain to secure the container in place or they must be specifically designed for container handling. Never drag, roll, or slide a cylinder in an attempt to move it. E. Never drop cylinders; never permit cylinders to strike each other; and never strike cylinders with a metal instrument. F. Inspect cylinders regularly for corrosion or leaks. In case of a leak, promptly remove the cylinder to the outside (in accordance with manufacturer’s recommendations) and call ESD for assistance. G. Do not use cylinders without a regulator. H. Never attempt to refill a cylinder. I. Never tamper with any part of a valve such as the safety nuts or packing nuts. Equipment Safety for Radio Frequency and Microwave Processing The use microwave technology is increasingly being investigated for existing and new materials processes. Particular advantages and benefits have been identified for applications in ceramics. As progress is made towards commercializing these applications, those who are unfamiliar with the processing equipment will need to be aware of the associated safety issues. This paper reviews the current literature on related health effects, regulatory safety standards, equipment designs practices and guidelines for safe equipment use. Introduction Whenever microwave or radio frequency (RF) technology is considered for a particular industrial process, one of the first concerns to be raised is “Is it safe?” Quite often the answer is “Yes, depending on how you use it.” Admittedly, such a response is hardly comforting to a key decision maker who is new to or unfamiliar with microwave processing. Without a thorough understanding of the issues regarding the safe use of microwave technology, a cautious and slightly skeptical manager might well be reluctant to invest in a new process having unforeseen and potentially costly consequences. An understanding of a few basic topics relating to the health and safety issues involved in microwave and RF (hereinafter the term “microwave” includes RF frequencies) processing provides confidence that it can be as safe as most conventional heating technologies. The most important topics relate to a) known health effects from working with microwave equipment, b) established regulatory standards and guidelines for safety equipment use, c) design practices of industrial equipment that ensure adherence to safety standards, and d) recommended practices and procedures for safe equipment operation. The following sections present an overview of these topics, highlighting certain key fundamentals that will help provide a general understanding and working knowledge for ceramists involved in materials research and process development. Certain topics, particularly equipment design, require a much greater degree of study to fully understand all aspects of importance. As specific applications progress towards commercialization, ceramists will prudently seek the advice and involvement of experts in these fields to ensure a successful and safe implementation of their technology. 21 Health Effects related to Microwave Equipment Public concern over the health and safety issues relating to human exposure to electromagnetic fields has increased dramatically in recent years. Much of this concern is due to the rapid proliferation of cell phone use worldwide, even though electromagnetic fields are emitted by numerous other natural and man-made sources.1 As a result, numerous studies have been and are being conducted to determine the health effects and risks. Findings covering a broad range of frequencies have been published. Of particular interest are studies involving the “non-ionizing” microwave frequencies, generally de- fined as ranging from 3 kHz to 300 GHz, whose energy levels are an extremely small fraction of that required to ionize tissue and disrupt cellular DNA.2 This is in contrast to Gamma and X-ray frequencies having energy levels sufficient to ionize (displace electrons within the atomic structure of) exposed materials. The primary – and as yet, the only definite, proven - effect in biological materials of microwave radiation exposure is thermal heating3 , which presents a potential health risk due to overheating. However, much of the public concern has been focused on whether any thermal effects exist and pose a health risk. Cancer Related Effects of Microwave Exposure Numerous recent epidemiological studies on the relationships between various cancers and exposure to electromagnetic fields have been reviewed by Elwood.4 Sources of emissions studied included radio and television transmitters, cell phones, radar and occupational environments, while cancer types studied included brain, lung, testicular, lymphatic and hematopoietic cancers, adult and childhood leukemia and Hodgkin’s disease. Not all studies gave details of the level of exposure, but those that did indicate exposure levels were within established regulatory or otherwise recommended guidelines where such guidelines exist. The results of these studies are inconsistent at best and show no statistically significant evidence of a link between incidences of cancer and exposure to electromagnetic fields at microwave frequencies. In most cases the incidence rate showed no significant increase in risk from casual exposure. For example, some studies on broadcast transmitters indicated a marginally increased risk amongst residents near one such emission source but no increased risk near other similar sources. One study on occupational expo- sure actually showed a decrease in mortality rate that was attributed to a “healthy worker effect”. Non-Cancer Related Effects Clinical and epidemiological studies of effects on cataracts, sexual function and fertility, spontaneous abortion and birth defects, neurological and cardiovascular disorders, and other non-cancer epidemiological effects have been conducted.1 As in the cancer related studies, the results are largely inconsistent and, in some cases, subject to scrutiny due to confounding by other causes. For example, inconsistent findings between studies on cell phone use conducted in different countries were suspected to be partly due to cultural influences. Where conclusive evidence of an effect exists, it has mostly been shown to be due to a thermal response of the tissue. An interesting example is the auditory response from high intensity pulse modulation of electromagnetic fields, whereby thermal expansion in soft tissues in the head is conducted to the ear.5 This annoying effect, however, is not a health risk provided the heat absorption is not sufficient to cause tissue damage. On the other hand, the eyes and testes are considered particularly vulnerable to excessive heating due to their comparative lack of blood flow as a heat dissipation mechanism. While the above mentioned studies have failed to provide convincing evidence of a strong relation- ship between exposure and cancer, it should be noted that one cannot conclude from these results that other possible hazards do not exist. Furthermore, most studies generally cover a relatively short time frame, thus no conclusions can be made as to the likelihood or risks of any long term effects.6 Thermal Hazards to Microwave Exposure Thermal injury is a time-temperature phenomenon whereby the rate of tissue cell protein destruction exceeds its rate of self-repair for an amount of time sufficient to terminate cell metabolism.7 The rate of protein destruction increases with temperature, thus decreasing the time required for thermal injury as illustrated in Figure 1. 22 Figure 1. Threshold temperature vs. time at temperature for skin burns. The rate at which a given volume of tissue is heated by electromagnetic energy varies according to frequency and power density. Higher frequencies have a shorter penetration depth and thus will dissipate heat in a more concentrated volume nearer the skin surface. Similarly, a focused or “contact” source of power concentrates its energy within a smaller volume, resulting in a greater rate of local temperature rise. Therefore, a lower power level is required to cause burns by high frequency and/or focused exposures.8 As examples, a) a 20 Watt laser can cause a burn within a few seconds whereas a 150 Watt light bulb can make a person feel comfortably warm for hours, and b) a given power level at RF frequencies will cause a lower rate of temperature rise at a given location in a human body than at microwave frequencies due to the difference in penetration depth. Cardiac Pacemakers Many electronic devices can be subject to faulty operation if not properly shielded to prevent radio frequency interference (RFI). While some very early pacemakers were designed without RFI shielding, most or all pacemakers manufactured since the mid-1970’s include such shielding. A series of studies conducted to determine the maximum threshold of interference for safe operation indicated that newer models could withstand levels well above 1 mW/cm2.9 As a result, an editorial was published by the American Medical Association stating that the pacemaker interference issue “does not at this time constitute an important clinical problem.”10 High Voltage Although the health effects of electromagnetic exposure seem to generate the most public interest and concern, the hazards associated with high voltage are of equal importance to those working with industrial microwave equipment. Almost all microwave generators contain high voltage circuitry which can be lethal while the equipment is in operation and, in some cases, during non-operation depending on the equipment design. Most microwave generators contain circuitry that stores a high voltage electric charge in one or more capacitors. Although most do, not all designs provide for automatic safe discharge of stored energy, thus creating a potential hazard to service personnel. Injury or death may result when the human body becomes part of an active electrical circuit having a current capable of overstimulating the nervous system or damaging internal organs.11 The extent of injury due to exposure to high electrical energy depends on the type (AC or DC) and magnitude of electrical current, the path in which the current flows through the body, and duration of current flow. Direct contact with electrical energy, such as due to a high voltage arc to the body, often results in burns to the skin and internal tissue. A 50 or 60 Hertz (Hz) alternating current (AC) of 20 milliamps (mA) flowing through the chest area for an extended period can cause death due to respiratory paralysis, whereas a current of 100 mA can cause ventricular fibrillation.12 Under dry conditions, the body’s resistance is approximately 100,000 Ohms, while wet or broken skin can reduce the resistance to 1,000 Ohms. Thus, exposure to common 120 Volts AC mains voltage under dry conditions will produce a current of only 1.2 mA which is barely perceptible, but under wet conditions the resulting 120 mA current can cause death due to ventricular fibrillation. High voltage energy can further reduce the body’s overall resistance to 500 Ohms by breaking down the skin 23 layer. This results in extremely high current flow which can cause cardiac arrest and internal organ damage. The human body can tolerate up to five times the level of direct current (DC) than AC.13 Typical power supplies used in microwave ovens generate approximately – 4,000 Volts which can result in a body current of 8 Amps. Industrial microwave generators typically generate much higher voltages. Thus, even with the higher tolerance threshold, exposure to these voltages can quickly cause death due to cardiac arrest. Regulatory Standards For Safety Electromagnetic Exposure An important parameter used in establishing guidelines for reducing the risk of injury due to exposure to electromagnetic field is the “specific absorption rate” (SAR) which is usually expressed in units of Watts per kilogram (W/kg).14 Numerous studies have determined the minimum SAR at which a risk of thermal injury exists, and various international government agencies have adopted standards to limit exposure such that the maximum safe SAR is not exceeded. Most European countries have adopted guidelines established by the International Committee on NonIonizing Radiation Protection (ICNIRP) for maximum safe occupational and general public exposure levels for whole -body average SAR and localized SAR.15 These guidelines give rise to reference levels for plane wave power densities as given in Table 1 for frequency ranges of interest. Frequency Range 10-400 MHz 400-2000 MHz 2-300 GHz Occupation 1 f/400 5 General 0.2 f/2000 1 Table 1. ICNIRP recommended exposure reference levels for plane wave power densities (mW/cm2). The International Electrotechnical Commission (IEC) has specified a standard for industrial microwave heating equipment which defines maximum exposure levels for equipment operating under “normal conditions” (as the equipment was designed or intended) and “abnormal conditions” (such as with an empty cavity). Under this standard, which is applicable to equipment operating in the frequency range from 300 MHz to 300 GHz, the power density is measured at least 5 cm from any accessible location on the equipment and limited to 5 mW/cm2 during “normal” operation and 10 mW/cm2 during “abnormal” operation. Figure 2. ANSI/IEEE recommended maximum permissible exposure (MPE) for controlled environments per standard C95.1-1999. 24 Figure 3. IEEE recommended maximum permissible exposure (MPE) for uncontrolled environments per standard C95.1-1999. In the USA, the Federal Communications Commission (FCC) has adopted standards based on recommendations developed by the American National Standards Institute (ANSI) and Institute of Electrical and Electronics Engineers (IEEE) as defined under IEEE standard C95.1.17 This standard defines the maximum permissible exposure (MPE) averaged over a period of six minutes for “controlled environments” (where persons exposed generally are either cognizant of the potential for exposure or simply passing through the environment) and “uncontrolled environments” (where persons exposed have no knowledge or control over their exposure) as summarized in Figures 2 and 3. Table 2 highlights MPE values for specific industrial, scientific and medical (ISM) frequencies commonly used in materials processing applications. Frequency 915/896 MHz 2.45 GHz 5.8 GHz Controlled Environment 3 8.2 19 Uncontrolled Environments 0.6 1.6 3.9 Table 2. IEEE recommended maximum permissible exposure (MPE) for plane wave power densities (mW/cm2) at ISM microwave frequencies. The Occupational Safety and Health Administration (OSHA) has established a regulation applicable to frequencies from 10 MHz to 100 GHz whereby exposure is limited to no more than 10 mW/cm2 measured at 5 cm from the emission source and averaged over a 0.1 hour period.18 OSHA further establishes regulations for hazard labeling of equipment. High Voltage and Equipment Safety Safety guidelines have been established for voltages used with and generated by microwave equipment. Although the National Electrical Code (NEC) defines high voltage as greater than 600 Volts AC19, various safety requirements for electrical wiring apply to all voltages. These requirements, applicable in the United States, include circuit overload and ground fault protection devices, wire sizes and materials, conduits and shielding, enclosures and workspace clearances. Specific requirements apply to industrial machinery which includes most microwave processing equipment. Similar standards and requirements 25 have been established internationally by British Standards (BS), European Committee for Electrotechnical Standardization (CENELEC), International Electrotechnical Commission (IEC), and Japanese Industrial Standards (JIS). Microwave generators, power supplies and other components that make up industrial processing systems are governed under various standards established for product safety. Underwriters Laboratory (UL) and American National Standards Institute (ANSI) standards generally apply to products used in the United States, compliance to which is evaluated and certified by a Nationally Recognized Testing Laboratory (NRTL). Similarly, products used internationally must also comply with safety standards established within the countries where used, including those by Standards Council of Canada (SCC), the European Union “Low Voltage” and Machinery directives (CE Mark) and, to a limited extent, the Chinese Compulsory Certification (CCC Mark). Certain industry groups also have specific requirements for equipment, such as the SEMI S2 Environmental, Health, and Safety Guideline for Semiconductor Manufacturing Equipment. Equipment Design For Safety Microwave processing systems generally consist of three main elements: a microwave power generator, power delivery (waveguide) components and a process cavity (applicator). Systems can be as small and simple as a typical residential microwave oven or as large and complex as a industrial food processing conveyor. Many different types of generators and waveguide components are available and can be configured in a variety of ways depending on the process characteristics. However, they all perform essentially the same function: to safely and reliably generate and deliver microwave power to the process cavity. The process cavity itself can also be configured in many ways, but its primary function is to effectively “couple” the delivered microwave energy to the material being heated in such a manner as to meet the requirements of the heating process. Process cavities are generally designed for either “batch” or “continuous” material processing, while some are designed for semi-continuous flow. Many common design practices for safety apply to all types of commercial and industrial equipment used in materials processing as defined in the standards mentioned above. In addition to these commonalities, microwave processing systems utilize several features that are uniquely necessary to ensure reliable and safe operation. Most pertain to suppression of emissions, or “microwave leakage,” while others may be specific to certain materials processes. Microwave Leakage Suppression Once high power microwave energy is generated, it must be contained almost entirely within the processing system in order to comply with regulatory standards for safety and interference. The term “Faraday cage” (British physicist Michael Faraday, 1791-1867) has often been used to describe a microwave cavity in that it is an enclosure capable of blocking the entry or exit of electromagnetic waves. The ideal Faraday cage is a metallic enclosure with no holes, broken seams or openings of any kind. For all practical purposes, the term also applies to microwave generators and waveguide components. But for obvious reasons, no practical microwave processing system can be a completely continuous metallic enclosure as it must, as a minimum, allow access to its interior for entry and exit of the material to be heated. In most cases it must also have seams or openings suitable for assembly, viewing, ventilation, sensor insertion and other process related necessities. Material Entry/Exit for Batch Processing: The most common type of opening in a microwave heating system is the door of a household microwave oven. One can easily see that the door does not make complete contact with the oven cavity, leaving the casual observer to wonder what is preventing the micro- wave energy from radiating out of the oven. The door is designed with a nondissipative “reactive” ¼- wave choke along the opening perimeter that effectively blocks the transmission of energy at a specific frequency. Most industrial systems having batch cavities utilize such door seals, although some employ a direct contact seal using a woven metal mesh gasket or springy beryllium copper fingerstock. In either case, the door seal design is robust and capable of withstanding repeated openings without degradation in performance throughout the life of the equipment. Material Entry/Exit for Continuous Processing: Continuous flow process systems require openings that allow for material entry and exit on a continuous basis, such as for conveyorized and/or extruded 26 product. Depending on the size and geometry of these openings as required for the process material, the means for suppressing microwave leakage is either reactive, as in the case described above for door seals, or dissipative whereby microwave energy is actively absorbed within the structure of the opening, or a combination of both. In either case, microwave energy is attenuated at some rate as it passes through the opening. The rate of attenuation through these openings depends on the opening size and attenuation method used. Thus, the opening typically has some length in order to attenuate the energy to sufficiently safe regulatory levels, with larger openings generally having a lower attenuation rate and requiring greater length. The term “tunnel” is often applied to openings for continuous flow processing. Cavity Ventilation and Viewing Ports: Almost all microwave ovens have a window in the cavity door through which the cooking process can be observed. Close inspection of this window reveals the presence of a screen made of tiny perforations in thin metal. Each hole in the screen acts as a high-pass filter that effectively blocks the transmission of electromagnetic energy at microwave frequencies yet allows trans- mission of visible light. Other openings in the oven cavity, such as for ventilation and illumination, are perforations in the cavity wall that function in a similar manner. As microwave energy propagates through a waveguide or other restricted path, it is attenuated exponentially as a function of wavelength and the size of the path according to where P1 and P0 are the power densities at the path exit and entrance, x is the path length and α is the rate of attenuation in dB/unit length as energy propagates along the path. Figure 4 illustrates the rates of attenuation through a circular waveguide as functions of the inside diameter for various ISM frequencies. The diameter at which the attenuation rate approaches zero is the “cut-off” diameter for the respective frequency, and waveguides smaller than this dimension are said to be below or beyond cut-off. These curves are used to determine the minimum screen thickness, or hole “length,” that provides the necessary total attenuation for a given perforation hole diameter and power density. For example, suppose the highest internal power density at a cavity opening is determined to be 1 kW/cm2 and the regulatory limit to be met outside the cavity is 1 mW/cm2. Using equation 1, the min i- mum attenuation constant, α, required for a 0.020” thick screen is 345 dB/inch. Figure 4 then yields a maximum perforation hole diameter of roughly 0.08”. Figure 4. Attenuation curves for circular waveguide at three ISM frequencies. 27 Cut-off Tubes: The waveguide below cut-off principle is also commonly used for larger unobstructed openings, referred to as “cut-off tubes,” such as for optical thermometry, fluid flow, etc. However, the curves in Figure 4 apply only to unfilled tubes. When filled with a dielectric material, the effective inside diameter is increased by a factor equal to the square root of the material’s dielectric constant. This lowers the effective attenuation rate and increases the minimum tube length, although it will be counteracted somewhat for high dielectric loss materials that absorb energy propagating through the tube. The analysis is further complicated when the tube is filled only partially or with multiple materials of various dielectric properties, such as when flowing water in Teflon tubing through the cut-off tube. Feed-thru Openings: Inserting a metallic object, such as a thermocouple probe or wire, through a cavity opening can be extremely dangerous by causing excessive microwave leakage. Unless it is in intimate contact with the opening wall, the metal object in conjunction with the metallic opening wall will have a coaxial transmission line effect, thus allowing microwave energy to propagate freely through the opening and radiate from its end. Materials having a high dielectric constant can also create a similar effect when inserted through a cavity opening, such as passing a small column of water passing through a comparatively large cut-off tube. Electrical wires passing through a cavity opening require special techniques such as capacitive filtering to prevent leakage and other forms electrical interference in the external circuitry. Given the complexities involved with proper feed-thru design, professional advice and assistance should be sought whenever installing feed-thru devices in microwave cavities. Safety Interlock Devices Interlock devices are typically defined as mechanical and/or electrical components or sub-systems that prohibit the operation or functioning of other components or sub-systems if certain conditions are not satisfied. In the case of microwave processing systems, this usually applies to the devices that prohibit the operation of the microwave generator if a condition exists that might cause excessive microwave emissions. Cavity Access: Regulatory standards require interlock devices at all locations where the microwave cavity can be opened without the use of tools. Of course, the most common access point is the cavity door, although many industrial systems have other features that require periodic opening for maintenance or other such purposes. Interlock devices prevent the microwave generator from operating if the opening is not closed, and they are typically designed such that a failure of the interlock device leaves the system in a safe non-operative mode. US government standards applicable to residential and commercial micro- wave ovens require redundant interlock devices that are concealed and inaccessible, at least one device of which having a means of fail-safe monitoring. IEC standards also require redundant and concealed inter- lock devices at all cavity access locations, as well as interlocks for the presence and/or flow of material through the cavity if necessary to maintain emissions within the guide lines. Waveguide Flanges: An often neglected location for microwave leakage due to inadvertent carelessness during equipment maintenance is a waveguide flange connection. Many systems are designed to al- low easy disconnection of a waveguide component for routine maintenance, some even without the use of tools. In such cases an interlocking device is required to ensure proper re-assembly before bringing the system back on-line. In fact, literal interpretation of the IEC standards would require interlock devices at all waveguide flange connections, although this practice is rarely found or deemed necessary in industrial equipment. High Voltage: As described earlier, microwave generators contain high voltage circuitry that can be lethal when contacted inadvertently during operation. For this reason, interlock devices on enclosure access covers are typical of most contemporary equipment designs and required by almost all regulatory standards. These safeguards are generally sufficient to protect service personnel from exposure to stored high voltage energy hazards. Most circuit designs provide for safe electrical discharge within the time required to remove safety covers and gain access the internal circuitry. Although not required by regulatory standards, many equipment designs also incorporate interlock wiring into electrical connectors associated with inter-modular high voltage circuitry, thus disabling the high 28 voltage circuits whenever these connectors are not properly mated. However, even when the equipment is designed with such protection, quickly disconnecting an electrical cable and exposing its contacts may not allow sufficient time for stored energy to be discharged. Thus, caution must be exercised ANY time an electrical cable is disconnected. Warning Labels and Visual Indicators Many regulatory standards require various labels and indicators alerting the equipment operator of a potentially hazardous condition. Warning labels are required for both electrical shock and electromagnetic radiation hazards and must indicate briefly a) the nature of the hazard, b) the potential consequences of exposure to the hazard, and c) necessary actions to prevent exposure. Special labels are required for cavity doors and other openings to warn against allowing foreign objects to interfere with the door seals. Visual indicators are required to alert nearby personnel that the equipment is in operation. These indicators must be plainly visible during normal operating conditions or where personnel might typically be present. System Architecture and Process Safety Fire and explosion prevention is particularly challenging as it combines the volatile characteristics of certain materials processes with the unique propensity for ignition in a microwave system. Inert gas purging is commonly used to remove oxygen from the cavity atmosphere, and regular cleaning of interior surfaces helps to reduce the sources of fuel. But these practices may not be practical for or applicable to all processes. The system developer must have a thorough understanding of both the materials process and microwave technology. Recognizing that such hazards often are not completely avoidable, the design must minimize the hazard potential and effectively deal with a hazard event. There are many other aspects of the overall system design that are considered when minimizing the risks and hazards associated with microwave processing, including walk-in cavity access, high temperatures, automated mechanisms and moving parts. A thorough review of these considerations is well be- yond the scope of this paper, so materials process developers are encouraged to seek the advice of equipment experts having experience in similar processes. Guidelines For safety Equipment Operation Common sense plays an important role in the safe operation of any product regardless of the magnitude of its associated hazards. Apart from that, a few basic practices and habits should be institutionalized when operating microwave equipment. Safety Training: Basic first aid treatment and emergency rescue procedures should be a part of a formal safety training program. Many hazards, particularly those associated with high voltage, can be prevented from becoming lethal if immediate rescue action is taken. For example, electrocutions resulting in ventricular fibrillation do not necessarily cause immediate death, thus emergency cardiopulmonary resuscitation (CPR) can be administered to potentially save the life of the victim. Equipment Training: All personnel engaged in operating and/or maintaining industrial microwave equipment should receive proper training to be aware of the hazards associated with their respective tasks. As a minimum, all product user manuals and other documentation provided by the equipment manufacturer should be read and thoroughly understood before attempting operation or service. Safety training should emphasize awareness and recognition of both microwave radiation and high voltage hazards and appropriate responses when identified. In addition, service personnel should be knowledgeable and competent with regard to safe troubleshooting and repair of high voltage circuitry. Buddy System: Never operate or perform maintenance on industrial microwave equipment while alone. In the event of hazard exposure, the victim may be incapacitated and need immediate medical attention for survival. Leakage Detection: Every user of an industrial microwave heating system should have on hand or ready access to a high quality microwave leakage detector, also referred to as a microwave survey meter. 29 Leakage should be checked on a periodic basis and always after any maintenance has been performed on the equipment. Upon detecting excess emissions, the equipment should be immediately shut down and the cause of emissions investigated and corrected before restarting. Also, the leakage detector should be calibrated at least annually to ensure proper operation. Periodic Maintenance: Many hazards result from inadequate or improper equipment maintenance practices. A formal program of periodic inspection and maintenance should be implemented that addresses all potential hazards and hazard sources. The program should include not only the microwave equipment itself but also any other tools or equipment required for the maintenance tasks. The most basic tasks to be included are a) to inspect for microwave leakage, b) clean the cavity interior and all internal waveguide surfaces, and c) replace damaged or broken electrical connectors even if still functional. While there are indeed many hazards associated with industrial microwave and RF processing equipment, the risks associated with them are no greater than with conventional equipment when proper safe- guards have been implemented. Microwave heating technology has been a vital component of industrial production since the 1940’s and will continue to be applied as new materials processes are developed. Newcomers to this technology can develop a sense of security with its use by learning and understanding the basic concepts about health effects, regulatory standards, design safeguards and operational guidelines presented here. Laser Safety Hazards of Laser Light Laser beams can be hazardous, particularly for the eye (and sometimes also for the skin), mostly because they can have high optical intensities even after propagation over relatively long distances. Even when the intensity at the entrance of the eye is moderate, laser radiation can be focused by the eye's lens to a small spot on the retina, where it can cause serious permanent damage within fractions of a second – even when the power level is only of the order of a few milliwatts. Damage can result from both thermal and photochemical effects. Laser damage of the eye is not always immediately noticed: it is possible e.g. to burn peripheral regions of the retina, causing blind spots which may be noticed only years later. Ultraviolet lasers can cause corneal flash burns, a painful condition of the cornea. UV radiation can also cause photokeratitis and cataracts in the eye's lens. (For these reason the XeCl excimer laser has acquired the nickname “cataract machine”.) Mid-infrared lasers, particularly those operating at certain wavelengths with very strong absorption in the cornea (e.g. 3 μm or 10 μm), can also cause painful corneal injuries. How much light an eye can tolerate depends on many circumstances: not only the intensity, but also particularly the wavelength and the duration of irradiation (e.g. the pulse duration). There are detailed sets of rules for calculating safe exposure limits (maximum permissible exposure, MPE) for a given situation. Such rules are occasionally revised according to new scientific findings. Eyes are particularly sensitive, but laser radiation can also cause skin injury. For infrared light, this occurs mainly via thermal effects (thermal skin burns), similar to burning the skin with other means. The penetration depth depends on the wavelength, and for such reasons a laser beam at 1.5 μm wavelength causes more pain on the skin than a 1-μm beam. Whereas such burning should in most cases not have serious long-term consequences, ultraviolet light can in addition induce photochemical reactions. These can lead to changes in the pigmentation, erythema (sunburn), and (most importantly) skin cancer. Some laser safety issues arise from indirect effects of laser radiation: • • • Intense laser beams can incinerate materials and thus possibly start severe fires. Particularly in laser material processing, poisonous fumes, dust or hot droplets of molten material can affect nearby workers. For example, fumes containing arsenic, chromium or nickel can occur when metal pieces are cut, and plastic parts (polymers) can form dangerous organic substances. Secondary radiation (e.g. ultraviolet light or even X-rays) can be generated when high-intensity beams heat certain targets to high temperatures. 30 Non-Beam Hazards LASER is an acronym which stands for Light Amplification by Stimulated Emission of Radiation. The energy generated by the laser is in or near the optical portion of the electromagnetic spectrum (see Figure 1). Energy is amplified to extremely high intensity by an atomic process called stimulated emission. The term "radiation" is often misinterpreted because the term is also used to describe radioactive materials or ionizing radiation. The use of the word in this context, however, refers to an energy transfer. Energy moves from one location to another by conduction, convection, and radiation. The color of laser light is normally expressed in terms of the laser's wavelength. The most common unit used in expressing a laser's wavelength is a nanometer (nm). There are one billion nanometers in one meter. In addition to the direct hazards to the eye and skin from the laser beam itself, it is also important to address other hazards associated with the use of lasers. These non-beam hazards, in some cases, can be life threatening, e.g. electrocution, fire, and asphyxiation. Table 1 indicates some of the potential non-beam hazards associated with laser usage. Because of the diversity of these hazards, the employment of safety and/or industrial hygiene personnel to effect the hazard evaluations may be necessary. The optical spectrum. Laser light is nonionizing and ranges from the ultra-violet (100 - 400nm), visible (400 - 700nm), and infrared (700nm - 1mm). Not Only Light is Dangerous Further issues are not even related to laser beams: • High electric voltages are used in laser power supplies (e.g. for discharge lamps), creating hazards in maintenance operations or when cables are damaged. • Some laser systems contain hazardous chemicals such as certain laser dyes. • Other lasers contain potentially exploding or imploding glass tubes (e.g. arc lamps). In fact, probably most victims of accidents with lasers have been hurt by such hazards (particularly by electric shocks) rather than by laser radiation. Particularly Hazardous Situations The following list of important safety issues can never be complete, but is meant to improve awareness of the multitude of possible hazards: • High-voltage power supplies can be dangerous if workers can come into contact with the inner parts or with a defective high-voltage cable. • Some lasers require the handling of hazardous chemicals, e.g. carcinogenic dye solutions in dye lasers. Some of these solutions can penetrate the skin, and therefore need to be handled with special care. • Near-infrared laser beams are much more hazardous than visible light with the same power level, because their radiation is focused to the retina just in the same way as visible light, whereas the blinking reflex of the human eye (normally closing the eye's lid quickly when the intensity is too high) is not active. Also, no warning is possible e.g. through weak stray light: nothing can be seen when a dangerous beam propagates in an unexpected direction. • Ultraviolet lasers endanger not only eyes, but also the skin (see above). • Pulsed laser sources, e.g. Q-switched lasers or regenerative amplifiers, generate pulses with a peak power many orders of magnitude higher than the average output power even of a highpower laser. A single pulse from a hand-held miniature laser can totally destroy an eye. • In open laser setups, parasitic specular reflections (caused either by parts of the setup or by movable metallic tools, watchbands, rings, etc., but also by the residual reflectivity of anti- 31 • • reflection coatings) may allow hazardous beams to leave the setup, which might hit someone's eye. Optical fibers, e.g. transporting high optical powers between different rooms, may release dangerous radiation when being damaged. They therefore need to be specially protected and marked. High-power lasers (e.g. with powers in the kilowatt region) can damage not only the eye but also the skin within short exposure times, and can easily start a fire, e.g. when the beam hits materials such as wood or plastics; toxic fumes may also be generated. Often less dangerous are the following cases: • • setups with low-power visible beams, where the blinking reflex of the human eye may provide sufficient protection against occasional exposure of an eye with moderate power levels. sources operating in certain eye-safe spectral regions (e.g. with wavelengths longer than ≈ 1.4 μm) where the light is absorbed in the eye's lens and therefore cannot reach the (more sensitive) retina fully closed laser setups with an interlock, which automatically switches off the radiation source as soon as the case is opened. Laser Hazard Classification To give some guidance on adequate handling and required precautions, laser devices are assigned to different safety classes, with class 1 being the least dangerous (containing e.g. lasers with microwatt power levels) and class 4 the most hazardous one. Note that the assignment to a laser safety class depends not only on the laser power, beam quality and laser wavelength, but also on the accessibility of hazardous areas: even a high-power laser may be in safety class 1 when there is no risk that dangerous radiation can leave a fully encapsulated housing. Details such as the large diameter or the divergence of involved laser beams are largely ignored in such simplified classification schemes. The concept is solely to classify the laser product itself according to some emission limits, rather than evaluating a particular setup containing a laser. The classification is indirectly based on some exposure limits for the eye (see above), but also takes into account a number of worst case assumptions concerning e.g. the distance of persons from the laser aperture, the exposure duration and the possible use of optical instruments. Therefore, the classification tends to overestimate certain risks, and a complete safety assessment has to consider the details of the whole setup and the way it is used. Safety Standards There are a variety of laser safety standards including Federal and state regulations, and non-regulatory standards. The most important and most often quoted is the American National Standards Institute's Z136 series of laser safety standards. These standards are the foundation of laser safety programs in industry, medicine, research, and government. The ANSI Z136 series of laser safety standards are referenced by the Occupational Safety and Health Administration (OSHA) and many U.S. states as the basis of evaluating laser-related occupational safety issues. ANSI Z136.1 Safe Use of Lasers, the parent document in the Z136 series, provides information on how to classify lasers for safety, laser safety calculations and measurements, laser hazard control measures, and recommendations for Laser Safety Officers and Laser Safety Committees in all types of laser facilities. It is designed to provide the laser user with the information needed to properly develop a comprehensive laser safety program. For manufacturers of laser products, the standard of principal importance is the regulation of the Center for Devices and Radiological Health (CDRH), Food and Drug Administration (FDA) which regulates product performance. All laser products sold in the USA since August 1976 must be certified by the manufacturer as meeting certain product performance (safety) standards, and each laser must bear a label indicating compliance with the standard and denoting the laser hazard classification. 32 Table 1: International laser safety classes, with somewhat simplified and approximate descriptions. For details, consult the applicable laser safety standard documents. Safety class Simplified description 1 The accessible laser radiation is not dangerous under reasonable conditions of use. Examples: 0.2-mW laser diode, fully enclosed 10-W Nd:YAG laser 1M The accessible laser radiation is not hazardous, provided that no optical instruments are used, which may e.g. focus the radiation. 2 The accessible laser radiation is limited to the visible spectral range (400– 700 nm) and to 1 mW accessible power. Due to the blink reflex, it is not dangerous for the eye in the case of limited exposure (up to 0.25 s). Example: some (but not all) laser pointers 2M Same as class 2, but with the additional restriction that no optical instruments may be used. The power may be higher than 1 mW, but the beam diameter in accessible areas is large enough to limit the intensity to levels which are safe for short-time exposure. 3R The accessible radiation may be dangerous for the eye, but can have at most 5 times the permissible optical power of class 2 (for visible radiation) or class 1 (for other wavelengths). 3B The accessible radiation may be dangerous for the eye, and under special conditions also for the skin. Diffuse radiation (as e.g. scattered from the some diffuse target) should normally be harmless. Up to 500 mW is permitted in the visible spectral region. Example: 100-mW continuous-wave frequency-doubled Nd:YAG laser 4 The accessible radiation is very dangerous for the eye and for the skin. Even light from diffuse reflections may be hazardous for the eye. The radiation may cause fire or explosions. Examples: 10-W argon ion laser, 4-kW thin-disk laser in a non-encapsulated setup Note that there are different classification schemes (e.g. international and American ones), using classes such as 1 to 4 but with somewhat different definitions. (The American system uses classes I, IA, II, IIIA, IIIB and IV similar to the classes 1 to 4 of the international system, but with significant deviations.) Particularly important standards are the IEC 60825-1 international laser safety standard of the International Electrotechnical Commission (IEC) those based on the US user standard ANSI Z-136 (with various variations Z-136.X, in particular the Z-136.1, revised in 2007) The IEC standard has been fully adopted by the European standardization organization as EN 60825-1 and is published in national versions such as DIN EN 60825-1 in Germany. Note that these standards cover much more than only defining safety classes; they also determine the measures to be taken in order to work safely with laser products in such classes. There are also government regulations such as the relatively outdated 21 CFR 1040.10, which is still relevant for the US, although the IEC / EN standard is now also accepted there with some additions. 33 Generally, it is the duty of the manufacturer of a laser product to classify the product and to equip it accordingly with warning labels. However, the classification may change when a laser product is modified by a user, and the user is then responsible for reclassification. The Nominal Hazard Zone Originally, the required safety measures for a given laser setup where basically determined only by the safety class of the laser. As mentioned above, this classification does not reflect details such as beam divergence, which can be very relevant for safety issues: a strongly focused laser beam can be so divergent that within a moderate distance after the focus the intensities fall below the allowable exposure level for the eye. In such situations, one sometimes defines a “Nominal Hazard Zone” (NHZ) within which safe exposure levels may be exceed, in order to apply certain restricting measures to this zone instead of the whole room. Technical Precautions Examples of frequently used technical laser safety precautions are: • • • • • • • • the use of protective goggles (→ eye protection), strongly absorbing radiation with wavelengths near the laser wavelength full or partial encapsulation of laser systems, ideally with absorbing housing materials, avoiding specular reflections protective housings around dangerous working areas, monitoring the presence of persons e.g. with light curtains, laser scanners or people counters interlocks that automatically switch off lasers or block laser beams e.g. when a protective box or a door is opened key-operated switches for power supplies, preventing unauthorized use written warnings (indicating e.g. the types of lasers behind a door), warning lights (indicating that hazardous laser sources are operated) and automatic door locks, preventing people from entering dangerous areas beam stoppers (not only for main beams, but also for parasitic reflections), preventing dangerous beams from leaving the optical setup low-power visible pilot beams and the like, marking the paths of dangerous invisible laser beams Non-technical Measures Technical measures alone are generally not sufficient for keeping safety hazards under control. A number of non-technical measures are therefore very important: • • • • The risks have to be carefully assessed before anything adverse can happen. They need to be reassessed every time when important circumstances change, e.g. the devices used, applications, staff, and details of the room. On that basis, reasonable ways of dealing with these risks need to be developed. This involves the implementation of technical measures (see above) and establishing suitable working practices. The results need to be clearly described in written safety regulations. Adequate safety education needs to be ensured, such that all people who may be at risk are properly informed about both the risks and the proper ways to deal with them. Personal instruction by a knowledgeable person is certainly very valuable, and should be supplemented with additional training materials such as clearly written notes, a laser safety video or DVD. All responsibilities need to be properly assigned and clearly defined. It is also very important to establish a spirit which motivates all staff to take safety issues serious, recognize responsibilities for themselves and for their colleagues, suggest practical solutions, etc. Laser Safety Regulations Making laser safety regulations for some production facility is a difficult task, and for a research laboratory it is even harder. The reason is that there are partially conflicting goals: • Regulations must be clear and understandable for those reading them. 34 • • The rules should be sensible, ideally under all conceivable circumstances: the implied restrictions should be so that all risks are minimized without being in straight conflict with the actual goals of the work. The set of rules should be compact, so that people can be expected to read them carefully and to memorize them. It is clear that various trade-offs are inevitably involved, e.g. between compactness and suitability for many different circumstances, or between safety and productivity. Giving absolute priority to maximum safety while ignoring productivity and similar practical requirements will not even serve safety, because it increases the risk of regulations being ignored or forgotten. It can be difficult task to analyze existing hazards and to identify the most practical way of dealing with them. Common Obstacles Unfortunately, reasonable laser safety regulations are either not in place or (more frequently) routinely ignored in many places such as research and development laboratories. Possible reasons (but not good excuses) are: • • • • • • • • • • • • a lack of general knowledge on laser safety issues the lack of available information on specialized safety issues, e.g. related to potential hazards of ultrashort laser pulses from mode-locked lasers (hazard potential determined only by average power, or also by peak power and pulse duration?), or awareness of risks associated with fumes unexpected effects such as accidentally misaligned beams, vaporization of poisonous substances, defects or poor design of safety equipment, etc. wrong interpretation of labels like “low-power laser”: a 10-mW near-infrared laser may have a low power, but is still very dangerous to the eye! irrational assessment of risks and inappropriate judgment on working routines (“We have always done it like this!”) the general human tendency to underestimate invisible risks, particularly when they occur over long times without apparent effects missing safety devices (e.g. insufficient numbers of laser goggles in situations with visitors) highly inconvenient, uncomfortable or otherwise impractical safety devices, e.g. laser goggles which cannot be used over longer times excessive pressure to produce results quickly nonsensical laser safety regulations which undermine the awareness that the adherence to the rules is in the operator's own interest very formal and abstract sets of rules, obviously made primarily for avoiding legal problems for the bosses, rather than providing help in real life the negligence and the bad example of irresponsible supervisors, who sometimes even ridicule more responsible persons Due to such factors, which are difficult (if not impossible) to eliminate altogether, perfect laser safety (making accidents impossible) is probably impossible to reach. However, sensible regulations can greatly diminish the risks without affecting the productivity too severely. Laser Hazards & Beam Hazards The laser produces an intense, highly directional beam of light. If directed, reflected, or focused upon an object, laser light will be partially absorbed, raising the temperature of the surface and/or the interior of the object, potentially causing an alteration or deformation of the material. These properties which have been applied to laser surgery and materials processing can also cause tissue damage. In addition to these obvious thermal effects upon tissue, there can also be photochemical effects when the wavelength of the laser radiation is sufficiently short, i.e., in the ultraviolet or blue region of the spectrum. Today, most high-power lasers are designed to minimize access to laser radiation during normal operation. Lower-power lasers may emit levels of laser light that are not a hazard. The human body is vulnerable to the output of certain lasers, and under certain circumstances, exposure can result in damage to the eye and skin. Research relating to injury thresholds of the eye and skin has been carried out in order to understand the biological hazards of laser radiation. It is now widely 35 accepted that the human eye is almost always more vulnerable to injury than human skin. The cornea (the clear, outer front surface of the eye's optics), unlike the skin, does not have an external layer of dead cells to protect it from the environment. In the far-ultraviolet and far-infrared regions of the optical spectrum, the cornea absorbs the laser energy and may be damaged. Figure 2 illustrates the absorption characteristics of the eye for different laser wavelength regions. At certain wavelengths in the nearultraviolet region and in the near-infrared region, the lens of the eye may be vulnerable to injury. Of greatest concern, however, is laser exposure in the retinal hazard region of the optical spectrum, approximately 400 nm (violet light) to 1400 nm (near-infrared) and including the entire visible portion of the optical spectrum. Within this spectral region collimated laser rays are brought to focus on a very tiny spot on the retina. This is illustrated in Figure 3. Absorption characteristics of the human eye (From Sliney & Wolbarsht, Safety with Lasers and Other Optical Sources, Plenum Press, 1980) In order for the worst case exposure to occur, an individual's eye must be focused at a distance and a direct beam or specular (mirror-like) reflection must enter the eye. The light entering the eye from a collimated beam in the retinal hazard region is concentrated by a factor of 100,000 times when it strikes the retina. Therefore, a visible, 10 milliwatt/cm2 laser beam would result in a 1000 watt/cm2 exposure to the retina, which is more than enough power density (irradiance) to cause damage. If the eye is not focused at a distance or if the beam is reflected from a diffuse surface (not mirror-like), much higher levels of laser radiation would be necessary to cause injury. Likewise, since this ocular focusing effect does not apply to the skin, the skin is far less vulnerable to injury from these wavelengths. Focusing effects of the human eye(From Sliney & Wolbarsht, Safety with Lasers and Other Optical Sources, Plenum Press, 1980) If the eye is not focused at a distance or if the beam is reflected from a diffuse surface (not mirror-like), much higher levels of laser radiation would be necessary to cause injury. Likewise, since this ocular focusing effect does not apply to the skin, the skin is far less vulnerable to injury from these wavelengths. The Laser Safety Officer ANSI Z136.1 specifies that any facility using Class 3b or Class 4 lasers or laser systems should designate a Laser Safety Officer to oversee safety for all operational, maintenance, and servicing situations. This person should have the authority and responsibility to monitor and enforce the control of laser hazards. This person is also responsible for the evaluation of laser hazards and the establishment of appropriate control measures. 36 The Laser Safety Officer (LSO) may be a full or part-time position depending on the demands of the laser environment. This person may be someone from occupational health and safety, industrial hygiene, or similar safety related departments. The LSO may also be part of the engineering or production department. In any case, the LSO must be provided the appropriate training to properly establish and administer a laser safety program. Some of the duties the LSO may perform include hazard evaluation and establishment of hazard zones, control measures and compliance issues, approval of Standard Operating Procedures and maintenance/service procedures, approval of equipment and installations, safety training for laser personnel, recommendation and approval of personal protective equipment, and other administrative responsibilities. Controlling Laser Hazards Like any other potentially hazardous operation, lasers can be used safely through the use of suitable facilities, equipment, and well trained personnel. The ANSI Z136 series of laser safety standards provide a detailed description of control measures which can be put into place to protect against potential accidents. These control measures are divided into two distinctive categories, Engineering Controls and Administrative/Procedural Controls. Examples of Engineering Controls include protective housings and interlocks, protective filter installations, key-controls, and system interlocks. Administrative/Procedural Controls include standard operating procedures and personal protective equipment. Engineering Controls are generally more costly to develop but are considered far more reliable by removing the dependence on humans to follow rigorous procedures and the possibility of personal protective equipment failure or misuse. Administrative/Procedural Controls are designed to supplement Engineering Controls to assure that laser personnel are fully protected from potential laser hazards. The focus of these controls are to provide adequate education and training, provisions for protective equipment, and procedures related to the operation, maintenance and servicing of the laser. Safety training is desired for those working with Class 3 lasers and systems. Operation within a marked, controlled area is also recommended. For Class 4 lasers or systems, eye protectors are almost always required and facility interlocks and further safeguards are used. Control measures for each laser classification are defined fully in the ANSI Z136.1 laser safety standard. This document is the single most important piece of information regarding the safe use of lasers and should be part of every laser safety program. For more information on laser safety, please refer to this standard. ANSI Z136 laser safety standards may be obtained by contacting Laser Institute of America. A few guidelines to keep in mind: • Thoughtful risk assessment and sensible regulations are required before accidents occur (i.e. before the work begins). • Regulations must be practical and convincing, because otherwise they are likely to be breached. Staying on the “safe” side by imposing unrealistic and nonsensical rules on workers will undermine the respect for the regulations, and can thus be very counterproductive. • All responsibilities must be clarified for everyone involved. The assignment of a laser safety officer alone (possibly as a scapegoat without sufficient time and powers for enforcement of rules) is not sufficient. • Stupid arguments for breaching rules, e.g. of the style “we have always done it like that” or “I know others who also do that”, must be banned. • Formal adherence to given rules is not sufficient – operators must stay risk-aware during routine work. * Mr. Nikola Zlatanov spent over 20 years working in the Capital Semiconductor Equipment Industry. His work at Gasonics, Novellus, Lam and KLA-Tencor involved progressing electrical engineering and management roles in disruptive technologies. Nikola received his Undergraduate degree in Electrical Engineering and Computer Systems from Technical University, Sofia, Bulgaria and completed a Graduate Program in Engineering Management at Santa Clara University. He is currently consulting for Fortune 500 companies as well as Startup ventures in Silicon Valley, California. 37 View publication stats