Construction and Building Materials 199 (2019) 244–255 Contents lists available at ScienceDirect Construction and Building Materials journal homepage: www.elsevier.com/locate/conbuildmat Mechanical properties of coral concrete subjected to uniaxial dynamic compression Linjian Ma a,b, Zeng Li a,⇑, Jiagui Liu a, Liqun Duan a, Jiawen Wu a a b State Key Laboratory of Disaster Prevention and Mitigation of Explosion and Impact, Army Engineering University of PLA, 210007 Nanjing, China State Key Laboratory for Geomechanics and Deep Underground Engineering, China University of Mining and Technology, 221116 Xuzhou, China h i g h l i g h t s Mechanical properties of coral concrete under quasi-static and dynamic compressions are investigated. Coral concrete exhibits high-early strength and more brittle characteristics. The compressive strength and failure pattern are sensitive to strain rate. Energy dissipation and fractal dimension are calculated and found to be rate-dependent. Differences of failure pattern and mechanism between coral and conventional concrete are analyzed. a r t i c l e i n f o Article history: Received 16 September 2018 Received in revised form 4 December 2018 Accepted 6 December 2018 Keywords: Coral aggregate concrete Dynamic compressive strength Failure pattern Energy dissipation Fractal dimension a b s t r a c t The uniaxial compressive behavior of coral aggregate concrete was experimentally investigated under quasi-static to dynamic loading rates. Quasi-static compression tests of coral concrete at different curing ages were performed at a constant strain rate of 105 s1 using an electro-hydraulic servo-controlled test machine. Dynamic impact loading tests were conducted at stain rates from 101.48 s1 to 102.16 s1 utilizing a 100-mm-diameter split Hopkinson pressure bar (SHPB) system. The strain rate effects on the mechanical properties of coral concrete were assessed in terms of the uniaxial compressive strength, energy dissipation, fractal dimension and failure pattern. The coral concrete exhibits high-early strength and the post-peak stress-strain curves behave in a more brittle manner than conventional concrete. A more remarkable rate-dependence in the compressive strength of coral concrete than other cementbased composites was observed as the dynamic increase factor (DIF) increased from 1.73 to 2.56 with the strain rate increasing from 30.12 s1 to 143.32 s1. Different from the failure pattern of conventional concrete, the fracture plane of coral concrete directly penetrated through the coral shingles rather than cracking in the interface between the cement mortar and the coarse aggregate under both quasi-static and dynamic loadings, ascribing to the low strength of coral aggregates and the high intensity of bonding interface. The ratio of the absorbed energy to incident energy is between 0.3–0.5 and tends to decrease with an increase in strain rate. A higher loading rate may lead to more energy absorption consumed by generating more fracture planes and smaller fragments, which is in consistent with a higher value of fractal dimension. The fractal dimension in the range of 2.027–2.302 for coral concrete was also found to be proportional to the logarithm of the loading strain rate. Ó 2018 Elsevier Ltd. All rights reserved. 1. Introduction Recent developments of marine industry and island engineering have driven a dramatic increase in demand for construction materials such as steel, wood, natural rock and concrete. Cement based materials play a dominant role in the highly corrosive marine envi⇑ Corresponding author. E-mail address: lzx2447@163.com (Z. Li). https://doi.org/10.1016/j.conbuildmat.2018.12.032 0950-0618/Ó 2018 Elsevier Ltd. All rights reserved. ronment of remote island reef engineering on account of the properties of cost efficiency, durability, and workability. Nowadays, the feasibility and suitability of coral aggregates as a locally available alternatives to conventional aggregates for concrete preparation have gained widespread acceptance [1–7]. Coral aggregate concrete normally refers to the cement based composites made with coral aggregates and seawater. It has been extensively applied for a variety of marine structures such as sea embankments, coastal breakwaters, ship wharf, and other offshore structures since World 245 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 War II. Coral concrete structures on islands are subjected to environmental and artificial impacts during the service life. Therefore, there is a need to explore the mechanical properties of coral concrete under various circumstances for its application in marine engineering. Considerable efforts have been made to assess the performance characteristics of coral concrete in respect of mix proportion design, workability, durability, strength, as well as other basic physical and mechanical properties. The physical and mechanical properties of coral concrete were found to be different from conventional concrete, and in some ways, were similar with lightweight aggregate concrete [8]. The differences of mechanical behaviors between coral and conventional concrete are mainly attributed to the high compressibility and low crushing strength of corals with remarkable intra-granular voids and highly irregular shape [9,10]. It was reported that due to the high porosity of coral aggregates, coral concrete demanded more water than Portland cement concrete during the mixing procedure to achieve proper workability and strength [11]. The coral concrete exhibits highearly strength or rapid hardening phenomena, that is the strength of concrete mixed with coral aggregates and seawater grows faster at early age then slower at later age [12]. In fact, coral concrete of moderate strength up to 50 MPa can be easily prepared, whereas a higher designed strength grade is limited to the low strength of coral aggregates [13]. It was also confirmed that the long-term strength of coral concrete could maintain a high level and meet the engineering requirements [3]. While in the challenging marine environment with high temperature, high humidity and high salinity, the speed of carbonization and corrosion of concrete grows faster, especially for the steel reinforced concrete. The durability and service life of concrete structures on the remote islands are found to be shorter than that on the mainland [14,15]. Although the coral sand and seawater may help improve the pore structure and interfacial transition zone [16], the major factor restricting the use of coral concrete remains the chloride corrosion due to the inherent porous structure of corals and plenty of chloride ions from itself and seawater [17]. The chloride diffusion of coral concrete in tropical marine environment is characterized by low chloride binding capacity, high surface free chloride concentration and high apparent chloride diffusion coefficients [15]. With the exploration of active admixtures and composite fiber reinforcement, the performances of coral concrete in strength, corrosion resistance and brittleness can be remarkably improved [18]. The mechanical behaviors of coral concrete depend not only on the material compositions (concrete type, water-to-cement ratio, and size gradation of aggregates, etc.) but also on the loading conditions (temperature, stress state, loading rate, etc.). It is noted that the aforementioned literatures have been rarely involved in complicated stress states that the coral concrete is potentially subjected to, especially under dynamic loading scenarios, e.g., seismic oscillation, impacts induced by waves and ships, even bomb explosions in military activities, etc. As a matter of fact, it is well recognized that the inherent strain-rate sensitive property of concrete-like materials has a prominent effect on the mechanical characteristics. Therefore, a systematic evaluation on the dynamic properties of coral aggregate concrete can provide the main basis for improving the design and protective ability of marine engineering structures. This paper aims to experimentally assess the static and dynamic compression behavior of coral concrete at different loading rates. The effects of strain rate on uniaxial compressive strength enhancement, energy dissipation and failure pattern were evaluated. Furthermore, the fractal characteristics of coral concrete fragments under impact loads were also examined adopting the method of mass-frequency. 2. Materials and experimental procedure 2.1. Raw materials and mix proportion Both coral debris and coral sand adopted as coarse and fine aggregates were directly shipped from the islands in South China Sea. Unlike natural quartz sand or mineral rocks having a physical (a) Coral debris (b) Coral fragments (c) Coral sand Fig. 1. Corse and fine coral aggregates from the South China Sea Island. 246 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 tional aggregates. Thus, in view of the specification for mix proportion design of lightweight and conventional concrete, the mix proportion of the coral concrete in this study was determined and detailed in Table 4. Besides, a super plasticizer (SP) accounting for 0.1% of the mass of seawater with a water-reducing ratio of 25% was adopted considering the high water absorption characteristic of coral aggregates (around 10%). Meanwhile, the water-tocement ratio was kept near 0.5 to assure the workability. 2.2. Specimen preparation and basic physical properties The raw materials were stirred using a concrete blender with the sequence of cement, coral sand, coral fragments and seawater. To ensure a uniform mixing of raw materials, half of the seawater was first blended into the mixture after 60 s of dry-mixing for 30 s, then the other half was added and mix for 120 s. A slump of around 35 mm was achieved for the coral concrete mixture through slump test. After the mixing process, the mixture was then poured into the inside surface-oiled moulds (300 100 100 mm and 270 270 60 mm) for compaction on a vibrating table. The cast coral concrete was placed in the curing room at constant temperature of 20 ± 2 °C and relative humidity of 95%. The specimens were demoulded from the moulds after 3 d and were continually cured there for 28 d. In the present study, a set of fifteen cubic specimens with dimensions of 100 100 100 mm were fabricated for quasistatic tests. Nine specimens for dynamic experiments was cut into a standard cylinder with dimensions of U 100 50 mm followed the recommendation of L/D = 0.5–1 to limit the axial inertial effect [19]. The density of test samples is 2000–2200 kg/m3, which is much smaller than that of conventional concrete and a little larger than lightweight concrete. Ultrasonic pulse velocity (UPV) tests were performed using an RSM-SY5 (T) non-metal ultrasonic detection analyzer. UPV is an important parameter to tell whether the material is dense or porous since wave travels faster in solid phase than that in gaseous phase. The UPV of coral concrete is in the range of 2500–3000 m/s, which is remarkably slower than that of Fig. 2. Particle size distribution of coral sand. or chemical origin, coral debris and coral sand are the accumulation of died skeletal bodies of hermatypic polypary corals and shells, that is, mainly of biological sedimentary origin. The mineral composition of corals consists of as high as 97% calcium carbonate with specific gravity of 2.7–2.85. The coral debris (Fig. 1a) were first broken into smaller fragments (Fig. 1b) with a maximum diameter of 10 mm and were then sieved into a continuous gradation of 5–10 mm for coarse aggregates. The size distribution of coral sand is present in Fig. 2 with a fineness modulus of 2.24. The basic physical properties of coarse and fine aggregates including the bulk and apparent densities, porosity, water absorption, and mud content are detected complying with the Chinese standards GB/T 14684-2011, and the test results are listed in Tables 1 and 2, respectively. The cement used for concrete preparation was 42.5 ordinary Portland cement (P.O. 42.5), which was produced by China Anhui Conch Cement Co., Ltd. Artificial seawater was prepared in accordance with the American ASTM D11412003 and its chemical composition is given in Table 3. As shown in Table 1, the apparent density of coarse aggregate is 2564 kg/m3, which is between that of lightweight and convenTable 1 Physical properties of coral fragment. Bulk density/kg/m3 Apparent density/kg/m3 Porosity/% Water absorption/% Mud content/% Cylindrical compressive strength/MPa 981.9 2564 61.7 8.6 6 2.83 Table 2 Physical properties of coral sand. Bulk density/kg/m3 Apparent density/kg/m3 Porosity/% Water absorption/% Mud content/% 1228 2632 53.3 9.2 10.4 Note: The porosities of coral fragments and coral sand are calculated as following equation (Chinese National Standards – Sand for Construction (GB/T 14684-2011)): V 0 ¼ 1 qq1 100% 2 where V0 is the porosity, q1 and q2 are bulk density and apparent density of the tested material, respectively. Table 3 Chemical composition of artificial seawater. NaCl/kg/m3 MgCl26H2O/kg/m3 Na2SO4/kg/m3 CaCl2/kg/m3 KCl/kg/m3 24.5 11.1 4.1 1.2 0.7 Table 4 Mix proportion of coral concrete. Cement/kg/m3 Coral fragment/kg/m3 Coral sand/kg/m3 Artificial seawater/kg/m3 SP/kg/m3 W/C 500 714 586 238 0.24 0.476 Note: SP: superplasticizer; W/C = seawater/cement. 247 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 Table 5 Comparison of basic physical and mechanical properties of different types of concretes. Concrete type Density/kg/m3 UPV/m/s Elastic modulus/GPa Poisson’s ratio Coral concrete Conventional concrete [16] Lightweight concrete [17] 2000–2200 2400–2800 560–1950 2500–3000 4200–4700 3500–3800 21–32 32.5–34.5 10–30 0.22–0.25 0.20–0.22 0.20–0.25 conventional and lightweight concrete, indicating the porous characteristic of the specimens. A comparison of basic physical and mechanical properties of three types of concretes were given in Table 5. 2.3. Quasi-static tests The MTS 647.250 electro-hydraulic servo-controlled test system is utilized to conduct the uniaxial quasi-static compression test. It is composed of the main machine, oil source, control system and loading frame. The maximum static and dynamic loading forces are 2500 kN and 2750 kN, respectively. The displacement control mode was adopted and applied at a loading speed of 0.001 mm/s or at a constant strain rate of 105 s1. PTFE films were placed on the contact position between the specimen and two loading platens to mitigate the end effect. The extensometers with a gauge length of 25 mm and a resolution of 0.00001 mm were attached on the tested specimen along two perpendicular directions to monitor the axial and horizontal deformations. 2.4. Split Hopkinson pressure bar (SHPB) tests As a widely used apparatus developed by Kolsky [20], the split Hopkinson pressure bar (SHPB) was applied to quantify the dynamic compressive response of coral concrete under intermediate strain rate range of 101–103 s1. The SHPB technique is valid based on the assumptions that the stress wave propagates onedimensionally in an elastic bar without dispersion while the stress and strain within the specimen remains in an axially uniform state during the loading process [21]. The shape and amplitude of the induced incident pulse depend on the impact velocity and the length of the striker. A slowly rising ramped pulse is preferred not only to facilitate stress equilibrium but also to generate a nearly constant strain rate state in the sample [22]. However, during large diameter SHPB tests, a rectangular stress pulse with steep ramp is always generated by the impact of the striker, which arises the difficulty of achieving dynamic stress equilibrium for concretelike materials. It is also well known that the induced rectangular pulse consists of different frequency components, which propagate Loading System Gas gun Laser speedometer 8 rðtÞ ¼ AAbs Eb et ðtÞ > > > < Rt b eðtÞ ¼ 2C e ðtÞds 0 r Ls > > > :_ 2C b eðtÞ ¼ Ls er ðtÞ ð1Þ where the subscripts b, s, i, r, t denotes the bar, specimen, incident, reflected and transmitted pulses, respectively. Bar System Pulse shaper Strike bar with different velocities in the bar system, leading to the wave dispersion effect. The dispersion of stress pulse have great effect on the validity of the test data and become more severe as the bar diameter increases. Therefore, necessary pulse shaping technique is needed to adjust the incident waveform to half-sine-like pulse with high frequency oscillations being filtered out. Approaches of pulse shaping technique have been proposed for brittle materials such as rocks, concrete and ceramics in pioneering works [23– 25]. In the present study, a thin rubber disk named pulse shaper with 10 mm in diameter and 2 mm in thickness was placed in front of the incident bar to effectively minimize pulse dispersion in all tests. Furthermore, the lubricant was evenly smeared on the two ends of the specimen to reduce the effects of end friction and stress concentration [21,26,27]. The adopted 100 mm-diameter SHPB system is presented schematically in Fig. 3, which consists of a gas gun chamber, a striker bar (0.8 m in length), an incident bar (4 m in length) and a transmitted bar (3 m in length). The modulus of high-strength alloy steel bars is 205.6 GPa with a density of 7767 kg/m3, thus the velocity of wave propagating in the bars could be simply calcupffiffiffiffiffiffiffiffiffi lated as C ¼ E=q = 5145 m/s. The velocity of the strike bar is measured by a laser speedometer. The failure progress of specimens is captured using a high-speed camera with 105 fps. The incident, reflected and transmitted stress pulses are monitored with four semiconductor strain gauges mounted in the middle of the incident and transmitted bars through Wheatstone bridge, which is connected to a digital oscilloscope with a sampling frequency of 2 106 s1. According to the one-dimensional stress wave theory, these strain measurements are used to determine the time histories of stress r(t), strain e(t) and strain rate e_ (t) within the specimen as [20]: Specimen Incident bar Strain gauges Transmitted bar Computer Compression test: : BD test: Data Acquisition and Recording System Fig. 3. Schematic of a typical SHPB system. Damper 248 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 3. Results and discussions 3.1. Quasi-static test results 3.1.1. Complete stress-strain curves By combing the simultaneously measured results of the load transducer of MTS and extensometers fixed on the specimens, the non-linear stress-strain relationships of coral concrete under uniaxial compression are plotted in Fig. 4. As can be seen from Fig. 4, the complete compressive stress-strain curves of coral concrete can be divided into four stages: consolidation stage, elastic stage, plastic stage and fracture stage. Specifically, the consolidation stage is observed as an upward concave in the initial portion of the complete stress-strain curve, which is different from that of conventional concrete. This may be mainly caused by the pore structures of coral aggregates and the voids inside the concrete matrix being compacted as the loading stress increases. The consolidation stage indicates the typical porous and loose features of the microstructure of the coral concrete. The slope of the ascent linear stress-strain curve is between those of the lightweight and conventional concrete with the same strength grade. The descend stage of the stress-strain curve is much more abrupt and steeper compared to other concrete types. It is evident that the postpeak stress-strain relationship of coral concrete behaves in a more brittle manner. The low crushing strength of coral particles and special failure mode are the two main reasons resulting in the significant brittleness of coral aggregate concrete compared to normal concrete. The crushing strength of coral aggregates is much lower than gravels and pebbles and itself exhibits evident brittle characteristic [28]. Furthermore, owing to the high intensity of bonding interface, the fracture plane of coral concrete tends to penetrate directly through the coral aggregates rather than the interface between the cement mortar and the aggregates. The average compressive strength of coral concrete is 40.08 MPa and the corresponding failure strain is 0.185%, which is slightly larger than that of the conventional concrete. The elastic modulus was calculated by the slope of the approximate linear part of ascent stage of the stress-strain curve, and the average value appears to be 29.60 GPa, which is consistent with the research of pioneer experts [29–31]. Time history curves of transverse strain, longitudinal strain and Poisson’s ratio were together displayed in Fig. 5. Under uniaxial compression state, the Poisson’s ratio of coral Fig. 4. Stress-strain curves of coral concrete under quasi-static compression. Fig. 5. Time history curves of transverse strain, longitudinal strain and Poisson’s ratio. concrete specimen is around 0.254, which is basically the same as the other two types of concretes. 3.1.2. Compressive strength for different curing ages The tested average compressive strength of coral concrete cured for 3 d, 7 d, 14 d, 21 d and 28 d are 32.14 MPa, 35.43 MPa, 37.51 MPa, 38.04 MPa and 40.04 MPa, respectively. The normalized strength with respect to the 28-day strength of coral concrete along with the conventional and lightweight concrete are plotted against the curing age in Fig. 6. It is seen that the strength of coral concrete tends to increase faster during early period then slower during later period as compared to the conventional and lightweight concrete. Specifically, the coral concrete strength at 3 d and 7 d reaches over 80% and 90% of that at 28 d, whereas the development of the rest 10% of the ultimate curing strength lasts for three weeks. The high-early strength behavior of coral concrete is mainly caused by the chlorides in the coral aggregates and seawater and its inherent porous structure. The high content of chloride salts in coral concrete mixed with corals and seawater plays the role as rapid hardening agents [32,33]. In addition, the porous microstructure of coral aggregates performs the function of ‘‘water bag”. It absorbs and reserves a certain amount of water from the concrete slurry and releases the water in the hydration and Fig. 6. Strength development of three types of concretes for different curing ages. 249 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 3.2. SHPB test results 3.2.1. Dynamic stress-strain curves Typical waveform of signals measured by the strain gauges mounted on the incident and transmitted bars are presented in Fig. 7a. As seen in Fig. 7a, a tender and smoother ramp waveform is realized with a pulse shaper. The rising time of shaped incident pulse is nearly up to 250 ls, which is sufficient for five to ten wave reverberations in the sandwiched specimens to achieve a stress equilibrium state during impact loading. To qualitatively check the validity of the SHPB tests, time histories of dynamic strain pulses on the incident and transmitted ends of the specimen calculated using Eq. (1) and the strain rate with respect to time are plotted together in Fig. 7b. As illustrated in Fig. 7b, the difference of the transmitted and reflected pulses coincides approximately with the incident pulse, which indicates a dynamic equilibrium of the action and reaction forces is satisfied on both ends of the specimen throughout the loading process. The curve of strain rate as a function of time exists an evident platform, thus facilitating a roughly constant strain rate state for the duration of loading. To further quantitatively assess the dynamic stress state, the stress equilibrium factor d accounting for the relative stress difference is defined as [34]: Rt dðtÞ ¼ 30 20 10 0 . DC-1 (ε = 30.12 s-1) t = 250 μs -10 -20 -30 0 100 200 300 400 Rt ðei þ er Þdt 0 et dt DrðtÞ i. ¼h 0 raver ðtÞ R t ðei þ er Þdt þ R t et dt 2 0 where Dr and ravg are the stress difference and average stress at both ends of the specimen, respectively. In general, a dynamic stress equilibrium is achieved when d(t) is smaller than 5%. The curves of stress equilibrium factor with respect to time for different strain rates are plotted in Fig. 8. As demonstrated in Fig. 8, a long rising action time of more than 200 ls is obtained for various loading strain rates, which is 10– 12 times of the travelling time (16.7–20 ls) in the specimen to δ hardening process, which also enhances the early strength of coral concrete [8,31]. 500 600 700 800 t / μs (a) ð2Þ 30 0 20 δ 10 0 t = 205 μs -10 DC-5 (ε = 90.03 s-1) -20 -30 0 100 200 300 400 500 600 700 800 t / μs (b) 30 20 δ 10 0 t = 220 μs . DC-9 (ε = 143.32 s-1) -10 -20 -30 0 100 200 300 400 500 600 700 t / μs (c) Fig. 7. (a) Typical waveforms monitored from strain gauges; (b) dynamic strain pulses on both ends of specimen and strain rate history with a pulse shaper. Fig. 8. d as a function of time for different strain rates. 800 250 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 guarantee the stress equilibrium. It can also be determined from Fig. 8 that the specimens remain a stable stress equilibrium state during the most of the action time of incident stress pulse. Besides, the uniform state of stress and deformation along the length of the specimens have achieved prior to failure. The dynamic compressive stress-strain curves of coral concrete at strain rate ranging from 30.12 s1 to 143.32 s1 are shown in Fig. 9. Most of the stress-strain curves possess a similar shape and the post-peak stages demonstrate a strain-softening behavior due to fragmentation and granular flow. However, the shape of the DC-1 and DC-2 curves is apparently different from the other specimens, in which the strain decreased slightly after the peak stress. That was mainly due to the following reason: under the condition of relatively low impact speed, the specimen was not damaged thoroughly thus the deformation had a certain recovery after the impact, whereas the other specimens were pulverized when the impact speed was greatly higher. An obvious change in the stress-strain response of the coral concrete with increasing strain rate can be found. At a strain rate of 143.3 s1, the compressive strength of coral concrete is 102.5 MPa, which is approximately 2.6 times the quasi-static strength of 40.08 MPa. Both the dynamic compressive strength and deformation are sensitive to the loading strain rate caused by the combined effects of Stefan, cracking propagation and inertia. It is widely accepted that the viscous effect of 110 3.2.2. Strain rate effect on compressive strength The dynamic increase factor (DIF) defined as the ratio of dynamic compressive strength to quasi-static is regarded as an important parameter for the characterization of the ratedependence of material strength. Fig. 10 depicts the relationship between DIF and strain rate for coral concrete. A significant increase in dynamic compressive strength of coral concrete is observed over the applied strain rate. As shown in Fig. 10a, within the same regime of strain rate, the tested value of DIF of coral concrete is in the range of 1.73–2.56, which is slightly higher than that of conventional (between 1.5 and 2.25) [35–38]. The remarkable DC-1 (30.12 s-1) DC-2 (49.12 s-1) DC-3 (59.43 s-1) DC-4 (79.81 s-1) DC-5 (90.03 s-1) 100 90 80 σ / MPa free water in the micropores of concrete could increase the cohesive strength between coral aggregates and cement mortar with strain rates. Hence, the Stefan effect plays a dominant role in the elastic deformation stage before the initiation of microcracks. The propagation of microcracks with irreversible deformation always lags behind the dynamic loading. According to the theorem of impetus, the stress level of coral concrete specimen improves to counteract the external impulse, which is considered the main reason of rate-dependence of dynamic strength. As the lateral deformation is restricted by its inertia effect, the dynamic compressive strength increases with this equivalent confining pressure. The inertia effect may be more dominant in the post-peak stage. 70 60 50 40 30 20 10 0 0.00 0.01 0.02 0.03 0.04 0.05 ε (a) 110 DC-6 (97.34 s-1) DC-7 (100.58 s-1) DC-8 (123.66 s-1) DC-9 (143.32 s-1) 100 90 σ / MPa 80 70 60 50 40 30 20 10 0 0.00 0.01 0.02 0.03 0.04 0.05 0.06 0.07 ε (b) Fig. 9. Stress-strain relationships of coral concrete under SHPB tests: (a) DC-1–DC5; (b) DC-6–DC-9. Fig. 10. (a) Strain rate sensitivity of compressive strength; (b) fitting results of different empirical equations. 251 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 strength enhancement demonstrates a more intense ratesensitivity of coral concrete than other cement-based composites. Different empirical formulas have been proposed to account for the strain rate sensitivity of the uniaxial compressive strength of concrete. Fig. 10b presents the comparison of fitted results using four equations suggested by Al-Salloum [38], CEB [39], Ngo [40] and Grote [41]. The four fitting equations are listed as follows: DIF ¼ 3:248e_ þ 77:946 e_ þ 75:763 8 > 1:03as > < e_e_s DIF ¼ 1 > > : cs _e_ 3 es 9 > ; e_ 6 30 s1 > = > ; ; e_ > 30 s1 > ð3Þ ð4Þ where cs ¼ 10ð6:16as 2:0Þ ; as ¼ 1=ð5 þ 9f cs =f co Þ; f co ¼ 10 MPa; e_ s ¼ 3 105 s1 . Fig. 11. Typical energy evolution in a SHPB compression test. 0:056 e_ DIF ¼ 0:952 ; e_ s ¼ 3:33 105 s1 e_ s ð5Þ DIF ¼ 0:177 lge_ þ 1:832 ð6Þ As illustrated in Fig. 10b, all the predicted values of CEB formula are lower than the tested data, whereas the fitted results using exponential formula by Ngo and linear formula by Grote which describe DIF as a function of the logarithm of strain rate are in better agreement. By comparison, the adopted formula proposed by Yousef Al-Salloum turns to be the best candidate for predicting the dynamic strength enhancement of coral concrete. However, the application scope of the empirical formulas is still restricted due to the lack of available experimental data between the quasi-static and the intermediate strain rate regime. 3.2.3. Strain rate effect on energy dissipation In SHPB tests, the propagation of the waves in bars is an essential way to transfer the impact energy to the specimen. It is assumed that the dynamic loading process is adiabatic and the energy loss at the interfaces between the bars and the specimen are negligible [42]. Hence, the total absorbed energy can be indirectly derived from the difference of the incident, reflected and transmitted stress wave energy, which have the following expressions: 8 Ws ¼ Wi Wr Wt > > R > > < W i ¼ AB C B EB 0t e2i ðsÞds Rt > W r ¼ AB C B EB 0 e2r ðsÞds > > > Rt : W t ¼ AB C B EB 0 e2t ðsÞds ð7Þ where Wi, Wr, Wt, Ws represent the energy of incident, reflected, transmitted and absorbed energy, respectively. The amount of energy decrease as the aspect ratio of specimens increases, while the volume-specific energy absorbed by the specimen tend to be higher, which results in finer fragment size distribution [43–45]. The energy absorption mainly consumes as the fracture energy in the process of crack initiation and extension, the kinetic energy of the fragments and other forms of energy such as heat, sound and radiation. Therefore, the impact damage of concrete can be characterized by the energy dissipation during fracture process. From the perspective of energy evolution, the deformation and failure mechanisms of materials subjected to dynamic loading might be closely correlated. The typical energy evolution curves of coral concrete in SHPB tests are plotted in Fig. 11. As shown in Fig. 11, the incident, reflected and absorbed energy increase continually with time until they ultimately reach an upper limit value, whereas the transmitted energy remains constant occupying less than 5% of the total incident energy. Specifically, the moments of stress equilibrium t1, critical fracture t2, end of the plateau with constant strain rate t3, and end of the energy absorption t4 might divide the energy evolution process into five portions. The first portion (0–t1) is the initial unstable period before the valid stress equilibrium state, corresponding to the compaction stage in the stress-strain curve. As seen in Fig. 11, only little energy is absorbed during this period. The second (t1–t2) and third (t2–t3) portions are the steady period as the energy absorption maintains a constant rate and accounts for most of the total absorbed energy. During the fourth portion (t3–t4), the energy absorption keeps increasing while the growth rate decreases to nil, which might be named the transient period. The fifth portion is the last period in which the energy maintains its maximum value, implying that the specimen is completely destroyed by the impact. More specific representative energy measured at fracture moment t2 for different stain rates are listed in Table 6 and plotted in Fig. 12. Clearly, the specific incident and reflected energy increased nonlinearly with growing strain rate, while the transmitted energy exhibited a slight decayed tendency. An evident linear relationship was found between the absorbed energy and loading strain rate. An indicator Ws/Wi defined as the ratio of the absorbed energy to the incident energy is commonly adopted to evaluate the energy dissipation performance of porous materials [46]. Theoretical derivations by Lundberg proved that Ws/Wi owned an extreme value of 50%, and it could be attained only when the amplitude of the incident pulse was twice the yield stress of the specimen [42]. As illustrated in Fig. 13, a comparison of the energy absorption ratios of normal concrete [47], sandstone [48] and rock salt [49] have the same trend to decrease as the strain rate increases. It is obvious that the energy absorbability of coral concrete is between 30% and 50%, which is higher than that of other three materials. Table 6 Representative energy measured at time t1 for different loading rates. Specimen Strain rate/s1 Wi/J Wr/J Wt/J Ws/J Ws/V/ kJ/m3 Ws/ Wi/% DC-1 DC-2 DC-3 DC-4 DC-5 DC-6 DC-7 DC-8 DC-9 30.12 49.12 59.43 79.81 90.03 97.34 100.58 123.66 143.32 284.15 338.41 359.27 481.39 657.45 513.66 756.97 644.11 959.35 43.63 99.34 98.95 185.56 329.24 196.27 401.85 315.19 577.46 101.21 70.11 84.58 60.51 53.88 70.51 50.83 63.87 32.06 139.30 168.96 175.74 235.31 274.33 246.88 304.29 265.05 349.82 377 471 477 639 743 669 825 719 973 49.02 49.93 48.92 48.88 41.73 48.06 40.20 41.15 36.46 252 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 100 M/MT / % 10 DC-1 (R2 = 0.909) D = 2.027 DC-2 (R2 = 0.906) D = 2.076 DC-3 (R2 = 0.971) D = 2.149 DC-4 (R2 = 0.990) D = 2.194 DC-5 (R2 = 0.974) D = 2.240 1 0.1 0.01 1E-3 0.01 0.1 1 10 100 d / dmax (a) Fig. 12. Relationship between specific energy and strain rate. 100 0.6 Ws/Wi 0.4 M/MT / % 0.5 Coral concrete Normal concrete Tai (2009) Sandstone Li & Mao (2014) Rock salt You, et al. (2017) 0.3 10 DC-6 (R2 = 0.989) D = 2.276 DC-7 (R2 = 0.973) D = 2.289 DC-8 (R2 = 0.982) D = 2.280 DC-9 (R2 = 0.969) D = 2.302 0.2 0.1 1 1E-3 0.0 1.0 0.01 0.1 1 10 100 d/dmax 1.2 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 (b) . lgε / s-1 Fig. 14. Relative mass versus fragmentation size: (a) DC-1–DC-5; (b) DC-6–DC-9. Fig. 13. Ws/Wi as a function of strain rate. This may be mainly attributed to the peculiar porous and loose structure of coral aggregates. The porous microstructure plays an important role in the energy absorption of coral aggregate concrete under dynamic impacts. The energy dissipation ratio could be quantitatively correlated to the strain rate using an inverse linear equation: Ws ¼ 0:18 lge_ þ 0:79 Wi ð8Þ 3.2.4. Strain rate effect on fractal dimension Generally, crushed parts of a solid material have a selfsimilarity to the whole in geometry [50]. Fractal theory is an effective approach for the estimation of the geometric and mechanical characteristics of solid and granular materials after crushing. Therefore, the fractal crushing property of coral concrete subjected to dynamic loads can be quantitatively assessed by fractal dimension. A fractal model based on mass-frequency is described as a power law function in the cumulative mass-size distribution curves, which can be written as [43]: Z M/ 3 3D d dN / d ð9Þ where M refers to the cumulative mass after sieving, d and D are the sieve diameter and fractal dimension, respectively. The fragment size distributions of broken coral concrete specimens under dynamic compression were obtained by sieving with standard sieve series and the results were plotted in a log-log scale in Fig. 14. The fragments of coral concrete exhibited pronounced fractal feature since the cumulative mass appeared to be linearly related to fragment size. The slope of the fitted straight line is 3D according to Eq. (9). Fig. 15 depicts the fractal dimension of coral concrete at different strain rates. The fractal dimension increased from 2.027 to 2.302 as the strain rate increased from 30.12 s1 to 143.32 s1, implying a higher degree of fragmentation and selfsimilarity. The fractal dimension was found to be proportional to the logarithm of the loading strain rate. The value of fractal dimension as a function of strain rate can be further expressed as: D ¼ 0:46 lge_ þ 1:34 ð10Þ 3.2.5. Failure pattern and mechanism Fig. 16 depicts the failure mode of coral concrete under quasistatic compression. In quasi-static compression cases, several visible macro-cracks originated at the upper and lower ends of concrete cubes as the axial strain reached a threshold value around 103. With an increase in the irreversible deformation, the macrocracks extend mainly in the axial direction with few inclined fissures. The coral concrete ultimately split into multiple columns accompanied with the concentration of macro-cracks and the formation of fracture surfaces. From Fig. 16b we can see that the main 253 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 Fig. 15. Fractal dimension of coral concrete with respect to strain rate. failure plane directly penetrates through the coral debris rather than cracking in the interface between the cement and aggregates, which is quite different from the failure pattern of the conventional concrete. Fig. 17 presents the failure patterns of coral concrete specimens at different strain rates. With an increase in the loading rate, the damage level of the coral concrete disc undergoes edge crack, edge broken, major breakage, crushing and grinding. At lower strain rate, the specimen failed with few pieces of columns while the central core kept its integrity. As the strain rate grew higher, the specimen split into smaller fragments even powders. Fundamentally, higher impact velocity with more absorbed energy is consumed by generating more cracks and fracture planes resulting in the breakage of the coral concrete specimen into smaller pieces. Generally, the fracture of concrete begins and follows the weakest route with a least energy consumption. Internal flaws like pores, micro-cracks and weak bonding interface between cement mortar and coarse aggregate tend to be the weak regions in conventional concrete matrix. Consequently, the special failure mode of coral concrete is mainly caused by the low strength of coral aggregate and the high intensity of bonding interface. As demonstrated in Fig. 18, the interfacial transition zone between the coral aggregates and cement matrix is highly dense without any visible flaws. Due to the porous microstructure, coral aggregates can absorb and reserve water in the early stage of the mixing and release water during the hydration and hardening process. The local water-cement ratio is adjusted by the ‘‘absorption-release” action to enhance the adhesive strength between the aggregates and cement mortar [31]. On the other hand, the peculiar rough and porous surface texture of coral aggregates also contributes to a high frictional strength on the interface. The hydration products together with matrix may easily attach and accumulate on the rough surface and embed into the porous microstructures of coral aggregates, resulting in the high bonding intensity and frictional strength of the interfacial transition zone. 4. Conclusions Uniaxial quasi-static and dynamic compression tests on coral concrete specimens were conducted utilizing servo-hydraulic machine and split Hopkinson pressure bar system. The effects of loading strain rate on compressive strength, energy dissipation and failure pattern were evaluated. The main conclusions are drawn as follows. (a) Internal pores Broken coral coarse aggregates (b) Fig. 16. Failure pattern of coral concrete under quasi-static compression: (a) surface cracks; (b) fracture plane. The coral concrete exhibits high-early strength or rapid hardening phenomena for the 7 d compressive strength attains 90% of that at 28 d. The brittleness of coral concrete is more evident than that of conventional or lightweight concrete due to the high compressibility and low crushing strength of corals with remarkable intragranular voids and highly irregular shape. The average quasistatic compressive strength and elastic modulus of the coral concrete are 40.08 MPa and 29.60 GPa, which are slightly lower than the corresponding conventional concrete. The loading rate is proved to have significant effects on the dynamic compressive strength, energy dissipation, fractal dimension and failure pattern. The value of dynamic increase factor is in the range of 1.73–2.56 with the strain rate increasing from 30.12 s1 to 143.32 s1. An empirical formula accounting for the strength enhancement with respect to strain rate is found to be more satisfying with the experimental results. Unlike the failure pattern of conventional concrete, the main fracture cracks directly 254 L. Ma et al. / Construction and Building Materials 199 (2019) 244–255 Fig. 17. Failure pattern of coral concrete under dynamic compression. the work described is an original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part. Interface Acknowledgment The authors would like to express their grateful appreciations to the National Natural Science Foundation of China (Grant Nos. 51774295 and 51808551) for the financial support to this research. Coral aggregates Cement crystal Fig. 18. Micro-morphology of the interface of coral concrete. propagate through the coral shingles rather than breaking in the interface between the cement mortar and the aggregate, which is due to the low strength of coral aggregate and the high intensity of bonding interface. The incident, reflected and absorbed energy develop with an increase in the strain rate, while the transmitted energy approximately keeps unchanged. The ratio of absorbed energy to the incident energy is in the range of 0.3–0.5 and seems to be inversely proportional to the logarithm of the strain rate. More energy absorbed by the coral concrete specimen with higher loading rate is mainly consumed for generating new fracture surfaces resulting in smaller fragments. Fractal dimension is further adopted to characterize the breakage degree in response to various strain rates. 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