TOPIC 1: Water Common Definition of Water 1) A chemical substance, with chemical formula H2O, that is a clear, colorless, odorless, and tasteless liquid that may also occur in various forms such as gas (water vapor) and solid (ice) 2) An aqueous solution of a substance, for example, ammonia water, wastewater 3) A body of water, like seas, rivers, and lakes, and naturallyoccurring water like mineral water 4) Amniotic fluid, as in the pregnant woman’s water breaks In BioChem: Water is a chemical substance, with chemical formula H2O, that is a clear, colorless, odorless, and tasteless liquid that may also occur in various forms such as gas (water vapor) and solid (ice). In BioChem: Water, a substance composed of the chemical elements hydrogen and oxygen and existing in gaseous, liquid, and solid states. In BioChem: It is one of the most plentiful and essential of compounds. A tasteless and odourless liquid at room temperature, it has the important ability to dissolve many other substances. Molecular Structure of Water What is the structure of a water molecule? A water molecule consists of two hydrogen atoms and one oxygen atom. The three atoms make an angle; the H-O-H angle is approximately 104.5 degrees. The center of each hydrogen atom is approximately 0.0957 nm from the center of the oxygen atom. The structure of a single water molecule is shown on the left: What is the structure of a water molecule? Because oxygen is more electronegative than hydrogen (in other words, electrons tend to be in the neighborhood of the oxygen), the hydrogen atoms end up with a partial positive charge and the oxygen atom with a partial negative charge. This separation of charge produces a net dipole moment on the molecule; for the isolated water molecule this dipole moment is approximately 1.85 Debye units. This molecular structure leads to hydrogen bonding, which is a stabilized structure in which a hydrogen atom is in a line between the oxygen atom on its own molecule and the oxygen on another molecule. What is the structure of a water molecule? These pictures show a hydrogen-bonded structure between two water molecules: Properties of Water 1. Water is Polar. Water molecules are polar, with partial positive charges on the hydrogens, a partial negative charge on the oxygen, and a bent overall structure. This is because oxygen is more electronegative, meaning that it is better than hydrogen at attracting electrons. 2. Water is an Excellent Solvent. Water has the unique ability to dissolve many polar and ionic substances. This is important to all living things because, as water travels through the water cycle, it takes many valuable nutrients along with it. 3. Water has High Heat Capacity. It takes a lot of energy to raise the temperature of a certain amount of water by a degree, so water helps with regulating temperature in the environment. For example, this property allows the temperature of water in a pond to stay relatively constant from day to night, regardless of the changing atmospheric temperature. 4. Water has High Heat of Vaporization. Humans (and other animals that sweat) use water’s high heat of vaporization to cool off. Water is converted from its liquid form to steam when the heat of vaporization is reached. Since sweat is made mostly of water, the evaporating water absorbs excess body heat, which is released into the atmosphere. This is known as evaporative cooling. 5. Water has cohesive and adhesive properties. Water molecules have strong cohesive forces due to their ability to form hydrogen bonds with one another. Cohesive forces are responsible for surface tension, the tendency of a liquid’s surface to resist rupture when placed under tension or stress. Water also has adhesive properties that allow it to stick to substances other than itself. 5. Water has cohesive and adhesive properties. These cohesive and adhesive properties are essential for fluid transport in many forms of life. For example, they allow nutrients to be transported to the top of a tree against the force of gravity. 6. Water is Less Dense as a Solid than as a Liquid. As water freezes, the molecules form a crystalline structure that spaces the molecules further apart than in liquid water. This means that ice is less dense than liquid water, which is why it floats. This property is important, as it keeps ponds, lakes, and oceans from freezing solid and allows life to continue to thrive under the icy surface. Functions of Water Water is the "Universal Solvent" Water’s extensive capability to dissolve a variety of molecules has earned it the designation of “universal solvent,” and it is this ability that makes water such an invaluable life-sustaining force. On a biological level, water’s role as a solvent helps cells transport and use substances like oxygen or nutrients. Water-based solutions like blood help carry molecules to the necessary locations. Water Supports Cellular Structure Water also contributes to the formation of membranes surrounding cells. Without water, cell membranes would lack structure, and without proper membrane structure, cells would be unable to keep important molecules inside the cell and harmful molecules outside the cell. Water Supports Cellular Structure Water also contributes to the formation of membranes surrounding cells. Without water, cell membranes would lack structure, and without proper membrane structure, cells would be unable to keep important molecules inside the cell and harmful molecules outside the cell. Water Supports Cellular Structure Chemical Reactions of Water Water is directly involved in many chemical reactions to build and break down important components of the cell. Photosynthesis, the process in plants that creates sugars for all life forms, requires water. Water also participates in building larger molecules in cells. Molecules like DNA and proteins are made of repetitive units of smaller molecules. Putting these small molecules together occurs through a reaction that produces water. Water is required for the reverse reaction that breaks down these molecules, allowing cells to obtain nutrients or repurpose pieces of big molecules. Chemical Reactions of Water Water buffers cells from the dangerous effects of acids and bases. Importance of Water