Subject: Corrosion Engineering Course Instructor: Dr. Ameeq Farooq INSTITUTE OF METALLURGY & MATERIALS ENGINEERING UNIVERSITY OF THE PUNJAB, LAHORE Practice Questions: Set-01 Semester: 6th Date: 08-05-2023 Note: Before starting to solve the practice questions read out the following articles from your lecture notes and text book* Faraday’s Law of Electrolysis and Corrosion rate Expression (Faraday’s constant =96,487C/mole) PQ# 1: 15 g of aluminum metal are dissolved in a 1 M HCl solution. How many charges in coulombs have been produced by the anodic process? ( Al Al 3 3e ; Molar mass of aluminum (Al) = 26.98 g/mole) (Answer: Q=160930.8747C) PQ # 2: A sheet of zinc one meter wide by three-meter long has lost 40 g to corrosion over the past 80 days. Estimate weight loss in gmd. ( Zn Zn 2 2e ; Molar mass of zinc (Zn) = 65.38 g/mole; grams per square meter per day (gmd)) (Answer: Weight loss = 0.166gmd) PQ # 3: 23 g weight of copper (2 m × 1 m) loss in 15 years. Estimate that penetration rate in mm/year. (Millimeters per year (mm/year); Cu Cu 2 2e ; Density of copper = ρ= 8.96g/cm3; Molar mass of copper (Cu)= 63.55 g/mole) (Answer: Penetration rate=8.56×106 mm/year) PQ # 4: What would be the total corrosion current density associated with copper corrosion rate 0.04 gmd? (Molar mass of copper (Cu) = 63.55 g/mole; Cu Cu 2 2e ) (Answer: i=1.40 mA/m2 ) PQ # 5: Find the charge in coulomb which dissolute 12 g of silver in silver nitrate solution? ( Ag Ag 1 e ; Molar mass of silver (Ag) = 107.9 g/mole; Density of silver = ρ =10.5g/cm3) (Answer: Q=10730.7136 C) PQ # 6: How long has a current of 3 A to be applied through a solution of silver nitrate to dissolve a metal surface of 80 g? ( Ag Ag 1 e ; Molar mass of silver (Ag) = 107.9 g/mole; Density of silver = ρ =10.5g/cm3) (Answer: t=23846.03028 s) PQ # 7: Copper dissolved 9.85 g in 5 hours through acid solution. Calculate the magnitude of the current in ampere. (Molar mass of copper (Cu) = 63.55 g/mole; Cu Cu 2 2e ) (Answer: I=1.66 A) PQ # 8: Derive the general relation between gmd and mdd. (grams per square meter per day (gmd); milligram per square decimeter per day (mdd)) (Answer: 1gmd=10mdd) PQ # 9: Magnesium corrodes in seawater at a rate of 1.45 gmd. Estimate the rate in mm/y? (Density of magnesium = ρ =1.74g/cm3; grams per square meter per day (gmd); millimeters per year (mm/y)) (Answer: Penetration rate=0.3041 mm/year) PQ # 10: Lead corrodes in seawater at a rate of 1.45 gmd. Estimate the rate in mils/y (mpy)? (Density of Lead = ρ= 11.35g/cm3; grams per square meter per day (gmd); mils per year (mpy)) (Answer: Penetration rate=1.835 mpy) Page 1 of 2 Subject: Corrosion Engineering Course Instructor: Dr. Ameeq Farooq PQ # 11: Aluminum corrodes in tap water at a rate of 1.5 gmd. Estimate the rate in in/year (ipy)? (Direction: Density of aluminum = ρ =2.70 g/cm3; grams per square meter per day (gmd); inch per year (ipy)) (Answer: Penetration rate=7.98×103 ipy) PQ # 12: Laboratory corrosion tests on three alloys in an industrial waste solution show the following results: Density of Material (ρ) Material Weight Loss Pitting Factor (g/cm3 ) (gmd) A 2.7 40 1 B 9.0 62 2 C 7.8 5.6 9.2 Estimate maximum penetration in millimeters for each material at the end of one year. Weight loss Maximum Penetration ( Penetration rate ; Pitting factor ) Penetration rate (Answer: (A) Maximum Penetration =5.40 mm/year, (B) Maximum Penetration =5.028 mm/year, (C) Maximum Penetration =2.41 mm/year) PQ # 13: Derive the general relation between mm/y and gmd. (Direction: grams per square meter per day (gmd); millimeters per year (mm/y)) (Answer: 1gmd=0.365ρ mm/year) PQ # 14: Iron corrodes in an aqueous solution; the corrosion current is measured as 0.1 A/cm2. Estimate the rate of weight loss per unit area in units of mdd. (milligram per square decimeter per day (mdd); Molar mass of iron (Fe) = 55.84 g/mole; Fe Fe2 2e ) (Answer: weight loss=250034.0979 mdd) PQ # 15: Derive the general relation between gmd and mpy. (grams per square meter per day (gmd); mils per year (mpy)) (Answer: 1gmd=14.37ρ mpy) * Reference Book: 1. I. H. Khan; “Corrosion Technology”, Vol.1, Ed.2, AFAQ Publisher, Lahore, Pakistan; p.5-6, 41-44. 2. R. Winston Revie, Herbert H. Uhlig “Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering” Ed.4, John Wiley & Sons, Inc., Hoboken New Jersey; p.9-10, 16-17, 19. Page 2 of 2