How to Use Your Scientific Calculator Objectives After completing this activity, the student will be able to: 1. Convert numbers between scientific notation and standard form (decimal notation). 2. Enter scientific notation properly using their exponent key. 3. Understand the mathematical order of operations and properly perform calculations using it. 4. Understand basic algebra concepts. Background One of the most important tools in the arsenal of any scientist or engineer is their scientific calculator. Knowing how to properly use it not only ensures accurate results, but also saves time. This activity will cover a few of the basic calculator functions and underlying mathematical principles. Scientific Notation vs. Standard Form Scientists frequently deal with numbers that are both very large and very small. For example, the distance between two oxygen atoms in O2 is 0.000000000121 meters, while the distance between Earth and the Moon is 384,400,000 meters. Scientific notation is a more compact form that retains significant digits while removing placeholder zeroes. For example, 0.000000000121 meters can also be written as 1.21×10−10 meters, while 384,400,000 meters can be written as 3.844×108 meters. Order of Operations When performing a series of calculations, there is a set of rules that covers the precedence for which operation to perform first. In other words, we don’t simply enter calculations from left to right; rather we prioritize them according to the order of Parentheses followed by Exponents, then Multiplication & Division, and finally Addition & Subtraction. This order is often referred to as PEMDAS. (One way to remember the order is with the mnemonic device, “Please Excuse My Dear Aunt Sally.”) Consider the following example: 94 – (72 + 3 × 8) First, we perform the portion in Parentheses, (72 + 3 × 8). Of the three operations inside the parentheses, we perform the Exponent (72) then the Multiplication (3 × 8) and finally Add them together. 94 – (49 + 3 × 8) 94 – (49 + 24) 94 – (73) Lastly, we perform the Subtraction operation outside the parentheses: 94 – 73 = 21 Distributing in Algebra Distributing means spreading items out equally. Algebraic distribution means to multiply each of the terms within the parentheses by another term that is outside the parentheses. Each term gets multiplied by the same amount. For instance, if we wanted to multiply all of the terms within the following parentheses (b + c + d + e) 1| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. by the term a, where ‘a’ is any real number: positive, negative, integer, or fraction, we would multiply each of the terms inside the parentheses by the term a. a(b + c + d + e) = ab + ac + ad + ae If there is a positive (+) or negative sign (–) they are also distributed. Keep in mind that if a negative is multiplied by a negative the answer will be positive and if a negative is multiplied by a positive the answer will be negative. EXAMPLE 1: Distribute 2 over the terms 4x + 3y – 6 1. Multiply each term by the number(s) and/or variable(s) outside the parentheses 2(4x + 3y – 6) 2(4x) + 2(3y) – 2(6) 2. Perform the multiplication operation in each term. 8x + 6y – 12 EXAMPLE 2: Simplify the expression by distributing and combining like terms: 4x(x – 2) – (5x + 3) 1. Distribute the 4x over the x and the –2 by multiplying both terms by 4x: 4x(x – 2) = 4x(x) – 4x(2) = 4x2 – 8x 2. Distribute the negative sign over the 5x and the 3 by changing the sign of each term: – (5x + 3) = – (+5x) – (+3) = – 5x – 3 3. Combine the like terms: 4x2 – 8x – 5x – 3 = 4x2 – 8x – 5x – 3 = 4x2 – 13x – 3 Solving Equations using Algebra Solving linear equations involves using combinations of multiplication, division, addition and subtraction. Many formulas and equations include a coefficient (multiplier) with the variable. To get rid of the coefficient and solve the equation, you divide. EXAMPLE 1: Solve for x in 20x = 170 1. Determine the coefficient (in this example it is 20) of the variable and divide both sides by it: 20x 170 = 20 20 2. Reduce both sides of the equal sign: x = 8.5 2| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Multiplication is used where a number already divides the variable. Remember that the opposite operation of multiplication is division. EXAMPLE 2: Solve for y in y 11 = −2 1. Determine the value that divides the variable and multiply both sides by it. In this example, 11 is dividing the y, so that’s what you multiply by: y 11 ( ) = (−2)(11) 11 2. Reduce on the left side and multiply on the right: y = –22 The standard form of a linear equation is ax + b = c. In the previous two examples the value of b was 0. If instead b is a value you will solve the equation through addition/subtraction and then multiplication/division. EXAMPLE 3: Solve for z in 3z – 11 = 19 1. To isolate the z term, you add 11 to each side of the equation. The number 11 is chosen, because it is the opposite of –11 and the sum of –11 and 11 is 0. 3y – 11 = 19 + 11 +11 3y = 30 2. Now you have a linear equation (3y = 30) which can be solved by dividing each side of the equation by 3: 3y 30 = 3 3 y = 10 3| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. ACTIVITY PROCEDURE Part I –Scientific Notation A. Entering Scientific Notation First, locate the exponent key on your scientific calculator. It will most likely either be EXP or EE. If you cannot find it on your own, ask a classmate or your professor for help. If your calculator’s exponent key looks like ×10y or similar then you may run in to difficulties below so pay close attention. (Do NOT use the 10x located above the log key as this is antilog and will cause problems in some calculations below.) This exponent key is a shorthand way of entering “× 10 ^”. For example, we can enter 3.4×108 by typing “3 . 4 EXP 8” or “3 . 4 EE 8”. Notice, this saved us 3 keystrokes! But in addition to saving us time, it also prevents errors in the order of operations. Let’s try the following calculation both with and without using the exponent key. 5.12×108 6.5×10−4 Option #1: Without using the exponent key, you might enter: Button* Keystroke 5 1 . 2 1 3 2 4 × 5 1 6 0 7 ^ 8 8 9 ÷ 10 6 11 . 12 5 13 × 14 1 15 0 16 +/− 17 4 18 * Some calculators have yx instead of ^. This gives an answer of 7876.92308. Option #2: Now let’s try it using the exponent key. Button* Keystroke 5 1 . 2 1 3 2 4 EXP 5 8 6 ÷ 7 6 8 . 9 5 10 EXP +/− 11 12 4 13 * Some calculators have EE instead of EXP. This gives an answer of 7.87692×1011. Why the difference? Because your calculator strictly follows the order of operations. It multiplies 5.12 by 108, divides it by 6.5, and then multiplies that by 10−4. In other words, it thinks you meant: 5.12×108 6.5 × 10−4 The exponent key solves this by entering 6.5×10−4 as a single number rather than a series of operations. Not only that, it also saved us 5 keystrokes! 4| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Practice: Solve the following calculations on your scientific calculator, being sure to use the exponent key (EXP or EE) as necessary. 1) 7.1×103 + 4.2×103 = 2) 9.2×10-6 × 3.11×10-3 = 3) 8.27×105 ÷ 5.1×10-4 = 4) 5) 6) 3.2×1032 × 5.1×10−29 7.4×1012 4.17×1014 × 6.8×1025 8.3×10−6 × 3.22×1030 7.3×10−8 × 5.1×1014 6.1×1012 × 2.89×1021 = = = 5| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. When performing metric conversions, you will frequently find yourself using numbers such as 10−2, 10−6, and 103. Some calculators allow you enter this simply as EXP −2, EXP −6, and EXP 3, while others require the number 1 before the EXP or EE key like so: 1 EXP −2, 1 EXP −6, and 1 EXP 6. Practice Solve the following calculations on your scientific calculator, being sure to use the exponent key (EXP or EE) and a 1 as necessary. 103 m 7) 5.11 km × 8) 7.229 × 10−2 pm × 9) 14 dL × 1 km 10−1 L 1 dL × × 1 cm 10−2 m = 10−12 m 1 pm 1 GL 109 L × 1 μm 10−6 m = = B. Switching Between Scientific and Standard Notation Another useful skill on your scientific calculator is learning to switch numbers between standard notation (decimal notation) and scientific notation. Most scientific calculators make this easy with a simple keystroke or two. If you want your calculator to display answers in scientific notation, you will need to enter SCI mode. To display answers in standard notation, you will need to enter FLO mode. (FLO stands for “floating decimal” which causes the decimal point to appear in the normal position rather than always after the first digit.) Work with a classmate to find either the SCI and FLO modes (or keys) on your calculator. Once you’ve found it, try the following calculation: 6.41×108 × 0.037 After obtaining the answer, switch back and forth between SCI and FLO several times. When in SCI you should see 2.3717E7 or 2.3717×107. When in FLO you should see 23,717,000. 6| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Practice: Solve the following calculations on your scientific calculator, being sure to use the exponent key as necessary. Record your answers in both standard notation (FLO) and scientific notation (SCI). 10) 6.38×103 + 1.9×104 = FLO: ____________________ 11) 1.442×10−2 ÷ 7.6×103 = FLO: ____________________ 12) SCI: ____________________ 0.00073 × 0.00499 FLO: ____________________ 13) SCI: ____________________ SCI: ____________________ 8,400,000 ÷ 2.77×10−3 FLO: ____________________ SCI: ____________________ 7| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Part II –Order of Operations Practice Solve the following calculations, being sure to follow the order of operations (PEMDAS). 14) 2 + 3 × 7 – 4 = 15) 5 + (12 − 3) × 2 = 16) 3.1 × 4.2 5.7 × 2.8 = 17) 4 ÷ 22 + 8 × 32 = 18) 27 − 3 × (5 − 3)3 + 5 = 19) 42 + 53 ÷ 24 − (6 + 23)2 = 8| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Part III –Algebra Practice Distribute the following through the terms in the expression given: 20) -1 over the terms in the expression (4x + 2y – 3x +7) 21) a over the terms in the expression(a4 + 2a2 + 3) Solve for x in the following equations: 22) 12x = 300 23) 24) 𝑥 9 4𝑥 5 = 500,000 = 12 3 25) 𝑥 = 4 26) 3x + 10 = 31 27) 2(x + 4) = 8 1 28) 3 (𝑥 + 3) = −9 29) 3(x + 7) = 7(x + 2) 30) 2 – (2x + 1) = 4(x + 2) 9| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Introduction to Measurements EXPERIMENTAL TASK To learn to use a variety of common laboratory equipment while recording measurements with proper significant digits and units. Objectives After completing this experiment, the student will be able to: 1. Identify and use common laboratory equipment. 2. Determine the correct number of significant digits given by a device. 3. Record measurements with proper significant digits and units. Background This lab will give you an introduction to laboratory equipment, performing measurements, and recording data with correct units and significant digits. For any measurement, there is always a degree of uncertainty. Typically, we record all of the digits that we know with certainty plus a single uncertain digit. For example, let’s consider the volume of the liquid in the graduated cylinder to the right. First, note how the top of the liquid is curved. This is called a meniscus and the volume is always recorded at the bottom of the curve. Now, let’s determine which increments we can be certain of. In this case, both the 10’s place (40 mL, 50 mL) and 1’s place (41 mL, 42 mL, 43 mL, etc.) are marked. Therefore, we can be certain that the answer is 43 mL but we must estimate one more uncertain digit. In our case, the bottom of the meniscus appears to be directly on the 43 mark so we could record the volume as 43.0 mL. However, as the last digit is uncertain any reasonably close measurement (within +0.1 mL) would be acceptable (42.9 mL, 43.1 mL). Keep in the mind that you must always estimate one uncertain digit for any measurement that does not provide an exact reading – thermometers, rulers, analog clocks, etc. However, for devices with digital readouts such as analytical balances, digital clocks, or digital thermometers all digits displayed should be recorded. The last digit is still uncertain but the instrument did the estimating for you. Accuracy and Precision Precision is a measure of how consistent a series of measurements are. The more significant digits a device generates, the more precise it is considered because the measurements it produces will be consistently closer to one another. For example, a measurement of 43.0 mL (3 significant digits) is more precise than 43 mL (2 significant digits). This is different from accuracy which is how correct the answer is, or how close to the true value the measurement is. Although the two are frequently confused, they are completely different! For example, a measurement can be very precise without being accurate and vice-versa. (You can be consistently wrong – precise but inaccurate!) 10| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Density Density is the ratio of a substance’s mass to its volume. The density of liquids and solids is typically recorded in units such as g/mL or g/cm3, while the density of gases generally has units of g/L. Remember that 1 mL = 1 cm3. EXPERIMENT PROCEDURE Part I –Recording Measurements A. Mass Measurements 1. Determine the mass of a 250-mL beaker on an analytical balance. Be sure to “zero” or tare the balance before each measurement. 2. Determine the mass of a watch glass on an analytical balance. 3. Determine the mass of a 125-mL Erlenmeyer flask on an analytical balance. B. Volume Measurements I 1. Fill a 100-mL graduated cylinder with water until the bottom of the meniscus (curve in the upper part of the water) is exactly on the 100 mL mark. Record the volume. 2. Fill a 13×100 mm test tube with water from the graduated cylinder. Record the new volume in the graduated cylinder. 3. Fill a second test tube with water from the graduated cylinder. Record the volume in the graduated cylinder. C. Volume Measurements II 1. Fill a burette with water until the bottom of the meniscus is exactly on the 0 mL mark. Record the initial reading. 2. Dispense approximately 10 mL into a 125-mL Erlenmeyer flask. Record the new burette reading. 3. Dispense approximately 5 mL into the same 125-mL Erlenmeyer flask. Record the new burette reading. 11| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. D. Temperature Measurements 1. Half fill a 250-mL beaker with deionized water. Record the temperature of the water in Celsius using a thermometer. 2. Add ice to the beaker until the beaker is approximately two-thirds full. Hold the thermometer in the ice water and record the coldest observed temperature. 3. Empty the beaker and half-fill it again with deionized water. Place the beaker on a ring stand with an iron ring and wire gauze. The beaker should be approximately six inches above the Bunsen burner. Heat the water using a Bunsen burner to boiling then shut off the burner. Hold the thermometer in the water and record the hottest temperature. Part II –Density For this part of the experiment, we will record the volume by two different methods. First, we will take measurements using a ruler and calculate the volume using the appropriate formula (Direct Measurement). Then we will take the unknown and place it in a graduated cylinder containing a known amount of water (Displacement). 1. Obtain an unknown metal solid of any regular shape (rectangle, cylinder, or sphere). 2. Find the mass of the unknown metal solid on an analytical balance. 3. Using a metric ruler, take appropriate measurements to determine the volume of the unknown metal solid. Record all measurements in centimeters but still with proper significant digits. 4. Calculate the volume by direct measurement using the appropriate formula. a. Volume of a rectangular solid = length × width × height b. Volume of a cylinder = πr2h 4 c. Volume of a sphere = 3 𝜋r 3 5. Next, we will measure the volume of the unknown metal solid by displacement. Half-fill a 100-mL graduated cylinder and record the initial volume. 6. Tilt the graduated cylinder to a 45° angle and slowly add the unknown metal solid to the graduated cylinder. Record the final volume. 7. Calculate the volume by displacement by subtracting the initial volume from the final volume. 12| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Name: ______________________________ Date: _________________ Lab Partner: _________________________ Section: _______________ DATA, OBSERVATIONS, and RESULTS Record all measurements with proper significant digits and units. Part I –Recording Measurements A. Mass Measurements Mass of 250-mL beaker __________________ Mass of watch glass __________________ Mass of 125-mL Erlenmeyer flask __________________ B. Volume Measurements I Initial volume of water in graduated cylinder __________________ Volume minus one test tube of water __________________ Volume minus two test tubes of water __________________ C. Volume Measurements II Initial burette reading __________________ Burette reading after dispensing ~10 mL of water __________________ Burette reading after dispensing ~5 mL of water __________________ 13| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. D. Temperature Measurements Temperature of deionized water __________________ Temperature of deionized water and ice __________________ Temperature of boiling water __________________ Part II –Density Mass of unknown metal solid __________________ Measurements of unknown metal solid (in centimeters) (May include length, height, diameter, etc. as necessary) __________________ __________________ __________________ Calculate the volume of your unknown solid (Show work below) __________________ Initial volume of graduated cylinder __________________ Final volume of graduated cylinder plus unknown metal solid __________________ Volume of unknown metal solid (final – initial) __________________ Temperature of water __________________ 14| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Name: Date: Lab Partner: Section: POST−LABORATORY QUESTIONS Show all work. Give all answers with proper significant digits and units. 1. Calculate the density of your unknown metal solid using the volume found by direct measurement. _______________ g/cm3 2. Calculate the density your unknown metal solid using the volume found by displacement. _______________ g/mL 3. Which method do you think gave a more precise (not necessarily accurate) result – direct measurement or displacement? Explain your reasoning. 4. State the number of significant digits in each of the following measurements. o 5.00 ºC __________ o 0.03 cm __________ o 10.000 g __________ o 0.450 mL __________ 15| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept. Name: Lab Partner: Date: Section: PRE−LABORATORY ASSIGNMENT Answer the following questions BEFORE coming to lab. You will not be allowed to participate in lab unless ALL questions are complete. Show all work. Give all results with proper significant digits. 1. Sketch a beaker, an Erlenmeyer flask, a watch glass, and a graduated cylinder. Label each drawing. 2. Record the length of the line below using proper significant digits and units. Length of line: _________________ 3. A graduated cylinder contains 37.5 mL of water. A lump of iron with a mass of 45.38 g is dropped into the graduated cylinder and the water level rises to 43.3mL. What is the density of the iron sample? (Show work below.) 16| Scientific Calculator; Intro to Measurements © 2019 MiraCosta Chemistry Dept.