Balancing Chemical Equations What goes in must come out! Objectives At the end of the lesson, the learners will be able to: 1. carry an investigation to determine if mass is conserved in chemical reactions; 2. mathematically proved that matter is conserved in chemical reactions by balancing chemical equations; and 3. write and balance chemical equation. Balancing Chemical Equations Balancing a chemical equation is much like the work of an accountant who has to show every penny that comes in and where it has gone to. Law of Conservation of Mass You need to remember this law! The Law of Conservation of Mass states: that mass is neither created nor destroyed in any chemical reaction. Therefore balancing of equations requires the same number of atoms on both sides of a chemical reaction. The number of atoms in the Reactants must equal the Number of atoms in the Products Law of Conservation of Mass The mass of all the reactants (the substances going into a reaction) must equal the mass of the products (the substances produced by the reaction). Reactant + Reactant = Product Chemical Equations Because of the principle of the Conservation of Matter, an equation must be balanced. It must have the same number of atoms of the same kind on both sides. Lavoisier, 1788 REACTANTS PRODUCT Reactants - the starting materials, substances that changes when it is combined with another substance in a chemical reaction Product - the new substance. The substance that result of a chemical reaction. Other components of an equation Coefficient - is the number before a symbol or formula of a substance Subscript - is the number of atoms of the element found below the substance. Steps in Balancing an Chemical Equation 1. Count atoms of each element on the two side of the equation. 2. Determine which atoms needs to be balance . 3. Balance element one at a time by placing the correct coefficient in front of the chemical formula. Note that you can CHANGE the coefficient BUT NOT the subscript. Steps to Balancing a Chemical Equation 4. Multiply the coefficient of each element by the subscript of the element to count the atoms. Then list the number of atoms of each element on each side. 5. Recheck the number of atoms in the two sides of the equation. Repeat if there are discrepancies in the result. BALANCE CHEMICAL EQUATION are those whose coefficients result in equal numbers of atoms for each element in the reactants and products. Balancing Chemical Equations An easier way First you need an equation with the correct “formulae” ………. You’ll probably be given this in the question Just like this one Mg + O2 MgO Then all you do is list the atoms that are involved on each side of the arrow Mg + O2 MgO Mg O Mg O Then start balancing: [1] Just count up the atoms on each side Mg + O2 MgO 1 Mg 1 2 O 1 [2] The numbers aren’t balanced so then add “BIG” numbers to make up for any shortages Mg + O2 2 MgO And adjust totals 1 Mg 1 2 2 O 1 2 But the numbers still aren’t equal, so add another “BIG” number 2 Mg + O2 2 MgO 2 1 Mg 2 2 O 2 And adjust totals again NOW BOTH SIDES HAVE EQUAL NUMBERS OF ATOMS WE SAY THAT THE EQUATION IS BALANCED!! LETS PRACTICE ! NH2 + O2 NO + H2O BaSO4 + NaCl Na2SO4 + BaCl2 CaCO3 + H3PO4 Ca3(PO4 ) 2 + CO2 + H2 O 2. Al + HCl AlCl3 + H2 3. (NH4)2 Cr2O7 Cr2 O3 + N2 +H2O 4. CaCO3 + H3 PO4 Ca3 (PO4 )2 + CO2 + H2O 5. NaClO3 NaCl +O2 Mole Relationship in a Chemical Reaction Objective At the end of the lesson, you should be able to: to define a mole and molar mass 2) determine the molar mass of elements and compounds 3) determine whether your results support the Law of Conservation of Matter 1) MOLE RELATIONSHIP IN CHEMICAL EQUATION In all the chemical reactions that you studied, you balance all the equations in terms of number of atoms and molecules in the reaction. The coefficients in the balanced equation give the ratio of moles of reactants and products What is a Mole/ mol ? A mole (symbol, mol)is defined as the amount of a substance containing the same number of representative particles like atoms, molecules, ions or formula units. The mole is the SI (International System) unit for amount of substance. Mole/ mol a mole of a substance contains 6.022141 x 1023 representative particles. The number 6.02 x1023 is called Avogadro’s Number, in honor of Amadeo Avogadro. What is Molar mass? Molar mass is defined as the mass in grams of 1 mole of atoms or molecules of a substance. For instance, one mole of Carbon atoms has 1 molar mass of C is equal to 12 grams (or amu). Molecular Mass Molecular mass (also known as molecular weight) is the sum of the atomic mass of each atom in a molecule, multiplied by the number of atoms of that element in the molecule. Example; Water (H2O) Element H O No. of Atom 2 1 Atomic mass X 1.0 = 2.0 g X 16.0 = 16.0 g molar mass =18.0 g/mol Example # 2 Find the molar mass of glucose (C6H12O6) ELEMENT C H O NO. OF ATOMS 6 12 6 ATOMIC MASS X 12.0 g = 72.0 g X 1.0 g = 12.0 g X 16.0 g = 96.0 g molar mass: 180.0 g/mol thus, a mole of glucose weighs 180.0 grams Example # 3 Find the molar mass of Ca(PO4)2 ELEMENT NO. OF ATOMS ATOMIC MASS Ca P O 1 x 40.0 g = 40.0 g 1 (2) = 2 x 31.0 g = 62.0 g 4 (2) = 8 x 16.0 g = 128.0 g molar mass : 230.0 g/mol Calculate Molar mass Ex. 4NH3 + 5O2 4NO + 6H2O Calculate Molar mass 2 Li + 2 HNO3 2 LiNO3 + H2 1. Fe (OH)3 + H2 SO4 Fe2 (SO4 ) 3 + H2O Balancing Practice For more help go to: http://richardbowles.tripod.com/chemistry/bal ance.htm#part0 For some fun balancing equations go to: http://www.mpcfaculty.net/mark_bishop/bala ncing_equations_tutorial.htm THANK YOU! Try to balance these equations and calculate the molar mass. [1] Na + Cl2 NaCl [2] CH4 + O2 CO2 + H2O [3] Li + HNO3 LiNO3 + H2 [4] Al + O2 Al2O3