Review Questions electrons in atoms Multiple-choice exercise Use these values to assist you in answering some of the questions in this problems set: h = 6.626 x 10-34J·sec c = 2.9979 x 108 m/sec Show questions one by one 1. Researchers at Lawrence Berkeley National Lab have recently formed a new synthetic element with atomic number 118 and mass number 293. Which of the following elements would have chemical properties most similar to this new element? A. ? Xe B. ? Ir C. ? S D. ? Pb E. ? Ta 2. Which of the following relationships is incorrect with regard to electromagnetic radiation? A. ? none of these B. ? longer wavelength = higher energy C. ? longer wavelength = lower frequency D. ? higher frequency = higher energy E. ? all of these 3. Which of these elements would have the highest second ionization energy? A. ? hydrogen B. ? potassium C. ? calcium D. ? fluorine E. ? sulfur 4. An element Z has the configuration [Xe]6s2. The oxide of this element will have the formula: A. ? Z2O B. ? None of these C. ? ZO D. ? ZO2 E. ? Z2O3 5. Excluded Which of the following combinations of quantum numbers is not allowed? A. ? n = 3, l = 1, m(l) = 1, m(s) = ½ B. ? n = 1, l = 0, m(l) = 1, m(s) = ½ C. ? n = 4, l = 2, m(l) = 0, m(s) = ½ D. ? n = 5, l = 3, m(l) = -2, m(s) = -½ E. ? n = 2, l = 1, m(l) = -1, m(s) = -½ 6. An element having the configuration [Xe]6s1 belongs to the Group: A. ? halogens B. ? alkaline earth metals C. ? noble gases D. ? None of these E. ? alkali metals 7. Excluded For which of the following transitions does the light emitted have the shortest wavelength? A. ? n = 4 to n = 2 B. ? n = 2 to n = 1 C. ? n = 3 to n = 2 D. ? n = 4 to n = 3 E. ? n = 5 to n = 3 8. Which of the following statements are true? A. B. C. D. E. ? The first ionization energy of fluorine is greater than the first ionization energy of oxygen. ? All are false ? As the atomic number increases within a group of the representative elements, the tendency is for first ionization energy to increase. ? It is easier to remove an electron from Na+ than from Na. ? All particles with the electron configuration [Ar]4s2 have the same ionization energy. 9. How many unpaired electrons are there in an atom of tin in its ground state? A. ? 0 B. ? 2 C. ? 1 D. ? 4 E. ? 3 10. Excluded How many electrons in an atom can have n = 5, l = 3? A. ? None of these B. ? 14 C. ? 2 D. ? 10 E. ? 6 11. Which of the following forms of electromagnetic radiation has the shortest wavelength? A. ? infrared B. ? ultraviolet C. ? radio waves D. ? visible light E. ? microwaves 12. Which of the following atoms would experience the greatest energy loss when gaining an electron? A. ? N B. ? Mg C. ? Na D. ? Cl E. ? Li 13. Which of the following particles has the greatest atomic radius? A. ? S B. ? Al3+ C. ? Si D. ? Al E. ? P 14. How many electrons can fit in all of the orbitals in which n = 3? A. ? 18 B. ? 14 C. ? 32 D. ? 6 E. ? 2 15. Which of these elements has three electrons in degenerate orbitals? A. ? Pd B. ? Po C. ? Hg D. ? Si E. ? P 16. How many f orbitals have n = 3? A. ? 3 B. ? 0 C. ? 5 D. ? 7 E. ? 1 17. What is the wavelength of a photon whose frequency is 3.90 x 10 14 Hz? A. ? 4.51 nm B. ? 769 nm C. ? 1.27 x 10-3 D. ? 7.69 x 10-7 nm E. ? 1.30 x 105 nm 18. Of the following elements, which one is most likely to form an ion through the loss of two electrons? A. ? strontium B. ? aluminum C. ? sulfur D. ? chlorine E. ? sodium 19. A photon has a frequency is 3.90 x 1014 Hz. What is the energy of the photon? A. ? 1.13 x 1019 J B. ? 9.08 x 10-3 J C. ? 4.75 x 10-16 J D. ? 2.60 x 10-19 J E. ? 4.75 x 1016 J 20. Each electron in an atom has a unique set of four quantum numbers. This observation is credited to: A. ? Hund B. ? Bohr C. ? Heisenberg D. ? Pauli E. ? Mendeleev