This session will be recorded. MMAN2700: Thermodynamics Dr Irene Renaud-Assemat Please type any questions in the chat, I will answer them during the Q&A sessions PollEv.com/irenerenauda439 – Use your mobile phone Prepare a pen, paper and a calculator We will start at 5 past the hour to give everyone time to arrive. 1 Thermodynamics MMAN2700 Irene Renaud-Assemat i.renaudassemat@unsw.edu.au Room 208C Ainsworth Building J17 Who am I? MSc in Mechanical Engineering 2005 Teaching associate 2006-2011 PhD in Fluid Dynamics 2011 Teacher in High School 2011-2014 Lecturer in Mechanical Engineering 2014 - 2020 Senior Lecturer Mechanical Engineering 2020-present 3 TODAY How the topic will be delivered What is Thermodynamics Early engines A problem solving template Topic 1: Systems and Energy / Heat and Work 4 https://PollEv.com/irenerenauda439 5 6 7 Course organisation 8 Intended learning outcomes At the end of this course, you should be able to: Demonstrate knowledge of key concepts of thermodynamics Apply the 1st and 2nd law of thermodynamics to solve steady-state problems on closed and open systems, and to analyse the behaviour of cycles Carry out, on working machinery, measurements of thermodynamic and mechanical properties, and identify links between theoretical analysis methods and actual performance 9 Demonstrators Zhao Sha Tracey Nguyen Mohamed Mahmoud Ryan Zi Seng Chuah Justin Chuwardi Mobarak Hossain Guang Li 10 Course contents Topic 1: Systems and Energy • Heat and Work • 1st law in closed systems • Internal energy Topic 4: 1st law in open systems • Steady flow • Applications Topic 5: 2nd law of thermodynamics • Entropy • Applications Revisions Topic 2: Energy balances Laboratories • • • • • Thermoboards • Compressor rig Ideal gases Enthalpy Moving boundary work Isentropic and polytropic processes Topic 3: Properties of pure substances Timetable – Teaching activities Week 1 Wed 12-2pm; Thu 12-2pm Lectures: Topic 1 Week 2 Lectures: Topic 2 Example class Week 3 Lectures: Topic 2 Example class Quiz 1 (10%) Week 4 Lectures: Topic 3 Example class Lab 1 Week 5 Lectures: Topic 3 Example class Quiz 2 (10%) Week 6 Guest Lecture (Friday 24/03 2-4pm) Example class Week 7 Lectures: Topic 4 Example class Mid-term quiz (30%) Quiz 3 (10%) Week 8 Lectures: Topic 5 Example class Lab 2 Week 9 Lectures: Topic 5 Example class Week 10 Lectures: Revisions Example class 12 How the unit runs Assessment Support Laboratories – 2 x 15% 3 Quizzes (Wednesday in weeks 3, 5 and 7 at 6pm) – 3 x 10% Final exam – 40% Email: i.renaudassemat@unsw.edu.au Demonstrators Textbooks G.F.C Rogers & Y. Mayhew, Thermodynamics and Transport properties of fluids, SI units, 5th edition, Blackwell publishing Y.A. Cengel, M.A. Boles & M. Kanoglu, Thermodynamics: An engineering approach, 9th edition in SI units, McGraw Hill education 13 Course communication Microsoft Teams For communication: Please check Teams regularly for any important announcements Post your questions in the relevant channel. Expect a response within one business day Teaching material is uploaded on Moodle For assessment You can contact me by email, I will do my best to reply within one business14day Q&A 15 What is thermodynamics? “the branch of physics that is concerned with the relationship between heat and other forms of energy” Collins Dictionary (online) Thermo dynamics Heat 16 Work / movement Early engines 17 The problem This Photo by Unknown Author is licensed under CC BY-NC-ND This Photo by Unknown Author is licensed under CC BY-SA 18 Evolution of steam engines – the industrial revolution Savery mine pump, late 17th century + No moving parts - Machining limitations so only worked to ~10m depth - Needed to cool cylinder – intermittent working - wasted energy in re-heating cylinder each cycle 19 Egg experiment https://www.youtube.com/watch?v=6R215vLf29w 20 Newcomen atmospheric engine, early 18th century Injected water to cool steam Could replace 500 horses + not limited by depth as it drove an old-style pump in the mine - still wasted energy re-heating the cylinder after injection of cold water each cycle http://www.animatedengines.com/newcomen.html 21 Watt steam engine, late 18th century Separate condenser from boiler >3 times more efficient 22 The principles (Flanders & Swann Lyrics) “The 1st law of thermodynamics Heat is work and work is heat…” “The second law of thermodynamics Heat cannot of itself pass from one body to a hotter body” http://www.youtube.com/watch?v=VnbiVw_1FNs&t=2m7s Thermodynamics: heat and work 23 First and Second Law by an old comedy duo, Flanders and Swann The first law of thermodynamics: Heat is work and work is heat. Heat is work and work is heat. Very good. The second law of thermodynamics: Heat cannot of itself pass from one body to a hotter body. Heat cannot of itself pass from one body to a hotter body. Heat won't pass from a cooler to a hotter. Heat won't pass from a cooler to a hotter. You can try it if you like but you far better not-er! You can try it if you like but you far better not-er! 'Cause the cold in the cooler will get hotter as a rule-r, 'Cause the cold in the cooler will get hotter as a rule-r, Because the hotter body's heat will pass to the cooler 'Cause the hotter body's heat will pass to the cooler First Law: Heat is work and work is heat and work is heat and heat is work. Heat will pass by conduction. Heat will pass by conduction. Heat will pass by convection. Heat will pass by convection. Heat will pass by radiation. Heat will pass by radiation. And that's a physical law! Heat is work, and work's a curse And all the heat in the universe Is gonna cool down 'Cause it can't increase Then there'll be no more work And there'll be perfect peace Really? Yeah, that's entropy, man! And all because of the second law of thermodynamics, which lays down: That you can't pass heat from a cooler to a hotter Try it if you like but you far better not-er 'Cause the cold in the cooler will get hotter as a rule-r 'Cause the hotter body's heat will pass to the cooler Oh, you can't pass heat from the cooler to the hotter You can try it if you like but you'll only look a fool-er 'Cause the cold in the cooler will get hotter as a ruler And that's a physical law... Oh, I'm hot! Hot? That's because you've been working! Oh, Beatles nothing! And that's the first and second law of thermodynamics! 24 A problem solving template 1. State the problem 2. Draw a relevant diagram and label it 3. Write down any assumptions 4. Write down any physical laws or equations 5. Write down any properties 6. Do the calculation 7. Discuss the answer 25 A problem solving template 1. State the problem 2. Draw a relevant diagram and label it 3. Write down any assumptions 4. Write down any physical laws or equations 5. Write down any properties 6. Do the calculation 7. Discuss the answer A cylindrical vessel has a diameter of 2 inches and a length of 2m. If it is filled with water (density 1g/cm3) calculate the mass of liquid in the vessel. 26 A problem solving template 1. State the problem 2. Draw a relevant diagram and label it 3. Write down any assumptions 4. Write down any physical laws or equations 5. Write down any properties 6. Do the calculation 7. Discuss the answer A cylindrical vessel has a diameter of 2 inches and a length of 2m. If it is filled with water (density 1g/cm3) calculate the mass of liquid in the vessel. 27 Q&A 28 Topic 1: Systems and Energy 29 Contents System and its properties (definitions) Work and Heat 30 Systems and its properties 31 System and boundaries System: “a set of connected things or devices that operate together” Cambridge Dictionary (online) Surroundings System System boundary 32 Open and closed Closed No transfer of material between system and surroundings Open Material can be transferred between system and surroundings Systems - examples Closed system with a moving boundary Closed system – control mass Isolated system Open system – control volume E.g. compressors, pumps, turbines, heat exchangers… 34 Properties of a system 6 state properties: Temperature, T Pressure, p Density, 𝜌𝜌 (or specific volume v) Internal energy, u Non-capital letters mean ‘per unit mass’, or ‘specific’ Enthalpy, h E.g. specific volume (𝑚𝑚3 /𝑘𝑘𝑘𝑘) = 1/density Entropy, s “A quantity is a property if its change in value between 2 states is independent of the process” (Moran & Shapiro, 2008) 35 36 37 38 Pressure Force per unit area – SI unit: N/m2 (or Pa) Other units: bar, psi, mmHg… Isotropic – equal in all directions Gauge pressure vs absolute pressure 𝑃𝑃𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔 = 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 − 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 = 𝑃𝑃𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔 + 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 Isotropic 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 = 𝜌𝜌𝐻𝐻𝐻𝐻 𝑔𝑔𝑔 where 𝜌𝜌𝐻𝐻𝐻𝐻 is the density of mercury, g is the local gravitational acceleration and h is the height of the mercury column above the free surface barometer Negative pressure?? Absolute: p=0 → vacuum Standard atmospheric pressure: 1atm = 1.013bar 1 bar = 105 Pa Barometer 39 40 41 42 Temperature Temperature scales: Celsius, Fahrenheit scales depend on material and 2 datum points Thermodynamic temperature scale: Kelvin (no dependence on particular substance) 𝑇𝑇 𝐾𝐾 = 𝑇𝑇 °𝐶𝐶 + 273.15 Thermal equilibrium 0th law “If 2 bodies are in thermal equilibrium with a 3rd body, they are also in thermal equilibrium with each other” or “2 bodies at the same temperature are at thermal equilibrium”’ Freezing point of water Boiling point of water A C B 43 Equilibrium and the state postulate Equilibrium: a system is in a state of equilibrium (or balance) if no changes occur in any of the macroscopic properties of the system State postulate: 2 independent intensive properties are required to specify the state of a system e.g. e.g. {p,T} → {ρ, 𝑢𝑢, ℎ, 𝑠𝑠} ideal gas law 𝑝𝑝𝑝𝑝 = 𝑚𝑚𝑚𝑚𝑚𝑚 44 Intensive vs extensive Extensive depends on system size, i.e. extent of the system m (kg), V (m3), U (kJ), H (kJ), S (kJ/K) Intensive is independent of system size T (K), p (kN/m2), v (m3/kg) 45 Can transform extensive to intensive: 𝑉𝑉 1 𝑚𝑚3 v= = 𝑚𝑚 𝜌𝜌 𝑘𝑘𝑘𝑘 𝑈𝑈 𝑘𝑘𝑘𝑘 𝑢𝑢 = 𝑚𝑚 𝑘𝑘𝑘𝑘 46 Process Equilibrium: all forces balanced and temperatures equal Process: changes system from one equilibrium state to another Path: can be plotted on process diagram Quasi-equilibrium process: very close to equilibrium along the path Infinitesimally small driving force or temperature difference 47 Q&A 48 Start problem sheet 1: Systems and Energy You should be able to answer the foundation questions and standard questions up to question 8. What to do next Write up your notes Next lecture tomorrow at 12pm Heat and Work 1st law of thermodynamics in closed systems Post your questions on Teams in the specific channel AENG10003: Engineering Science 1: Thermofluids 49 50 Q&A 51