Name Date Class THE BEHAVIOR OF GASES Chapter Test B A. Matching Column A 1. At constant volume and temperature, the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of the component gases. 2. The volume of a fixed mass of gas is directly proportional to its Kelvin temperature if the pressure is kept constant. Column B a. combined gas law b. ideal gas constant (R) c. diffusion 3. The rate of effusion of a gas is inversely proportional to the square root of its molar mass. d. compressibility 4. the contribution each gas in a mixture makes to the total pressure of that mixture e. Boyle’s law 5. a measure of how much the volume of matter decreases under pressure f. partial pressure 6. For a given mass of gas at constant temperature, the volume of the gas varies inversely with pressure. 7. the tendency of particles to move toward areas of lower concentration until the concentration is uniform throughout P ×V P ×V 8. 1 1 = 2 2 T1 T2 9. the escape of a gas through a tiny hole in a container of gas 10. 8.31 (L·kPa) / (K·mol) g. Dalton’s law of partial pressures h. effusion i. Charles’s law j. Graham’s law of effusion B. Multiple Choice 11. Reducing the volume of a contained gas by one third, while holding temperature constant, causes pressure to a. be decreased by two thirds. b. be increased by two thirds. c. be decreased by one third. d. be increased by one third 12. Which of the following would double the pressure on a contained gas at constant temperature? a. doubling the volume of the container b. halving the number of particles in the container c. doubling the number of particles in the container d. none of the above 13. A gas occupies a volume of 2.50 L at a pressure of 350.0 kPa. If the temperature remains constant, what volume would the gas occupy at 1750 kPa? a. 5.00 L c. 12.5 L b. 0.500 L d. 1.40 × 102 L 14. If the temperature of a gas in a closed container increases a. the pressure of the gas decreases. b. the average kinetic energy of the molecules decreases. c. the molecules collide with the walls of the container less frequently. d. the pressure of the gas increases. 15. Absolute zero is a. –273.15°C. b. the lowest possible temperature. c. the temperature at which the average kinetic energy of particles would theoretically be zero. d. all of the above 16. The graph of several pressure-volume readings on a contained gas at constant temperature would be a. a straight line. c. a horizontal line. b. a curved line. d. a vertical line. 17. At constant pressure, the volume of a fixed mass of gas and its Kelvin temperature are said to be a. directly related. c. unrelated. b. inversely related. d. constant. 18. The temperature of 6.24 L of a gas is increased from 25.0°C to 55.0°C at constant pressure. The new volume of the gas is a. 13.7 L. c. 6.87 L. b. 5.67 L. d. 2.84 L. 19. A temperature of –25°C is equivalent to: a. 248 K. c. –25 K. b. 25 K. d. 298 K. 20. A sample of chlorine gas has a pressure of 7.25 kPa at 20.0°C. What will its pressure be at 60.0°C if its volume remains constant? a. 2.42 kPa c. 21.8 kPa b. 8.24 kPa. d. 6.38 kPa 21. If a sample of oxygen occupies a volume of 2.15 L at a pressure of 58.0 kPa and a temperature of 25°C, what volume would this sample occupy at 101.3 kPa and 0°C? a. 1.35 L c. 4.10 L b. 1.13 L d. 3.44 L 22. The volume (in L) that would be occupied by 5.00 mol of O2 at STP is a. 0.411 L. c. 41.6 L. b. 22.4 L. d. 112 L. 23. How many moles of H2 would be contained in 4.0 L of the gas at 202.6 kPa and 127°C? a. 89.6 mol c. 0.24 mol b. 6.38 mol d. 0.77 mol C. Problems Solve the following problems in the space provided. Show your work. 27. A sample of hydrogen occupies a volume of 1.20 L at a pressure of 425 kPa. If the temperature of the gas is kept constant, what would the new volume of the gas be at 615 kPa? 28. A sample of nitrogen occupies a volume of 0.650 L at 20.0°C. What volume would the gas occupy at 40.0°C if the pressure remains constant? 29. The temperature of a sample of helium at 85.0 kPa is 37°C. If the volume of the gas remains constant, at what temperature (in °C) would the pressure of the gas be at 98.0 kPa? 30. If a sample of oxygen gas occupies a volume of 3.50 L at 57°C and 80.0 kPa, what volume would the gas occupy at STP? 31. How many grams of CO2 would be contained in 8.0 L at 152 kPa and 27°C? D. True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 33. Doubling the number of particles of gas in an inflated tire doubles the pressure of the gas in the tire. 34. Halving the Kelvin temperature of a gas in a rigid container decreases the gas pressure by one half. 35. The graph of a relationship between variables that is directly proportional is a straight line. 36. At constant volume, if the Kelvin temperature of a gas is doubled, the pressure of the gas is halved.