PHYSICS NAME OF LEARNER: Thermodynamics SECTION: Topic: 1st Law of Thermodynamics Content Standards The learners demonstrate understanding of 1st law of thermodynamics. Performance Standards The learners should be able to solve, using experimental and theoretical approaches, multi-concept, rich-content problems. DATE: Learning Competencies (MELCS) State the relationship between changes internal energy, work done, and thermal energy supplied through the First Law of Thermodynamics. (STEM_GP12GLTIIh-62) Learning Outcomes SCORE: distinguish the relationship among internal energy, work done, and thermal energy (heat) using the 1st Law of Thermodynamics; perform a virtual laboratory activity using a simulation to justify the statements of the 1st Law of Thermodynamics. Prepared by: JONATHAN B. JULITO MA in Phyics Education Introduction THERMODYNAMICS Thermodynamics is the study of the relations between heat, work, temperature, and energy. The laws of thermodynamics describe how the energy in a system changes and whether the system can perform useful work on its surroundings. Heat and Internal Energy Internal Energy is all the energy of a system that is associated with its microscopic components - atoms and molecules. This energy includes the following - random rotational and vibrational motion of molecules, potential energy within and between molecules. Heat is the transfer of energy across the boundary of a system due to a temperature difference between the system and its surroundings. In our study, we will mostly consider the interaction of energy of a system with its surrounding. The diagram on the right shows the difference of a system from surroundings and how it is found inside one universe. The system, like the flask and the cylinder, holds energy. This energy may transfer from the system to the surroundings through heat. This happens when the system has a higher temperature compared to the surroundings. Heat may also move from the surroundings to the system when it has higher temperature compared to the system. Warm it up! Instructions: You have learned all about the methods of heat transfer. Lets us have a quick recall of these concepts! Study the diagram below and identify whether convection, radiation or conduction process is present. Introduction When heat is transferred, there will changes in the temperature. Like in the figure above, the blue block will have increase in temperature upon the transfer of energy from the red block. This change in temperature would commonly indicate a change in the internal energy. However, there are also instances wherein energy is transferred by heat without changing the temperature. This occurs through compression or expansion of materials such as gas. This transfer of energy is achieved through work. WORK It is the measure of energy transfer that occurs when an object is moved over a distance by an external force at least part of which is applied in the direction of the displacement. Work done Work done on a system - the measure of energy transferred from the surroundings to the system Work done by the system - the measure of energy transferred from the system to the surroundings Remember that energy comes in different forms and one of which is the mechanical energy. This energy is composed of the kinetic and potential energy which is produced due to the motion and configuration of the system. Application of concept What enables the hot air balloons to fly? Write a brief explanation below. ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ___________________________________________________________ ______________________________________________ Explore The First Law of Thermodynamics states that energy can be converted from one form to another with the interaction of heat, work and internal energy, but it cannot be created nor destroyed, under any circumstances. Mathematically, this is represented as: ΔU=q+w Virtual Laboratory Activity: Energy, Heat and Work Objectives: At the end of this activity, you will be able to: use a PHET simulation on the 1st Law of Thermodynamics; distinguish the relationship between heat, work and internal energy of a system using PHT simulation; Materials: PHET simulation (access via application or online) pen and paper PHET Simulation: Explore Virtual Laboratory Activity: Energy, Heat and Work Procedure: Part A 1. Ready a clean piece of paper and a ballpen. 2. Open the PHET simulation on the 1st Law of Thermodynamics. 3. Study how you will use the PHET simulation. Use the guide below. 4. This little guy represents the "work" involved in the simulation. If you push the handle to the right, the surroundings is doing work on the system, If the little guy is pushed back, the system of gas is doing work on the surroundings. 5. Thermometer indicates increase or decrease temperature in the system. the in 2. Click on the handle of the pump and pull up to introduce gas in the container. 6. Gauge measures the pressure in the container. 1. Press Measurement Tools to activate the ruler for the container. 3. Move the blue arrow up to add heat and down to remove heat. Notice that the simulation will show fire and ice, respectively. Part B 1. Pump gas into the container until the initial temperature reaches 300K. 2. Observe the measurement of the pressure when the gas was introduced. a. Guide Question 1: Did the pressure increase or decrease? Explain. _________________________________________________________________________________ _____________________________________________________________________________ 3. Add heat on the system. a. Guide Question 2: What happened to the pressure in the container? b. Guide Question 3: What happened to the temperature in the container? Explain. _________________________________________________________________________________ _____________________________________________________________________________ c. Guide Question 4: What happened to the volume of the gas? Is the work done by the system or on the system? Explain. _________________________________________________________________________________ _____________________________________________________________________________ 4. Remove heat from the system. (Move blue arrow down). a. Guide Question 5: What happened to the pressure in the container? b. Guide Question 6: What happened to the temperature in the container? Explain. _________________________________________________________________________________ _____________________________________________________________________________ c. Guide Question 7: What happened to the volume of the gas? Explain. _________________________________________________________________________________ _____________________________________________________________________________ Explore Virtual Laboratory Activity: Energy, Heat and Work Procedure: 5. Move the yellow handle to the right. h. Guide Question 8: What happened to the pressure in the container. Explain. ___________________________________________________________________________________________ ___________________________________________________________________ i. Guide Question 9: What happened to the temperature in the container? Explain. ____________________________________________________________________________________________ __________________________________________________________________ j. Guide Question 10: Is work being done on the system or done by the gas system? Explain. ____________________________________________________________________________________________ __________________________________________________________________ Conclusion: Based on the activity, how are heat, work and internal energy related with each other? _______________________________________________________________________________________________ _______________________________________________________________________________________________ 3. Move the blue arrow up to _______________________________________________________________________________________________ add heat and down to remove heat. Notice that the _______________________________________________________________________________________________ simulation will show fire and ice, respectively. _______________________________________________________________________________________________ References 1st Law of Thermodynamics. (2013, October 2). Retrieved October 22, 2021, from Chemistry LibreTexts website: https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Text book_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Thermo dynamics/The_Four_Laws_of_Thermodynamics/First_Law_of_Thermodynamics G as Properties. (2021). Retrieved October 22, 2021, from Colorado.edu website: https://phet.colorado.edu/sims/html/gas-properties/latest/gas-properties_en.html R ichardson, M. (2012). First law of Thermodynamics with PHET [YouTube Video]. Retrieved from https://www.youtube.com/watch?v=DlyBaIy6Zj4