MAY 10, 2022 Blending Hydrogen into the Gas Grid: What Are the Impacts Behind-the-Meter? Paul Glanville, PE—R&D Director, Building Energy Efficiency Kristine Wiley—Vice President, Hydrogen Technology Center LOW-CARBON, LOW-COST ENERGY INNOVATION ©2022 GTI Energy. All rights reserved. 2 A Few Production Notes Before We Begin • Your microphone is automatically muted, and your camera is off as an attendee in a Zoom Webinar • We are recording this webinar for future viewing • Use the Q&A button at the bottom of your screen to submit questions – Click on the Q&A icon and type your question into the Q&A box to submit to our moderator ©2022 GTI Energy. All rights reserved. 3 Why Blend Hydrogen? Near-term Decarb. at Scale • Feasibility: Roadmaps emphasize near-term potential in blended H2 distribution in gas grids to end users • Scale-up: With increasing scale/blend %, delivered H2 stimulates demand, driving down generation/storage costs – US/Canada network is 5.4 million km, serving 85 million customers! Source: Hydrogen Roadmap Europe, https://www.fch.europa.eu/news/hydrogen-roadmap-europe-sustainable-pathway-european-energy-transition ©2022 GTI Energy. All rights reserved. 4 Why Blend Hydrogen? Near-term Decarb. at Scale Fossil-Free Gas: Like efficiency and renewable methane, many utilities view delivered H2 as essential to long-term net zero emissions goals Source: NW Natural’s Vision 2050, RNG Constrained scenario. Other market leaders with similar plans include SoCalGas, Dominion Energy, National Grid, Enbridge, ATCO Gas, FortisBC, and many others. And They’re Off! Numerous pilots are underway now (typ. ≤ 20% H2 by vol.) with more homes and businesses in receiving H2/natural gas over 2022. Source: S&P Global. Add’l prominent pilots involving end users include those in Canada – British Columbia, Alberta, Ontario, and Quebec; and USA - California, Minnesota, New Jersey, New Mexico, New York, Oregon, Utah, and others. ©2022 GTI Energy. All rights reserved. 5 History Doesn’t Repeat, but it Rhymes • Public gas distribution begins in US in 1816 (Baltimore) • Gasified pine tar, coal, oil ~1000 US plants at peak (1890s) • Syngas (H2/CO, “water gas” and “coal gas”), byproducts also sold – Initially revenues were 90% lighting, then expanded into domestic/commercial (via leasing), then industrial uses • In 20th century, pipeline tech. brings “natural” gas to cities Gas Works Park – Seattle (Decomm. 1956) • Through 1930s, “enrich” mfd. gases by blending NG (~2X HHV) • Post-WWII favors straight conversion (DC, NYC) – Conversion took 30-40 years in US, “single largest task” was converting customer equipment (utility-led or contractor) • Legacy of mfg. gas transition remains in appliance design/codes, some current use (e.g., Hawaii Gas) Appliance Design Guide (1944) – Still Used by Industry!!** ©2022 GTI Energy. All rights reserved. 6 * Source: Tarr, J. “Transforming An Energy System: The Evolution of the Manufactured Gas Industry and the Transition to Natural Gas in the United States (1807-1954),” in Olivier Coutard (ed.), The Governance of Large Technical Systems (London: Routledge, 1999), 19-37. // ** AGA Testing Laboratories, Primary Air Injection Characteristics of Atmospheric Gas Burners – Research Bulletin No. 26, 1944. Flame Types – Greater reactivity (flammability, ignition, temperature) – No carbon (fewer emissions, humid exhaust, visibility) – Premixed vs. Partially-Premixed matters! • For typical, unadjusted equipment, look for: – Startup issues: flashback/blowoff, ignition Premixed – Lower volumetric density/smaller size (de-rating, embrittlement, etc.) Partially-premixed • Hydrogen has very different properties from natural gas Partially-premixed Non-premixed (Diffusion) H2 as a Fuel: The Basics Source: Arthur Jan FijaΕkowski/ WikiCommons λ=0 – Emissions impact: CO, NOx, etc. 0<λ<1 1≤λ – Shift in heating: surfaces, de-rating, impact on efficiency Wobbe Index (WI) used to define fuel interchangeability ππΌ = π»π»π ππΊ Combustion Air Requirement Index (CARI) predicts air/fuel ratio impacts πΆπ΄π πΌ = π΄ππ/πΉπ’ππ π ππ‘ππ ππΊππ’ππ Fuel Composition and λ can predict SL and Tadiabatic, flame where π1 πΆπ΄π πΌ1 = π2 πΆπ΄π πΌ2 ©2022 GTI Energy. All rights reserved. 7 H2 as a Fuel: Gas Quality and Tiered Approach Hydrogen Blending as Gas Quality Issue While impacts vary, general blending levels are: Sp. Gravity • Med. Blending (10%-30% H2 by vol.) Adjustments needed • High Blending: (> 30% H2 by vol.) Specially-designed equipment required (e.g., H2 Boiler) Ground laid for “tiered approach” by extensive RD&D in EU/UK, where “hydrogen ready” equip. are currently available Index (100% CH4 = 1) at 60 F and Atm. Pressure • Low Blending (< 10% H2) No or minor equipment adjustments HHV Wobbe Index Comb. Air Requirement CO2 1.1 1.1 1.0 1.0 0.9 0.9 0.8 0.8 0.7 0.7 0.6 0.6 0.5 0.5 At 30% hydrogen blend, mixture: - is 26% less dense - has 20% lower HHV (vol.) - has 7% lower Wobbe Index - requires 23% less combustion air - emits 12% less CO2 (energy adj.) 0.4 0.3 0.2 0.1 0.4 0.3 0.2 0.1 0.0 Source: THyGA Project (2021) 0% 10% 20% 30% 40% 50% 60% 70% Volume % H2 with balance CH4 80% ©2022 GTI Energy. All rights reserved. Source: Heating & Hotwater Industry Council (UK) 0.0 100% 90% 8 H2 as a Fuel: Burner Impacts Partially-Premixed Example Premixed Example Flame Sense/ Temp. Sense Combustion Controller Premixed Surface Combustion Premixed Fuel/Air Premix Blower Assembly Fuel Gas Valve Mixer (Venturi) Combustion Air (1 .1 < λ < 1 .5, typ.) Distribution Tube/ Plate Assembly Ignitor(s) Other potential config.: blue-flame type burner, pos t-blower fuel/air mixing, electronic-type gas control Pneumatic Signal (typ.) Majority of: Furnaces/RTU, storage WH, cooking, hearth, outdoor Most of: Hot water/steam boiler, pool/process heater Increasing H2: Shifts λprimary to 1.0, can increase Tflame/SL, but impacts are equipment specific on flame, heat transfer, air flow, NOx emissions Majority of: Tankless WH, fuel-fired heat pump, mCHP Most of: Low NOx versions of PP-type equipment Increasing H2: Can shift λoverall leaner for pneumatic controls, but compensating electronic controls (constant λ) result in increased Tflame/SL ©2022 GTI Energy. All rights reserved. 9 Recent Results from Lab & Field Common Concerns: In typical, unadjusted customer equipment, will blended H2/NG… • Cause equipment to immediately malfunction? • Lead to unsafe operating temperatures? • Adversely impact efficiency? • Significantly reduce heat output? • Increase NOx or CO emissions? • Increase leakage within building? Answers from important but limited datasets* • Short-term tests only, often not North American context • Inconsistent testing approach https://www.mdpi.com/1996-1073/15/5/1706 Background, literature survey, results in recently published GTI Energy paper – highlighting early laboratory/field measurements up to 30% H2 ©2022 GTI Energy. All rights reserved. * :GTI Energy Glanville, P. Overview of Blended Hydrogen Impacts on Water Heating Equipment, 2021 ACEEE Hot Water Forum. / UC Irvine: link / CSA/AGA: link / https://thyga-project.eu/ AHRI - link / PRCI - link 10 Recent Results from Lab & Field Wait a minute, I thought 20% H2 was fine… • 2013 NREL/GTI Energy study said 5%-15% H2 was “feasible with very few modifications” For CEC, UC Irvine found that a common ULN Water Heater could not operate ≥ 10% H2 while tankless could up to 20% – Largely based on 2004-2009 EU NaturalHy study, different equipment • Studies by AGA (2018) and PRCI (2020) point to up to 20% H2, but knowledge gaps above 5% blended • In Europe beyond NaturalHy, several pilots verify range – Dutch pilot in Ameland, boilers/cooking equipment tested up to 30% H2 • CSA (2021) and UCI (2020) document some issues with common equipment within these ranges → • 2021 AHRI study, incl. FMEA, states up to 20% H2 OK for new equipment, w/o adjustment – existing equipment may be replaced For CSA, test lab could not sustain ignition of vent-free radiant space heater at 15% H2 ©2022 GTI Energy. All rights reserved. * GTI Energy: Glanville, P. Overview of Blended Hydrogen Impacts on Water Heating Equipment, 2021 ACEEE Hot Water Forum. / UC Irvine: link / CSA/AGA: link / https://thyga-project.eu/ AHRI - link / PRCI - link 11 Recent Results – GTI Energy Methods Scope of Testing - “Simulator” testing and In-situ • Natural gas, 0%-30% H2 in CH4 in 5% increments • Simulator tests operated manually: Furnace (in-shot), Water heater burners: Standard NOx (2), Ultra Low NOx (2) • For in-situ, appliances with automation of loads: Two furnaces (High/Std. eff.), Three water heaters (Standard NOx, ULN #1, ULN #2) In-situ Furnace Testing In-situ Water Heater Testing Furnace Burner “Simulator” Water Heater Burner “Simulator” ©2022 GTI Energy. All rights reserved. 12 Recent Results – GTI Energy Methods • Coordinated with utility team in mid 2021, GTI Energy sampled emissions from 15 appliances – Pre/post measurement of emissions (0%-10%), material temperatures, observations on safety – Water heaters (standard, Ultra Low NOx), furnaces, ranges, dryers, fireplaces • 2022 plans for three additional demonstrations, expanding equipment population GTI Energy sampling of residential furnace with 0% - 10% H2 blends (left) at facility “village” (right) ©2022 GTI Energy. All rights reserved. 13 Do Equipment Malfunction? Standard NOx WH – 30% H2 / 70% CH4 • Based on GTI Energy Lab/Field Testing to date, generally no issues in normal operation • Ignition and sustained operation successful over 0%-30% (lab), 0%-10% (field) for all equipment • Minimal visual difference with “blue flame” burners, some dimming of radiant burners • Limited issues seen with UCI/CSA tests (noted) ULN #1 WH – 30% H2 / 70% CH4 ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 14 Do Equipment Malfunction? ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 15 Do Equipment Malfunction? • Measurable delay in “rolling” ignition for furnaces, increase with H2, cold vs. hot start, low vs. high fire • “Flashback” created outside of furnace testing plan, but uncertainty why? Simplified Flame Flame Speed Fuel/Air λ < 1 (Partially Premixed) λ > 1 (Premixed) If VFuel/Air >> VFlameSpeed Blowoff If VFuel/Air << VFlameSpeed Flashback 30% H2 / 70% CH4 70% CH4 / 30% H2 25% H2 / 75% CH4 – 0.12 speed 0.12X Speed ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 16 How is Heat Output Impacted? Reduced slightly in excess of Wobbe Index shift, consistent result in literature • GTI Energy data vs. output measurements in EU literature review For GTI Energy tests water heater input results consistent, but nuanced results – ULN #1 near exact with Wobbe Index From THyGA project literature review focus on output, similar results seen though wide range in impact Data Source – THyGA Project: https://thyga-project.eu/deliverable-d2-3-impact-of-hydrogen-admixture-oncombustion-processes-part-ii-practice/ ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 17 Do NOx and CO Emissions Increase? Generally, no. GTI Energy data show reduction in NOx across the board (energy input adjusted) and small change in CO emissions Ultra Low NOx #1 “Slug Test” ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 18 Do NOx and CO Emissions Increase? Generally, no. GTI Energy field data show flat/reduction in NOx emissions (within error) Location Equipment Name Burner Type A Water Heater #1 “Pancake” Burner B Water Heater #2 “Pancake” Burner D Water Heater #3 ULN Burner #2 E Water Heater #4 “Pancake” Burner D Furnace #1 “In-shot” Burners E Furnace #2 “In-shot” Burners B Wall Furnace #1 “In-shot” Burners G Wall Furnace #2 “Ribbon” Burners C Fireplace #1 Perforated Burner A Range/Oven #1 Standard Range Burner E Range/Oven #2 Standard Range Burner F Range/Oven #3 Standard Range Burner Water Heater Furnace Range Oven ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 19 Recent Results - Recap Based on data collected to date in typical, unadjusted customer equipment, will blended H2/NG… • Cause equipment to immediately malfunction? Not likely • Lead to unsafe operating temperatures? Not likely • Adversely impact efficiency? Not likely Source: Northern Gas Networks • Significantly reduce heat output? In excess of Wobbe • Increase NOx or CO emissions? Generally, no • Increase leakage within building? Not worsened by blending But what about.. • Higher blends/pure hydrogen? Long-term impacts? Testing to failure? • Broader population of equipment (type, age, installation)? Emerging technologies and retrofit packages? Source: Gersen, Van essen, 2020 ©2022 GTI Energy. All rights reserved. Disclaimer: Conclusions based on results and methods of GTI Energy Projects/References noted only and may not be widely applicable 20 H2 Blending Impacts on Equipment – What’s Next • Continued testing/sampling of more diverse equipment (e.g., H2 heat pumps), indoor distribution leakage, use of in-line H2 sensors • Coordinate/support update to codes and standards impacted by H2-based fuels • Development of mitigation tech. and high-H2 tolerant components/equipment • Recent ~$3 million award to GTI Energy-led team on H2 in large comm. and industrial applications – Test/model H2 tolerance of wide range of large equipment categories (e.g., boilers) – Material testing for long-term impacts, Air Quality simulation to quantify regional benefits/impacts ©2022 GTI Energy. All rights reserved. 21 Thank You! For More Information Paul Glanville, PE R&D Director, Building Energy Efficiency Kristine Wiley Vice President, Hydrogen Technology Center Watch for a follow-up survey Research discussed supported by Utilization Technology Development (https://www.utd-co.org/) Research team on H2 Impacts in Buildings: Alex Fridlyand, Brian Sutherland, Frank Johnson, Kaushik Biswas, Kris Jorgensen, Luke Bingham, Will Asher, Yan Zhao, and others ©2022 GTI Energy. All rights reserved. 22