Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 1. What is the main component of natural gas? Methane is the main component of natural gas. Natural gas is around 85% - 95% methane. 2. What is the chemical formula for methane? CH4 Copyright © CSA Group 2 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 3. How does dry natural gas differ from wet natural gas? Wet has gas contains heavier hydrocarbons, such as propane, butane, pentane, hexane and heptanes. Dry gas do not contain these heavier hydrocarbons. 4. What is the chemical formula for propane? C3H8 Copyright © CSA Group 3 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 5. What substance is added to natural gas and propane to give them a distinctive odor? An odorant known as ethyl mercaptan. 6. Define the term specific gravity. It is the comparison between the density of any substance to the density of another, usually water or air. Copyright © CSA Group 4 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 7. What are the specific gravities of natural gas and propane vapor? Natural gas’ specific gravity = .55 Propane’s specific gravity = 1.52 or 1.53 8. What are the ratios of expansion from liquid to gas for both natural gas and propane? Natural gas’ ratio of expansion = 1:600 Propane’ ratio of expansion = 1:270 Copyright © CSA Group 5 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 9. What are the boiling temperatures for both natural gas and propane? Natural gas boils at -260 degrees F Propane boils at -44 degrees F 10. Define calorific value. The energy released when a given volume of fuel is burned. Copyright © CSA Group 6 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases What are the accepted calorific values in Btu/ft3 for natural gas and propane? Natural gas = 1000 Btu/ft3 Propane = 2520 Btu/f3 11. 12. What are the limits of flammability for natural gas and propane? Natural gas = 4 – 15% Propane = 2.4 – 9.5% Copyright © CSA Group 7 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 13. Fill in the blanks with the correct word/phrase from the Choices listed below. ❖ Choices: lowered below, 0.55, heat, boiling temperature, –44ºF, dry, heat content, 1.52/1.53, vapor, British Thermal, –258ºF, CH4 , sour, temperature, C3H8, boiling, raise Copyright © CSA Group 8 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 14. Continued a) b) c) d) e) f) Wet gas is natural gas containing propane, butane, pentane, and other heavy hydrocarbons. Sour gas produced a common ingredient used in rubber products, carbon black. Natural gas with all the heavier hydrocarbons removed is also called dry gas. The accepted chemical composition for natural gas is CH4. Propane is C3H8. Air has specific gravity of 1.0. Vaporized propane’s specific gravity is 1.52 or 1.53 For natural gas it is 0.6. At atmospheric pressure, propane has a boiling point of –44°F. For natural gas, the boiling point occurs at –258°F Copyright © CSA Group 9 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 14. Continued g) h) i) The following statements refer to the vaporization of propane. If the temperature of a fuel gas is lowered below its boiling point, it will not vaporize. Propane cylinder pressure always varies with the temperature. Considering temperature/pressure relationships, in a propane cylinder, an increase in pressure means that the saturation point or boiling temperature becomes progressively higher. Vapour pressure is the term given to the molecular movement of LP (propane) gas vapours Calorific value is the heat content of a fuel. It is the energy released when a given volume of fuel is burned. The common measurement unit used when gas is burned is the British thermal unit. It is expressed as the amount of heat required to the raise the temperature of one pound of water one degree Fahrenheit. Copyright © CSA Group 10 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 15. From the Choices listed, select the word/phrase that correctly completes each sentence. ❖ Choices: bleach, butyl mercaptan, ethyl mercaptan Since natural gas is undetectable by smell, the odorant agent ethyl mercaptan is added for safety purposes. Copyright © CSA Group 11 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 16. From the Choices listed, select the two-word combination that correctly completes the following statement. ❖ Choices: dense relativity, specific gravity, relative, density, saturation point The comparative weight of a volume of a liquid to an equal volume of water is its specific specific gravity or relative density. Copyright © CSA Group 12 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 17. Select from the following Choices the number relationship that correctly completes the following statement. ❖ Choices: 0.58, 1.54, 0.51, 7.6 The specific gravity of liquid propane is .51 Copyright © CSA Group 13 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 18. Select from the following Choices the number ratio that correctly completes each of the following statements. Choices: 1:270, 1:300, 1:600, 1:670 At atmospheric pressure, propane gas expands at the ratio of 270:1 when changing from a liquid to a gas. The expansion ratio of natural gas from a liquid to a gas is 600:1. Copyright © CSA Group 14 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Properties and Safe Handling of Fuel Gases 19. From the following Choices select the number(s) combination that is appropriate to the fuel designation in the table. ❖ Choices: 12; 2.4 - 9.5; 920; 3600, 4 -15; 11; 1300; 3600 Combustion Data Propane Natural gas Flame Speed (inches/s) 11 12 Limits of Flammability (%) Max. Flame Temperature (°F) 2.4 - 9.5 3600 4 - 15 3600 Ignition Temperature (°F) 920 1300 Copyright © CSA Group 15 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 20. What is the term used for the chemical process in which the rapid oxidation of fuel results in the production of heat? Combustion 21. Approximately what percentage of air is made up of oxygen? Air is 20% oxygen Copyright © CSA Group 16 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 22. What are the approximate ignition temperatures (in °F and °C) for propane and natural gas? Natural gas = 1300 degrees F (700 degrees C) Propane = 920 degrees F (495 degrees C) 23. What are the products of combustion for a hydrocarbon fuel? Carbon dioxide (CO2), water vapour (H20) and heat Copyright © CSA Group 17 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 24. State the formula for perfect combustion for natural gas. CH4 + 2O2 + 8N2 → CO2 + 2H20 + 8N2 + heat 25. What is added to the combustion process to ensure complete combustion? C3H8 + 5O2 + 20N2 + excess air → 3CO2 + 4H2O + 20N2 + excess air + heat Copyright © CSA Group 18 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 26. Name two products of incomplete combustion. Carbon monoxide and aldehydes 27. How are the three divisions of air supply categorized? Combustion air, excess air and dilution air Copyright © CSA Group 19 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 28. What is the term used to describe the air that is mixed with fuel gas before the point of ignition? Primary air 29. What is the purpose of dilution air? The purpose of dilution air is to cool the hot vent gases and to provide a source of air to the draft control device Copyright © CSA Group 20 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 30. What is the air-to-gas ratio that applies to all fuel gases? The ratio is 10:1 31. What is the normal percentage of combustion air to excess air requirements for an atmospheric burner? A volume of excess air equal to 50% of the combustion air volume Copyright © CSA Group 21 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 32. What are the total air volume supply requirements for an atmospheric burner? 1000 Btu of input requires 30ft3 of total air supply 33. List four possible causes of incomplete combustion, other than lack of air. - Flame temperature drops below 1300 degrees F - Cracked heat exchanger causing less air and increased CO - Negative air pressure - Blocked venting Copyright © CSA Group 22 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 34. What are the three color zones of a stable Bunsen flame? Inner cone, outer cone, outer mantle 35 -38. In Questions 35 through38, select from the following the word/phrase that correctly completes each statement. ❖ Choices: secondary, to the total, heat, 5 ft3, excess, total, 920, oxygen, propane, aldehydes, primary, fuel, 1300, 50%, 15 ft3, odor, dilution, CH4, incomplete, oxidation Copyright © CSA Group 23 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 35. The Combustion Triangle’s elements are fuel , heat, and oxygen . 36. CH4 is the chemical designation for natural gas. Its ignition temperature is 1300 °F or 700°C. An ignition temperature of 920 °F or 495°C and a chemical designation of C3H8 identifies Propane. Copyright © CSA Group 24 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 37. Aldehydes : transparent, colorless gases with a suffocating smell that is toxic and irritating to the eyes. They are produced by the partial oxidation of fuel gas(es). Carbon monoxide : It can cause death if enough is inhaled; it has no, odor, taste, or smell; it is hard to detect without proper equipment; and it’s one of the most harmful products of incomplete combustion. Copyright © CSA Group 25 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 38. Combustion air is subdivided into the two classifications of primary air and secondary air. Total air describes the volume of air required to allow the appliance to operate safely and efficiently. The volume of excess air required for the efficient operation of atmospheric burner fired equipment is equal to 50% of the combustion air requirement or 5 ft3 for each 1000 Btu. The volume of dilution air required for appliances equipped with a draft control device should be equal to the total of the combustion and excess air supplied the burner or 15 ft3 for each 1000 Btu. Copyright © CSA Group 26 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 39. Select from the following Choices the type of combustion that correctly matches the definition described. ❖ Choices: Complete combustion, Incomplete combustion, Stoichiometric combustion Copyright © CSA Group 27 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 39. Continued Definition The mathematically exact volume of air that must be mixed with a fuel gas to achieve perfect combustion. Complete combustio n All fuel is completely burned and no harmful products of incomplete combustion are produced. Copyright © CSA Group Stoichiome tric combustio n Unburned fuel will contain carbon, hydrogen Incomplete carbon monoxide and complex chains of combustio alcohol (aldehydes) n 28 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 40. Match each Definition to one of the following categories of air. ❖ Copyright © CSA Group 29 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 41. From the following Choices, select the correct term that matches each description. Copyright © CSA Group 30 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 42. From the following Choices match the cause the symptoms described in the Table: ❖ Choices: Cracked Heat Exchanger, Negative Air Pressure, Blocked Venting, Flame Temperature Copyright © CSA Group 31 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion Description of Symptoms 23. Continued Excessive cold air is chilling the flame front Excessive air being exhausted from building Flame characteristics change as soon as the blower comes on Impingement on the cold metal surface of the heat exchanger Smoke stick check at draft hood indicates negative pressure A change in CO2/O2 levels in flue gases when the blower starts Excessive flue gas spilling out of the draft hood Copyright © CSA Group Flame Temperature Negative Air Pressure Cracked Heat Exchanger Flame Temperature Blocked Venting Cracked Heat Exchanger Blocked Venting 32 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 43. The amount of gas/air mixture passing through a burner port is referred to as port loading. It can be changed by altering either the orifice size or the manifold pressure. It is important for a stable flame; it is expressed as Btu/h per sq. in. of port area. Copyright © CSA Group 33 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 44. A reduction in gas density occurs at high altitudes, i.e., for every 2000 ft rise in elevation the barometric pressure decreases by 1 psia. The volume of natural gas will thus expand to 1.072 ft3 (Boyles Law). Describe an effect of this less dense gas on its flow. The volume of the balloon will increase when there is atmospheric pressure. Copyright © CSA Group 34 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 45. The combustion process must maintain a temperature of approximately 1300 °F (700°C) for natural gas. 46. A stable gas flame is a flame that does not waver, lift off the burner, or flash in the mixing tube. Copyright © CSA Group 35 Gas Trade 3 – Answer Key Unit: Properties, Characteristics and Safe Handling of Fuel Gases Assignment: Combustion 47. From the following Choices, select the correct amount of air to supply the input stated. ❖ Choices: 100, 3500, 2550, 1000, 255, 350, 10, 2500 100,000 Btu/h requires 1000 ft3 combustion air. 35,000 Btu/h requires 3500 ft3 combustion air. 255,000 Btu/h requires 2550 ft3 combustion air. Return to Table of Contents slide Copyright © CSA Group 36