Name: _______________________________ Electron Configuration Modeling Activity Background Electron configurations for atoms and ions indicate properties of that atom or ion. Electron configurations allow the behavior of the atom or ion to be predicted. Although an electron’s precise location cannot be exactly determined at a point in time, the most probable location for an electron can be identified in orbitals. How the electrons fill the orbitals can be explained by the following rules: 1. Aufbau Principle: electrons occupy orbitals of the lowest available energy first before filling higher energy orbitals Energy Level n= 1 2 3 4 5 nucleus 2. Hund’s Rule: electrons in the same sublevel will occupy empty orbitals before double occupying an orbital CORRECT— place one electron in each orbital for 2p before placing two electrons in each orbital. 1s 2s 2p INCORRECT— placing two electrons in one orbital while leaving empty orbitals in 2p. 1s 2s 2p Atoms or ions that have completely full sublevels (no unpaired electrons) are the most energetically stable arrangement of electrons. Those with exactly half-filled sublevels are the next most stable. American Association of Chemistry Teachers |1-629 1 3. Pauli Exclusion Principle: two electrons in the same orbital will have different magnetic spins (spin-up and spin-down) 1s Correct The magnetic properties can be observed in real life for the predicted electron configuration. If all orbitals have been occupied with spin-up and spin-down electrons, the atom or ion is described as diamagnetic. This means it will be repelled by a magnet (though often only to a very small degree, not noticeable by the human eye). If there are orbitals that are not double occupied with electrons, the atom or ion is described as paramagnetic. This means it will be attracted to a magnet. North 1s Incorrect South Magnetic Field Lines e- e- South North Spin + ½ Spin–up Spin - ½ Spin–down Pre-Activity Questions 1. Complete the following about orbitals. Orbital Block No. of orbitals No. Electrons each sublevel can hold Sketch or describe shape s-block p-block d-block 2. In an electron configuration, which electrons are the valence electrons? How do these electrons affect the properties of an element? American Association of Chemistry Teachers |1-629 2 Objective To create electron configurations for various atoms and ions by following the Pauli Exclusion Principle, Aufbau Principle, and Hund’s Rule, and to use these to predict behavior of atoms and ions. Materials 18 flat marbles of one color 18 flat marbles of a different color Orbital Diagram Modeling Sheet Procedure You are going to create electron configurations with the help of the Orbital Diagram Modeling Sheet for a variety of atoms and ions following the rules laid out in the Background section. The different colored flattened marbles represent electrons with opposite spins. An orbital is “full” when it holds two electrons with opposite spins. Complete the following steps for each atom or ion in the table below: 1. Identify the total number of electrons needed for the atom or ion. 2. Construct the requested electron configuration by placing the marbles to on the Orbital Diagram Sheet. Double check that you have used the total number of electrons needed for the atom or ion. 3. Write the electron configuration requested for each atom or ion to your data collection. 4. Sketch the orbital diagram using arrows to represent spin-up and spin-down electrons. 5. Be sure to get instructor approval when necessary (marked with a ). No. of Total Electrons Atom / Ion Instructor Approval Electron Configuration He Orbital Diagram ___ ___ 1s ___ ___ ___ ___ ___ ___ ___ ___ 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s 2s 2p ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Be Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p N Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p O2– Orbital Diagram ___ 1s ___ 2s American Association of Chemistry Teachers ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p |1-629 3 No. of Total Electrons Atom / Ion Instructor Approval Electron Configuration Ne Orbital Diagram ___ ___ 1s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Al Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Al3+ Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p S Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p - Cl Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Ar Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p V Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Cr Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Fe Orbital Diagram ___ 1s ___ 2s American Association of Chemistry Teachers ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p |1-629 4 No. of Total Electrons Atom / Ion Instructor Approval Electron Configuration Fe3+ Orbital Diagram ___ ___ 1s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s ___ ___ ___ ___ ___ ___ ___ ___ 2p 3s 3p 4s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Cu Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p As Orbital Diagram ___ ___ 1s 2s Br ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p - Orbital Diagram ___ ___ 1s 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Kr Orbital Diagram ___ 1s ___ 2s ___ ___ ___ ___ ___ ___ ___ ___ 3d 4p Analysis 1. What do you notice about the electron configurations you wrote for elements in the same group, such as He, Ne, Ar, and Kr, or N and As? 2. Compare the electron configurations of Al, Al3+, O2– and Ne. Then compare Br- and Kr. What patterns can be found to suggest why some elements tend to be found as ions instead of neutral atoms? Explain these patterns in terms of the energetic stability of the electron arrangements. American Association of Chemistry Teachers |1-629 5 3. Use your answer to the previous two questions to predict the charge that would form on Ca and N if they were to form ions and explain your reasoning for your predictions. 4. A few of the atoms and ions in the table above did not perfectly follow the electron configuration rules laid out in the background information. Explain why each of these configurations was different from what the rules would predict. 5. Explain what is wrong with the following electron configurations. Then annotate the configuration to correct the error. a. 1s2 2s2 2p6 3s2 3p6 4s2 4d10 4p6 b. 1s2 2s2 2p6 3s3 3d5 6. Based on the orbital diagrams for the atoms and ions in this activity, list which atoms/ions would be diamagnetic and which atoms/ions would be paramagnetic. American Association of Chemistry Teachers |1-629 6 Conclusion Summarize what you have learned about how electrons behave in atoms and ions. Include the following terms in your summary: Pauli Exclusion Principle, Aufbau Principle, Hund’s Rule, valence electrons, energy levels, neutral atom, ion, electron configuration, orbitals, stability, spin-up, spin-down, stability, diamagnetic, paramagnetic Extension 1. Connecting properties of electron behavior to medical technology. Research how magnetic resonance imaging (MRI) technology works and how it is used to diagnose different diseases. Prepare a short powerpoint presentation, poster, or infographic explaining your findings. 2. Exploring diamagnetism and paramagnetism. Research different forms of magnetism, including (but not limited to) diamagnetism and paramagnetism. Provide examples of different kinds of magnetic materials and how they can be used. Prepare a short powerpoint presentation, poster, or infographic explaining your findings. American Association of Chemistry Teachers |1-629 7