Lawrence P Grana, MSEE 1 Summer, AY 2021-2022 A material that has energy bands either completely empty or completely full is an insulator. The resistivity of an insulator is very large or, conversely, the conductivity of an insulator is very small. There are essentially no charged particles that can contribute to a drift current. The bandgap energy Eg of an insulator is usually on the order of 3.5 to 6 eV or larger if an electric field is applied, the electrons can gain energy, move to higher energy states, and move through the crystal. If an electric field is applied, the holes can move and give rise to a current. The bandgap energy may be on the order of 1 eV This energy-band diagram represents a semiconductor for T 0 K. shows the case of a partially full band in which there are many electrons available for conduction, so that the material can exhibit a large electrical conductivity a case in which the conduction and valence bands overlap at the equilibrium interatomic distance There are three distribution laws determining the distribution of particles among available energy states. Maxwell–Boltzmann probability function The behavior of gas molecules in a container at fairly low pressure Bose–Einstein function The behavior of photons, or black body radiation Fermi–Dirac probability function Electrons in a crystal obey this law Equation (3.80) is known as the Maxwell–Boltzmann approximation, or simply the Boltzmann approximation, to the Fermi–Dirac distribution function.