Balance equation 1. 2. Group 1 metal + water alkaline + H2 Metal + O2 metallic oxide Oxidation number!!!!!!!!!!!!!!!!!!!!!!!!!!!!! - 4Al + 3O2 2Al2O3 Mg + Br2 MgBr2 2Fe + 3Cl2 2FeCl3 4Li + O2 2Li2O Zn + F2 ZnF2 3Mg + N2 Mg3N2 3. Displacement reaction Metal Reactivity series Non-metal F > Cl > Br > I No one reactive element + less reactive compound less reactive element + more reactive compound Oxidation number !!!!!!!! - Zn + AgNO3 ZnNO3 + Ag Mg + AlCl3 Cl2 + BaBr2 A B C D Density 0.50 0.70 2.40 3.50 Conductivity ofelectricity Yes No Yes no Hardness Soft Hard Hard Soft Group1 metal is ‘A’ How many grams of 3.2mol of N2 gas? 14+14 * 3.2 = 89.6 What is the volume of 3.2 mol of N2 gas under r.p.t 3.2 * 24dm-3 = 76.8 How many mole of NaCl needed to prepare 1.3mole*dm-3 500cm3 solution 0.5 *1.3 = 0.65 What is the concentration when dissolve 0.6 mol of NaOH into water to make a 60cm3 solution? 0.6 / 0.06 = 10mol*dm-3 2g of NaHCO3 reacts with excess HCl (aq) calculate the volume of Co2(g) NaHCO3 (s) + HCl(aq) NaCl (aq) + H2O (l) + CO2(g) 1. 2 g/ 23+1+12+16*3 + 0.02 mol NaHCO3 2. 3. Mole of CO2 = mole of NaHCO3 V Co2 = 0.02 * 24dm-3 = 0.48 dm-3 MOLE CALCULATION 1. 18 grams of limestone reacted with excess dilute hydrochloric acid. 3840cm^3 of carbon dioxide was formed with r.t.p. work through the calculation to find the percentage purity of this sample of limestone, which is impure calcium carbonate, CaCO3. Give yours to two significant figures. Ar value : C=12 , Ca=40 , O=16 CaCO3 + 2HCl CaCl2 + CO2 + H2O 1. 2. 3. 4. 5. 6. The molar mass of calcium carbonate: 100g/mol Volume of CO2 in dm-3 = 3.84 Moles of CO2 = 3.84/24 = 0.16mol Moles of CaCO3 in limestone sample = 0.16 mol Mass of CaCO3 in limestone sample = 16g Percentage purity = 16/18 * 100 = 88% 2. Methyl benzoate can be prepared by reacting methanol with benzoic acid CH3OH (methanol) + C6H5CO2H (benzoic acid) C6H5CO2CH3 + H2O When 24.4g of benzoic acid is reacted with excess methanol, 25.84g of methyl benzoate is produced. Work through the calculation to find the percentage yield of methyl benzoate. Ar value : C=12 , H=1 , O=16 1. 2. 3. 4. 5. 6. Molar mass of benzoic acid = 122g/mol Moles of benzoic acid = 24.4/122 = 0.2 mol Moles of methyl benzoate expected (if 100% yield) = 0.2mol Molar mass of methyl benzoate = 136g/mol Mass of methyl benzoate expected (if 100% yield) = 0.2 * 136 = 27.2g Percentage yield = 25.84/27.2 *100 = 95 3. A student reacts to 5.4g of aluminum with excess oxygen. 4Al + 3O2 2Al2O3 The mass of aluminum oxide produced is 8.67 g. Calculate the percentage yield. Ar values: Al=27 , O=16 1. 2. 3. 4. Mole of aluminum = 5.4/27 = 0.2mol Mole of 2Al2O3 = 0.1mol Mass of 2Al2O3 = 0.1*102 = 10.2 Yield = 8.67/10.2*100 = 85%