Activity #4: Physical vs. Chemical Changes I can use laboratory observations to be able to determine the differences between physical and chemical changes. Background: Chemical substances are always coming in contact with other chemical substances in the natural world. These substances are also exposed to the physical variables of the environment, like temperature changes and applied forces. This combination, in turn, influences the stability of these chemical substances and may or may not change their physical state or the chemical makeup of the substances altogether. In part A of this activity, you will observe how variables in the physical environment change chemical substances. Then, in part B, you will observe how chemical substances change in the presence of other substances. By the end of the activity, you will be able to identify what evidence would lead a chemist to determine if a physical or chemical change has occurred. Part A: Physical Changes 1. Obtain an ice cube and place it into an evaporating dish. Place the evaporating dish onto a hotplate set on high temperature. Observe how the ice cube changes until the substance seems to “disappear.” Allow the evaporating dish to cool on a wire gauze. 2. Take a sheet of white paper. Crease the paper lengthwise and rip in two. Repeat this process over and over until you can no longer rip the paper. Make sure you get the resulting pieces of paper into the recycle bin. 3. Obtain an antacid tablet. Using a mortar and pestle, grind the antacid tablet into a powder. Your teacher will demonstrate how to properly use a mortar and pestle. Save the powder for Part B of the activity. 4. Fill your 150-mL beaker with 60 mL of distilled water. Add a pea-sized amount of salt to the beaker and stir until dissolved. Pour 30-mL of the salt solution into your evaporating dish and heat until dryness on a hotplate set to high temperature. Allow the evaporating dish to cool on a wire gauze. 5. Fill a 150-mL beaker with 60 mL of distilled water. Add one drop of green food dye. Stir until completely dissolved. Save the solution for Part B of the activity. Part B: Chemical Changes 1. Obtain a piece of aluminum wire and place it into the bottom of a test tube. Add copper (II) sulfate solution to the test tube to a height of one-third the height of the tube. Let the test tube sit undisturbed while the other steps of Part B are performed before observing. Till wire is not visible? 2. Light the Tirrell burner and adjust the burner to produce an appropriate nonluminous flame like was learned earlier in the semester. Obtain a strip of magnesium. While holding the magnesium with crucible tongs, hold the strip of magnesium at the tip of the inner core of the flame. Tap the product onto a watch glass to observe. Note: DO NOT LOOK DIRECTLY INTO THE BURNING MAGNESIUM. 3. Transfer the ground antacid tablet to a 150-mL beaker. Carefully add 50-mL of hydrochloric acid. Lower a lighted wood splint into the beaker as the changes take place. DO NOT DROP THE WOOD SPLINT INTO THE BEAKER! 4. Add 10 drops of bleach to the mixed green food dye from Part A while stirring. Add a few drops, if necessary, to get a definite change of the solution. Then add 10 drops of vinegar while stirring. Add a few more drops, if necessary, to get a definite change of the solution. 5. Teacher demo: A piece of zinc is placed in 6 M HCl, then the gas is tested with a wood splint. Data Table for the Observations of Physical and Chemical Changes Chemical Substances and Change ice heated Observations Before Change Chunks of solid intact, white, and cold Long and nice paper torn width, blank with sharp edges antacid tablet Solid, intact, circle and white pulverized sodium chloride White powder dissolved and evaporated food coloring mixed in water aluminum wire in copper (II) sulfate Green liquid, and a separate clear liquid Grey rod in blue liquid combusted magnesium Solid, rigid grey strip antacid powder in HCl Brown strip skinny, top had heat source Grey chunks zinc metal in HCl Observations During/After Change No longer a solid but a liquid and is bubbling, and hot Short width but still long, and sides are rigid Powder, white, and not intact The salt took a while to dissolve, it dissolved when I stirred it Green liquid turned clear liquid green Liquid turned clear, but grey rod turned puffy and red The Strip produced a very bright light turned white, Parts fell off The mixture extinguished the heat source Bubbles formed; the liquid got foggy. When Can the original substance be restored? yes yes yes yes yes no No No No food coloring water, bleach, and then vinegar Green liquid exposed to heat, the resulting gas created a combustion The bleach turned No liquid blue, while the vinegar turned liquid yellow Post-Activity Questions: 1. For which type of change could you restore the original chemical substance after the change? Physical change 2. Place the following changes into the appropriate column Evidence of a Physical Change explosion grind/pulverize cut/tear/saw change of color melt Dissolve gas production Evidence of a Chemical Change signs of new matter explosion production of heat formation of light evaporating boil 3. Were there any changes that fit into both categories? If so, what would you have to do to ensure that a specific type of change occurred? Yes, change of color, gas production, production of heat, formation of light and explosion are all dual-category. You’d either have to cool or heat it or mix it with a specific metal. If you can undo the interaction, then you’ve made a physical change. If you can’t, or new matter was formed, then you’ve made a chemical change. 4. Did the water heated in the evaporating dish in Part A really disappear? If not, explain what happened. No, the heated water evaporated and turned into a gas. 5. What do you believe was the white residue left in the evaporating dish after heating the salt solution? The salt. 6. Explain how the gas produced from the reaction of antacid and HCl differed from that of the gas produced from the reaction of zinc metal and HCl. What do you believe the two gases were? Zinc and HC1 produced hydrogen gas, while antacid and HC1 formed Co2. Hydrogen gas was flammable, while co2 put out the fire. 7. Watch the following two videos. https://www.youtube.com/watch?v=0Ad9tholMEM https://www.youtube.com/results?search_query=hindenburg Explain how the observations of zinc and hydrochloric acid relate to this tragedy. Zinc and hydrochloric acid produce hydrogen gas, which is flammable and what Hindenburg was filled with. A spark ignited the gas and caused the tragedy. 8. Write the chemical formula for the following chemical substances used in this activity. antacid (calcium carbonate) NaHCO3 sodium chloride NaCl copper (II) sulfate CuSO4 bleach (sodium hypochlorite) NaClO vinegar (acetic acid) CH₃COOH