BY NADINE ELLIS-HALL OBJECTIVES illustrate that carbon atoms can form single and double bonds, branched and unbranched chains and ring compounds; write formulae to represent simple organic compounds; list the general characteristics of a homologous series OBJECTIVES write general and molecular formulae for members of a given homologous series deduce the homologous series given the fully displayed and condensed formulae of compounds; write fully displayed structures and names of branched and unbranched alkanes and unbranched alkenes, alcohols, and alkanoic acid; OBJECTIVES define structural isomerism; write the fully displayed structures of isomers given their molecular formulae Properties of Carbon The carbon atom have the ability of to form strong covalent bonds with other carbon atoms in chains, rings or branched structures It has the ability of carbon to form 4 bonds Types of formulae Molecular Formula – C4H10 Condensed formula – CH3CH2CH2CH3 Structural Formula – Characteristics of Homologous series All members have the same general formula All members have the same functional group (this is the bond or group of atoms that determines the reactions/ chemical properties). Successive members differ from each other by CH2 Characteristics of Homologous series All members can be made using the same general method All members have similar chemical properties Members have gradual changes in physical properties Homologous series IUPAC rules for Naming Find and name the longest continuous carbon chain. Identify and name groups attached to this chain. Number the chain consecutively, starting at the end nearest a substituent group. Designate the location of each substituent group by an appropriate number and name. IUPAC rules for Naming Assemble the name, listing groups in alphabetical order using the full name (e.g. cyclopropyl before isobutyl). The prefixes di, tri, tetra etc., used to designate several groups of the same kind, are not considered when alphabetizing Naming Number of carbon Prefices Homologous series Suffices 1C meth Alkane ane 2C eth Alkyl yl 3C prop Alkene ene 4C but Alcohol ol 5C pent Carboxylic Acid oic acid 6C hex Ester yl oate 7C hept 8C oct 9C non 10C dec Structural isomerism Structural isomers are molecules with the same molecular formula but different structural formula because of difference in the spatial arrangement of the atoms. Examples Examples Examples