SPE/IADC 103967 Drilling Performance and Environmental Compliance—Resolution of Both With a Unique Water-Based Fluid Steven Young and Gamal Ramses, M-I Swaco Copyright 2006, SPE/IADC Indian Drilling Technology Conference and Exhibition This paper was prepared for presentation at the 2006 SPE/IADC Indian Drilling Technology Conference and Exhibition held in Mumbai, India, 16–18 October 2006. This paper was selected for presentation by an SPE/IADC Program Committee following review of information contained in an abstract submitted by the author(s). Contents of the paper, as presented, have not been reviewed by the Society of Petroleum Engineers or International Association of Drilling Contractors and are subject to correction by the author(s). The material, as presented, does not necessarily reflect any position of the SPE, IADC, their officers, or members. Electronic reproduction, distribution, or storage of any part of this paper for commercial purposes without the written consent of the Society of Petroleum Engineers and International Association of Drilling Contractors is prohibited. Permission to reproduce in print is restricted to an abstract of not more than 300 words; illustrations may not be copied. The abstract must contain conspicuous acknowledgment of where and by whom the paper was presented. Write Librarian, SPE, P.O. Box 833836, Richardson, TX 75083-3836, U.S.A., fax 1.972.952.9435. Abstract In an industry where the technical demands on a drilling fluid are ever increasing, the use of invert emulsion fluids has been seen as a necessity to meet required drilling performance criteria. At the same time there is increasing pressure to comply, and even exceed, the tightening environmental demands on our industry which has made the use and associated waste treatment of these invert fluids complex and costly. A drilling fluid, which has the drilling performance characteristics of an invert emulsion fluid, but can exhibit the benign environmental characteristics of a simple water-based fluid, has long been the goal of fluids development. This paper describes the development and application of a unique water-based fluid that utilizes a triple inhibition approach to delivering invert emulsion-like drilling performance. Each component of the fluid system has also been designed to ensure compliance with some of the world’s most demanding environmental requirements. The resulting fluid is flexible in formulation such that it can be utilized in freshwater on land wells to meet chloride discharge requirements, can be formulated in seawater for shelf wells to meet low toxicity and logistics requirements, and can be formulated in saturated salt water to meet toxicity and performance requirements for deepwater environments. The applications of this fluid on a global basis will be evaluated, comparing the drilling performance and economics to offset wells which have utilized both conventional waterbased fluids and invert emulsion fluids. Introduction Invert emulsion drilling fluids, also known as “oil-based muds” (OBM) and synthetic-based muds (SBM), have traditionally always been the fluids of choice when drilling demanding wells that required a fluid that ensured a high degree of wellbore stability, was capable of insuring high rate of penetration (ROP), gave good lubricity and demonstrated the lowest potential for stuck pipe. The development of a water-based drilling fluid which could exhibit similar drilling characteristics tod an invert emulsion drilling fluid has long been seen as the ultimate goal of drilling fluids research and development. Invert emulsion drilling fluids (OBM) are universally recognized as being the most efficient fluids to drill with due to the absence of contact between the drilled formations and water, and due to the inherent oil wetting and lubricity characteristics of these fluids. The advantages of invert emulsion drilling fluids have been well documented. The major advantages are: a) Improved wellbore stability b) High degree of contamination tolerance c) Improved rate of penetration d) Low coefficient of friction e) Thin, lubricated filter cake f) Low dilution rates and ease of engineering g) High degree of re-usability The disadvantages of invert emulsion drilling fluids are typically outweighed by the advantages and have similarly been well documented. The major disadvantages are: a) Poor environmental characteristics b) Poor fracture sealing behavior (higher losses) c) Density sensitive to temperature/pressure d) Gas solubility e) High unit cost f) Logistical issues with bulk fluid transfers Several water-based drilling fluid systems have been developed over the past decade that have began to close in on the goal of OBM-like drilling performance.1-9 A few of the more successful WBMs have been: a) Potassium/salt/glycol fluids b) Silicate gluids c) CaCl2/polymer fluids d) Cationic fluids Despite these successes, however, the approaches taken with these fluids have not been completely successful in inhibiting the hydration of highly water sensitive clays and have various limitations. Potassium/salt/glycol and CaCl2/polymer fluids cannot reach the inhibition levels of an OBM, thus in highly water-sensitive shales, bit balling, accretion, wellbore instability and poor ROP can result. Silicate fluids exhibit highly inhibitive properties but have 2 problems related to logistics and mud formulation limitations. Cationic polymer systems can be almost as inhibitive as an OBM; however, the cost of running the system, toxicity of cationic polymers, and their incompatibility with other anionic drilling fluid additives has resulted in only limited success in the field. In addition to these generalized system developments, there have been a number of individual product developments that have allowed the performance of such systems to be pushed closer to that of an OBM. Effective lubricants, ROP enhancers, and more efficient filtration-control polymers are some examples. These developments have all resulted in various inhibitive water-based fluids which are relatively finely tuned to perform in certain areas whilst drilling through specific shale types. However the flexibility of an OBM in a multitude of drilling environments is one of the areas in which current WBM have not yet reached the level of OBM performance. Research and Development A research and development initiative was undertaken to evaluate the potential for improving upon existing highperformance water-based drilling fluid (HPWBM) technologies, or developing a new HPWBM technology. Giving the overall goal of the development project – to find a WBM that would give similar performance characteristics to that of an IEM – it was determined that development of individual products, which could enhance existing systems, would be insufficient to achieve the goal. With this in mind, a complete system approach was taken. Learning from previously developed and utilized HPWBM, it was deemed critical that throughout the development focus should be maintained on the entire performance spectrum of an IEM, and not limited to only one aspect of IEM performance. The following were determined to be the key development criteria: • High degree of inhibitive response across a wide range of shale types • Significant reduction in clay dispersion and hydration compared to existing inhibitive systems • Lower degree of accretion and cuttings agglomeration related problems • Environmentally acceptable on a global basis • Highly flexible in formulation – easily controllable filtration and rheology profiles, and usable with various base brines • Highly solids and contamination tolerant • Economical in both make-up and maintenance • High degree of engineering control possible The test matrix involved testing novel system components in four different base fluids (freshwater, seawater, 10% KCl, and 20% NaCl). Testing was conducted on four differing shale substrates (from highly swelling to highly dispersive), and used a variety of inhibition test methods (shale dispersion, bentonite tolerance, shale swelling, shale hardness, shale accretion) which are described more fully in a previous publication.10 In addition to these inhibition performance tests, the novel formulated fluids were also subject to fluids performance testing (lubricity, filtration, rheology, SPE/IADC 103967 contamination tolerance, thermal stability, etc.) to evaluate their overall performance. The test results achieved were compared to three baselines of a mineral oil-based fluid, a NaCl/polymer water-based fluid, and a silicate highperformance, water-based fluid. Generalized formulations for the novel HPWBM, and formulations for the three baseline fluids are shown in Tables 1a-d. The final result of this research and development project was a new water-based drilling fluid which exhibited laboratory performance characteristics which were in the realm of those achieved by OBM and far exceeded those exhibited by other water-based fluids. This fluid was then taken to the field test stage. New Fluid Formulation From the final results of our extensive matrix of testing, a final novel HPWBM emerged consisting of four synergistic basic products; a brief description of these key components follows. Typical formulations for this fluid for a Gulf of Mexico deepwater well, a South China Sea shelf well and a Western USA land well are given in Table 2. Hydration Suppressant. The optimum product developed is a multi-functional, complex, slightly cationic, polyamine-based material of specific molecular weight, which is fully watersoluble. The compound is compatible with other common drilling fluid additives used in WBM, exhibits a pH buffering effect, and has no hydrolyzable functionality. The unique molecular structure of this material has been shown by molecular modeling techniques to provide a perfect fit between clay platelets, tending to collapse the clays hydrated structure and greatly reduce the clay’s natural tendency to take up water. The material requires minimal ionicity for maximum functionality, and is equally stable in high salinity and hardness environments. In addition to its ideal inhibitive function, the material has been designed to exhibit minimal toxicity, to be biodegradable, and to be safe to handle. Dispersion Suppressant. The optimum product developed is a low-molecular-weight, mildly cationic, fully water-soluble copolymer that exhibits good biodegradability and low marine toxicity. The polymeric material is designed to have a molecular weight and charge density that promotes superior inhibition by limiting water penetration into the clays and binding clay platelets together. The molecular weight and charge of the polymer allows rheological flexibility over a wide range of fluid densities while tolerating high salinity and hardness. The compound has the characteristics of controlling both dispersion and accretion of water-sensitive clays. Rheology Controller. Xanthan gum was chosen as the optimum rheology control agent for the fluid, based on the high efficiency of the polymer and its function across a broad range of salinities and to hardness. The high low-shear-rate viscosity (LSRV) and efficient carrying capacity of the polymer optimizes rheological control and improves fluid performance in extended reach and deepwater environments by allowing optimization of hydraulics and hole cleaning. In complex, deepwater wells, an alternate rheology control, based on an optimized synergistic biopolymer SPE/IADC 103967 combination, can be used to achieve a flatter rheology profile (minimal effect of temperature on yield point and gel strength) which allows further optimization of hydraulics and hole cleaning in these operational environments Filtration Controller. A low viscosity, highly modified, polysaccharide polymer was chosen as the optimal filtrationcontrol agent for the system. This polymer is stable in low to high salinities, and at high hardness levels. The low-viscosity contribution of the polymer allows for optimal filtration control, to be achieved even at high solids loading (high mud weights). The low contribution to viscosity from this polymer also allows for increased rheological optimization to improve system drilling performance. Accretion Suppressant. The optimum product developed is a unique blend of coating agents, surfactants and lubricants designed to coat drill cuttings and metal surfaces to reduce the accretion tendency of hydrated cuttings on the surface of metals and with each other. This blended material is designed to exhibit stability across a wide range of salinities and be compatible with highly solids-laden (high mud weight) fluids. The accretion suppressant aids in preventing any buildup of drill solids below the bit, allowing the cutters good contact with new formation for improved rate of penetration. The component also lowers torque and drag by reducing the coefficient of friction and by thinning out and lubricating the filter cake. The development and selection of each of these components were coordinated, optimizing upon the synergies between the chemistry and performance the materials. This resulted in an improvement in the flexibility of the overall system design. The net result of this development process is a high-performance, water-based fluid which has the capability of both performing in a wide variety of base fluids, and over a wide density and temperature range. New Fluid Performance From initial results of laboratory testing (Figures 1-5), it can be seen that these newly developed components of this novel HPWBM individually exhibit performance characteristics that exceed those previously seen from modern water-based drilling fluid additives. The hydration suppressant shows a high degree of recovery of shale pieces exposed to the inhibitor in a variety of brines, and shows little softening of shales on exposure. The product also shows a tendency to prevent shale swelling. The Optimum concentration range for this product lies at 2-3% by volume. The dispersion suppressant shows a high level of resistance to shale dispersion and contributes towards a reduction in shale accretion. The optimum concentration range for this product lies at 2-3 lbm/bbl. The accretion suppressant shows high efficiency at preventing shale cuttings from adhering to metal surfaces, and also contributes towards a lower friction coefficient. The optimum concentration range for this product lies at 1-3% by volume. Bringing all of the components together into a final HPWBM formulation readily demonstrated the synergistic 3 benefits obtained and demonstrated the true performance that can be achieved with such a design of water-based fluid. Summaries of a few of the laboratory test results are shown as Figures 6 to 12. This testing was carried out on four outcrop shale substrates which were used in their native state: • Raw Bentonite –Wyoming bentonite ore, which is predominantly sodium montmorillonite and has high swelling characteristics. The moisture content is low at ~2%. • Foss Eikeland Shale – an outcrop shale from Norway which has ~15% sodium montmorillonite, and exhibits high tendency to dispersion and accretion. This shale has moderate moisture content at ~12%. • Oxford Clay – an outcrop shale from Great Britain which has ~10% sodium montmorillonite, and shows a tendency to both swell and disperse. This shale has moderate moisture content at ~14%. • Arne Clay – an outcrop clay from Great Britain composed predominantly of kaolinite. The material is fragile and has a very high tendency to disperse and accrete. This shale has low moisture content at ~6%. Four drilling fluid systems are compared in these test results shown: 1. OBM – conventional mineral-oil-based fluid, 80/20 O/W ratio, YP = 15, ESV= ~1000 v, and density 12 lbm/gal. 2. NaCl/polymer – a WBM typically used in US GOM, with 20% wt NaCl and 1-lb/bbl PHPA polymer. YP = 15, weighted to 12 lbm/gal with barite. 3. KCl/silicate – one of the most inhibitive WBM with 10% KCl and 8% sodium silicate. YP = 15, weighted to 12 lbm/gal with barite. 4. HPWBM – newly formulated high-performance water-based drilling fluid, which was weighted to 12 lbm/gal and YP = 15. The formulation is given in Table 1. Figure 6 shows the comparative shale inhibition results using the slake durability test method. Figures 7a-d show comparative shale inhibition using the cuttings hardness test method. Figure 8 shows the comparative performance of the fluids with respect to cuttings accretion using the rolling bar test method. Figure 9 shows the comparative lubricity measured using the Fann metal/metal lubricity test at two different loadings. Figure 10 shows the comparative effect of solids loading using OCMA bentonite as the contaminant. From these tests, it can be seen that the HPWBM significantly outperformed both the NaCl/polymer and the KCl/silicate water based fluids and could be compared directly with the performance of the OBM. Figure 11 shows the inhibition characteristics of the new water-based fluid using different base fluids of seawater, 10% KCl brine, and 20% NaCl brine. In all of these tests the fluids were formulated with 3% hydration suppressant, 2-lb/bbl dispersion suppressant, and 1.5% accretion suppressant. This 4 demonstrates the flexibility of the fluid that was desirable and was part of the design criteria. Based on these, and many other test results, the new water-based drilling fluid was considered, from a laboratory standpoint, to be a significant improvement over existing water-based fluids and to show great promise as a true performance equivalent to invert emulsion drilling fluids. In addition to the above, more complex testing such as molecular modeling of inhibitor chemical behavior in shale substrates, shale membrane testing, and large-scale accretion and ROP testing was conducted prior to the newly formulated fluid being considered for field trial. Environmental Performance Given the potential scope of use of this newly developed HPWBM, a rigorous series of environmental tests were performed to ensure that the fluid would have minimal impact on the external environment on discharge. In addition a series of engineering guidelines were developed with respect to measurement and control of the fluid with the desire to optimize product additions and minimize whole drilling fluid dilution requirements. Initial marine toxicity testing was carried out according to the United States EPA guidelines, using the marine shrimp species mysidopsis bahia. Each of the components of the system were tested individually, at the uppermost recommended concentration level, in a standardized test fluid (Generic Mud #7) to determine the LC50. In addition to the component testing, a number of whole drilling fluid formulations were tested using the same EPA test protocol and species. Seawater and 20% sodium chloride-based fluids were tested both with and without drill solids contamination. Test results obtained are shown in Table 3. Achieving shale inhibitive performance without using a potassium ion is an important benefit of the new HPWBM. A number of marine test species used globally (e.g. US Gulf of Mexico, Offshore Brazil, Offshore India) are sensitive to high potassium contents. Further marine toxicity testing was carried out on each of the chemical components of the materials of the system according to the North Sea (PARCOM) testing protocol. Testing was carried out on three different species (skeletonema costatum – a marine algae, acartia tonsa – a crustacean, corophium volutator – a sediment reworker and scophthalmus maximus juvenile – a fish) according to the harmonized North Sea environmental testing requirements. In addition to the toxicity testing, the biodegradability in seawater (procedure OECD 306) and potential for bioaccumulation (procedure OECD 117) were also tested for each of the chemical components. Available heavy metals were also analyzed by ICP-MS. These initial tests showed that the products chosen were all of acceptably low toxicity, showed no tendency to bioaccumulate and had very low available heavy metals content. One component of the accretion suppressant required a chemical change to comply with specific chemical group selection for the Norwegian environmental authorities, and the product was reformulated to meet these requirements with similar technical performance. The hydration suppressant material showed lower than required biodegradation rates SPE/IADC 103967 using the Seawater Test Method, and a chemical “tweak” was made to this product composition to improve biodegradability without sacrificing optimum performance. The net result of these changes was to provide a North Sea optimized fluid formulation that meets all the environmental demands of this operating area. Similar requirements are set for operations in East Coast Canada, Australia, New Zealand and Vietnam. For land drilling applications, initial environmental evaluation was carried out according to the Canadian Microtox testing protocol, which evaluates the effect of the system components on the growth of bacteria. All of the system components were tested and deemed to be acceptable for use and discharge to land at their normal operating concentrations with the exception of the fluid-loss controller and the accretion suppressant. Chemical redesign of the fluid loss controller has resulted in a material which passes the Microtox test. A reformulated accretion suppressant that meets the Microtox test criteria is still under development. Other test criteria taken into consideration foro use and discharge on land are electrical conductivity and seed germination studies. In the former case the ability to provide an effective shale inhibitive fluid in a base of freshwater (without requirement for use of highly conductive salts of potassium, calcium or aluminum) and the utilization of additives that have a low residual conductivity has allowed the new HPWBM, and solids contaminated with this fluid, to meet electrical conductivity requirements without resorting to dilution or treatment of effluent/solids. Seed germination studies (on bean sprouts) have been carried out comparing germination rates in agricultural soil vs. germination rates in the same soil contaminated with up to 20% of the new HPWBM. These results show no reduction in either seed germination quantity or in seedling elongation over a 72-hour period by contamination of the soil with the new HPWBM. At a 10% contamination level, the seed elongation test showed an average improvement in the contaminated soil when compared to the baseline. When using the new HPWBM in the field, engineering principles and procedures can be applied to the system to ensure further protection to the environment over and above those applied to more conventional inhibitive water-based fluids. The chemical composition, high inhibitive performance and tolerance to drill solids of the new HPWBM allow engineering recyclability to be practiced. Dewatering. Use of a custom developed deflocculation chemistry package applied to a solids-laden HPWBM fluid, allows the recycling of “base brine” that can be used as dilution fluid for the existing circulating system, or can be used as the base for building a new fluid system. Typically carried out in land drilling operations, the dewatering process recovers approximately 60 – 70% of the measured hydration suppressant and 50 – 60% of the measured accretion suppressant along with a solids-free base fluid. In low-density fluids, this process can translate to a reduction in fluid and chemical discharges of up to 50% as compared to more conventional water-based fluids. Storage and Reuse. By maintaining the new HPWBM within programmed parameters (good solids control and optimized dilution treatment) throughout a well, the new HPWBM can be stored, reconditioned (if required) and reused SPE 103967 on a subsequent well. This is possible because of the longterm stability of the system chemistry and the highly inhibitive and solids-tolerant nature of the system. With effective reconditioning and reuse principles applied, the new HPWBM can allow a reduction in chemical discharges of up to 60% as compared to more conventional water-based fluids. Engineering Guidelines Prior to the initial field trials of the new HPWBM, a series of operational engineering guidelines, and some specific system engineering tests, were developed to ensure the most optimum control could be maintained over the drilling fluid at the rigsite, and that optimized drilling performance could then be obtained through use of the fluid. Over the course of the initial field trials, and with usage of the system in a number of highly complex drilling scenarios, these guidelines have been modified to again allow for the best performance to be achieved whilst utilizing this fluid system. These operational guidelines can be summarized in the following points: Rheology. Rheological parameters are controlled to meet the requirements of a pre-determined hydraulics plan that is designed to optimize hole cleaning and minimize ECD effects, whilst maximizing pressure drop across the drill bit. Hydraulics calculations are run throughout drilling of the well and parameters adjusted accordingly to maintain optimization. It is critical to adhere to optimized hole cleaning guidelines (controlled rate of penetration, drill pipe rotation, circulation time, tripping procedures) as the gauge hole and high cuttingsgeneration rate can rapidly lead to wellbore cleaning problems. MBT/Drill Solids. Although the new HPWBM will tolerate high levels of drill solids contamination, in order to maintain optimum drilling performance (hydraulics and filtration) it is essential to maintain a good control over drill solids content. This is achieved primarily by use of good solids-control equipment (fine shale-shaker screens) coupled with controlled dilution when necessary. The actual levels of drill solids that are acceptable to maintain optimum properties will be a function of the drilling fluid density. A chart outlining these guidelines for solids contents and MBT is shown as Figure 12. Hydration Inhibitor Concentration. Typically the volume of the hydration inhibitor is 3% and maintained throughout drilling, with an expected 5-15% concentration depletion possible depending on area, shale type, and drilling parameters. The concentration of the hydration suppressant is measured directly in the drilling fluid via a developed filtrate titration test, allowing optimum control to be maintained. Maintenance should be done via concentrated whole mud premix when maintaining system volume during the drilling process, however direct additions of the hydration suppressant can be made without detrimental effect on system properties. After gaining experience with the formations in an area, it may be possible to maintain the concentration at a lower level (not below 2% or a detrimental performance is observed) to optimize economics. Observation of softer cuttings at the shale shaker is an indicator of too low levels of hydration suppressant. Dispersion Suppressant Concentration. Typically 2 lbm/bbl of the dispersion suppressant is maintained throughout 5 drilling, with an expected 10-25% concentration depletion being seen depending on area, shale type, and drilling parameters. The concentration of the dispersion suppressant is measured directly in the drilling fluid via a developed hydrolysis/back titration test on whole fluid allowing optimum control to be maintained. Maintenance should be done via concentrated whole mud premix when maintaining system volume during the drilling process, however direct additions of the dispersion suppressant can be made without detrimental effect on system properties. Observation of sticky, dull cuttings at the shale shaker is an indicator of too low levels of dispersion suppressant. Accretion Suppressant Concentration. Typically 2% by volume of the accretion suppressant is maintained throughout drilling, with little depletion being seen. The concentration of the accretion suppressant is measured directly in the drilling fluid via a developed retort analysis test on whole fluid allowing optimum control to be maintained. Maintenance should be done via concentrated whole mud premix when maintaining system volume during the drilling process, however direct additions of the accretion suppressant can be made without detrimental effect on system properties. After gaining experience with the formations in an area, it may be possible to maintain the concentration at a lower level (not below 1% or a detrimental performance is observed) to optimize economics Observation of whole cuttings that easily adhere to each other at the shale shaker is an indicator of too low levels of accretion suppressant. In certain areas, and at higher fluid densities, concentrations of up to 3% by volume may be required for optimum drilling performance. Field Usage The HPWBM described above was first operationally introduced for field trials in late 2001, in the deepwater arena of the Gulf of Mexico. Since these initial trials, the fluid has been utilized on over four hundred wells on a global basis. In over 50% of the applications, the HPWBM initial selection has been on the basis of replacing either existing or planned usage of invert emulsion fluids. A generalized breakdown of the applications of the new HPWBM fluid by well type, and by well geographic locations, is shown in Figures 13a and 13b. The unique performance of the new HPWBM has led to its consistent usage in a variety of difficult drilling situations. Some of the highlights of its usage are: • Deepwater record: 9,472 ft water depth, offshore Brazil • Maximum mud weight: 17.2 lbm/gal, Wyoming US • Maximum angle built: >90o, United Arab Emirates; Brazil • Maximum number of intervals in one well: five (20, 17, 14.5, 12.25, 8.5-in.), Gulf of Mexico • Longest interval: 9,384 ft, South China Onshore • Longest directional interval: 8900 ft of 17½-in, 65° angle, North Sea Benchmarks against diesel, mineral oil and syntheticbased invert emulsion fluids as well as other water-based fluids have been conduced, evaluating the drilling performance, environmental performance and economic 6 performance of the new HPWBM in the field. In all of the areas used, the new HPWBM has proven itself to far exceed the performance of other inhibitive water-based fluids in terms of improved wellbore stability, improved drilling performance (ROP), ease of maintenance of fluid properties, lower dilution rates and improved economics of the drilling operation. In addition the new HPWBM has proven in many cases to show equivalent drilling performance to invert emulsion fluids with respect to wellbore stability and drilling rates. (Figure 14a-b). The enhanced shale inhibition characteristics and low risk of accretion seen from the new HPWBM has allowed the use of high performance PDC drill bits to achieve optimal drilling rates even through some extremely reactive shale formations, while the gauge wellbore that characterized drilling with this new HPWBM has ensured ease of directional control maintenance. The use of the new HPWBM has been characterized by large, well-defined, cuttings (Figure 15a-b) readily removed by the primary solids-control equipment on the first pass, ensuring that the fluid does not become rapidly contaminated by drill solids, and that dilution rates to maintain drilling fluid parameters is low. Also characteristic has been clean bits and bottomhole assemblies (Figure 16a-b) recovered from drilling with the new HPWBM in areas where bit and BHA balling has been the norm with other inhibitive water-based fluids. Conclusions The HPWBM developed and described in this paper is unique in its design with a total-system approach. The fluid system contains products specifically chosen to be synergistic and to satisfy all of the requirements of a high-performance drilling fluid. Unlike previously developed and used inhibitive waterbased fluids, the new HPWBM is extremely flexible in its design and easy to engineer and control under various conditions. Laboratory tests indicated that the system could be successfully formulated with a variety of base brines (from freshwater to saturated salt) and at densities ranging from 8.6 to 16 lbm/gal. This has been borne out by field application where fluids based on freshwater, seawater, NaCl and KCl have been used, and fluid densities of up to 17.2 lbm/gal have been utilized. The environmental characteristics of the new HPWBM have been designed to meet and exceed the environmental requirements for use and discharge of such drilling fluids on a global basis. This has been borne out by the acceptability of the fluid to the regulators in each country where it has been used. Significant additional environmental benefits from the new HPWBM have been realized by applying recycling techniques suited to the system design. Development and application of field testing procedures to measure actual product concentrations and implementation of sound engineering guidelines have aided in ensuring that the performance of the new HPWBM is maintained at an optimal level. The extensive field usage of the new HPWBM has demonstrated that the fluid can be easily prepared, has good screen-ability through fine shaker screens and has outstanding drilling performance. The use of this fluid to drill numerous highly reactive shale formations gas confirmed the laboratory SPE/IADC 103967 predictions for cuttings integrity and wellbore stability. Performance and flexibility are two attributes that bring this drilling fluid closer to an invert emulsion based drilling fluid than any other. Acknowledgements The authors wish to thank Mary Dimataris for her help with the manuscript and M-I SWACO for permission to publish this paper. References 1. Downs, J.D., van Oort, E., Redman, D.I., Ripley, D. and Rothmann, B.: “TAME: A New Concept in Water-Based Drilling Fluids for Shales,” SPE 26699, Offshore Europe Conference, Aberdeen, Sept 7-10, 1993. 2. Simpson, J.P., Walker, T.O., and Jiang, G.Z.: “Environmentally Acceptable Water-Base Mud Can Prevent Shale Hydration and Maintain Borehole Stability,” SPE 27496, SPE/IADE Drilling Conference, Dallas, Feb 15-18, 1994. 3. Chenevert, M.E.: “Shale Alteration by Water Absorption,” Journal of Petroleum Technology (Sept 1970) 1141. 4. Young, S. and Maas, T. “Novel Polymer Chemistry Increases Shale Stability” AADE 01-NC-HO-41, AADE National Drilling Conference, Houston, Mar 27-29, 2001. 5. Patel, A., Stamatakis, E., Friedheim, J.E. and Davis, E.: “Highly Inhibitive Water-Based Fluid System Provides Superior Chemical Stabilization of Reactive Shale Formations” AADE 01-NC-HO-55, AADE National Drilling Conference, Houston, Mar 27-29, 2001. 6. Retz, J.R., Friedheim, J., Lee, L.J., and Welch, O.O.: “An Environmentally Acceptable and Field-Practical Cationic Polymer Mud System,” SPE 23064, Offshore Europe Conference, Aberdeen, Sept 3-6, 1991. 7. Stamatakis, E., Thaemlitz, C.J., Coffin, G. and Reid, W.: “A New Generation of Shale Inhibitors for Water-Based Muds,” SPE 29406, SPE/IADC Drilling Conference, Amsterdam, Feb 28 – Mar 2, 1995. 8. Clark, R.K., Scheuerman, R.F., Rath, H. and Van Laar, H.G.: “Polyacrylamide/Potassium Chloride Muds for Drilling WaterSensitive Shales,” Journal of Petroleum Technology (June 1976) 719. 9. Schlemmer, R., Patel, A., Friedheim, J., Young, S. and Bloys, B.: ”Progression of Water-Based Fluids Based on Amine Chemistry – Can the Road Lead to True Oil Mud Replacements?” AADE-03-NTCE-36, AADE National Drilling Technology Conference, Houston, April 1-3, 2003. 10. Young, S., Patel, A., Stamatakis, E., Cliffe, S.: Designing for the Future – A Review of the Design, Development and Testing of a Novel, Inhibitive Water-Based Drilling Fluid. AADE-02-60, AADE National Drilling Technology Conference, Houston, April 2-3, 2002. SPE/IADC 103967 7 Table 3 Mysidopsis bahia Test Results Test Substance/concentration EC50, ppm SPP Dispersion suppressant *(3% Vol) >300,000 Hydration suppressant *(3 lbm/bbl) >500,000 Accretion suppressant * (3% Vol) 248,000 Polymer viscosifier * (2 lbm/bbl) >500,000 Fluid loss controller * (5 lbm/bbl) >500,000 Seawater HPWBM 268,000 Seawater HPWBM (a) >300,000 20% NaCl HPWBM 249,000 20% NaCl HPWBM (a) >300,000 Field HPWBM (b) 219,000 Table 1a Typical Composition of HPWBM (20% NaCl) Seawater (mL) 293.0 NaCl (g) 80.4 Filtration controller (g) 4.0 Polymer viscosifier (g) 0.8 Dispersion suppressant (g) 2.0 Hydration suppressant (g) 10.5 Accretion suppressant (g) 7.5 Table 1b Typical Composition of Silicate Mud Freshwater (mL) 290.0 Sodium silicate (mL) 42.0 Soda ash (g) 0.5 KCl (g) 30.0 Fluid loss agent (g) 5.0 Polymer viscosifier (g) 1.0 Acceptable internal limits are >100,000 ppm SPP. * Tested in Generic mud #7. # Each fluid contained 3% vol hydration suppressant, 2-lbm/bbl cispersion suppressant, and 2% vol accretion suppressant. Weighed to 12.0 lbm/gal with barite. (a) Contained 30-lbm/bbl OCMA clay (b) 20% NaCl-based Field mud after drilling Gulf of Mexico deepwater well Table 1c Typical Composition of NaCl/Polymer Mud Freshwater (mL) 323.0 NaCl (g) 73.2 NaOH (g) 0.5 Bentonite (g) 5.0 Fluid loss agent (g) 3.0 PHPA (g) 1.0 Polymer viscosifier (g) 0.5 Table 1d Typical Composition of Oil Based Mud Mineral oil (mL) 255.0 Primary emulsifier (mL) 10.0 Secondary emulsifier (mL) 2.0 Lime (g) 7.5 Polymer fluid loss agent (g) 2.0 Organoclay viscosifier (g) 6.0 25% CaCl2 Brine (mL) 75.0 120 Cuttings Recovery (%) 100 80 60 40 20 Oxford Foss Eikeland 0 0 Shale type Arne 0.01 0.02 0.03 Material concentration Fig. 1 – Inhibition performance of hydration suppressant by hotroll dispersion testing. 350 #1 - Gulf of Mexico deepwater well #2 - South China Sea shelf well #3 - Western USA land well 0 300 1% 2% 250 Torque (ftlbs) Table 2 Typical Field Composition of HPWBM Product / formulation # #1 #2 #3 Freshwater 320 Seawater (mL) 290 315 NaCl 80 KCl (g) 20 Filtration controller (g) 3 4 3 Polymer viscosifier (g) 1.25 1 1.25 Dispersion suppressant (g) 2 2 2 Hydration suppressant (g) 10 8 10 Accretion suppressant (g) 8 6 3% 200 Shale 150 100 50 0 5 6 7 8 9 10 11 12 13 14 15 Num ber of turns Fig. 2 – Inhibitive performance of hydration suppressant by bulk hardness method (Oxford Clay). 8 SPE/IADC 103967 Raw Bentonite 120 120 100 Seaw ater Percentage shale recovery Linear expansion (%) Oxford Clay Foss Eikeland 100 80 3% Hydration Suppressant 60 40 20 Arne Clay 80 60 40 20 0 12 0 11 0 90 Tim e (Minutes) 10 0 80 70 60 50 40 30 20 2 10 0 0 Fig. 3 – Inhibitive performance of hydration suppressant by linear swelling test. (Nahr Umhr shale). OBM NaCl/Polym er KCl/Silicate HPWBM Fig. 6 – Comparative shale inhibition by slake durability testing. 350 300 50 Torque (ftlbs) Cuttings Recovery (%) 60 40 30 20 10 Oxford 250 200 OBM 150 NaCl/Polym er 100 KCl/Silicate HPWBM 50 Shale Foss Eikeland 0 0 1 lbm /bbl Shale type Arne 2 lbm /bbl 0 5 6 7 8 3 lbm /bbl 9 10 11 12 13 14 15 Number Of Turns Material concentration Fig. 4 – Inhibitive performance of dispersion suppressant by slake durability testing Fig. 7a – Comparative shale hardness testing (raw bentonite). 350 OBM 60 300 50 250 Torque (ftlbs) % cuttings accreted 70 40 30 20 10 NaCl/Polym er KCl/Silicate HPWBM Shale 200 150 100 Arne Foss Eikeland 0 0 0.01 Oxford 0.02 Shale type 0.03 Material concentration Fig. 5 – Performance of accretion suppressant by rolling bar test. 50 0 5 6 7 8 9 10 11 Num ber of Turns 12 13 14 15 Fig. 7b – Comparative shale hardness testing (Foss Eikeland Clay). SPE/IADC 103967 9 350 0.4 250 ftlbs 0.35 400 ftlbs OBM NaCl/Polym er 300 Torque (ftlbs) 250 Coefficient Of Friction KCl/Silicate HPWBM Shale 200 150 100 0.3 0.25 0.2 0.15 0.1 0.05 50 0 0 OBM 5 6 7 8 9 10 11 Num ber of Turns 12 13 14 KCl/Silicate HPWBM Fig. 9 – Comparative lubricity 12.0-lbm/bbl fluids by Fann metal/metal tester. Fig. 7c – Comparative shale hardness testing (Oxford Clay). 100 350 OBM NaCl/Polym er 300 KCl/Silicate 250 HPWBM YP (lbs/100ft2) Torque (ftlbs) NaCl/Polym er 15 Shale 200 150 100 90 OBM 80 NaCl/Polym er 70 KCl/Silicate 60 HPWBM 50 40 30 20 50 10 0 0 5 6 7 8 9 10 11 Num ber of Turns 12 13 14 15 Fig. 7d – Comparative shale hardness testing (Arne Clay). 0 50 100 150 200 ppb OCMA clay added 250 300 Fig. 10 – Comparative solids tolerance by YP after aging at 200F, 16 hr. Seawater 10% KCl 60 20% NaCl 100 Raw Bentonite Percentage Shale accretion Foss Eikeland Arne Clay 40 30 20 Shale Recovery (%) Oxford Clay 50 90 80 70 60 50 40 30 20 10 10 0 0 OBM NaCl/Polym er KCl/Silicate HPWBM Fig. 8 – Comparative shale accretion potential by rolling bar testing. Raw Bentonite Oxford Clay Foss Eikeland Arne Clay Fig. 11 – Shale inhibition of HPWBM formulated in differing base brines. 10 SPE/IADC 103967 18 8 9 10 11 12 13 14 15 16 17 18 Mud Weight (lbm/gal) SBM SBM 2 SBM 0 SBM 4 1 0.5 SBM 6 SBM 8 2 1.5 SBM 10 3 2.5 SBM 12 HPWBM 14 3.5 HPWBM MBT lbm/bbl Drill Solids % vol Days per 1,000ft BML MBT (lbm/bbl), drill solids (%) 4 16 Fluid type used Fig. 12 – HPWBM engineering guidelines - drill solids and MBT content vs. mud weight. Fig. 14a – Drilling performance comparison for offset wells in deepwater Gulf of Mexico. 80 Max ROP 70 Min ROP ROP (ft/hr) 60 50 40 30 20 Shelf wells SBM SBM Deepwater Wells NaCl/Polymer Land Wells SBM 0 HPWBM 10 Fluid system used Fig. 13a – Usage of HPWBM by well type. Fig. 14b – Drilling performance comparison for deepwater Gulf of Mexico offset wells (16-in. hole section). North America South America Europe/CIS Africa Middle East Far East Fig. 13b – Usage of HPWBM by geographic area. Fig. 15a – PDC generated cuttings from drilling 12¼-in. hole section in Vietnam with HPWBM. SPE/IADC 103967 Fig. 15b – PDC generated cuttings from drilling 17½-in. hole section in Gulf of Mexico with HPWBM. Fig. 16a – Clean bottom hole assembly pulled after drilling reactive clay secion in Gulf of Mexico with HPWBM. 11 Fig. 16b – Clean underreamer assembly pulled after drilling reactive clay secion in Gulf of Mexico with HPWBM.