Course Specification Term 2 (AY 21-22) Course Name: Chemistry Course Code: CHM51 Grade: 10 Advanced Aim: The Grade 10 Chemistry course provides students with a college-level foundation to support future advanced coursework in Chemistry. The course will give students the opportunity to cultivate their understanding of Chemistry through inquiry-based investigations as they explore topics as Structure & Properties of Matter, Chemical Bonding & Reaction, Matter, Energy & Equilibrium, Organic & Nuclear Chemistry. Course Outline: Unit Number of Periods Term 2 Unit 2: Chemical Bonding and Reaction (Continued) 36 • 2.3 – Chemical Reactions (Inspire Chemistry, Unit 2 – Module 8: Lesson 1 – 3) 10 • 2.4 – The Mole (Inspire Chemistry, Unit 2 – Module 9: Lesson 1 – 4) 13 • 2.5 – Stoichiometry (Inspire Chemistry, Unit 2 – Module 10: Lesson 1 – 4) 13 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 1 of 46 Unit 2: Chemical Bonding and Reaction 2.3 – Chemical Reactions Inspire Chemistry – Module 8 – Lesson 1: Reactions and Equations CHM.5.3.01.014.01 Distinguish between chemical reaction and chemical equation A chemical reaction is a rearrangement of the atoms in one or more substances to form different substances. It occurs when reactants are converted to products. A chemical equation is a statement that uses chemical formulas to show the identities and relative amounts of the substances involved in a chemical reaction. CHM.5.3.01.014.02 List different observations (or physical evidences) that indicate that a chemical reaction may be taking place The different observations (Physical Evidences) include: 1) Release of energy as heat or light 2) Absorption of heat 3) Production of gas 4) Formation of a precipitate (solid) 5) Color change 6) Odor change CHM.5.3.01.014.03 Explain the difference between reactants and products in a chemical equation Reactants are the initial components (starting substances). Products are the resultant components (substances formed during the reaction). Example: For the following reaction, identify the reactant(s) and product(s) CaO(s) + CO2(g) → CaCO3(s) Reactants: CaO and CO2 Product: CaCO3 CHM.5.3.01.014.04 Identify reactants and products in a chemical equation Example: For each of the following chemical reactions or equations, identify the reactant(s) and product(s) Chemical Reaction or Equation Solid aluminum, Al, reacts with oxygen gas, O2, to form solid aluminum oxide, Al2O3 Reactant Aluminum, Al Oxygen, O2 Product Aluminum oxide, Al2O3 Carbon tetrachloride, CCl4, is prepared in the liquid form, by the reaction of chlorine gas, Cl2, and methane gas, CH4. Hydrogen chloride is also formed in the reaction. Chlorine, Cl2 Methane, CH4 Carbon tetrachloride, CCl4 Hydrogen chloride, HCl Ca + 2HCl → CaCl2 + H2 Ca HCl NH3 O2 CaCl2 H2 NO H2O 4 NH3 + 5 O2 → 4 NO + 6 H2O G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 2 of 46 CHM.5.3.01.014.05 Describe what do the arrows and coefficients mean in chemical equations Arrows: They separate reactants from products and specify direction A coefficient is the number written in front of a reactant or a product that is used to balance chemical equations. Coefficients: They specify the relative amount of the components CHM.5.3.01.014.06 Identify the meaning of different symbols used in equations Symbols Used in Chemical Equations Symbol Explanation + Separates two or more reactants or products → “Yields,” separates reactants from products ⇌ Yields,” separates reactants from products Indicates a reversible reaction (s) Designates a reactant or product in the solid state It is placed after the formula (l) Designates a reactant or product in the liquid state It is placed after the formula (g) Designates a reactant or product in the gaseous state It is placed after the formula (aq) Designates an aqueous solution; the substance is dissolved in water It is placed after the formula ∆ → Indicates that heat is supplied to the reaction X A formula written above or below the yields sign indicates its use as a catalyst → CHM.5.3.01.014.06 Describe word equation A word equation is a statement to indicate the reactants and products of chemical reactions. Example: Write the word equation for the following chemical Reaction: N2(g) + 3H2(g) → 2NH3(g) Nitrogen gas and hydrogen gas react together to produce ammonia gas. CHM.5.3.01.014.08 Compare and contrast a skeleton equation and a chemical equation The skeleton equation includes the formulas of reactants and products (without indicating their amounts). The chemical equation gives the relative amounts of reactants and products. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 3 of 46 CHM.5.3.01.014.09 Write a skeleton equation for a word equation and vice versa Example: Write the skeleton equation for the following word equation: “Iron reacts with oxygen to form iron (III) oxide” Skeleton equation: CHM.5.3.01.014.10 is conserved Fe + O2 → Fe2O3 Explain why it is important to balance a chemical equation while identifying what Because mass is neither created nor destroyed in chemical reactions (according to the Law of conservation of mass), the number of atoms of all elements must be equal on both sides of the reaction arrow In a chemical equation, mass and number of atoms are conserved. CHM.5.3.01.014.11 Explain why when balancing a chemical equation, the subscript of the formula is not adjusted When balancing a chemical equation, the subscript of the formula is not adjusted because this will change the identity of the substance. CHM.5.3.01.014.12 Identify the quantitative information revealed by a chemical equation The quantitative information revealed by a chemical equation is the number of molecules, and atoms of each element or compound composing the reactants and products CHM.5.3.01.014.13 Describe the steps used in balancing an equation The steps for balancing an equation: 1) Write the skeleton equation for the reaction 2) Count the atoms of the elements in the reactants 3) Count the atoms of the elements in the products 4) Change the coefficients to make the number of atoms of each element equal on both sides of the equation, showing that atoms are conserved 5) Write the coefficients in their lowest possible ratio 6) Check you work G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 4 of 46 CHM.5.3.01.014.14 Balance different chemical equations Example: Balance each of the following chemical equations. __Fe2 O3(g) + __H2 (g) → __ Fe(s) + __H2 O(g) 1, 3, 2, 3 __Cl2(g) + __CH4 (g) → __CCl4 (l) + __HCl(g) 4, 1, 1, 4 __Zn(s) + __CuCl2 (aq) → __ZnCl2 (aq) + __Cu(s) 1, 1, 1, 1 __F2(g) + __H2 O(l) → __HF(g) + __O2(g) 2, 2, 4, 1 CHM.5.3.01.015.01 Build, using molymods, a model for representing chemical reactions and chemical compounds Inspire Chemistry – Module 8 – Lesson 2: Classifying Chemical Reactions CHM.5.3.01.016.01 Define a synthesis reaction while writing the general equation, particulate diagram and some examples Synthesis Reaction is a chemical reaction in which two or more substances react to produce a single product General Equation: X + Y → XY Particulate Diagram: Examples: Fe(s) + S(s) → FeS(s) 2Al(s) + 3Br2(g) → 2AlBr3(s) 2Cu(s) + O2(g) → 2CuO(s) G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 5 of 46 CHM.5.3.01.017.01 Write a balanced chemical equation for a synthesis reaction Example: Consider the following diagram that represents the reaction between iron and sulfur. Identify the type of the reaction and write a balanced chemical equation for the reaction taking place. Type of the reaction: Synthesis Reaction Balanced Chemical Equation: Fe(s) + S(s) → FeS(s) or 5Fe(s) + 5S(s) → 5FeS CHM.5.3.01.016.02 Define a combustion reaction while writing the general equation, particulate diagram and some examples Combustion reaction is a simple type of synthesis reaction, where a substance combines with oxygen and releases energy in the form of heat and light. Not all combustion reactions are synthesis reactions. In some combustion reaction, one substance replaces another in the formation of products. General Equation: X + O2 → XO2 Particulate Diagram: Examples: 2H2(g) + O2(g) → 2H2O(l) C(s) + O2(g) → CO2(g) C3H8 (g) + 5 O2 (g) → 3 CO2 (g) + 4 H2O (l) 2 C2H6(g) + 7 O2(g) → 4 CO2(g) + 6 H2O(l) C3H6O(l) + 4 O2(g) → 3 CO2(g) + 3 H2O(l) CHM.5.3.01.024.01 combustion - Compare between the products of complete combustion and incomplete Complete Combustion: The products are carbon dioxide and water Example: CH4 + 2O2 → CO2 + 2H2O - Incomplete Combustion: The products are carbon monoxide and water G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 6 of 46 Example: 2CH4 + 3O2 → 2CO + 4H2O CHM.5.3.01.024.02 Describe the side effect of incomplete combustion Incomplete combustion produces carbon monoxide; a toxic poisonous gas, that binds with heamoglobin to form carboxyheamoglobin, and this reduces the ability of red blood cells to carry oxygen and causes suffocation CHM.5.3.01.017.02 Write balanced chemical equations, and/or word equations for the complete and incomplete combustion of hydrocarbons (as methane and butane) Examples: Combustion of Methane, CH4 Complete combustion: Combustion of Butane, C4H10 Complete combustion: CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(l) 2 C4H10(g) + 13 O2(g) → 8 CO2(g) + 10 H2O(l) Methane reacts with oxygen to produce carbon dioxide and water Butane reacts with oxygen to produce carbon dioxide and water Incomplete combustion: Incomplete combustion: 2 CH4(g) + 3 O2(g) → 2 CO(g) + 4 H2O(l) 2 C4H10(g) + 9 O2(g) → 8 CO(g) + 10 H2O(l) Methane reacts with oxygen to produce carbon monoxide and water Butane reacts with oxygen to produce carbon dioxide and water CHM.5.3.01.025.01 Compare between complete and incomplete combustion through a lab activity CHM.5.3.01.016.03 Define a decomposition reaction while writing the general equation, particulate diagram and some examples Decomposition reaction is a chemical reaction in which a single compound breaks into two or more elements or new compounds General Equation: XY → X + Y Particulate Diagram: Examples: 2 NaCl → 2 Na + Cl2 ∆ K2CO3(s) → K2O(s) + CO2(g) CaCO3 → CaO + CO2 CHM.5.3.01.017.03 Write a balanced chemical equation for a decomposition reaction G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 7 of 46 Example: Consider the following diagram that represents heating some solid ammonium chloride, NH4Cl, in a test tube. Upon Heating, bubbles of ammonia gas, NH3, and hydrogen chloride gas, HCl, are produced. Identify the type of the reaction and write a balanced chemical equation for the reaction taking place. Type of Reaction: Decomposition Reaction Balanced Chemical Equation: NH4Cl(s) → NH3(g) + HCl (g) CHM.5.3.01.020.01 Define a single-replacement reaction while writing the general equation, particulate diagram and some examples Single-replacement reaction is a chemical reaction in which the atoms of one element replace the atoms of another element in a compound General Equation: X + YZ → XZ + Y Particulate Diagram: Examples: Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s) Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g) Cl2(g) + 2KBr(aq) ⟶ 2KCl(aq) + Br2(l) MQ + Z → ZQ + M G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 8 of 46 CHM.5.3.01.020.02 Explain how an activity (reactivity) series of metals is organized Reactivity is the ability to react with another substance. The activity series of metals orders metals by their reactivity with other metals. The most active metals are on the top of the list, and the least active metals are at the bottom of the list. CHM.5.3.01.020.03 Explain; using activity (reactivity) series, whether or not a metal will always replace another metal in a compound dissolved in water A specific metal can replace any metal listed below it that is in a compound. A specific metal cannot replace any metal listed above it that is in a compound. CHM.5.3.01.020.04 Use the activity (reactivity) series of metals to predict if a metal can replace hydrogen or another metal in a solution while writing the products of the reaction; if any Example: Using the reactivity series, predict whether each of the following reactions will occur or not. If a reaction will occur, write (R). If a reaction does not occur write (NR). Mg + HCl → R Cu + MgCl2 → NR Zn + AgNO3 → R Ag + NaNO3 → NR G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 9 of 46 CHM.5.3.01.021.02 Perform a practical experiment to predict the relative reactivity of certain metallic elements CHM.5.3.01.020.05 Use the activity (reactivity) series of halogens to predict if a halogen can replace another halogen in a solution while writing the products of the reaction; if any Example: Using the reactivity series, predict whether each of the following reactions will occur or not. If a reaction will occur, write (R). If a reaction does not occur write (NR). Br2 + HCl → CHM.5.3.01.017.04 NR Cl2 + 2 HBr → R Cl2 + 2 HI → R I2 + 2 HCl → NR Write a balanced chemical equation for a single-replacement reaction Example: A student carried out an experiment to compare the reactivity of magnesium, Mg, and copper, Cu. a) In which of the two experiments did a reaction take place? Justify your answer. Experiment 1. The color of solution changed from blue to colorless. Pieces of reddish brown copper are deposited. b) For the reaction that took place: Identify its type and write a balanced chemical equation. A single-replacement reaction Mg(s) + CuSO4(aq) → MgSO4(aq) + Cu(s) c) Which metal is more reactive Cu or Mg? Magnesium, Mg, is more reactive than Cu. Mg can replace copper in its solution but Cu cannot replace Mg in its solution. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 10 of 46 CHM.5.3.01.016.05 Define a double-replacement reaction while writing the general equation, particulate diagram and some examples Double replacement is a chemical reaction that involves exchange of ions between two compounds. General Equation: XY + WZ → XZ + WY Particulate Diagram: Examples: Ca(OH)2(aq) + 2HCl(aq) ⟶ CaCl2(aq) + 2H2O(l) AgNO3(aq) + NaCl(aq) → AgCl(s) + NaNO3(aq) 2NaOH(aq) + FeCl2(aq) →Fe(OH)2(s) + 2NaCl(aq) FeCl3(aq) + 3NaOH(aq) → Fe(OH)3(s) + 3NaCl(aq) CHM.5.3.01.016.06 Describe what happens to the anions in a double-replacement reaction In a double replacement reaction, the anions change places. The anion of one compound bonds with the cation of the second compound. The anion of the second compound bonds with the cation of the first compound. Two new compounds are formed. CHM.5.3.01.016.07 Describe the result of a double-replacement reaction A double replacement reaction produces two different compounds (A solid precipitate, water or gas) CHM.5.3.01.017.05 Describe the guidelines for writing double-replacement reactions The guidelines for writing double-replacement reactions: 1) Write the components of the reactants in a skeleton equation 2) Identify the cations and the anions in each compound 3) Pair up each cation with the anion from the other compound 4) Write the formulas for the products using the pairs from Step 3 5) Write the complete equation for the double-replacement reaction 6) Balance the equation G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 11 of 46 CHM.5.3.01.016.08 Compare and contrast single-replacement and double-replacement reactions Single-replacement Reaction Double-replacement Reaction The atoms of one element replace atoms of another element in a compound Two compounds dissolved in water exchange positive ions Examples: Examples: 2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g) 2KI(aq) + Pb(NO3)2(aq) → PbI2(s) + 2KNO3(aq) Mg (s) + CuSO4 (aq) ⟶ MgSO4 (aq) + Cu(s) K2CO3(aq) + BaCl2(aq) → 2KCl(aq) + BaCO3(s) Cl2 (g) + 2NaI (aq) ⟶ 2NaCl (aq) + I2 (aq) CHM.5.3.01.017.06 Write a balanced chemical equation for a double-replacement reaction Example: Aqueous solutions of sulfuric acid, H2SO4, and potassium hydroxide, KOH, react to form potassium sulfate, K2SO4 and water, H2O. Write the balanced equation for the above reaction. H2SO4(aq) + 2KOH(aq) → K2SO4(aq) + 2H2O(l) CHM.5.3.01.016.04 Identify the reaction type when a chemical equation, word equation or a particulate diagram is given and vice versa Example: Identify the type of the chemical reaction given in the table below. Chemical equation Type of chemical reaction C2H4 (g) + 3O2 (g) ⟶ 2CO2 (g) + 2H2O (g) Combustion Zn (s) + CuSO4 (aq) ⟶ ZnSO4 (aq) + Cu(s) Single-replacement CaCO3(s) ⟶ CaO(s) + CO2(g) Decomposition H2(g) + F2(g) ⟶ 2 HF(g) Synthesis Ca(OH)2(aq) + 2HCl(aq) ⟶ CaCl2(aq) + 2H2O(l) Double-replacement Cl2(g) + 2KBr (aq) ⟶ 2KCl (aq) + Br2 (l) Single-replacement Decomposition Synthesis AX + BY → AY + BX G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Double replacement Page 12 of 46 CHM.5.3.01.021.01 Conduct practical experiments or develop simulation software to compare the types of reactions (synthesis, decomposition, single displacement, double displacement) Inspire Chemistry – Module 8 – Lesson 3: Reactions in Aqueous Solutions CHM.5.3.03.006.01 Define aqueous solution, solute and solvent Aqueous solution is a solution in which the most plentiful substance is water. Solute is the substance dissolved in a solution. Solvent is the most plentiful substance in a solution. In aqueous solutions, the solvent is always water. CHM.5.3.03.006.02 Describe the difference in the behavior of molecular compounds and ionic compounds as solutes in aqueous solutions Molecular Compounds in Solution Some solutes are molecular compounds that form ions when they dissolve in water. Example: Hydrogen chloride, HCl: + HCl(aq) → H(aq) + Cl− (aq) Ionic Compounds in Solution Ionic compounds consist of positive and negative ions held together by ionic bonds. When some ionic compounds dissolve in water, their ions can separate (they dissociate). Example: Sodium chloride, NaCl: NaCl(aq) → Na+(aq) + Cl− (aq) G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 13 of 46 CHM.5.3.03.006.03 List three common types of products produced by reactions that occur in aqueous solutions The three common types of products are: 1) Solids or precipitates 2) Water 3) Gases CHM.5.3.03.003.01 Compare chemical equations and complete ionic equations Chemical equation: It is a statement using chemical formulae to describe the identities and relative amounts of the reactants and products involved in the chemical reaction. Complete ionic equation: It is chemical equation that shows all of the particles in a solution as they really exist. It is a chemical equation where the electrolytes in an aqueous solution are written as dissociated ions. Note: 1. Only strong electrolytes are to be written as ions. 2. Compounds or elements in the solid, liquid or gaseous states remain intact and do not dissociate. Example: Consider the reaction of aqueous solutions of sodium hydroxide, NaOH, and hydrochloric acid, HCl, to form aqueous sodium chloride, NaCl, and water, H2O. Write the balanced chemical equation and the complete ionic equation for the reaction taking place. Balanced Chemical Equation: NaOH(aq) + HCl(aq) ⟶ NaCl(aq) + H2O(l) − + + − Complete Ionic Equation: Na+(aq) + OH(aq) + H(aq) + Cl− (aq) → Na (aq) + Cl(aq) + H2 O(l) CHM.5.3.03.003.02 Compare a net ionic equation and a complete ionic equation Complete ionic equation: All dissolved ionic compounds and highly ionized molecular compounds are shown as free ions. Net ionic equation: It includes only the particles that take part in the reaction. Example: Consider the reaction of aqueous solutions of sodium hydroxide, NaOH, and hydrochloric acid, HCl, to form aqueous sodium chloride, NaCl, and water, H2O. Write the balanced chemical equation and the complete ionic equation for the reaction taking place. − + + − Complete Ionic Equation: Na+(aq) + OH(aq) + H(aq) + Cl− (aq) → Na (aq) + Cl(aq) + H2 O(l) + − Net Ionic Equation: H(aq) + OH(aq) → H2 O(l) CHM.5.3.03.006.04 Define spectator ion Spectator ions are ions that do not participate in a chemical reaction. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 14 of 46 CHM.5.3.03.006.05 Identify spectator ions in a given chemical equation Examples: Identify the spectator ions for each of the following reactions. Reaction Spectator Ions Na2S(aq) + 2HCl(aq) → 2NaCl(aq) + H2S(g) Na+ and Cl‒ NaCl(aq) + AgNO3(aq) → NaNO3(aq) + AgCl(s) Na+ and NO3‒ CuCl2(aq) + 2NaOH(aq) → Cu(OH)2(s) + 2NaCl(aq) Na+ and Cl‒ KHCO3(aq) + HNO3(aq) → KNO3(aq) + CO2(g) + H2O(l) K+ and NO3‒ CHM.5.3.03.006.06 Describe the different solubility rules for ionic compounds Solubility Rules for Ionic Compounds Compounds containing the following ions Solubility Li+, Na+, K+ and ammonium (NH4+ ) Soluble Nitrates (NO− 3 ) and acetate, (CH3 COO− ) Soluble Chloride, (Cl‒), bromide, (Br‒), and iodide, (I‒) Sulfate salts (SO2− 4 ) Hydroxide, OH‒ sulfide, S2‒ Carbonates, (CO2− 3 ), and phosphates, (PO3− 4 ) Exceptions Soluble When these ions pair with Ag+, or Pb2+, the resulting compounds are insoluble Soluble 2+ 2+ 2+ When SO2− 4 pairs with Sr , Ca , Ba , Pb2+ and Ag+, the resulting compound is insoluble Insoluble When these ions part with Li+, Na+, K+, NH4+ , Ca2+, Sr2+, or Ba2+, the resulting compounds are soluble Insoluble When these ions part with Li+, Na+, K+, NH4+ , Ca2+, Sr2+, or Ba2+, the resulting compounds are soluble Insoluble When these ions part with Li+, Na+, K+, or NH4+ , the resulting compounds are soluble G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 15 of 46 CHM.5.3.03.003.03 Write a balanced chemical equation, complete ionic equation, net ionic equation and word equation for reactions that form precipitates (using solubility rules) Example: Consider the reaction between copper (II) sulfate solution, CuSO4, and barium nitrate solution, Ba(NO3)2. a) Write the balanced chemical equation with state symbols for the above reaction. CuSO4(aq) + Ba(NO3)2(aq) ⟶ Cu(NO3)2(aq) + BaSO4(s) b) Write the complete ionic equation for the above reaction. − − 2+ 2+ Cu2+ (aq) + SO2− 4 (aq) + Ba (aq) + 2NO3 (aq) ⟶ BaSO4(s) + Cu (aq) + 2NO3 (aq) c) Write the net ionic equation for the above reaction Ba2+ (aq) + SO2− 4 (aq) ⟶ BaSO4(s) Example: In a lab experiment, when solutions of lead (II) nitrate, Pb(NO3)2 (aq), and potassium iodide, KI(aq), were mixed together, a yellow precipitate was formed. a) Identify the type of product formed in the above reaction. A precipitate b) Write the word equation for the above reaction. Lead (II) nitrate + Potassium iodide → Lead (II) iodide + Potassium nitrate c) Write a balanced chemical equation with state symbols for the above reaction. Pb(NO3)2(aq) + 2 KI(aq) → PbI2(s) + 2 KNO3(aq) d) Write the net ionic equation for the above reaction. Pb2+(aq) + 2 I―(aq) → PbI2(s) e) Identify the spectator ion(s). K+ and NO3― CHM.5.3.03.006.07 Use solubility rules to predict the result of a double displacement reaction (using solubility rules) Example: Using the solubility rules, predict whether each of the following reactions of aqueous solutions result in the formation of a precipitate or not. If a precipitate is formed, write (P), if no precipitate it formed write (NP). NaOH + KCl → CHM.5.3.03.006.08 NP P NaCl + AgNO3 → NP CaCl2 + KI → P Ca(NO3)2 + Na2SO4 → Identify the type of reaction that occurs in aqueous solutions The reaction that occurs in an aqueous solution is a double-replacement reaction G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 16 of 46 CHM.5.3.03.006.09 Type of Reaction Describe the three reactions that take place in aqueous solutions Description & Examples Reactions that form precipitates - It is a double-replacement reaction. Dissolved substances are mixed. When they react, a solid is formed, visible as a white or colored cloudiness in the reaction mixture. Example: Consider the reaction of aqueous solutions of sodium chloride, NaCl, and silver nitrate, AgNO3, to form solid silver chloride, AgCl, and aqueous sodium nitrate, NaNO3. Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction taking place. Balanced Chemical Equation: NaCl(aq) + AgNO3(aq) → NaNO3(aq) + AgCl(s) − − Complete Ionic Equation: Na+(aq) + Cl−(aq) + Ag +(aq) + NO3(aq) → Na+(aq) + NO3(aq) + AgCl(s) − Net Ionic Equation: Ag + (aq) + Cl(aq) → AgCl(s) Reactions that form water - It is a double-replacement reaction. Evidence of the reaction may not be observable because water is colorless, odorless, and already makes up most of the solution. Example: Consider the reaction of aqueous solutions of sodium hydroxide, NaOH, and hydrochloric acid, HCl, to form aqueous sodium chloride, NaCl, and water, H2O. Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction taking place. Balanced Chemical Equation: NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l) + + − − Complete Ionic Equation: Na+(aq) + OH(aq) + H(aq) + Cl− (aq) → Na (aq) + Cl(aq) + H2 O(l) − + Net Ionic Equation: OH(aq) + H(aq) → H2 O(l) Reactions that form gases - It is a double-replacement reaction. Gases as carbon dioxide, CO2, hydrogen, H2, sulfur dioxide, SO2, and hydrogen sulfide, H2S, may be formed. Bubbles are produced or seen as the reaction proceeds. 1. Acid + Metal → Salt + Hydrogen ✓ Metal is not an alkali metal as Na, K or Li or Ca because the reaction is highly explosive ✓ Metal is not Cu or Ag because they are highly Unreactive G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 17 of 46 Example: Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction between hydrochloric acid solution, HCl, and magnesium, Mg. Balanced Chemical Equation: Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g) + 2+ − Complete Ionic Equation: Mg (s) + 2H(aq) + 2Cl− (aq) → Mg (aq) + 2Cl(aq) + H2 (g) + Net Ionic Equation: Mg (s) + 2H(aq) → Mg 2+ (aq) + H2 (g) 2. Acid + Metal Carbonate → Salt + Water + Carbon Dioxide ✓ This is a double replacement reaction and a decomposition reaction. Example: Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction between hydrochloric acid solution, HCl, and sodium carbonate solution, Na2CO3. Balanced Chemical Equation: Na2CO3(aq) + 2HCl(aq) → 2NaCl(aq) + CO2(g) + H2O(l) + − + − Complete Ionic Equation: 2Na+(aq) + CO2− 3(aq) + 2H(aq) + 2Cl(aq) → 2Na (aq) + 2Cl(aq) + CO2(g) + H2 O(l) + Net Ionic Equation: CO2− 3(aq) + 2H(aq) → CO2(g) + H2 O(l) 3. Acid + Metal Bicarbonate (Metal hydrogen carbonate) → Salt + Water + Carbon Dioxide Example: Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction between hydrochloric acid solution, HCl, and sodium bicarbonate solution, NaHCO3. Balanced Chemical Equation: NaHCO3(aq) + HCl(aq) → NaCl(aq) + CO2(g) + H2O(l) When carbonic acid, H2CO3, is formed, it decomposes to water, H2O(l), and carbon dioxide gas, CO2(g). − + + − Complete Ionic Equation: Na+(aq) + HCO3(aq) + H(aq) + Cl− (aq) → Na (aq) + Cl(aq) + CO2(g) + H2 O(l) + Net Ionic Equation: HCO− 3(aq) + H(aq) → CO2(g) + H2 O(l) 4. Acid + Metal Sulfite → Salt + Water + Sulfur dioxide Example: Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction between hydrochloric acid solution, HCl, and sodium sulfite solution, Na2SO3. Balanced Chemical Equation: Na2SO3(aq) + 2HCl(aq) → 2NaCl(aq) + SO2(g) + H2O(l) + − + − Complete Ionic Equation: 2Na+(aq) + SO2− 3(aq) + 2H(aq) + 2Cl(aq) → 2Na (aq) + 2Cl(aq) + SO2(g) + H2 O(l) + Net Ionic Equation: SO2− 3(aq) + 2H(aq) → SO2(g) + H2 O(l) G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 18 of 46 5. Acid + Metal Sulfide → Salt + Hydrogen Sulfide Example: Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction between hydrochloric acid solution, HCl, and sodium sulfide solution, Na2S. Balanced Chemical Equation: Na2S(aq) + 2HCl(aq) → 2NaCl(aq) + H2S(g) 2− + + − Complete Ionic Equation: 2Na+(aq) + S(aq) + 2H(aq) + 2Cl− (aq) → 2Na (aq) + 2Cl(aq) + H2 S(g) 2− + Net Ionic Equation: S(aq) + 2H(aq) → H2 S(g) 6. Base + Ammonium Salt → Salt + Water + Ammonia Example: Write the balanced chemical equation, complete ionic equation and net ionic equation for the reaction between ammonium chloride solution, NH4Cl, and sodium hydroxide solution, NaOH. Balanced Chemical Equation: NH4Cl(aq) + NaOH(aq) → NaCl(aq) + H2O(l) + NH3(g) + + − + − Complete Ionic Equation: NH4(aq) + Cl− (aq) + Na (aq) + OH(aq) → Na (aq) + Cl(aq) + H2 O(l) + NH3 (g) + − Net Ionic Equation: NH4(aq) + OH(aq) → NH3 (g) + H2 O(l) CHM.5.3.03.003.04 Write a balanced chemical equation, complete ionic equation, net ionic equation and word equation for reactions that form water (Reaction of a strong acid with a strong base) Example: Mixing sodium hydroxide with hydrochloric acid o Balanced chemical equation: NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l) o Complete ionic equation: Na+(aq) + OH–(aq) + H+(aq) + Cl–(aq) → Na+(aq) + Cl–(aq) + H2O (l) o Net ionic equation: H+(aq) + OH–(aq) → H2O (l) o Word equation: Sodium hydroxide reacts with hydrochloric acid to form sodium chloride and water CHM.5.3.03.003.05 Write a balanced chemical equation, complete ionic equation, net ionic equation and word equation for reactions that form gases (Reaction of acid with metal, metal carbonate, metal bicarbonate, metal sulfite, metal sulfide, and reaction of a base with an ammonium salt) Please refer to KPI 2.3.47 (Reaction that form gases) G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 19 of 46 CHM.5.3.03.002.01 and H2S) Describe how to test for the presence of different gases (NH3, CO2, H2, O2, SO2 Testing for Gases Some common experiments that will most likely produce a gas are: 1) When a solid substance is heated 2) When an acid is added to a substance 3) When an alkali is added to a substance The following table shows the different tests and observations the students should carry out and have when identifying the listed gases. Gas Test & Result Smell Ammonia NH3 - Test: Approach a red litmus paper Result: The gas turns red litmus paper blue Carbon dioxide CO2 - Test: Bubble the gas through limewater for a short time Result: Lime water turns milky Odorless Hydrogen H2 - Test: Approach a lighted splint Result: The gas burns with a squeaky pop sound with a lighted splint Odorless Oxygen O2 - Test: Approach a glowing splint Result: The gas relights a glowing splint Odorless Sulfur dioxide SO2 - Test: Bubble the gas through an orange solution of potassium dichromate (VI). Result: The gas turns aqueous potassium dichromate (VI) into green Smells like burnt matches Test: Approach a damp lead (II) acetate paper Test: The gas turns the damp lead (II) acetate paper black Smell of rotten eggs Hydrogen sulfide H2S CHM.5.3.03.003.07 - Pungent smelling gas Describe an overall equation while listing the steps An overall equation is an equation that combines two reactions. The steps in writing an overall equation are: 1. Write the equation for the first reaction 2. Write the equation for the second reaction 3. Combine the equations with both reactants on one side and both products on the other side 4. Cross out any substances that are on both sides of the equation CHM.5.3.03.003.08 Write the overall equation for different reactions Example: Consider the reaction between sodium bicarbonate, NaHCO3, and hydrochloric acid, HCl. Write the overall equation for the reaction taking place. NaHCO3(aq) + HCl(aq) → NaCl(aq) + H2CO3(aq) H2CO3(aq) → CO2(g) + H2O(l) ______________________________________ G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 20 of 46 NaHCO3(aq) + HCl(aq) → NaCl(aq) + CO2(g) + H2O(l) CHM.5.3.01.022.01 Compare between the reaction of metallic and non-metallic oxides with water and the types of obtained solutions Metallic oxides are basic while non-metallic oxides are acidic. A metallic oxide solution is basic, it turns red litmus paper blue and has a pH greater than 7. A non-metallic oxide solution is acidic, it turns blue litmus paper red and has a pH less than 7. CHM.5.3.01.022.02 Plan and conduct a demonstration (considering safety rules) to compare the properties of nonmetallic and metallic oxides CHM.5.3.03.006.10 Predict the nature of products (water, gas, a precipitate) of the chemical reactions that take place in aqueous solutions Type of Reaction Synthesis Combustion Decomposition Reactants Suggested Products Two or more substances One compound ✓ Metal and oxygen ✓ Non-metal and oxygen ✓ A compound and oxygen ✓ The oxide of the metal ✓ The oxide of the nonmetal ✓ Two or more oxides One Compound Two or more elements and/or compound G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) General Equation X + Y → XY X + O2 → XO2 XY → X + Y Page 21 of 46 Single-replacement ✓ A metal and a compound ✓ A non-metal and a compound ✓ A new compound and the replaced metal ✓ A new compound and the replaced non-metal X + WZ → XZ + W Double-replacement Two compound Two different compounds, one of which is a solid, water or a gas XY + WZ → XZ + WY 2.4 – The Mole Inspire Chemistry – Module 9 – Lesson 1: Measuring Matter CHM.5.3.01.002.01 Define mole Mole is the SI base unit to measure the amount of a substance. Abbreviation: mol A mole is the number of carbon atoms in exactly 12 g of pure carbon-12. A mole of anything contains 6.022140857 × 1023 representative particles CHM.5.3.01.002.02 Explain why chemists use the mole Chemists use the mole because it is a convenient way of knowing how many representative particles are in a sample. It allows chemists to accurately calculate the number of atoms, molecules or formula units in a substance CHM.5.3.01.002.03 Describe Avogadro's number It is the number 6.022140857 × 1023, which is the number of representative particles in a mole. CHM.5.3.01.003.01 State the mathematical relationship between Avogadro's number and one mole One mole contains Avogadro's number (6.00×1023) of representative particles Number of Representative Particles = Number of moles × 6.00×1023 Number of moles = Number of Representative Particles 6.00 × 1023 CHM.5.3.01.003.02 Describe, using particulate diagrams, different types of representative particles Representative particles can be atoms, ions, molecules, or formula unit. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 22 of 46 CHM.5.3.01.003.03 List the conversion factors used to convert between particles and moles 6.00 × 1023 representaive particles and 1 mol 6.00 × 1023 1 mol represntative particles CHM.5.3.01.004.01 Calculate the number of representative particles present in given moles of an element (atomic or molecular) or a compound and vice versa Representative Particles and Moles Substance Chemical Formula Representative Particle Representative Particles in 1.00 mol Copper Cu Atom 6.02 × 1023 Atomic Nitrogen N Atom 6.02 × 1023 Nitrogen gas N2 Molecule 6.02 × 1023 Water H2O Molecule 6.02 × 1023 Calcium ion Ca2+ Ion 6.02 × 1023 Calcium fluoride CaF2 Formula unit 6.02 × 1023 Example: Calculate the number of representative particles of each of the following: (Use Avogadro’s number as 6.00 × 1023) 12.0 mol Ag Number of Particles = 12.0 × 6.00 × 1023 = 7.20 × 1024 atoms of Ag 18.0 mol H2O Number of Particles = 18.0 × 6.00 × 1023 = 1.08 × 1025 molecules of H2 O 0.150 mol NaCl Number of Particles = 0.150 × 6.00 × 1023 = 9.00 × 1023 formula units of NaCl 1.20⨯10‒2 mol H2 Number of Particles = 1.20 × 10−2 × 6.00 × 1023 = 7.20 × 1021 molecules of H2 Example: How many moles contain the given quantity below? G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 23 of 46 (Use Avogadro’s number as 6.00 × 1023) 1.2⨯1015 molecules of CO2 Number of moles = Number of Particles 1.2 × 1015 = = 2.0 × 10−9 mol 6.00 × 1023 6.00 × 1023 3.6⨯1021 formula units of NaCl Number of moles = Number of Particles 3.6 × 1021 = = 6.0 × 10−3 mol 6.00 × 1023 6.00 × 1023 3.0⨯1027 formula units of KI Number of moles = Number of Particles 3.0 × 1027 = = 5.0 × 103 mol 6.00 × 1023 6.00 × 1023 Example: Which of the following contains larges number of moles? 3.00 ⨯ 1024 atoms of Ne or 6.00 ⨯ 1024 atoms of Xe Number of Representative Particles 3.00 × 1024 Number of moles of Ne = = = 5.00 mol 6.00 × 1023 6.00 × 1023 Number of Representative Particles 6.00 × 1024 Number of moles of Xe = = = 10.0 mol 6.00 × 1023 6.00 × 1023 6.00 ⨯ 1024 atoms of Xe contains larger number of moles than 3.00 ⨯ 1024 atoms of Ne Inspire Chemistry – Module 9 – Lesson 2: Mass and the Mole CHM.5.3.01.003.04 Define molar mass Molar mass is the mass in grams of one mole of any pure substance Unit is g/mol G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 24 of 46 CHM.5.3.01.004.02 Calculate molar mass of an element The molar mass of any element is numerically equal to its atomic mass and has a unit of g/mol. Example: As per the periodic table, an atom of copper, Cu, has an atomic mass of 63.55 amu. The molar mass of Cu is 63.55 g/mol. 1 mole of Cu or 6.00 × 1023 atoms of Cu has a mass of 63.55 g. CHM.5.3.01.003.05 List the conversion factor needed to convert between mass and moles of an atom Mass = Number of Moles × Molar Mass Mass Conversion Factor: Molar Mass and CHM.5.3.01.004.03 Molar Mass Mass Calculate the mass (in grams) of an element given its moles and vice versa Example: Calculate the mass of 4.50 moles of cobalt, Co. m = n × M = 4.50 × 58.93 = 265 g Example: Calculate number of moles in 118 g of cobalt, Co. Number of moles = Mass 118 = = 2.00 moles Molar Mass 58.93 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 25 of 46 CHM.5.3.01.003.06 Define atomicity Atomicity is the total number of atoms present in one mole of an element or compound CHM.5.3.01.003.07 Identify the atomicity of a given species Example: Identify the atomicity of each of the following species. Species Atomicity NH3 4 H2SO4 7 Al2(SO4)3 17 H2O 3 S8 8 H2 2 Na 1 CaI2 3 Mg(OH)2 5 C12H22O11 45 CHM.5.3.01.004.05 Calculate the number of atoms in an element or compound given moles and vice versa Number of atoms = Number of Moles × (6.00 × 1023) × atomicity Example: Calculate the number of nitrogen atoms present in 0.50 moles of dinitrogen trioxide, N2O3, molecules. Number of nitrogen atoms = 0.50 × (6.00×1023) × 2 = 6.0×1023 atoms Example: Calculate the number of oxygen atoms present in 2.00 moles of aspirin, C9H8O4, molecules. Number of oxygen atoms = 2.00 × (6.00×1023) × 4 = 4.8×1024 atoms G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 26 of 46 Inspire Chemistry – Module 9 – Lesson 3: Moles of Compounds CHM.5.3.01.003.08 Describe what a subscript in a chemical formula indicates The subscripts in a chemical formula represent the number of moles of an element in a given compound. CHM.5.3.01.001.01 chemical formula Describe the relationship between the mole information of a substance and its The mole information of the individual elements shows the ratio of the elements in a compound. These mole ratios become the subscripts of the chemical formula. CHM.5.3.01.001.02 Identify the number of moles of atoms and ions for a given chemical formula of a compound (ionic and molecular) Example: Consider one mole of CCl2F2. Identify the number of moles of each atom in the compound. 1 mole of CCl2F2 contains: 1 mole of C atoms 2 moles of Cl atoms 2 moles of F atoms Example: Consider one mole of Al2(SO4)3. Identify the number of moles of each ion in the compound. 3 1 mole of Al2(SO4)3 contains: 2 moles of Al3+ ions moles of SO2− 4 ions CHM.5.3.01.004.06 compound Calculate the number of moles of atoms (elements) in a given moles of a Example: Calculate the number of moles of phosphorus atoms and oxygen atoms in 2.00 moles of P4O10. 1 mole of P4O10 contains 4 moles of P atoms and 10 moles of O atoms. 2.00 mole of P4O10 contains 8.00 moles of P atoms and 20.0 moles of O atoms. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 27 of 46 CHM.5.3.01.004.07 Calculate the number of moles of ions in a given moles of a compound Example: Iron (III) sulfate, Fe2(SO4)3, is sometimes used in the process of water purification. Calculate the number of moles of iron (III) ions and sulfate ions in 4.00 moles of Fe2(SO4)3. 1 mole of Fe2(SO4)3 contains 2 moles of Fe3+ ions and 3 moles of SO2− 4 ions. 3+ 4.00moles of Fe2(SO4)3 contains 8.00 moles of Fe ions and 12.0 moles of SO2− 4 ions. CHM.5.3.01.003.09 Describe the molar mass of a compound The molar mass of a compound is the sum of the masses of all elements in that compound. CHM.5.3.01.003.10 Describe how to determine the molar mass of a compound and how the molar masses of the ions that make up this compound relate to the law of conservation of mass Multiply the mass of one mole of each element by the number of moles of that element in the chemical formula. Add the resulting masses. During the formation of a compound, the calculated molar masses of the reactants are equal to the calculated molar masses of the products. This shows that matter is conserved in a chemical reaction. CHM.5.3.01.004.08 Calculate the molar mass of a compound (ionic and molecular) Example: Calculate the molar mass of CaSO4 Molar mass = (1 × 40.08) + (1 × 32.07) + (4 × 16.00) = 136.15 g/mol Example: Calculate the molar mass of CO2 Molar mass = (1 × 12.01) + (2 × 16.00) = 44.01 g/mol CHM.5.3.01.004.09 Calculate the mass of a given moles of a compound and vice versa Example: Calculate the mass of 2.00 moles of CaSO4 m = n × M = 2.00 × 136.15 = 272 g Example: Calculate number of moles in 10.0 g of calcium carbonate, CaCO3. Number of moles = Mass 10.0 = = 0.100 moles Molar Mass 100.09 CHM.5.3.01.001.03 Explain how a chemical formula is used to determine the number of moles in a given mass of compound Convert the mass to moles, multiply the number of moles by the ratio of the number of atoms or ions to one mole, and multiply by Avogadro’s number. CHM.5.3.01.004.10 Calculate the number of representative particles present in given mass of a compound (ionic and molecular) and vice versa G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 28 of 46 Example: Consider a 10.0 g sample of calcium carbonate, CaCO3 (Ca = 40, C = 12, O = 16) Answer the following questions: a) Calculate the number of moles of the sample Number of moles = Mass 10.0 = = 0.100 moles Molar Mass 100 b) How many calcium ions, Ca2+, are present in the sample? 1 mole of CaCO3 contains 1 mol of Ca2+ ions 0.100 moles of CaCO3 contains 0.100 mol of Ca2+ ions Number of Ca2+ ions = 0.100 × 6.00 × 1023 = 6.00 × 1022 Ca2+ ions c) How many carbonate ions, CO2− 3 , are present in the sample? 1 mole of CaCO3 contains 1 mol of CO2− 3 ions 0.100 moles of CaCO3 contains 0.100 mol of CO2− 3 ions 2− 23 Number of CO3 ions = 0.100 × 6.00 × 10 = 6.00 × 1022 CO2− 3 ions d) Calculate the mass, in grams, of one formula unit of CaCO3. Mass of on Formula unit = Molar Mass 100 = = 1.67 × 10−22 g 23 23 6.00 × 10 6.00 × 10 Example: Consider a 2.3 g sample of ethanol, C2H5OH (C = 12, H = 1, O = 16) Answer the following questions: a) Calculate the number of moles of the sample Number of moles = Mass 2.3 = = 0.050 moles Molar Mass 46 b) How many carbon atoms, C, are present in the sample? 1 mole of C2H5OH contains 2 moles of C atoms 0.050 moles of C2H5OH contains 0.10 mol of C atoms Number of C atoms = 0.10 × 6.00 × 1023 = 6.0 × 1022 C atoms c) How many hydrogen atoms, H, are present in the sample? 1 mole of C2H5OH contains 6 moles of H atoms 0.050 moles of C2H5OH contains 0.30 mol of H atoms Number of H atoms = 0.30 × 6.00 × 1023 = 1.8 × 1023 H atoms d) How many oxygen atoms, O, are present in the sample? 1 mole of C2H5OH contains 1 mole of O atoms 0.050 moles of C2H5OH contains 0.050 mol of O atoms Number of O atoms = 0.050 × 6.00 × 1023 = 3.0 × 1022 H atoms G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 29 of 46 Inspire Chemistry – Module 9 – Lesson 4: Empirical and Molecular Formulas CHM.5.3.01.006.01 Define percent composition Percent composition is the percent by mass of each element in a compound. CHM.5.3.01.009.01 experimental data Calculate the percent composition (percent by mass of an element) from If you know the relative mass of each element in a compound, you can calculate the percent composition of the compound. The percent by mass of an element in a compound is the mass in grams of the element divided by the mass in grams of the compound, multiplied by 100%. The percent composition of a compound is always the same. The percent of all the elements in a compound adds up to 100%. 𝐏𝐞𝐫𝐜𝐞𝐧𝐭 𝐛𝐲 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐞𝐥𝐞𝐦𝐞𝐧𝐭 = 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐞𝐥𝐞𝐦𝐞𝐧𝐭 × 𝟏𝟎𝟎 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐜𝐨𝐦𝐩𝐨𝐮𝐧𝐝 Example: What is the percent by mass of a sample of a compound that contains 85 g element X and 15 g element Y? Percent by mass of X = 85 × 100 = 85 % 100 Percent by mass of Y = 15 × 100 = 15 % 100 CHM.5.3.01.009.02 chemical formula Calculate the percent composition (percent by mass of an element) from the The subscripts in the formula are used to calculate the mass of each element in a mole of that compound. Using the individual masses of the elements and the molar mass, you can calculate the percent by mass of each element. 𝐏𝐞𝐫𝐜𝐞𝐧𝐭 𝐛𝐲 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐞𝐥𝐞𝐦𝐞𝐧𝐭 = 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐞𝐥𝐞𝐦𝐞𝐧𝐭 𝐢𝐧 𝟏 𝐦𝐨𝐥𝐞 𝐨𝐟 𝐜𝐨𝐦𝐩𝐨𝐮𝐧𝐝 × 𝟏𝟎𝟎 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐜𝐨𝐦𝐩𝐨𝐮𝐧𝐝 Example: Calculate the percentage by mass of hydrogen in methane, CH4. (C = 12, H = 1) Percent by mass of H = 4×1 16 × 100 = 25 % G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 30 of 46 CHM.5.3.01.006.02 Define empirical formula Empirical formula is the formula with the smallest whole-number mole ratio of the elements. CHM.5.3.01.006.03 Describe the experimental data that is needed to calculate percent composition of an unknown compound Experimental analyses are used to determine the mass of each element in a sample. CHM.5.3.01.009.03 Determine the empirical formula of a compound given the mass of the elements Example: A sample of a compound contains 3.2 g of sulfur, S, and 4.8 g of oxygen, O. Find the empirical formula of the compound. (S = 32, O = 16) 1. Write given quantity 2. Calculate number of moles m n=M n= O 3.2 g 4.8 g 3.2 = 0.10 mol of S 32 n= 0.10 =1 0.10 3. Divide moles by the smallest value 4. Write the simplified ratio then deduce the empirical formula S 4.8 = 0.30 mol ofO 16 0.30 =3 0.10 SO3 CHM.5.3.01.009.04 Determine the empirical formula of a compound given the percent composition Example: A sample of a compound contains 50% sulfur, S, and 50% oxygen, O. Find the empirical formula of the compound. (S = 32, O = 16) 1. Write given quantity S 50% O 50% 2. Write the quantity in grams 50 g 50 g 3. Calculate number of moles m n= M n= 50 = 1.5625 mol of S 32 4. Divide moles by the smallest value 1.5625 =1 1.5625 n= 50 = 3.125 mol ofO 16 3.125 =2 1.5625 5. Write the simplified ratio then SO2 deduce the empirical formula CHM.5.3.01.006.04 Define molecular formula Molecular formula specifies the actual number of atoms of each element in one molecule or formula unit of a substance CHM.5.3.01.007.01 Describe, using examples, the difference between empirical formula and molecular formula G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 31 of 46 An empirical formula is the smallest-whole number ratio of elements that make up a compound, ex The empirical formula of C6H6 is CH A molecular formula specifies the actual number of atoms of each element in one molecule or formula unit of the substance, ex C6H6 Example: Use the following table to write the empirical formula for each given molecular formula. Molecular formula Empirical formula CO CO C12H22O11 C12H22O11 C3H6O3 CH2O P4O10 P2O5 NH3 NH3 C6H12O6 CH2O C8H10N4O2 C4H5N2O N2O4 NO2 CHM.5.3.01.009.05 Determine molecular formula of a compound given the experimentally determined molar mass of the compound 𝐍𝐮𝐦𝐛𝐞𝐫 𝐨𝐟 𝐞𝐦𝐩𝐢𝐫𝐢𝐜𝐚𝐥 𝐟𝐨𝐫𝐦𝐮𝐥𝐚 𝐮𝐧𝐢𝐭𝐬 = 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐦𝐨𝐥𝐞𝐜𝐮𝐥𝐚𝐫 𝐟𝐨𝐫𝐦𝐮𝐥𝐚 𝐦𝐨𝐥𝐚𝐫 𝐦𝐚𝐬𝐬 𝐨𝐟 𝐞𝐦𝐩𝐢𝐫𝐢𝐜𝐚𝐥 𝐟𝐨𝐫𝐦𝐮𝐥𝐚 Example: A compound has a molar mass of 360 g/mol and its empirical formula is CH2O. What is the molecular formula of the compound? (C = 12, H = 1, O = 16) Number of empirical formula units = molar mass of molecular formula 360 = = 12 molar mass of empirical formula 30 There are 12 units of CH2O The molecular formula is C12H24O12 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 32 of 46 Example: A student analyzed a sample of a compound whose molecular formula has a molar mass of 32 g/mol. The compound contained 1.4 g of nitrogen, N, and 0.20 g of hydrogen, H. Answer questions a and b. a) What is the empirical formula of the compound? (N = 14, H = 1) 1. Write given quantity 2. Calculate number of m moles n = M n= N H 1.4 g 0.20 g 1.4 = 0.10 mol of N 14 3. Divide moles by the smallest value n= 0.10 =1 0.10 4. Write the simplified ratio then deduce the empirical formula 0.20 = 0.20 mol of H 1 0.20 =2 0.10 NH2 b) What is the molecular formula of the compound? Number of empirical formula units = Molar mass of the molecular formula 32 = =2 Molar mass of the empirical formula 16 Molecular formula is N2H4 CHM.5.3.01.010.01 Plan and conduct a practical experiment, (considering safety rules) to determine the empirical formula of a chemical compound (such as magnesium oxide) CHM.5.3.01.008.01 Explain the relationship between the empirical formula and the molecular formula through simulation software CHM.5.3.01.008.02 Explain the relationship between the empirical formula and the molecular formula using models and/or drawings CHM.5.3.01.005.01 Determine the Percent of composition of a specific chemical compound through practical experiment 3.3 – Stoichiometry Inspire Chemistry – Module 10 – Lesson 1: Defining Stoichiometry CHM.5.3.01.011.01 Define stoichiometry Stoichiometry is the study of quantitative relationships between the amounts of reactants used and amounts of products formed by a chemical reaction. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 33 of 46 CHM.5.3.01.011.02 Explain the importance of the law of conservation of mass in chemical reactions The law of conservation of mass states that matter is neither created nor destroyed. Bonds in a chemical reaction break and reform to produce products, but the amount of matter at the end of the reaction is the same as it was at the beginning. This is seen in a chemical reaction when the same number of each type of atom exists on both sides of the equation. CHM.5.3.01.011.03 Interpret a balanced chemical equation in terms of moles, mass and representative particles (atoms, molecules and formula units) Example: Interpret the following balanced equation in terms of moles, mass, representative particles and the show that the law of conservation of mass is observed. (Na = 23, Cl = 35.5, Pb = 207, N = 14, O = 16) 2 NaCl(aq) In terms of representative particles In terms of moles In terms of Mass Law of Conservation of Mass + Pb(NO3)2(aq) → 2NaNO3(aq) + PbCl2(s) 2 formula units of NaCl 1 formula unit of Pb(NO3)2 2 formula units of NaNO3 1 formula unit of PbCl2 2 moles of NaCl 1 mole of Pb(NO3)2 2 moles of NaNO3 1 mole of PbCl2 117 g of NaCl 331 g of Pb(NO3)2 170 g of NaNO3 278 g of PbCl2 117 g + 331 g = 448 g Reactants 170 g + 278 g = 448 g Products Mass is Conserved G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 34 of 46 Example: Interpret the following balanced equation in terms of moles, mass, representative particles and the show that the law of conservation of mass is observed. (C = 12, O = 16, H = 1) CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) In terms of representative particles 1 molecule of CH4 2 molecules of O2 1 molecule of CO2 2 molecules of H2O In terms of moles 1 mole of CH4 2 moles of O2 1 mole of CO2 2 moles of H2O 16 g of CH4 64 g of O2 44 g of CO2 36 g H2O In terms of Mass Law of Conservation of Mass 16 g + 64 g = 80 g Reactants 44 g + 36 g = 80 g Products Mass is Conserved CHM.5.3.01.011.04 Compare the mass of the reactants and the mass of the products in a chemical reaction while explaining how these masses are related The coefficients indicate the molar relationship between each pair of reactants and products. The masses of reactants and products are equal. CHM.5.3.01.011.05 Describe a mole ratio A mole ratio is the ratio between the numbers of moles of any two substances in a balanced chemical equation. CHM.5.3.01.011.06 Identify the source from which a chemical reaction’s mole ratios are derived A chemical reaction’s mole ratios are derived from the relationships between coefficients in a balanced chemical equation. The number of mole ratios that can be written for a chemical reaction that has a total number of n substances is: (n)(n – 1). Number of substances in a chemical reaction (n) 3 4 5 6 Total number of mole ratio (n)(n – 1) 6 12 20 30 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 35 of 46 CHM.5.3.01.011.07 Write a balanced chemical equation for a word equation while determining the possible mole ratios Example: Consider the thermal decomposition of solid potassium chlorate to form solid potassium chloride and oxygen gas. Write a balanced chemical equation and the possible mole ratios for the reaction. Balanced Chemical Equation: 2 KClO3(s) → 2KCl(s) + 3O2(g) The mole ratios that can be written for the above reaction are as follows: 2 mol KClO3 2 mol KClO3 and 2 mol KCl 3 mol O2 2 mol KCl 2 mol KCl and 2 mol KClO3 3 mol O2 3 mol O2 3 mol O2 and 2 mol KClO3 2 mol KCl Inspire Chemistry – Module 10 – Lesson 2: Stoichiometric Calculations CHM.5.3.01.011.08 Explain why a balanced chemical equation is needed to solve a stoichiometric problem The coefficients in the balanced equation indicate the molar relationship between each pair of reactants and products. CHM.5.3.01.012.01 List the steps included in stoichiometric calculations o Step 1 – Start with a balanced equation. Interpret the equation in terms of moles. o Step 2 – Convert from grams to moles of the given substance. Use the inverse of the molar mass as the conversion factor. o Step 3 – Convert from moles of the given substance to moles of the unknown substance. Use the appropriate mole ratio from the balanced chemical equation as the conversion factor. o Step 4 – Convert from moles of unknown to grams of unknown. Use the molar mass as the conversion factor. G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 36 of 46 CHM.5.3.01.012.02 Calculate the number of moles of a reactant or a product given the number of moles of another reactant or product Example: Consider the following reaction: N2(g) + 3 H2(g) → 2 NH3(g). 0.60 moles of nitrogen, N2, reacts with hydrogen, H2, to form ammonia, NH3. a) Calculate number of moles of H2 needed to react with 0.60 moles of N2. N2 1 mole 0.60 moles 3 H2 3 moles ? Number of moles of H2 = 1.8 moles b) Calculate number of moles of NH3 produced when 0.60 moles of N2 reacted. N2 1 mole 0.60moles 2 NH3 2 moles ? Number of moles of NH3 = 1.2 moles G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 37 of 46 CHM.5.3.01.012.03 Calculate the mass of a reactant or a product given the number of moles of another reactant or product and vice versa Example: Acetylene gas, C2H2, is produced by adding water to calcium carbide, CaC2, according to the following equation: CaC2(s) + 2 H2O(l) → C2H2(g) + Ca(OH)2(aq). Answer the following question. a) Calculate the mass of C2H2 produced when 4.00 moles of CaC2 reacted. (C = 12, H = 1) CaC2 1 mole 1 mole 4.00 moles C2H2 1 mole 1 × 26 g ???? g Mass of C2H2 = 104 g b) Calculate the mass of H2O needed to react with 4.00 moles of CaC2. (C = 12, H = 1) CaC2 1 mole 1 mole 4.00moles 2 H2O 2 mole 2 × 18 g ???? g Mass of CaC2 = 144 g CHM.5.3.01.012.04 Calculate the mass of a reactant or a product given the mass of another reactant or product Example: Acetylene gas, C2H2, is produced by adding water to calcium carbide, CaC2, according to the following equation: CaC2(s) + 2 H2O(l) → C2H2(g) + Ca(OH)2(aq). Answer the following questions. (Ca = 40, C = 12, H = 1, O = 16) a) Calculate the mass of CaC2 needed to react with 3.60 g of H2O. CaC2 1 mole 1 × 64 g ???? g 2 H2O 2 moles 2 × 18 g 3.60 g Mass of CaC2 = 6.40 g b) Calculate the mass of C2H2 produced when 3.60 g of H2O reacts with CaC2. C2H2 1 mole 1 × 26 g ???? g 2 H2O 2 moles 2 × 18 g 3.60 g Mass of C2H2 = 2.60 g G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 38 of 46 Inspire Chemistry – Module 10 – Lesson 3: Limiting Reactants CHM.5.3.01.013.01 Describe the reason why a reaction between two substances comes to an end One of the reactants is used up. CHM.5.3.01.013.02 Distinguish between limiting reactant and excess reactant in a chemical reaction Limiting reactant is the reactant that controls the amount of product formed in a chemical reaction Excess reactant is the substance that is not used up completely in a reaction (It is only partially consumed in the reaction) CHM.5.3.01.033.01 Explain the importance of using an excess reactant in a chemical reaction Using an excess of one reactant causes reactions to be driven to continue until all of the limiting reactant is used up. This technique can also speed up a reaction. Steps to identify limiting reactant: 1) Find number of moles of each reactant 2) Divide each number of moles by the reacting ratio 3) The smaller quantity is the limiting reactant CHM.5.3.01.013.03 Identify limiting reactant and excess reactant in a chemical reaction given the particulate diagram of reactants Example: Hydrogen gas reacts with oxygen gas to form water vapor according to the following balanced chemical reaction: 2H2(g) + O2(g) → 2 H2O(g) Consider the following particulate diagram for the reaction taking place answer questions a & b? a) Identify the limiting reactant and the excess reactant. The limiting Reactant is H2 and the excess reactant is O2. Explanation: H2 O2 Given 6 moles 5 moles Divide by reacting ratio 6 =3 2 5 =5 1 Limiting reagent H2 (The smaller amount) G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 39 of 46 Hence, the 6 moles of H2, will completely react with 3 moles of O2 to form 6 moles of H2O b) How many moles of the excess reactant remains when the reaction stops? 6 moles of H2 will react with 3 moles of O2 Amount of O2 remaining = 5 – 3 = 2 moles CHM.5.3.01.013.04 Identify limiting reactant and excess reactant in a chemical reaction given the number of moles of reactants Example: Methane,CH4, burns in oxygen, O2, to form carbon dioxide, CO2, and water vapor, H2O, according to the following equation, 𝐂𝐇𝟒(𝐠) + 𝟐𝐎𝟐(𝐠) → 𝐂𝐎𝟐(𝐠) + 𝟐𝐇𝟐 𝐎(𝐠) . A sample of 0.250 moles of CH4 was burnt in 1.25 moles of O2. Answer questions a & b. a) Identify the limiting reactant and the excess reactant. The limiting reactant is CH4 and the excess reactant is O2. Number of moles Divide by reacting ratio Limiting reagent CH4 O2 0.250 moles 1.25 moles 0.250 = 0.250 1 1.25 = 0.625 2 CH4 (The smaller amount) b) Calculate the mass of the excess reactant that remains when the reaction stops. 0.250 moles of CH4 will react with 0.500 moles of O2 Amount of O2 remaining = 1.25 – 0.500 = 0.750 moles Mass of excess reactant remaining = n × M = 0.750 × 32 = 24.0 g CHM.5.3.01.013.05 Identify limiting reactant and excess reactant in a chemical reaction given the mass of reactants Example: A 3.4 g sample of ammonia, NH3, reacts with 3.2 g of oxygen, O2, to form nitrogen monoxide, NO, and water, H2O, according to the following balanced equation: 4 NH3 + 5 O2 → 4 NO + 6 H2O (Molar mass NH3 = 17 g/mol, O2 = 32 g/mol, NO = 30 g/mol & H2O = 18 g/mol) a) Identify the limiting reagent. NH3 Number of moles m n= M Divide by reacting ratio Limiting reagent n= 3.4 = 0.20 moles 17 0.20 = 0.050 4 O2 n= 3.2 = 0.10 moles 32 0.10 = 0.020 5 O2 (The smaller amount) b) Identify the excess reagent. NH3 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 40 of 46 CHM.5.3.01.013.06 Calculate the mass of excess reactant that remains after the reaction is complete Please refer to KPI 2.5.17 CHM.5.3.01.013.07 Calculate the number of moles of excess reactant that remains after the reaction is complete Please refer to KPI 2.5.16 CHM.5.3.01.013.08 Calculate the mass of product(s) produced in a chemical reaction given a particulate diagram, mass or mole of the reactants Please refer to the example below CHM.5.3.01.013.09 Calculate number of moles of product(s) produced in a chemical reaction given a particulate diagram, mass or mole of the reactants Please refer to the example below Example: The particulate diagram of the reactants is given Hydrogen gas reacts with oxygen gas to form water vapor according to the following balanced chemical reaction: 2H2(g) + O2(g) → 2 H2O(g) Consider the following particulate diagram for the reaction taking place answer questions a – d. a) Identify the limiting reactant and the excess reactant. The limiting Reactant is H2 and the excess reactant is O2. Explanation: H2 O2 Given 4 moles 3 moles Divide by reacting ratio 4 =2 2 3 =3 1 Limiting reagent H2 (The smaller amount) G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 41 of 46 b) Calculate the amount of the excess reactant, in moles, that remain when the reaction stops. 2H2 2 moles 4 moles : O2 1 mole ????? 2 moles of O2 (out of 3 moles) will react with 4 moles of H2 Amount of O2 remaining = 3 – 2 = 1 mole c) Calculate the amount of the product, in moles, that forms when the reaction stops. 2H2 2 moles 4 moles : 2H2O 2 moles ????? 4 moles of H2O will form d) Draw the amount of the product formed and the excess reactant remaining. 4 moles of H2 will completely react with 2 moles of O2 where 1 mole of O2 remains. 4 moles of H2O are formed G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 42 of 46 Example: The mass of the reactants is given Consider the following information to answer questions a – g. A 1.24 g sample of P4, reacts with 9.60 g of O2, to form P4O6, according to the following balanced equation: P4 + 3 O2 → P4O6 (Molar mass P4 = 124 g/mol, O2 = 32 g/mol & P4O6 = 220 g/mol) a) Identify the limiting reagent. P4 Number of moles m n= M n= Divide by reacting ratio O2 1.24 = 0.0100 moles 124 n= 0.0100 = 0.0100 1 Limiting reagent 9.60 = 0.300 moles 32 0.300 = 0.100 3 P4 b) Identify the excess reagent. O2 c) Calculate the number of moles P4O6 formed. P4 1 mole 1×124 g 1.24 g P4O6 1 mole 1 mole ?? Number of moles of P4O6 = 0.0100 moles d) Calculate the mass of P4O6 formed. Mass of P4O6 = n × M = 0.0100 × 220 = 2.20 g e) After the reaction is completed, calculate the number of moles of excess reactant that reacted. P4 1 mole 1×124 g 1.24 g 3 O2 3 moles 3 moles ?? Number of moles of O2 reacting = 0.0300 moles f) After the reaction is completed, calculate the number of moles of excess reactant REAMAINING. Number of moles of O2 remaining = 0.300 – 0.0300 = 0.270 moles g) Calculate the mass of the excess reactant remaining. Mass = n × M = 0.270 × 32 = 8.64 g G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 43 of 46 Example: The number of moles of the reactants is given Methane, CH4, burns in oxygen to form carbon dioxide, CO2, and water vapor, H2O, according to the following balanced equation: 𝐂𝐇𝟒(𝐠) + 𝟐𝐎𝟐(𝐠) → 𝐂𝐎𝟐(𝐠) + 𝟐𝐇𝟐 𝐎(𝐠) . A sample of 0.250 moles of methane was burnt in 1.25 moles of oxygen. Answer questions a – f. a) Identify the limiting reactant. Number of moles m n= M Divide by reacting ratio Limiting reactant CH4 O2 0.250 moles 1.25 moles 0.250 = 0.250 1 1.25 = 0.625 2 CH4 (The smaller amount) b) Calculate the number of moles and mass of CO2 formed. CH4 1 mole 0.250 mol CO2 1 mole ????? Number of moles of CO2 formed = 0.250 moles Mass of CO2 formed = n × M = 0.250 × 44 = 11.0 g c) Calculate the number of moles and mass of H2O produced. CH4 1 mole 0.250 mol 2H2O 2 moles ????? Number of moles of H2O produced = 0.500 moles Mass of H2O produced = n × M = 0.500 × 18 = 9.00 g d) Calculate the total number of moles of products formed. Total moles of products = number of moles of CO2 + number of moles of H2O = 0.250 + 0.500 = 0.750 moles e) Calculate the total mass of products formed. Total mass of products = mass of CO2 + mass of H2O = 11.0 + 9.00 = 20.0 g G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 44 of 46 f) After the reaction is completed, calculate the mass of the excess reactant remaining. CH4 1 mole 0.250 mol 2 O2 2 moles ??? Number of moles of O2 reacting = 0.500 moles Number of moles of O2 remaining = 1.25 – 0.500 = 0.750 moles Mass of O2 remaining = n × M = 0.750 × 32 = 24.0 g CHM.5.3.01.013.10 Conduct an experiment to determine the limiting reactant, the quantity of the products and of the reactant in excess in a chemical reaction Inspire Chemistry – Module 10 – Lesson 4: Percent Yield CHM.5.3.01.013.11 Distinguish between theoretical yield and actual yield in stoichiometric calculations Theoretical yield is the maximum amount of product that can be produced from a given amount of reactant Actual yield is the measured amount obtained CHM.5.3.01.013.12 Explain why the actual yield is usually less than the calculated theoretical yield Due to one of the following: 1) Not all reactions often go to completion 2) Impure reactants produce less product than expected 3) Competing side reactions may consume some of the reactants 4) Some of the product may be lost when it is purified CHM.5.3.01.013.13 Define the percent yield of a chemical reaction Percent yield is the ratio of the actual yield to the theoretical yield multiplied by 100 𝐏𝐞𝐫𝐜𝐞𝐧𝐭𝐚𝐠𝐞 𝐲𝐢𝐞𝐥𝐝 = 𝐀𝐜𝐭𝐮𝐚𝐥 𝐘𝐢𝐞𝐥𝐝 × 𝟏𝟎𝟎 𝐓𝐡𝐞𝐨𝐫𝐞𝐭𝐢𝐜𝐚𝐥 𝐘𝐢𝐞𝐥𝐝 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 45 of 46 CHM.5.3.01.013.14 Calculate percent yield and theoretical in a chemical reaction Example: A 500. g sample of copper (II) sulfate pentahydrate, CuSO4.5H2O, is heated until complete decomposition where anhydrous copper(II)sulfate, CuSO4, is formed according to the following ∆ reaction: CuSO4 . 5H2 O → CuSO4 + 5H2 O. Answer questions a and b. a) Calculate the theoretical yield of CuSO4. CuSO4.5H2O 1 mole 1 × 250 g 500. g CuSO4 1 mole 1 × 160 g ???? g Mass of CuSO4 = 320. g b) Calculate the percent yield of the anhydrous salt, CuSO4 , if the actual mass of the CuSO4 is 160.g. Percentage yield = Actual Yield Theoretical 160. × 100 = 320. × 100 = 50.0 % CHM.5.3.01.033.02 Identify which type of yield (theoretical yield, actual yield, or percent yield) is a measure of the efficiency of a chemical reaction The percent yield This document was created for educational purposes. The document is not meant for publication or mass printing or production. It is made to support the UAE Ministry of Education and Applied Technology High School students for AY 2021 – 2022 G10 Advanced Chemistry– CHM51 – Course Specification – Term 2 (Detailed KPIs) Page 46 of 46