Advanced Composite Material Portfolio Selector Guide f Thermoset f Thermoplastic f Ancillaries f RTM & BMC Table of Contents Introduction to Toray Advanced Composites Advanced Composite Materials Selector Guide Materials Technology and Capabilities Market-Leading Technology and Capabilities Introduction 3 Thermoset Epoxy 4- 7 Cyanate Ester 8- 9 High Temperature Polyimide and BMI Toray Cetex Thermoplastic Materials ® 10 - 11 12 - 13 Toray MicroPly™ Ancillary Composite Materials Thermoset Film Adhesives 14 - 15 Thermoset Syntactics 16 - 19 Resin Transfer Molding and Bulk Molding Compounds 20 - 21 Toray AmberTool® Composite Tooling Prepregs 22 - 23 Toray Advanced Composites is a global leader in the development and manufacture of a wide range of advanced composite material solutions for aerospace, satellite, communications, and high performance industrial markets. Our goal is to increase our customers’ advantage with our market-leading product portfolio, a world-class technical support team, and award-winning customer service. Toray Advanced Composites operates five prepreg manufacturing sites globally, with three facilities in North America and two in Europe. Three of our facilities offer true carbon-free areas to serve the sensitive radome and communication industries with low dielectric constant and low-loss materials. Our major production sites operate aerospace-quality systems and are certified to ISO9001:2015 and/or AS9100D. Your Global Partner Toray Advanced Composites is unique in the industry, offering a broad spectrum of thermoplastic and thermoset prepreg systems, with particular expertise in high performance thermoplastic composites (under the brand name Toray Cetex®). Our broad product portfolio supports programs from prototyping through to high-volume manufacture of parts. Innovation Our state-of-the-art manufacturing facilities around the world allow Toray to efficiently supply composite materials to global customers. Ongoing investments in facilities and personnel ensure production excellence to meet today’s requirements and tomorrow’s demand. Stop by and see for yourself. We welcome customer visits and look forward to the opportunity to work with you on your next project. Investing in innovation for over 45 years, our strong customer focus on tailored systems, combined with our comprehensive laboratory and testing capabilities, allows for rapid development, customization, and database development. Our experience in thermoset and thermoplastic resins, various composite fibers, and part design allows us to rapidly innovate to customer needs. Recognized in the industry for providing optimized fiber and resin solutions, we deliver advanced customer-oriented products to the market. For more product information such as product data sheets, case studies, or technical papers, please use the following resources: Search for the Toray TAC Product Selector www. 2 | Advanced Composites Materials Selector Guide www.toraytac.com Go to our online resource center for case studies and technical papers Introduction to Toray Advanced Composites | 3 Toray MicroPly™ product properties are not fire-retardant Minimum cure temperature applies to ensure product performance Toray MicroPly™ products compatible with the resin matrix indicated Thermoset Epoxy Since each application and material combination is unique, the customer is responsible for performing their own evaluations for specific uses Advanced Composite Prepreg Product Selector of the Toray MicroPly™ products in their own applications. 8020-FR FR Epoxy BT250E-1 Epoxy 125°C (257°F) BT250E-6 Epoxy 131°C (268°F) E650 Epoxy E720 Epoxy 121°C (250°F) 110°C (230°F) 120°C (248°F) E721-FR FR Epoxy E722 E731 Modified Epoxy Modified Epoxy Epoxy E732 Epoxy E745 Epoxy E750 Epoxy E760 Epoxy 204°C (399°F) Modified Epoxy 180°C (356°F) RS-1 Epoxy RS-17B Epoxy 107°C (225°F) 171°C (340°F) E726 EX-1522 4 | 120°C (248°F) 105°C (221°F) 140°C (284°F) 170°C (338°F) 118°C (244°F) 148°C (298°F) ENGINES/HIGH TEMP AIRCRAFT INTERIORS AEROSPACE SPACE AND SATELLITE SYNTACTICS AEROSTRUCTURES LOW DIELECTRIC LOSS & CONSTANT LOW TEMPERATURE CURE LOW MOISTURE ABSORPTION HIGH TEMPERATURE PERFORMANCE IMPACT RESISTANT CORROSION RESISTANT CHEMICAL RESISTANT FLAME RETARDANT TOUGHENED POST CURABLE PRESS FORMING 30 12 30 12 5 12 60 12 60 12 60 12 60 12 14 12 21 6 60 12 60 12 21 12 21 12 30 6 30 12 material test criteria 121°C (250°F) f Aerospace flight qualified 60 minutes f MIL-R-9300 qualified f Flame-retardant version available 127°C (260°F) f Aerospace flight qualified f High modulus system for rotor blades 2 hours f Complete FAA-accepted database on four product forms 70°C (158°F) f Easier lamination due to medium tack level 3.5 hours 120°C (248°F) f Honeycomb bondable 60 minutes 120°C (248°F) f Direct lamination to honeycomb without the use of resin film 60 minutes f Fire resistant under FAR 25.853 Appendix F material test criteria (ii) f MicroPly™SC72A cure at 125°C minimum 120°C (248°F) f Excellent drapeability 60 minutes f General purpose component prepreg 120°C (248°F) f Controlled flow 60 minutes f Good surface finish 125°C (257°F) f Enhanced resin clarity for cosmetic components 60 minutes 160°C (230°F) f Hot-in hot-out press processing f Short cure cycles 120–160°C (248–320°F) 4 minutes 135°C (275°F) f High toughness and impact properties 60 minutes 135°C (275°F) f Flexible cure schedules 80–180°C (176–356°F) 60 minutes f Structural applications with F1 f MicroPly™SC72A cure at 125°C minimum 180°C (356°F) f High temperature resistance and high mechanical performance 2 hours f Exceptional high temperature performance 177°C (350°F) f Fire retardant, V-0 level f Low moisture absorption 2 hours f Low outgassing, low dielectric constant and loss 93°C (200°F) f Excellent balance of mechanical properties, toughness, and modulus 90 minutes 177°C (350°F) f Flexible cure system (135°C–177°C) f Extensive space flight heritage 2 hours INDUSTRIAL RADOMES LAUNCH 12 TCF4045 30 TCF4035 f Good adhesive properties to honeycomb core f Fire resistant under FAR 25.853 Appendix F SC8020 SC72A EM-5A EM-3 TC310 TC263 RS-15H 12 EF8020 30 EF72 f Flexible cure schedules 70–130°C (158–266°F) f Post curable for higher Tg applications AFP/ATL 80°C (176°F) 5.5 hours 80°C (176°F) 5.5 hours FILM ADH FREEZER LIFE # MONTHS AUTOCLAVE 121°C (250°F) 121°C (250°F) MARKET SEGMENTS PRODUCT ATTRIBUTES OUT LIFE # DAYS KEY PRODUCT CHARACTERISTICS OOA/VBO Epoxy RTL LAMINATE CURE TEMPERATURE AND TIME UD TAPE NEAT RESIN DRY Tg ONSET PROCESSING Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 5 Thermoset Thermoset 8020 RESIN MATRIX WOVEN PREPREG PRODUCT FORMATS Toray MicroPly™ products compatible with the resin matrix indicated Thermoset Epoxy Since each application and material combination is unique, the customer is responsible for performing their own evaluations for specific uses Advanced Composite Prepreg Product Selector of the Toray MicroPly™ products in their own applications. TC250 TC264-1 TC275-1 TC275-1E NEW TC346 NEW TC350-1 TC380 NEW TC522 NEW TC750 NEW 6 | 177°C (350°F) f Lower cost resin system compared to cyanate 90 minutes esters f RS-36-1 is the higher Tg version Epoxy 140°C 130°C (265°F) f Aerospace flight qualified f Toughened system (285°F) 2 hours f Post curable for higher Tg f Flame-retardant version available 180°C post cure (356°F) with 180°C (356°F) f NCAMP database on fabric version post cure 2 hours f Ideal for flame retardancy applications Epoxy 124°C 118-127°C (255°F) (245-260°F) f Ideal for ducting and composite panels 90 minutes Epoxy 164°C 135°C (275°F) f Aerospace flight qualified f Low moisture uptake, high Tg retention (327°F) 6 hours f Ideal system for large structures f OOA/VBO processable 183°C post cure (362°F) with (optional) post cure 177°C (350°F) 2 hours Epoxy 168°C 135°C (275°F) f Longer out time version of TC275-1 f Allows construction of thick or larger (334°F) 6 hours composites structures f OOA/VBO processable post cure (optional) 177°C (350°F) 2 hours Epoxy 221°C 180°C (356°F) f Structural values retained at high temperatures f High temperature resistance (430°F) 2 hours f SFI 56.1 flame retardancy at 1-ply thickness and UL94 V0 flame retardancy at 2 mm post cure thickness (200g 2x2 Twill HM63 12K 42% RC) 200°C (392°F) Epoxy 191°C 177°C (350°F) f Industry standard 177°C epoxy f Good hot/wet properties (376°F) 2 hours f Good CAI properties 221 MPa (32 ksi) Epoxy 201°C 180°C (356°F) f Aerospace flight qualified f Excellent balance of OHC and CAI properties (394°F) 2 hours f Excellent hot/wet strength retention Modified 189°C 180°C (356°F) f Outstanding compression after impact f Low dielectric constant and loss Epoxy (372°F) 2 hours f Outstanding hot/wet properties Epoxy 160°C 180°C (356F) f Versatile cure schedules—80°C (176°F) to 180°C (356°F) (320F) 2 hours f Toughened system with good balance of mechanical properties f Optimized tack and drape 21 12 21 12 45 12 28 12 21 12 60 12 INDUSTRIAL 12 ENGINES/HIGH TEMP 14 AIRCRAFT INTERIORS LAUNCH TCF4045 TCF4035 12 SC8020 30 SC72A EM-5A EM-3 TC310 12 TC263 30 RS-15H EF8020 EF72 12 AFP/ATL 30 AUTOCLAVE FREEZER LIFE # MONTHS RADOMES AEROSPACE SPACE AND SATELLITE SYNTACTICS AEROSTRUCTURES LOW DIELECTRIC LOSS & CONSTANT FILM ADH LOW TEMPERATURE CURE LOW MOISTURE ABSORPTION HIGH TEMPERATURE PERFORMANCE IMPACT RESISTANT CORROSION RESISTANT CHEMICAL RESISTANT FLAME RETARDANT TOUGHENED POST CURABLE PRESS FORMING MARKET SEGMENTS PRODUCT ATTRIBUTES OUT LIFE # DAYS OOA/VBO 181°C (358°F) KEY PRODUCT CHARACTERISTICS RTL LAMINATE Epoxy CURE TEMPERATURE AND TIME UD TAPE NEAT RESIN DRY Tg ONSET PROCESSING Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 7 Thermoset Thermoset RS-36 & RS-36-1 RESIN MATRIX WOVEN PREPREG PRODUCT FORMATS Toray MicroPly™ products compatible with the resin matrix indicated Thermoset Cyanate Ester Since each application and material combination is unique, the customer is responsible for performing their own evaluations for specific uses Advanced Composite Prepreg Product Selector of the Toray MicroPly™ products in their own applications. BTCy-1A Cyanate Ester 238°C (461°F) with post cure 185°C (365°F) 207°C (405°F) with post cure BTCy-2 Cyanate Ester 191°C (375°F) EX-1515 Cyanate Ester 121°C (249°F) RS-3/ RS-3C Cyanate Ester TC410 Cyanate Ester TC420 8 Cyanate Ester | 174°C (345°F) with post cure 191°C (375°F) 254°C (490°F) with post cure 112°C (234°F) 181°C (358°F) with post cure 176°C (349°F) 348°C (658°F) with post cure post cure (optional) 232°C (450°F) 2 hours 177°C (350°F) 2 hours at post cure (optional) 204°C (400°F) 60 minutes 177°C (350°F) 90 minutes 121°C (250°F) 3 hours post cure (optional) 177°C (350°F) 2 hours 177°C (350°F) 2 hours post cure (optional) 232°C (450°F) 60 minutes 121°C (250°F) 3 hours post cure (optional) 177°C (350°F) 177°C (350°F) 3 hours post cure (optional) 260°C (500°F) 12 14 6 21 12 f Industry standard prepreg system 30 12 f Lowest CTE, CME, outgassing f Ideal system for stable structures 7 6 21 6 INDUSTRIAL 30 ENGINES/HIGH TEMP f Toughened version of BTCy-1 f Low void content with lower AIRCRAFT INTERIORS RADOMES LAUNCH SPACE AND SATELLITE AEROSPACE AEROSTRUCTURES TCF4050 TCF4035 EM-5A TC4015 SF-5 12 RS-4A 14 EX-1543 f Low moisture absorption f Low dielectric constant and loss EX-1516 FREEZER LIFE # MONTHS AFP/ATL MARKET SEGMENTS SYNTACTICS TCF4001 FILM ADH HIGH TEMPERATURE PERFORMANCE LOW MOSITURE ABSORPTION LOW TEMPERATURE CURE LOW DIELECTRIC LOSS & CONSTANT IMPACT RESISTANT CORROSION RESISTANT CHEMICAL RESISTANT FLAME RETARDANT TOUGHENED POST CURABLE PRESS FORMING 177°C (350°F) 90 minutes AUTOCLAVE 190°C (374°F) TORAY MICROPLY™ PRODUCT ATTRIBUTES OUT LIFE # DAYS KEY PRODUCT CHARACTERISTICS OOA/VBO Cyanate Ester RTL LAMINATE CURE TEMPERATURE AND TIME UD TAPE NEAT RESIN DRY Tg ONSET PROCESSING pressure cures f Ideal for satellite or radome applications f Toray lowest dielectric loss prepreg f Ideal for high-energy radomes f 121°C (250°F) curing cyanate ester system for low-residual cure stresses f Post curable for higher Tg for satellite structures f Low dielectric constant and loss f Toray’s highest temperature cyanate ester f Excellent thermal stability f Epoxy-like processing with Tg of BMI f Used on heatshields and supersonic leading edges Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 9 Thermoset Thermoset BTCy-1 RESIN MATRIX WOVEN PREPREG PRODUCT FORMATS Toray MicroPly™ products compatible with the resin matrix indicated Thermoset High Temperature Polyimide and BMI Since each application and material combination is unique, the customer is responsible for performing their own evaluations for specific uses Advanced Composite Prepreg Product Selector of the Toray MicroPly™ products in their own applications. 371°C (700°F) Call for cure details 10 | 30 12 30 12 DS77 Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | INDUSTRIAL ENGINES/HIGH TEMP 6 AIRCRAFT INTERIORS 10 for jet engine applications f Non-MDA PMR-15 replacement f Short-term service temperature capability of 538°C (1000°F) f Better hot/wet properties versus AFR-PE-4E f Lower pressure cure processing f More robust processing of thick components versus AFR-PE-4E f Post cure not required SPACE AND SATELLITE f Ultra-high service temperature AEROSTRUCTURES LOW TEMPERATURE CURE LOW MOSITURE ABSORPTION HIGH TEMPERATURE PERFORMANCE IMPACT RESISTANT FLAME RETARDANT TOUGHENED 6 AEROSPACE RADOMES Polyimide 30 MARKET SEGMENTS SYNTACTICS LAUNCH NRPE CORROSION RESISTANT Call for cure details CHEMICAL RESISTANT 454°C (850°F) POST CURABLE TC890 AFP/ATL RS-51 PRESS FORMING 366°C (690°F) 285°C (545°F) with post cure f Excellent high temperature thermal stability f Good moisture resistance f Moderate toughness FILM ADH AUTOCLAVE Polyimide AFR-PE-4 Polyimide 900HT 204°C (400°F) 2 hours followed by 250°C (482°F) 6 hours Call for cure details OOA/VBO 203°C (397°F) FREEZER LIFE # MONTHS KEY PRODUCT CHARACTERISTICS RTL LAMINATE BMI OUT LIFE # DAYS WOVEN PREPREG CURE TEMPERATURE AND TIME UD TAPE NEAT RESIN DRY Tg ONSET TORAY MICROPLY™ PRODUCT ATTRIBUTES 11 Thermoset Thermoset RS-8HT RESIN MATRIX PROCESSING SF-44 PRODUCT FORMATS Toray Cetex® Thermoplastic Tm Melting point temperature; only shown for semi-crystalline (PAEK family) Advanced Composite Prepreg and Laminate Product Selector thermoplastic products 260–320°C (500–608°F) f Designed for interior applications with good TC940 215°C (419°F) 240–270°C (435–518°F) 160°C (320°F) TC1000 Design PET PolyethyleneTerephthalate PP Polypropylene PEI Polyetherimide 199–216°C (390–421°F) 320–350°C (608–662°F) TC1000 Premium PEI Polyetherimide TC1100 TC960 Amorphous Amorphous 320–350°C (608–662°F) PPS Polyphenylenesulfide 280°C (536°F) 300–330°C (572–626°F) TC1200 PEEK Polyetheretherketone 343°C (649°F) 370–400°C (698–752°F) TC1225 LMPAEK Low-Melt Polyaryletherketone 305°C (581°F) 340-385°C (644-725°F) TC1320 PEKK Polyetherketoneketone 337°C (639°F) 370–400°C (698–752°F) 12 | INDUSTRIAL AERO ENGINES AIRCRAFT INTERIORS RADOMES LAUNCH SPACE AND SATELLITE AEROSTRUCTURES MECHANICAL PERFORMANCE LOW MOSITURE ABSORPTION FLAME RETARDANT IMPACT RESISTANT 153°C (307°F) CORROSION RESISTANT PC Polycarbonate CHEMICAL RESISTANT TC925 FST DURABILITY/ TOUGHNESS f Temperature and solvent resistant f Use as a preform insert for compression and AFP/ATL 249–271°C (480–520°F) PRESS FORMING 220°C (428°F) AUTOCLAVE PA6 Nylon 6 AEROSPACE overmolding to improve part performance FST properties (OSU < 25/25) f Value-oriented solution f Good surface qualities, impact toughness f Good impact resistance for recreational and low cost applications f High toughness for vehicle and low cost applications f Laminates are available to customer specifications f Excellent FST performance f Lower cost option than Premium where OEM specifications are not required f Excellent FST performance (OSU < 15/15) f Moderate solvent resistance f Widely used in aircraft interiors, qualified to OEM specifications f Microcrack free f Low flammability, achieves 35/35 for OSU performance f Good CAI properties 229 MPa (33.2 ksi) f Ideal for leading edges, beams, clips, and floor panels f Good high temperature properties f Very good CAI properties 265 MPa (38.4 ksi) f Ideal for structural applications f Lower processing temperature with good high temperature performance f May be overmolded with PEEK for final part f Very good CAI properties 282 MPa (40.9 ksi) f Ideal for structural applications f Outstanding solvent and impact resistance f Very high CAI properties 337 MPa (48.9 ksi) f Ideal for structural applications f Lower processing temperature material Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 13 Thermoplastic Thermoplastic TC910 MARKET SEGMENTS PRODUCT ATTRIBUTES WELDABLE/JOINTING KEY PRODUCT CHARACTERISTICS RTL LAMINATE PROCESSING TEMPERATURE Tp WOVEN PREPREG MELTING TEMPERATURE Tm UD TAPE POLYMER PROCESSING HIGH TEMPERATURE PERFORMANCE PRODUCT FORMATS Toray MicroPly™ Film Adhesives Thermoset Since each application and material combination is unique, the customer is responsible Advanced Composite Film Adhesive Product Selector their own applications. for performing their own evaluations for specific uses of the Toray MicroPly™ products in 30 12 21 12 21 12 21 12 14 6 f Moisture-resistant cyanate ester film 14 6 f Excellent high temperature 14 6 INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS 12 RADOMES 30 LAUNCH SPACE AND SATELLITE AEROSTRUCTURES LOW TEMPERATURE CURE LOW MOSITURE ABSORPTION HIGH TEMPERATURE PERFORMANCE CORROSION RESISTANT IMPACT RESISTANT CHEMICAL RESISTANT 12 FLAME RETARDANT 30 TOUGHENED FREEZER LIFE # MONTHS POST CURABLE OUT LIFE # DAYS KEY PRODUCT CHARACTERISTICS AFP/ATL CURE TEMPERATURE AND TIME PRESS FORMING NEAT RESIN DRY Tg ONSET AEROSPACE AUTOCLAVE RESIN MATRIX MARKET SEGMENTS PRODUCT ATTRIBUTES OOA / VBO PROCESSING Toray MicroPly™ Film Adhesives Epoxy EF72 Epoxy EF8020 Epoxy RS-15H Epoxy TC263 Epoxy TC310 Epoxy 112°C (234°F) 120°C (248°F)—60 minutes f High strength f Excellent filleting to honeycomb core 102°C (215°F) 80°C (176°F)—5.5 hours f Flexible cure schedules 70–130°C (158–266°F) Alternate cures f Ideal for metal or composite bonding are available 93°C (200°F)—6 hours f Low temperature curing adhesive 99°C (211°F)1 Alternate cures are available 110°C (230°F) 121°C (250°F)—2 hours f High peel strength f Ideal for metal or composite bonding f Ideal composite bonding film 157°C (315°F) 177°C (350°F)—2 hours adhesive Toray MicroPly™ Film Adhesives Cyanate Ester TC4015 Cyanate 176°C (349°F) Ester 321°C (610°F) with post cure 121°C (250°F)—5 hours 177°C (350°F)—2 hours post cure (optional) 204°C (400°F)—2 hours 177°C (350°F)—2 hours post cure (optional) 232°C (450°F) 1.5–2 hours 177°C (350°F)—2 hours post cure (optional) 232°C (450°F)—> 60 min f Compatible with Toray EX-1515 prepreg f Low-shrinkage cyanate ester film adhesive f Low outgassing adhesive f Compatible with 177°C (350°F) curing cyanate ester prepregs properties f Compatible with TC420 1 - Tg estimated from base resin data 14 | Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS RADOMES LAUNCH SPACE AND SATELLITE AEROSTRUCTURES LIGHTNING STRIKE PROTECTION AEROSPACE LOW MOSITURE ABSORPTION HIGH TEMPERATURE PERFORMANCE IMPACT RESISTANT FLAME RETARDANT TOUGHENED POST CURABLE AFP/ATL 6 PRESS FORMING 14 OOA / VBO FREEZER LIFE # MONTHS CORROSION RESISTANT 327–371°C (620–700°F)— f Compatible with RS-51 (AFRPE), NRPE, 2 hours minimum TC890 (900HT), 635LM, PMR-15 f 260–288°C (500°–550°F) service capability f Does not contain MDA f Available as a film, supported or unsupported OUT LIFE # DAYS MARKET SEGMENTS PRODUCT ATTRIBUTES CHEMICAL RESISTANT 310–360°C (590–680°F) depending on final cure temperature KEY PRODUCT CHARACTERISTICS RTL LAMINATE Polyimide CURE TIME AND TEMPERATURE WOVEN PREPREG DS77 DRY Tg ONSET PROCESSING UD TAPE RESIN MATRIX PRODUCT FORMATS AUTOCLAVE Toray MicroPly™ Film Adhesives High Temperature Polyimide | 15 Ancillary Composite Materials Ancillary Composite Materials EX-1516 Cyanate 126°C (258°F) Ester EX-1543 Cyanate 191°C (376°F) Ester 211°C (412°F) with post cure RS-4A Cyanate 195°C (383°F) Ester 238°C (460°F) with post cure Toray MicroPly™ Syntactics Thermoset Since each application and material combination is unique, the customer is responsible Advanced Composite Syntactic Product Selector their own applications. for performing their own evaluations for specific uses of the Toray MicroPly™ products in INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS RADOMES LAUNCH SPACE AND SATELLITE AEROSTRUCTURES LIGHTNING STRIKE PROTECTION LOW MOSITURE ABSORPTION AEROSPACE HIGH TEMPERATURE PERFORMANCE IMPACT RESISTANT FLAME RETARDANT 12 TOUGHENED 30 CORROSION RESISTANT f Excellent protective surface finish f Available with embedded lightning FREEZER LIFE # MONTHS POST CURABLE 121°C (250°F) 60 minutes TACK LIFE # DAYS MARKET SEGMENTS PRODUCT ATTRIBUTES AFP/ATL 119°C (246°F) Epoxy Surfacing Film KEY PRODUCT CHARACTERISTICS PRESS FORMING CURE TEMPERATURE AND TIME AUTOCLAVE TC235SF-1 NEAT RESIN DRY Tg ONSET OOA / VBO RESIN MATRIX PROCESSING CHEMICAL RESISTANT Toray MicroPly™ Surfacing Films Epoxy strike foils f Reduces shop floor finishing for productivity savings f Generally compatible with 120°C and 177°C curing epoxy resin prepreg systems TCF4045 Modified Epoxy 180°C (356°F) 130°C (265°F) 2 hours 179°C (355°F) 3 hours f Low density 0.64 g/cc (40 pcf) f Compatible with 121–135°C (250–275°F) curing materials e.g., TC250 f Post curable for higher Tg f Excellent low dielectric loss and constant f Density of 0.61 g/cc (38.5 pcf) 12 21 12 14 6 INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS 30 80°C (176°F)— 5.5 hours f Low density Alternate cures f Flexible cure schedules 70–130°C are available (158–266°F) RADOMES 140°C (284°F) 12 LAUNCH Epoxy 30 f Low density f Easily contoured and shaped SPACE AND SATELLITE TCF4035 120°C (248°F) 60 minutes AEROSTRUCTURES 106°C (222°F) LOW TEMPERATURE CURE Epoxy LOW MOSITURE ABSORPTION SC8020A 12 HIGH TEMPERATURE PERFORMANCE 106°C (222°F) 30 Minimum 125°C (257°F) f Density/strength tailored by changing cure pressure/limiting 60 minutes volume available for expansion IMPACT RESISTANT Epoxy AEROSPACE CORROSION RESISTANT SC72A FLAME RETARDANT 114°C (237°F) 12 TOUGHENED Epoxy 14 (40 pcf) density POST CURABLE ES72A-2 f High expansion (8–10 x) 0.64 g/cc AFP/ATL 121°C (250°F) 60 minutes FREEZER LIFE # MONTHS PRESS FORMING 116°C (240°F)1 OUT LIFE # DAYS OOA / VBO Epoxy EXPANDING EM-3 KEY PRODUCT CHARACTERISTICS PASTE CURE TEMPERATURE AND TIME FILM NEAT RESIN DRY Tg ONSET MARKET SEGMENTS PRODUCT ATTRIBUTES 1 - Tg estimated from base resin data 16 | Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 17 Ancillary Composite Materials Ancillary Composite Materials RESIN MATRIX PROCESSING CHEMICAL RESISTANT PRODUCT FORMATS AUTOCLAVE Toray MicroPly™ Syntactics Epoxy Toray MicroPly™ Syntactics Thermoset Since each application and material combination is unique, the customer is responsible Advanced Composite Syntactic Product Selector their own applications. for performing their own evaluations for specific uses of the Toray MicroPly™ products in 18 | 295°C (563°F) 204°C (400°F)— 2 hours post cure 250°C (482°F)— 6 hours f Low density 0.62 g/cc (39 pcf) f Compatible with RS-8HT and other BMI 14 6 INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS RADOMES MARKET SEGMENTS PRODUCT ATTRIBUTES LAUNCH SPACE AND SATELLITE AEROSTRUCTURES LOW TEMPERATURE CURE LOW MOSITURE ABSORPTION CORROSION RESISTANT IMPACT RESISTANT CHEMICAL RESISTANT HIGH TEMPERATURE PERFORMANCE INDUSTRIAL FREEZER LIFE # MONTHS PROCESSING ENGINES/HIGH TEMP OUT LIFE # DAYS AEROSPACE AIRCRAFT INTERIORS RADOMES LAUNCH LOW TEMPERATURE CURE KEY PRODUCT CHARACTERISTICS SPACE AND SATELLITE BMI CURE TEMPERATURE AND TIME AEROSTRUCTURES SF-4 NEAT RESIN DRY Tg ONSET PRODUCT FORMATS FILM RESIN MATRIX LOW MOSITURE ABSORPTION Toray MicroPly™ Syntactics Other Thermoset Matrices HIGH TEMPERATURE PERFORMANCE FLAME RETARDANT 6 IMPACT RESISTANT post cure 232°C (450°F) 60 minutes 7 splice f Density of 0.28–0.55 g/cc (17–35 pcf) f Compatible with TC420 prepregs CORROSION RESISTANT 232°C (450°F) with post cure f Expanding syntactic film/core CHEMICAL RESISTANT 176°C (349°F) 6 AEROSPACE Ancillary Composite Materials Ancillary Composite Materials Cyanate Ester 14 FLAME RETARDANT TCF4050 f Low density 0.38 g/cc (24 pcf) f Compatible with TC420 prepregs TOUGHENED post cure 232°C (450°F) 60–90 minutes 177°C (350°F)—2 hours 6 POST CURABLE post cure (optional) Cyanate Ester 14 TOUGHENED TCF4001 6 MARKET SEGMENTS PRODUCT ATTRIBUTES POST CURABLE post cure 249°C (480°F)—2 hours 177°C (350°F)—2 hours 14 pcf) f Good structural properties f Low dielectric constant and loss f Density of 0.61 g/cc (38 pcf) f Low dielectric constant and loss f Compatible with Toray RS-3 AFP/ATL 254°C (490°F) with post cure 176°C (349°F) Cyanate Ester f Density of 0.16–0.38 g/cc (10–24 AFP/ATL post cure 232°C (450°F)—2 hours 177°C (350°F)–2 hours PRESS FORMING 240°C (464°F) with post cure 193°C (379°F) 12 AUTOCLAVE 177°C (350°F)—2 hours Cyanate Ester 28 AUTOCLAVE post cure (optional) 227°C (441°F) f Expansion ratio of 4 x OOA / VBO 177°C (350°F)—2 hours OOA / VBO 204°C (400°F) FREEZER LIFE # MONTHS EXPANDING Cyanate Ester OUT LIFE # DAYS KEY PRODUCT CHARACTERISTICS PASTE CURE TEMPERATURE AND TIME PROCESSING EXPANDING SF-5 NEAT RESIN DRY Tg ONSET PASTE EX-1541 RESIN MATRIX FILM EM-5A PRODUCT FORMATS PRESS FORMING Toray MicroPly™ Syntactics Cyanate Ester systems Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 19 Resin Transfer Molding and Bulk Molding Compounds Advanced Composite RTM and BMC Product Selector MC1200 PEEK 343°C (649°F) 385°C (725°F) f PEEK-based BMC with SM and IM fibers f Fire retardant MC1322 NEW PEKK 331°C (628°F) 380°C (715°F) f PEKK-based BMC with SM fibers | HM IM SM INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS RADOMES AEROSPACE Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | INDUSTRIAL IMPACT RESISTANT ENGINES/HIGH TEMP CORROSION RESISTANT f PPS-based BMC with SM and IM fibers f Fire retardant AIRCRAFT INTERIORS CHEMICAL RESISTANT 330°C (626°F) AFP/ATL 280°C (536°F) PRESS FORMING PPS AUTOCLAVE MC1100 OOA / VBO PROCESSING TEMPERATURE MARKET SEGMENTS PRODUCT ATTRIBUTES FLAME RETARDANT PROCESSING INDUSTRIAL ENGINES/HIGH TEMP AIRCRAFT INTERIORS MELTING TEMP Tm 20 LAUNCH LOW MOSITURE ABSORPTION HIGH TEMPERATURE PERFORMANCE RESIN MATRIX KEY PRODUCT CHARACTERISTICS LIGHTNING STRIKE PROTECTION IMPACT RESISTANT CORROSION RESISTANT CHEMICAL RESISTANT FLAME RETARDANT TOUGHENED POST CURABLE TOUGHENED FIBER TYPE 21 RTM & BMC RTM & BMC BMC Toray Cetex® LAUNCH LAUNCH AEROSPACE IMPACT RESISTANT 6 OOA / VBO 14 standard modulus (SM) fiber HM f Chopped fiber epoxy BMC with IM 6 MARKET SEGMENTS PRODUCT ATTRIBUTES SPACE AND SATELLITE 191°C (375°F) 14 modulus (HM) fiber SPACE AND SATELLITE Epoxy f Chopped fiber epoxy BMC with high AEROSTRUCTURES MS-4H 6 AEROSTRUCTURES 191°C (375°F) 14 modulus (HM) fiber PROCESSING LIGHTNING STRIKE PROTECTION Epoxy f Chopped fiber epoxy BMC with high LIGHTNING STRIKE PROTECTION MS-1H 138°C (280°F)—15–30 min post cure 177°C (350°F)—1–2 hours 138°C (280°F)—15–30 min post cure 177°C (350°F)—1–2 hours 138°C (280°F)—15–30 min post cure (free standing) 177°C (350°F)—1–2 hours LOW MOSITURE ABSORPTION 164°C (327°F) CORROSION RESISTANT Epoxy FREEZER LIFE # MONTHS KEY PRODUCT CHARACTERISTICS CHEMICAL RESISTANT MS-1A OUT LIFE # DAYS CURE TEMPERATURE AND TIME AFP/ATL HIGH TEMPERATURE PERFORMANCE RADOMES 4 hrs RADOMES 177°C (350°F) f Toughened epoxy for structural applications f Low minimum viscosity of 23 cPs 2 hours SPACE AND SATELLITE AEROSTRUCTURES LOW MOSITURE ABSORPTION 4 hrs HIGH TEMPERATURE PERFORMANCE FIBER TYPE NEAT RESIN DRY Tg ONSET PRESS FORMING OOA / VBO BMC Thermoset RESIN MATRIX RTL LAMINATE 24 hrs AEROSPACE FLAME RETARDANT Epoxy TOUGHENED RS-50 167°C (332°F) 231°C (448°F) with post cure 203°C (397°F) POST CURABLE Cyanate Ester 173°C (345°F) 4 hrs MARKET SEGMENTS PRODUCT ATTRIBUTES AFP/ATL RS-16 EX-1545 177°C (350°F) f Low viscosity at room temperature of 150 cPs 2 hours f Post curable 177°C (350°F) f Toughened resin system with low viscosity of 140 cPs at 43°C (110°F) 2 hours f Long pot life for complex parts 135°C (275°F) f Low temperature cure resin system f Post curable for higher Tg 2 hours PRESS FORMING 200°C (392°F) PROCESSING AUTOCLAVE Cyanate Ester Cyanate Ester POT LIFE KEY PRODUCT CHARACTERISTICS SM EX-1510 CURE TEMPERATURE AND TIME 2 PART NEAT RESIN DRY Tg ONSET RESIN 1 PART PRODUCT FORMATS AUTOCLAVE RTM Resins Toray AmberTool® Composite Tooling Prepregs Advanced Composite Tooling Prepreg Product Selector MARKET SEGMENTS PRODUCT ATTRIBUTES LAUNCH RADOMES HX42 Epoxy 219°C (426°F) 234°C (453°F) 60°C (140°F) 8 hours f Proven system for aerospace f Shorter cure schedule at lower temperatures f Excellent surface finish f 210°C (410°F) end use temperature 5 12 HX50 Epoxy 190°C (374°F) 220°C (428°F) 55°C (131°F) 6 hours f Low intital temperature f Versatile curing options 40–55°C (104–131°F) f Excellent surface finish for small-to-medium-sized autoclave 60 hours 6 60 hours 6 14 6 INDUSTRIAL SPACE AND SATELLITE ENGINES/HIGH TEMP AEROSTRUCTURES AIRCRAFT INTERIORS LOW TEMPERATURE CURE LOW MOSITURE ABSORPTION HIGH TEMPERATURE PERFORMANCE 12 IMPACT RESISTANT 8 FREEZER LIFE # MONTHS FLAME RETARDANT f Extended out life for larger scale tooling applications f High temperature end use performance f Versatile curing options 50–75°C (122–167°F) OUT LIFE # DAYS TOUGHENED 65°C (149°F) 12 hours KEY PRODUCT CHARACTERISTICS POST CURABLE 229°C (444°F) TYPICAL CURE TEMPERATURE AND TIME AFP/ATL 203°C (397°F) Tg PEAK PRESS FORMING Epoxy NEAT RESIN DRY Tg ONSET AUTOCLAVE HX40 RESIN OOA / VBO CORROSION RESISTANT AEROSPACE CHEMICAL RESISTANT PROCESSING tooling f 180°C (356°F) end use temperature f Fast cure and excellent surface finish f Improved handleability f Available in carbon reinforcements from 205gsm to 990gsm f Excellent drape for complex shapes f 180°C (356°F) end use temperature HX56 Epoxy 185°C (365°F) 209°C (408°F) 55°C (131°F) 6 hours TC40 BMI 213°C (415°F) 315°C (597°F) 182°C (360°F) f High service temperature f Excellent thermal stability 6 hours post cure 210°C (410°F) 2 hours | Advanced Thermoplastic and Thermoset Composite Products for Aerospace and Industrial Applications | 23 Composite Tooling Composite Tooling 22 Locations and Capabilities SOLUTIONS Thermoplastic composites Thermoset composites Carbon-free manufacturing Parts manufacture Fairfield - CA, USA Nottingham, UK Morgan Hill - CA, USA Nijverdal, the Netherlands CERTIFICATIONS ISO 9001:2015 AS9100D ISO 14001:2015 ISO 45001:2018 Camarillo - CA, USA Toray Advanced Composites USA Inc. 18255 Sutter Blvd. Morgan Hill, CA 95037, USA Tel: +1 (408) 465 8500 explore@toraytac-usa.com Toray Advanced Composites ADS LLC 2450 Cordelia Road Fairfield, CA 94534, USA Tel: +1 (707) 359 3400 explore@toraytac-usa.com Toray Advanced Composites Netherlands B.V. G. van der Muelenweg 2 7443 RE Nijverdal, NL Tel: +31 (0)548 633 933 explore@toraytac-europe.com Toray Advanced Composites UK Ltd Amber Drive, Langley Mill Nottingham, NG16 4BE, UK Tel: +44 (0)1773 530899 explore@toraytac-europe.com ©2021 Toray Advanced Composites. All data given is based on representative samples of the materials in question. Since the method and circumstances under which these materials are processed and tested are key to their performance, and Toray Advanced Composites has no assurance of how its customers will use the material, the corporation cannot guarantee these properties. Toray®, (Toray) AmberTool®, (Toray) Cetex®, (Toray) MicroPly™, and all other related characters, logos, and trade names are claims and/or registered trademarks of Toray Industries Inc. and/or its subsidiary companies in one or more countries. Use of trademarks, trade names, and other IP rights of Toray Industries Inc. without prior written approval by such is strictly prohibited. www.toraytac.com TORAY_CompositeSelectorGuide_V2.1_2022-04-19 Guangzhou, China