Paper 1: Multiple Choice 10. Which of the following compounds has/have the empirical formula CH2O? 1. What is the correct formula for zinc sulfate? I. CH3COOH II. C6H12O6 III. C12H22O11 A. C. PbSO4 PbS B. D. ZnS ZnSO4 A. B. C. D. 2. A compound with an empirical formula of N2O3 has a composition of contains 36.8% nitrogen and 63.2% oxygen by mass. If the molar mass of unknown formula is 152g/mol, what is the molecular formula? A. N2O3 C. N3O2 11. Which is a correct definition of the term empirical formula? B. N4O6 D. N6O2 3. What amount of oxygen, O2, (in moles) contains 1.8×10 molecules? A. 0.0030. B. 0.030 C. 0.30 D. 3.0 A. B. 22 C. D. 4. Which compound has the empirical formula with the greatest mass? A. C2H6 B. C4H10 C. C5H10 D. C6H6 5. When the equation above is balanced, what is the coefficient for oxygen? 6. B. 3 D. 5 B. 0.10 C. 20 CH2 C7H10 B. D. C3H4 C9H10 3Cu +_HNO3 → _Cu(NO3)2 +_H2O + _NO What is the coefficient for HNO3 when the equation is balanced? 9. 4 B. 6 C. 8 1 mol of H2SO4 1 mol of CH3COOH 2 mol of H2O2 2 mol of NH3 13. A. B. C. D. Avogadro’s constant has the same value as the number of molecules in 1 mol of solid iodine. atoms in 1 mol of chlorine gas. ions in 1 mol of solid potassium bromide. protons in 1 mol of helium gas. 15. What is the empirical formula of a compound containing 50% by mass of element X (Ar = 20) and 50% by mass of element Y (Ar = 25)? Copper can react with nitric acid as follows. A. A. B. C. D. 14. What is the total number of atoms in 0.20 mol of propanone, CH3COCH3? 22 A. 1.2×10 23 B. 6.0×10 24 C. 1.2×10 24 D. 6.0×10 D. 80 A hydrocarbon contains 90% by mass of carbon. What is its empirical formula? A. C. 8. 4 What amount (in moles) is present in 2.0 g of sodium hydroxide, NaOH? A. 0.050 7. C. formula showing the numbers of atoms present in a compound formula showing the numbers of elements present in a compound formula showing the actual numbers of atoms of each element in a compound formula showing the simplest ratio of numbers of atoms of each element in a compound 12. Which sample has the least number of atoms? __C2H2(g) + __O2(g) → __ CO2(g) + __ H2O(g) A. 2 II only III only I and II only II and III only A. B. C. D. D. 10 XY X3Y2 X4Y5 X5Y4 The percentage by mass of the elements in a compound is C = 72%, H = 12%, O = 16%. What is the mole ratio of C:H in the empirical formula of this compound? A.1 : 1. No. Ans 1 B. 1 : 2. 2 3 C. 1 : 6. 4 D. 6 : 1 5 6 7 8 9 10 11 12 13 14 15 Paper 2 Short Answer Questions Please show your work for full credit. Marks will be taken off for insufficient rationale and/ or show of work. 16. Write the formula, molar mass, and percent composition of each element of copper (II) phosphate. (5) …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… 17. Find out the percentage of water by mass in sodium sulfate decahydrate. (4) . …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… 18. The relative molecular mass of aluminum chloride is 267 and its composition by mass is 20.3% Al and 79.7% chlorine. Determine the empirical and molecular formulas of aluminum chloride. …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… (4) 19. What is the mass of 0.45 mol of potassium phosphate? …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… (3) 20. How many moles of potassium ions are there in 0.45 mol of potassium phosphate? …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… (2) 21. How many carbon atoms are in 0.67 mol of glycerol, C3H5(OH)3? …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… (2) BONUS: (4 points) After combustion with excess oxygen, a 12.501 g of a petroleum compound produced 38.196 g of carbon dioxide and 18.752 of water. A previous analysis determined that the compound does not contain oxygen. Establish the empirical formula of the compound. …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… …………………………………………………………………………………………… Name: ______________________________ Paper 1 Paper 2