The Atom, Atomic Structure & Theories ATOMS • Are the smallest unit of matter that have all the properties of an element. • They composed of smaller subatomic particles as protons, neutrons, and electrons. 66 Atomic Theories Democritus • Greek philosopher proposes the existence of the Atom. All atoms: • Are small hard particles • Are made of a single material formed into different shapes and sizes • Are always moving, and they form different materials by joining together He called them atoma which is Greek for “indivisible”. Atomic Theories Aristotle • He did not think there was a limit to the number of times matter could be divided. • He thought that all substances were built up from only four elements: Earth Fire Water Air Atomic Theories John Dalton • Although the concept of the atom dates back to the ideas of Democritus, the English meteorologist and chemist John Dalton formulated the first modern description of it as the fundamental building block of chemical structures. Solid Sphere Model or Bowling Ball Model Proposed by John Dalton Atomic Theories Dalton’s Atomic Theory 1. All matter is composed of small particles called atoms. 2. Atoms of a given element are identical in size, mass, and other properties; atoms of different elements differ in size, mass, and other properties. 3. Atoms cannot be sub-divided, created or destroyed. 4. Atoms of different elements combine in simple whole number ratios to form a chemical compounds. 5. In chemical reactions atoms are combined separated or rearranged. Atomic Theories Dalton’s Atomic Theory However, Further studies conducted examined each postulate of Dalton’s atomic theory as follows: 1. 2. 3. 4. Atoms of elements today can be destroyed by artificial transmutation called bombardment or nuclear fission. With the existence of Isotopes, the second postulate is only partially accepted. Isotopes are atoms of the same element having the same atomic number but of different atomic masses. Atoms consist of smaller particles such as protons, neutrons and electrons. These particles can be extracted to exist in individual form so that they are called Particles of matter. It is true that they combine to form molecules, but they combine not only in small whole number ratio but also in large whole number ratio such as formation of organic compounds. Atomic Theories Joseph John Thompson English chemist and physicist; discovered 1st subatomic particles. • Atoms contain negatively charged particles called electrons and positively charged matter. • Created a model to describe the atom as a sphere filled with positive matter with negative particles mixed in: Referred to it as the Plum Pudding Model or Raisin Bun Model Atomic Theories Ernest Rutherford New Zealand physicist, who conducted an experiment about the bombardment of gold foil with alpha particles. To account for the results of the experiment, Rutherford proposed the following 1. 2. 3. • Atom consists of a large empty space Atoms consists of very small but massive region, hence, the particles that bounced back were presumed to have hit this region. The Discovery of Nucleus. Those which deflected approached the positive part, hence, there was repulsion since the alpha particles were also positive. Proposed the: Nuclear Model Atomic Theories Neils Bohr Danish physicist who discovered energy levels. Concluded that electrons are located in planet-like orbits around the nucleus in certain energy levels. •Electrons travel around the nucleus in definite paths and fixed distances. •Electrons can jump from one level to a path in another level. Atomic Theories Erwin Shrodinger Austrian physicist; developed the electron cloud model. His Theory: •The exact path of electrons cannot be predicted. •The region referred to as the electron cloud, is an area where electrons can likely be found. Electron Cloud Model Proposed by Erwin Schrodinger Electron Cloud Model Proposed by Erwin Schrodinger Atomic Theories James Chadwick English physicist; who discovered neutrons Neutrons have no electrical charge. Neutrons have a mass nearly equal to the mass of a proton. Unit of measurement for subatomic particles is the atomic mass unit (amu). Subatomic Particle Symbol Mass (g) Mass (u) Charge Proton p+ 1.67252 x 10-24 1.0073 Positive (+) 1.0087 No Charge (0) 0.00055 Negative (-) Neutron Electron nº e- 1.67482 x 10-24 9.109 x 10-28 Atomic Number & Mass Number ATOMIC NUMBER • number of protons in a nucleus • Each element has a characteristic atomic number • The number of electrons equals the atomic number in a neutral atom MASS NUMBER/ ATOMIC MASS • Total number of protons and neutrons in an atom Atomic mass (A) A = protons + neutrons A = Atomic no. (Z) + neutrons Atomic Number (Z) Z = No. of Protons Z = No. of Electron for neutrally charged atoms No. of Neutrons =Mass Number – Atomic number Exercise 1 Complete the following table: Element Atomic No. Mass No. A 17 35 B 108 C D E No. of p+ No. of e- No. of nº 92 146 47 82 125 27 Atomic mass (A) A = protons + neutrons A = Atomic no. (Z) + neutrons No. of Neutrons =Mass Number – Atomic number 14 Atomic Number (Z) Z = No. of Protons Z = No. of Electron for neutrally charged atoms