Workshop Valonia-Bruselas, Casos de Éxito, de la investigación a la innovación y emprendimiento Agua, energía y valorización de residuos 14 de abril 2014 Universidad Católica del Norte Drenaje Electro-ósmotico De la investigación científica a soluciones tecnológicas para la minería Claudio Acuña. Director Departamento Ingeniería Química UCN Líder en Minería Ceitsaza Organizan Desert Water Technology Research Center Developing and transferring technology for a sustainable use of water resources in arid zones www.ceitsaza.cl/ 2 Applications of Electro-osmotic de-watering In dump leaching Patent in progress Funded BHP-Cluster program World class chain of suppliers of technology and Innovation 2012-2013 Prepared by: Claudio Acuña Leonardo Romero Julio Valenzuela December 10th, 2013 3 Topics • • • • • • • Electro-osmotic de-watering since when?. How useful are papers Fine particles an clays Applications in mining Scaling up: To be or not to be Experience in industrial heap leaching How much does it cost? Environment / Economy 4 Electro Osmotic De-watering (EOD) • Phenomenology since 1912 • McGill Papers application on food and tailings • Application in tailings and remediation IN SITU • Solution transport independent of permeability 5 Electro Osmotic De-watering, process EOD and clay base minerals Inovative process in a heterogenous media. Clays and rocks Clays are fine particles (below 38 microns) High capilary presure (water retention) Remediation + solution recovery (water, acid, metals) Limiting factor solid electrical resistance 7 EOD in fine sludge applications sludge 92% fines, 78% humedad K. Reddy, A. Urbanek, A.Khodadoust,2006, Electroosmotic dewatering of dredged sediments, J. of Env. Mng. 78 pp. 200–208 ) 8 Electro-osmotic de-watering, levels EOD application on soils 10 Electro-osmotic de-watering (EOD) Electric field application. Effect of DEO after 3 weeks (Fouri, Johns, Jones. Dewatering of mine tailing using EOD. Can Geotech. 2007. J. 44: 160-172) 11 Origin of the problem in heap leaching dumps • Dump leaching accumulation: acid solution • 10 to 19% humidity: acid and metals (0.8 -15 gpl) • Millions of accumulated of solids: potential percolation Solution occurrence of acid solutions by the road 12 EOD testing and scale up Validation Bench scale (50 mm and 200 mm) 5 kg Configuration design Lab scale ( 20 liters) 50 kg Filed testing Pilot scale ( 1 m3) 1500 kg EOD impact on water drainage 0.16 a 0.52 Reducción de humedad, proyectados 72ho con base SOLO a las 18 horas 14 Pilot scale results Comparison with base line (natural drainage) Configuration (confidential) Humudity difference with base line Time reduction to achieve same humidity Kw-hr/m3 Energy consumption 1-4 1.3 0.32 14.9 2-5 1.4 0.24 32.5 3-4 2.0 0.19 13.5 4-6 2.0 0.25 6.8 Conclusion and future work • Electro-osmotic de-watering can be applied in copper heap leaching reducing drainage time and humidity. • Additional solution can be recovered reducing eventual percolation in final dump with energy consumption from 6 to 15 kW-hr/m3 • The technique can be adapted to different ore types selecting an electrode configuration. 16