Phases of Matter Intro Solid – State of matter with definite shape and definite volume Liquid – State of matter with definite volume, but not definite shape Gas – State of matter with no definite shape and no definite volume Intro Plasma – State of matter in which atoms have been stripped of all of their electrons Plasmas can only occur at very high energies It is estimated that 99% of matter in the universe is plasma Kinetic Theory of Matter All particles of matter are in constant motion There are forces of attraction between all atoms Behavior of Gases Gas particles behave like billiard balls They will continue in a straight line until they hit the side of their container, or another gas particle Air particles move at approximately 1000mph at room temperature Weak force of attraction between particles Behavior of Gases Behavior of Liquids Water also has kinetic energy at room temperature So, why aren’t water molecules flying around and colliding with each other and the walls? Water molecules have much less kinetic energy and much stronger forces of attraction The same is true for all liquids at room temperature Behavior of Liquids Behavior of Liquids Behaviors of Solids Solids have low velocity and strong forces of attraction at room temperature This is what gives them their definite shape and definite volume Behaviors of Solids All Three Phases Phase Changes Freezing – Liquid to Solid Melting – Solid to Liquid Phase Changes Vaporization – Liquid to Gas Condensation – Gas to Liquid Phase Changes Boiling and Evaporation are both types of Vaporization Boiling – When a liquid is heated to its boiling point the atoms at the bottom of the liquid are moving fast enough to overcome the forces of attraction Evaporation – Occurs at temperatures below the boiling point and occurs at the surface of a liquid Phase Changes Phase Changes Sublimation – Solid to Gas Deposition – Gas to Solid Phase Changes Ionization – Gas to Plasma Recombination – Plasma to Gas Phases Changes Plasma Gas Forces of Attraction Kinetic Energy and Temperature Deposition Liquid Sublimation Solid Heating Curves Heating Curve – Graph that shows how much heat it takes a substance to increase in temperature and change phases How we calculate heat q=mcΔT q-heat (Joules or J) m-mass (grams) c-specific heat ΔT-change in temperature (C) Heating Curves Review Problem For this unit we will always use water. 5g of water is heated up from 30°C to 50°C. The specific heat of water is 4.186. How much heat did the water gain? m=5g c=4.186 ΔT=50-30=20°C q=mcΔT q=(5)(4.186)(20)=418.6J Heating Curves When a substance goes through a phase change, the temperature of the substance does not increase until every molecule has changed phases This is what heating curves show us Heating Curves Heating Curves To calculate how much heat a phase change needs we use the latent heat of fusion equation q=mLf Latent heat of fusion for water is 334J/g Remember: you DO NOT need to memorize any equations or constants Heating Curves Practice How much heat would it take to convert 5g of ice into 5g of water? m=5g Lf=334J/g q=mLf q=(5)(334)=1670J Heating Curves Water freezes at 0°C Water vaporizes at 100°C You do need to memorize these, but they’re not hard to remember Heating Curves Practice How much heat does it take to heat 10g of ice from -20°C to 50°C? BREAK THIS PROBLEM INTO 3 STEPS Step 1: How much heat does it take to get 10g of ice from -20°C to 0°C? m=10g c=4.186 ΔT=20°C q=mcΔT q=(10)(4.186)(20) q=837.2J Heating Curves Step 2:How much heat does it take to change 10g of ice into 10g of water? m=10g Lf=334J/g q=mLf q=(10)(334) q=3340J Heating Curves Step 3: How much heat does it take to heat up 10g of water from 0°C to 50°C? m=10g c=4.186 ΔT=50°C q=mcΔT q=(10)(4.186)(50)=2093J Heating Curves Add the heat from each step to get your final answer 837.2J + 3340J + 2093J It takes 6720.2J to heat 10g of ice from -20°C to 50°C Gas Laws Pressure – Result of a Force distributed over an area SI units – Pascals (Pa) Equation – P=F/A Force is measured in Newtons (N) Area is measured in meters squared (m2) Gas Laws Practice A force of 20N is applied to the top of a container that has an area of 2m2. What is the pressure applied to that container? F=20N A=2m2 P=F/A P=20/2=10Pa Gas Laws Gas Pressure – The force exerted by a gas on the walls of its container Factors that affect gas pressure 1)Number of molecules 2)Temperature 3)Volume Gas Laws The more gas molecules in a container, the higher gas pressure there will be You would say that the number of gas molecules in a container is directly related to the gas pressure As the number of molecules increases the gas pressure also increases Gas Laws Changing the volume of a container will also change the gas pressure in a container As you decrease the volume the gas pressure will increase Volume and gas pressure are inversely related As one goes up the other goes down Gas Laws Changing the temperature in a container will change the gas pressure of the container When temperature increases the molecules move faster and collide with the walls of the container more How are temperature and gas pressure related Directly Related As one goes up, the other also goes up Gas Laws Charle’s Law shows the relationship between volume and temperature 𝑉1 𝑉2 = 𝑇1 𝑇2 If the volume of a container increases, the temperature of the container must also increase How are temperature and volume related? Directly Related Gas Laws Boyle’s Law shows the relationship between pressure and volume 𝑃1 𝑉1 = 𝑃2 𝑉2 If the pressure of the container increases, the volume of the container must decrease and vice versa How are pressure and volume related? Inversely Related Gas Laws SI Units Pressure – Pascals (Pa) Volume – Liters (L) Temperature – Kelvin (K) Gas Laws Practice A container of gas initially as a volume of 5L and a pressure of 10Pa. The volume of the container then increases to 10L. What is the final pressure of the container? V1=5L P1=10Pa V2=10L P2=? P1V1=P2V2 (5)(10)=P2(10) 50=P2(10) 5=P2 P2=5Pa Gas Laws Practice A container of gas initially has a volume of 5L and a temperature of 100K. Then, the temperature is increased to 300K. What is the final volume of the gas? V1=5L T1=100K T2=300K V2=? V1/T1=V2/T2 5/100=V2/300 0.05=V2/300 V2=15 V2=15L Gas Laws 𝑉1 𝑉2 = 𝑇1 𝑇2 𝑃1 𝑉1 𝑇1 = 𝑃2 𝑉2 𝑇2 𝑃1 𝑉1 = 𝑃2 𝑉2 Combined Gas Law Gas Laws Practice A container of gas initially has a volume of 10L, a temperature of 150K, and a pressure of 50Pa. Then the volume is increased to 20L and the temperature is increased to 300K. What is the final gas pressure of the container? V1=10L T1=150K P1=50Pa V2=20L T2=300K P2=? 𝑃1 𝑉1 𝑃2 𝑉2 = 𝑇1 𝑇2 50 10 𝑃2 20 = 150 300 3.33 = 0.06𝑃2 𝑃2 = 55.5𝑃𝑎