IEEE ELECTRON DEVICE LETTERS, VOL. 32, NO. 5, MAY 2011 623 AlGaN/GaN High-Electron-Mobility Transistors Fabricated Through a Au-Free Technology Hyung-Seok Lee, Member, IEEE, Dong Seup Lee, and Tomas Palacios, Member, IEEE Abstract—This letter reports undoped AlGaN/GaN highelectron-mobility transistors (HEMTs) fabricated with a Si-CMOS-compatible technology based on Ti/Al/W ohmic and Schottky contacts. The use of ohmic recess is key to reduce the contact resistance of this Au-free metallization below 0.5 Ω · mm. Comparison of HEMTs fabricated on the same wafer with and without ohmic recess shows that the recess provides a tenfold reduction in contact resistance, resulting in a fivefold lower forward voltage drop at IDS = 100 mA/mm. The reported Au-free AlGaN/GaN HEMT fabrication technology provides similar performance (i.e., contact resistance, leakage current, and breakdown voltage) than state-of-the-art Au-based AlGaN/GaN HEMTs and can be used in standard Si fabs without the risk of contamination. Index Terms—GaN, high-electron-mobility transistor (HEMT), ohmic contact, recess etch, 2-D electron gas (2DEG). I. I NTRODUCTION D UE to their combination of low conduction losses and fast switching speed, AlGaN/GaN high-electron-mobility transistors (HEMTs) are attractive for applications in power electronics [1]. In addition to the excellent material properties, GaN-on-Si wafers with a diameter of 6 inches are commercially available, which enables the fabrication of GaN high-voltage transistors in some of the many 6-inch fabs traditionally used for the processing of Si devices [2]. This flexibility is an important consideration for these devices to be able to compete with Si power devices in terms of cost. Conventional metallization in III–V semiconductors is, however, based on Au contacts, which are not allowed in Si fabs due to contamination issues. Therefore, the development of CMOS-compatible metals with a sufficiently low contact resistance (< 0.5 Ω · mm) [3] in GaNbased HEMTs is a key step to enable the processing of these devices in Si fabs. A Ti/Al/XY /Au stack, where XY is a diffusion layer for Au (e.g., Ni, Pd, or Mo), is the most widely used ohmic metal scheme for the fabrication of GaN devices [4]–[6]. A contact resistance (Rc ) below 0.6 Ω · mm is commonly obtained in this metallization [6]. The Au layer is believed to improve the contact resistance by forming Ga vacancies in the semiconductor [5] and by preventing the oxidation of the metal surface. However, long-term Au diffusion has been proposed Manuscript received January 13, 2011; revised February 2, 2011; accepted February 3, 2011. Date of publication March 21, 2011; date of current version April 27, 2011. This work was supported in part by the ARPA-E ADEPT program. The review of this letter was arranged by Editor G. Meneghesso. The authors are with the Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, MA 02139-4307 USA (e-mail: hslee75@mit.edu; dongseup@mit.edu; tpalacios@mit.edu). Color versions of one or more of the figures in this letter are available online at http://ieeexplore.ieee.org. Digital Object Identifier 10.1109/LED.2011.2114322 Fig. 1. (a) Schematic cross section of the fabricated undoped AlGaN/GaN HEMTs with S/D ohmic recess. (b) SEM image of the cross section of a Ti/Al/W contact after annealing. Before metallization, the ohmic contact region was recessed ∼30 nm. as an important degradation mechanism for ohmic contacts [5]. Therefore, in addition to enabling device fabrication in Si fabs, a Au-free metallization scheme would also help to avoid longterm contact degradation. Au-free ohmic contacts can be obtained by intentionally doping the AlGaN/GaN structure [7]. However, a highly doped AlGaN/GaN layer increases the electric field under the gate, degrading both the breakdown voltage and the leakage current [8]. Ion implantation is another approach to get Au-free contacts, although the required high-dose implants and high dopant activation temperatures create defects that can influence the device characteristics [9]. Selective regrowth of the ohmic contacts has also been used to form Au-free contacts by enhancing tunneling of carrier through the highly doped regrown layers [10]. However, the regrowth step significantly increases the fabrication complexity and cost. In this letter, we use recessed ohmic contacts to demonstrate the fabrication of AlGaN/GaN HEMTs with a Au-free Si-compatible technology. A low Rc of 0.49 Ω · mm is obtained, and its influence on the device characteristics is also described. II. E XPERIMENTAL P ROCEDURE Fig. 1(a) shows a simplified cross-sectional view of the fabricated undoped AlGaN/GaN HEMTs. The AlGaN/GaN epilayer was grown by metal-organic chemical vapor deposition on a 4-inch Si (111) wafer and consists of an ∼1.8-μm undoped GaN buffer layer and an ∼17.5-nm Al0.26 Ga0.74 N barrier with an ∼2-nm unintentionally doped GaN cap layer. Mesa isolation was formed by electron cyclotron resonance (ECR) reactive ion etching with a 100-W BCl3 /Cl2 plasma. The region underneath the ohmic contacts was recessed 15 and 30 nm by using ECR etching with an etch rate of ∼1 nm/min and an RF bias of 0741-3106/$26.00 © 2011 IEEE Authorized licensed use limited to: University of Wisconsin. Downloaded on February 01,2022 at 15:51:57 UTC from IEEE Xplore. Restrictions apply. 624 IEEE ELECTRON DEVICE LETTERS, VOL. 32, NO. 5, MAY 2011 Fig. 2. Contact resistance as a function of annealing temperature for Ti/Al/W with different recess depths. The inset shows the I–V characteristics across a 10-μm gap in as-deposited and annealed Ti/Al/W contacts with ∼30-nm recess. ∼75 V [11]. A Veeco Dimension 3100 atomic force microscope was used to measure the etch depth. A Ti/Al/W (600/1000/ 300 Å) metal stack was then deposited by electron beam evaporation. The thin W layer prevents the oxidation of the Al layer. Linear transmission line method (LTLM) structures were fabricated at the same time with the transistor devices. The ohmic metal stack was annealed in a rapid thermal processing chamber at 600 ◦ C–1000 ◦ C in nitrogen ambient. Fig. 1(b) shows a scanning electron microscope (SEM) image of the recessed contact after annealing at 870 ◦ C. To study the effect of the ohmic recess on the source/drain (S/D) contact resistance, a sample was processed with the same metal stack (Ti/Al/W) but without recessed contacts. As a control experiment, an additional sample with conventional ohmic metallization (Ti/Al/Ni/Au metal stack annealed at 870 ◦ C) [11] was fabricated. All samples have nominally the same epitaxial structure and fabrication process, except for the S/D ohmic contact. After the formation of the ohmic contacts, a 3-nm-thick Ga2 O3 gate dielectric was grown by exposing the gate region to an O2 plasma treatment, and then a gate electrode with a Ti/Al/W metal stack was deposited by electron beam evaporation. Finally, the devices were passivated by a 20-nm-thick Al2 O3 dielectric formed by atomic layer deposition [12]. III. M EASUREMENT R ESULTS Fig. 2 shows the Rc of Ti/Al/W metallization as a function of annealing temperature for samples with different ohmic recesses. While the contacts annealed below 700 ◦ C exhibit nonlinear characteristics (see the inset in Fig. 2), a clear ohmic behavior has been obtained for contacts annealed at 800 ◦ C or above. The samples without ohmic recess showed ohmic behavior after a 900 ◦ C anneal, and the lowest Rc in these samples was 2.02 Ω · mm in the contacts annealed at 950 ◦ C for 30 s. The Rc was decreased to 1.71 Ω · mm in the samples with ∼15-nm ohmic recess etch and a 30-s anneal at 870 ◦ C. The lowest Rc (0.49 Ω · mm) was obtained in a fully recessed sample (∼30-nm recess) annealed at 870 ◦ C for 30 s. It should Fig. 3. (a) Total resistance for different ohmic metallizations as a function of contact distance. (b) Optical micrograph images of the surface in (left) Ti/Al/W recessed contacts and (right) standard Ti/Al/Ni/Au contacts. Fig. 4. DC I–V output characteristics of undoped AlGaN/GaN HEMTs with Ti/Al/W contacts ( ) with and ( ) without a 30-nm ohmic recess. As a reference, the I–V characteristics of a standard transistor ( ) with nonrecessed Ti/Al/Ni/Au ohmic metallization are also shown. be noted that, in the ∼30-nm recessed samples, the entire AlGaN barrier, including the 2-D electron gas (2DEG), has been removed underneath the contact region. This indicates that the Ti/Al/W metallization needs to be in direct contact with the 2DEG at the sidewall of the recess region in order to minimize Rc . Also, the formation of a (Ti, Al)N [5] layer after the anneal helps to reduce the energy barrier between the ohmic metal and the 2DEG channel. Fig. 3(a) shows the total resistance versus TLM contact spacing as measured in a sample annealed under optimized conditions. As a reference, a control Authorized licensed use limited to: University of Wisconsin. Downloaded on February 01,2022 at 15:51:57 UTC from IEEE Xplore. Restrictions apply. LEE et al.: AlGaN/GaN HEMTs FABRICATED THROUGH A Au-FREE TECHNOLOGY 625 IV. S UMMARY A Si-compatible fabrication technology for undoped AlGaN/GaN HEMT has been successfully demonstrated using recessed ohmic contacts and gate dielectrics. The optimum annealing temperature for recessed Ti/Al/W ohmic metallization was 870 ◦ C. The recessed contacts had over one order of magnitude lower contact resistivity (∼6.5 × 10−6 Ω · cm2 ) than the nonrecessed contacts (∼8.7 × 10−5 Ω · cm2 ). By comparison with a HEMT with conventional Ti/Al/Ni/Au S/D contacts (∼3.1 × 10−6 Ω · cm2 ), a HEMT with recessed Ti/Al/W contacts showed less than 15% difference in the forward voltage drop at IDS = 100 mA/mm. In addition, the surface morphology of the Ti/Al/W contacts was much smoother. These results enable the fabrication of high-performance GaN power devices in Si fabs without the risk of contaminating the Si wafers, which enables the large-scale production of GaN power electronics. Fig. 5. O FF-state IDS −VDS characteristics of undoped AlGaN/GaN HEMTs with and without ohmic recess. sample with Ti/Al/Ni/Au metallization annealed at 870 ◦ C is also shown. The specific contact resistivities (ρc ) on the recessed and then nonrecessed Ti/Al/W contacts were ∼6.5 × 10−6 Ω · cm2 (Rc ≈ 0.49 Ω · mm) and ∼8.7 × 10−5 Ω · cm2 (Rc ≈ 2.1 Ω · mm), respectively, as measured on LTLM structures. It should be noted, however, that the definition of specific contact resistivity is questionable in the case of sidewall contacts where the metal is in direct contact with the 2DEG channel. The ρc of the control sample (Ti/Al/Ni/Au) was ∼ 3.1 × 10−6 Ω · cm2 (Rc ≈ 0.38 Ω · mm). Fig. 3(b) shows optical micrographs of the surface morphology of Ti/Al/W recessed contacts (left) and conventional Ti/Al/Ni/Au contacts (right). The Ti/Al/W metallization shows a much smoother morphology, which has been attributed to the lack of AlAu4 alloys [4]. The smooth surface of Ti/Al/W contacts is an additional advantage when scaling down device dimensions [14]. The current–voltage characteristics of transistors fabricated with the optimized recessed contacts, nonrecessed contacts, and the control sample are shown in Fig. 4. The measured device had a gate length Lg = 3 μm, gate–source distance Lgs = 1.5 μm, and gate–drain distance Lgd = 1.5 μm. All the devices have a similar threshold voltage of ∼ −2.2 V, gate leakage current of < 10−1 mA/mm, and three-terminal breakdown voltage of ∼87 V (see Fig. 5). The lower contact resistance of the optimized Au-free structure allows much lower voltage drop for the same output current level, a very important characteristic for high-voltage power electronics. For example, the forward voltage drops at IDS = 100 mA/mm are VDS = 0.78 V and VDS = 1.31 V for the recessed and nonrecessed samples, respectively. 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