MEASUREMENT OF MATTER 1 ■ Matter can be measured or described: 1. Qualitatively - a descriptive which reflects the quality of something in size, appearance, value, etc 2. Quantitatively - relating to, measuring, or measured by the quantity of something 2 Units and Dimensions ■ In order to make quantitative observations, measurements are needed. ■ When we measure properties of matter, we must compare it with a known standard. ■ Measurements are therefore expressed with a value and unit. ■ The scientific system of measurement is referred to as the Système Internationale (SI) or the International System of units. – Based on the metric system, – Seven fundamental quantities. 3 Fundamental (Base) SI Quantities Quantity Unit Symbol Mass Kilogram kg Length Metre m Time Second s Temperature Kelvin K Electric current Ampere A Amount of substance Mole mol Luminous intensity Candela cd 4 5 Derived Quantities ■ These are some commonly used units which are combinations of the fundamental (base) quantities. 6 Prefixes in the SI ■ SI units are modified through the use of prefixes when they refer to either smaller or larger quantities. Prefix Symbol Multiple of Base Prefix Symbol Multiple of Base tera T 1012 deci d 10-1 giga G 109 centi c 10-2 mega M 106 milli m 10-3 kilo k 103 micro µ 10-6 hecto h 102 nano n 10-9 deka d 10 pico p 10-12 7 Scientific Notation ■ Used when writing very large or small numbers in a convenient standard form. ■ Express the following quantities in scientific notation: – (a) The diameter of a sodium atom, 0.000 000 000 372 m – (b) The distance from the Earth to the Sun, 150,000,000,000 m 8 Conversions ■ Converting between units is necessary at times. – ___ K = 20°C – 1 kg = ___ g – 10 µg = __ g – 10 µg = __ kg – 1 m3 = __ cm3 – 280 m/s = ___ km/hr 9 10 Significant Figures ■ The number of significant figures for a measurement is the total number of digits recorded. ■ For example: – mass of ball = 54.07 g – 4 significant figures 11 Rules for Determining # of Significant Figures ■ All non-zero digits are significant. ■ Zeros in the middle of a number are always significant. ■ Exact numbers can be considered to have an unlimited number of significant figures. ■ Zeros at the beginning of a number are not significant; they act only to locate the decimal point. – 0.006 61 g has three significant figures. 12 Rules for Determining # of Significant Figures ■ Zeros at the end of a number and after the decimal point are always significant. – These zeros would not be shown unless they were significant. – 55.220 K has five significant figures ■ Zeros at the end of a number and before the decimal point may or may not be significant. E.g. 7500 m – If number is expressed in scientific notation, then every # is significant. 13 Significant Figures in Numerical Calculations ■ When adding or subtracting, the final answer cannot have more decimal places than any of the original numbers. – 15.02 g + 9986.0 g + 3.518 g = 10,004.538 g ■ When multiplying or dividing, the final answer cannot have more significant figures than any of the original numbers. – 14.79 cm x 12.11 cm x 5.05 cm (4 s.f.) (4 s.f.) (3 s.f.) 3 =904 cm (3 s.f.) 14 Precision and Accuracy • Accuracy refers to how close a given measurement is to the true value. • Precision refers to how well a number of independent measurements agree with one another. 15 Accuracy of Measurements ■ 16 Accuracy of Measurements ■ When adding or subtracting measurements, their absolute uncertainties are added. ■ When multiplying or dividing, their relative uncertainties are added. ■ If objects are too small for adequate reading by the instrument, then a large number of the objects can be measured and the reading can be divided by the number of objects. (The AU is also divided by the number of objects.) – E.g. 100 lead beads displaces 14.5 ± 0.5 cm3 of water in a measuring cylinder. – Avg vol of one lead bead = 14.5 /100 ± 0.5/100 cm3 = 0.145 ± 0.005 cm3 17