09/02/2020 Overview Fundamentals of Materials Science and Engineering Course Objective Introduce fundamental concepts in MSE You will learn about: • materials structure • how structure dictates properties • how processing can change structure This course will help you to: • use materials properly • realize new design opportunities with materials Course Information Lecturer: Time: Location: Dr. Maria Natalia R. Dimaano W: 7:00 - 9:00 AM F: 7:00 - 8:00 AM Rm. 210 (W) Rm. 109 (F) Faculty of Engineering, UST Activities: • • • • • • • Present new material/lecture Review lecture concepts Discuss homeworks Quizzes and major examinations Discuss online activities Oral and written reports on materials Field trip to MIRDC, DOST 1 09/02/2020 Course Material Required Text: William, Smith F., Hashemi, Javad, Presuel-Moreno, Francisco, Foundations of Materials Science and Engineering, 6th ed., Mc Graw Hill, Inc., NY. 2019. Optional Material: References cited in course outline and Materials Mentor Quicknotes by ASM International Grading • Your grades will periodically be posted under the Grades link on the course web site. • Discuss anytime conflicts beforehand. Materials are … Engineered structures … not blackboxes Structures ….. has many dimensions Structural Feature Atomic Bonding Dimension [m] < 1010 Missing 1 extra atom 1010 Crystals (ordered atoms) 108 101 Second phase particles 108 104 Crystal texturing > 106 Technology: development and transfer of knowledge and techniques to provide society with its needs and comforts. • To continue to offer what consumers expect and need, designers must keep abreast with NEW MATERIALS DEVELOPMENT Materials Science: a discipline involving investigation of relationships that exist between the structure and properties of materials. Engineering materials: materials whose structures are designed to develop specific properties for a given application. 2 09/02/2020 Materials Engineering: deals with synthesis and use of knowledge (structure, properties, processing and behavior) to develop, prepare, modify and apply materials to specific needs. Materials Science and Engineering: - A major field of study involving generation and application of knowledge relating the composition, structure, and processing of materials to their properties and uses. Structure, Processing and Properties • Properties depend on structure. • Processing can change structure. – Ex. Hardness vs. structure of steel. %Fe3C 6 9 12 3 Brinell Hardness 280 240 Fine 200 pearlite Coarse pearlite 160 120 Spheroidite 80 0 – Ex. Structure vs. cooling rate of steel. 15 800 Hard ness [ BHN ] 0 700 600 martensite 500 400 300 Tempered martensite 200 cementite pearlite 100 0.01 0.1 1 10 100 1000 0.2 0.4 0.6 0.8 1.0 Composition [ wt% C ] Cooling Rate [ C/s ] Why Study Materials? Many applied scientists and engineers will, at one time or another, be exposed to a design problem involving materials. Materials scientists are specialists who are totally involved in the investigation and design of materials 3 09/02/2020 The Materials Selection Process 1. Pick Application Determine required properties Properties : Mechanical, electrical, thermal, magnetic, optical, deteriorative. 2. Properties Identify candidate material/s Material: structure, composition 3. Materials Identify required processing Processing: changes structure and overall shape. Ex. Castings, sintering, vapor deposition, doping, forming, joining, annealing 4. Additional selection criteria Six Different Property Categories • Mechanical Property: relates deformation to an applied load or force • Electrical Property: stimulus is an electric field • Magnetic Property: demonstrates the response of material to the application of a magnetic field • Thermal Property: behavior of solids relative to its heat energy absorbed or given off • Optical Property: stimulus is electromagnetic or light radiation • Corrosive Property: indicates the chemical reactivity of materials Electrical resistivity [ 108-m ] ELECTRICAL • Electrical resistivity of copper 6 Temperature [ F ] -400 -300 -200 -100 0 +100 5 4 3 2 1 0 -250 -200-150-100 -50 0 +50 Temperature [ C ] • Adding impurity atoms to Cu increases resistivity . • Deforming Cu increases resistivity. 4 09/02/2020 THERMAL • Space Shuttle Tiles – Silica fiber insulation offers low heat conduction • Thermal conductivity of copper. 400 Cu-Zn alloy 300 250 200 150 200 100 100 50 0 0 10 20 30 40 Composition [ wt%Zn ] Thermal conductivity [ BTU/ft-F ] Thermal conductivity [ W/m-K ] – It decreases when Zn is added. OPTICAL • Transmittance: – Aluminum oxide may be transparent, translucent, or opaque depending on material structure. Single crystal Polycrystal High porosity Polycrystal Low porosity MAGNETIC • Magnetic storage: • Magnetic permeability Recording medium width Signal in gap write Recording head read vs. composition – Adding 3 atomic % Si makes better Fe a better recording medium! Magnetizaton – Recording medium is magnetized by recording head. Signal out Fe+3%Si Fe Magnetic Field 5 09/02/2020 DETERIORATIVE Crack speed [ m/s ] • Stress and saltwater …. - causes cracks! • Heat treatment: slows crack speed in saltwater as is 108 held at 100C for 1 hr before testing 1010 Increasing load Material: 7150 – T651 Al “alloy” (Zn, Cu, Mg, Zr) MATERIALS CYCLE Extracting raw materials Recycling/disposing of used products and systems Creating bulk materials, components and devices Services of products and systems Manufacturing engineered materials Fabricating products and systems Extraction of Raw Materials • Basic ingredients are obtained from the earth – Chemical elements are the basic bldg. blocks of materials – Synthesis involves transforming gas, liquid and solid elements by chemical and physical means combined to form solid materials • There must be a concern for the by-products of refining and synthesis. 6 09/02/2020 Creating Bulk Materials, Components &Devices • Bulk Materials: products of synthesis, materials extraction, refinement and processing usually made in large quantities processing • Components: gears, electrical wire, screws, nuts, jet engine turbine blades, brackets, levers, etc. • Devices: more complex than components and designed to serve a specific purpose (i.e. resistors, microprocessors, switches, heating elements, etc.) • Product: individual units • Systems: aggregate of products, components and devices Roles of Engineers in Manufacturing • Manufacturing Engineers – select and • • coordinate specific processes and equipment to be used. Design Engineers – design the machines and equipment used in manufacturing, select and specify the materials to be used in order to meet the requirements. Materials Engineers – devote their major efforts toward developing new and better materials for use in commercial products. Materials Scientists – study how the structure of materials relates to their properties Materials Selection • What selection criteria are important to suit the requirements of products needed. • How do designers select to arrive at the best material? • What is an ideal material? In materials selection, COMPROMISE is the rule not the exception. 7 09/02/2020 Characteristics of an Ideal Material • • • • • • • • • endless and readily available source of supply cheap to refine and produce energy efficient strong, stiff, and dimensionally stable at all temperatures lightweight corrosion resistant no harmful effects on the environment or people biodegradable numerous secondary uses Selection Tools and Factors • Availability – material must be available at a • • reasonable cost and in the desired form (if not available in the desired state, the material should be convertible to the desired form). Economics – cost of materials and processing must be considered. Properties – materials performance characteristics Algorithms or Steps: • • • • Selection Tools Properties of materials Materials systems Additional Selection Criteria – – – – – – – existing specifications availability Processibility Near-net-shape production Quality and performance Consumer acceptance Design for assembly 8 09/02/2020 Basic Approaches to Final Materials Selection • minimum investment and high maintenance • high investment and low • maintenance optimum investment and maintenance Reasons why material selection decisions are among the most important the design engineer must make: • The number of materials available is large and constantly increasing. • Domestic and foreign competitions increasingly require product reevaluation. • Service requirements and consumer demands for reliability as well as function have become more severe. • In many cases, the material has a direct relationship to the appearance of the product and its sales appeal. • In many cases, the material dictates what processing must be used in order to manufacture the product. • Because of strict and comprehensive product-liability laws, failure of products can result in very costly litigation and damages. Aids to Materials Selection • A broad basic understanding of the nature, properties and processing of materials. • Tables of properties of engineering materials. Data must be computerized to allow easier access) • Magazines, periodicals, books, journals, compilation of current lists or charts of cost indices and quotations. • Rating charts. 9 09/02/2020 Three materials X, Y, and Z are available for a certain usage. Any material selected must have a good weldability. Tensile strength, stiffness, stability and fatigue strength are required with fatigue strength considered being the most important and stiffness the least important of these factors. The three materials are rated as follows in these factors. Properties Weldability X E Tensile strength Y P Z G G E Fair Stiffness Stability VG G G E G G Fatigue strength Fair G E Which material should be selected? Classification of Materials 1. Metals 2. Ceramics 3. Polymers 4. Composites 5. Electronic-related materials 6. Biomaterials Summary Course Goals • Use the right material for the job. • Understand the relation between properties, structure and processing. • Recognize new design opportunities offered by materials selection. 10