Unit 6: Chemical Equations & Reactions Part 1 Independence HS: Chemistry Chapter 10 Section 10.1 Reactions and Equations • Recognize evidence of chemical change. • Represent chemical reactions with equations. • Balance chemical equations. Chemical reactions are represented by balanced chemical equations. chemical change: a process involving one or more substances changing into a new substance chemical reaction reactant product chemical equation coefficient NGSS Standard: HS-PS1-7: Use mathematical representations to support the claim that atoms, and therefore mass, are conserved during a chemical reaction. Chemical Reactions ➢The process by which one or more substances are rearranged to form different substances is called a chemical reaction ➢Evidence? ➢–Change in temperature ➢–Change in color ➢–Odor, gas, or bubbles may form. • Chemical Equation- A chemical equation is a written representation of the process that occurs during a chemical reaction. • Chemical Equation & Reaction Symbols: a short, easy way to show chemical reactions plus signs separate two or more reactants and also two or more products 4 Fe + 3O2 2Fe2O3 horizontal arrow means the reaction yields or produces something • Chemical Formulas and Names: letters and numbers that represent a molecule Formula: Fe2O3 Name: Iron Oxide • Reactants: the substances in a chemical reaction that change into new substances. They are on the left side of the equation. 4 Fe + 3O2 reactants 2Fe2O3 • Products: the substances that are formed in a chemical reaction. They are on the right side of the equation. 4 Fe + 3O2 2Fe2O3 product • Subscripts: small numbers to the right of the element symbols that give the number of atoms 4 Fe + 3O2 2Fe2O3 • Coefficient: large numbers in front of the element symbols that give the number of molecules 4 Fe + 3O2 2Fe2O3 Chemical Equations reactants products SnO2(s) + 2H2(g) → Sn(s) + 2H2O(g) subscript state of matter coefficient yield sign Chemical Equations ❖ We can express a reaction using words ❖ We can express a reaction using chemical equations Reactants (LEFT) substances that undergo a reaction Products (RIGHT) new substances formed in a reaction Law of Conservation of Mass • You should know THIS, too! • In a chemical reaction, matter is neither created nor destroyed • In other words, the number and type of atoms going INTO a reaction MUST be the same as the number and type of atoms coming OUT • If an equation obeys the Law of Conservation, it is balanced. An Unbalanced Equation • CH4 + O2 🡪 CO2 + H2O Reactant Side Product Side 1 carbon atom 2 hydrogen atoms 3 oxygen atoms 1 carbon atom 4 hydrogen atoms 2 oxygen atoms NOT THE SAME! A Balanced Equation ● CH4 + 2O2 🡪 CO2 + 2H2O Reactant Side Product Side 1 carbon atom 4 hydrogen atoms 4 oxygen atoms 1 carbon atom 4 hydrogen atoms 4 oxygen atoms BOTH ARE EQUAL! Rules of the Game 1. Matter cannot be created or destroyed. 2. Subscripts CANNOT be added, removed, or changed. 3. You can ONLY CHANGE coefficients. 4. Coefficients can only go in front of chemical formulas...NEVER in the middle of a formula. A few extra tips: ⚫Try balancing big formulas first; save the free elements for last ⚫If the same polyatomic ion appears on both sides of the equation, it’s okay to treat it as one unit ⚫There is no one particular way to balance equations. Some equations are harder to balance than others and might require some creativity to solve Balancing Equations ⚫Balance the following equation by adjusting coefficients 🡪 Make a “t” chart to help! N2 + 3 H2 🡪 2NH3 reactants products N 2 21 H 6 2 63 Balancing Equations • Balance the following equation by adjusting coefficients 🡪 Try the “t” chart again! 2 KClO3 🡪 2KCl + 3 O2 reactants products K 1 2 12 Cl 1 2 1 2 O 3 6 2 6 Balancing Equations • Balance the following equation by adjusting coefficients 🡪 Try the “t” chart again! 🡪 THIS IS TOUGH! Fe2O3 + 3 H2SO4 🡪 Fe2(SO4)3 + 3 H2O reactants products Fe 2 2 O 3 3 1 H 6 2 62 SO4 3 1 3 Remember! Balance the larger molecules first… leave the single atoms until last! Balancing Chemical Equations Practice ➢ Write a balanced chemical equation for the following reactions. A) ___ K(s) + ___ H2O(l) → ___ H2(g) + ___ KOH(aq) B) ___ CaCl2(aq) + ___ Na2CO3(aq) → ___ CaCO3(s) + ___ NaCl(aq) C) ___ N2(g) + ___ H2(g) → ___ NH3(g) Balancing Chemical Equations Practice ➢ Write a balanced chemical equation for the following reactions. 2 K(s) + ___ H22O(l) → ___ H2(g) + 1 ___ KOH(aq) A) ___ 2 1 CaCl2(aq) + ___ Na2CO 1 3(aq) → ___ CaCO3(s) + ___ 1 NaCl(aq) B) ___ 2 1 N2(g) + ___ H32(g) → ___ NH3(g) 2 C) ___ Word Equations Translate the following word equation into an chemical equation: Hydrogen chloride in the liquid phase and sodium hydroxide in the solid phase yields aqueous sodium chloride and water Word Equations Hydrogen chloride in the liquid phase and sodium hydroxide in the solid phase yields aqueous sodium chloride and water HCl (l) + NaOH (s) NaCl (aq) + H20 Part 2: Classifying and Predicting Reactions Synthesis Reaction ➢Whenever two or more substances combine to form a single product, the reaction is called a synthesis reaction. Decomposition Reaction ➢Whenever a compound breaks down into two or more simpler substances, the reaction is called a decomposition reaction. 2H2O2(aq) → 2H2O(l) + O2(g) Single-Replacement Reaction ➢Whenever one element takes the place of another, the reaction is called a singledisplacement reaction. Activity Series Li Rb K Ca Na Mg Al Mn Zn Fe Ni Sn Pb H2 Cu Hg Ag Pt Au Most Active • This feature is found on your handy helper. • Use it to determine whether a singledisplacement reaction will occur (react) or not. Least Active Activity Series Li Rb K Ca Na Mg Al Mn Zn Fe Ni Sn Pb H2 Cu Hg Ag Pt Au Most Active Example #1: Is this combination possible? Pb + MgSO4 → PbSO4 + Mg Answer: No, because Mg is more active than Pb Example #2: Is this combination possible? NaNO3 + K → Na + KNO3 Answer: Yes, because K is more active than Na Least Active Double-Replacement Reaction ➢Whenever two ionic compounds trade cations, the reaction is called a double-displacement reaction. ➢One of the products will either be water, a gas, or most commonly a precipitate (insoluble in water). Combustion Reaction ➢ Whenever hydrocarbons combine rapidly with oxygen (usually by fire), the reaction is called a combustion reaction. Classifying Chemical Reactions ➢Reactions are classified into several categories. ➢ Synthesis (direct combination) ➢ Decomposition ➢ Single Replacement ➢ Double Replacement ➢ Combustion A + B → AB AB → A + B A + BC → AC + B AB + CD → AD + CB CxHy + O2 → CO2+ H2O • By recognizing these patterns, you can classify a reaction and make predictions about its products. • Compare these reactions to dancing! Identifying Chemical Reactions ➢ Identify each of the following chemical equations as synthesis, decomposition, single-displacement, doubledisplacement, or combustion reaction. A) B) C) Predicting Chemical Reactions Steps 1. Determine what type of reaction is being presented 2. Write the correct formulas for the product(s) 3. Balance the equation Example: CaCl2 + Al(OH)3 → ? 1. Double-displacement reaction 2. __CaCl2 + __Al(OH)3 → __Ca(OH)2 + __AlCl3 3. 3CaCl2 + 2Al(OH)3 → 3Ca(OH)2 + 2AlCl3 Predicting Chemical Reactions Practice ➢Predict the chemical reaction from combining sodium iodide with strontium hydroxide: 2NaI(aq) + Sr(OH)2(aq) → 2NaOH(aq) + SrI2(s) ➢Predict the chemical reaction from combining magnesium and copper (II) sulfate: Mg(s) + CuSO4(aq) → Cu(s) + MgSO4(aq)