494 Progress of Theoretical Physics, Vol. 42, No. 3, September 1969 Theory of Hall Effect. I --Nearly Free Electron-Hidetoshi FUKUY AMA, Hiromichi EBISA W A and Yasushi W ADA (Received March 5, 1969) A gauge-invariant expression of the Hall conductivity in a weak magnetic field is derived on the basis of the Kubo formula for nearly free electron systems. In order to calculate the correlation functions systematically, diagram techniques have been employed. It is shown that the Hall coefficient is inversely proportional to the square of the density of states at the Fermi energy, which justifies the conjectures of Mott and Ziman in connection with the discussion of liquid metals. § 1. Introduction It is well known that the measurements of Hall effects are effective to know the electronic properties of solids or liquids. For example the concept of impurity conduction has been introduced by the temperature dependence of the Hall coefficient. 1l Recently, careful measurements have been performed. Greenfield2l measured the Hall coefficients of several liquid metals and found that some of them have some deviations from the free-electron value. Alderson, Farrell and Hurd 3 l determined the temperature dependences of the coefficients for solid Cu, Ag and Au. Their data showed a new behavior at low temperatures. The absolute magnitudes of the coefficients had an apparent maximum as a function of temperature. The Hall effect in antiferromagneti c chromium has 4 been observed by Amitin and Kovalevskaya. l The coefficient has a characteristic temperature dependence. In order to understand these results the effects of many-body interactions or random array of atoms should be taken into account in each case. T'he purposes of the present series of papers are to develop a formalism in which such effects can be systematically investigated and to apply the discussion to a few typical examples. A Hall effect is observed because the paths of charged particles are being bent in a magnetic field due to the Lorentz force. Let us take the direction of a uniform current with the density Jx as the x-axis. Suppose a uniform magnetic field Hz is applied perpendicularly along the z-axis. One measures the induced electromotive force along the y-axis, that is, the electric field Ey, suppressing the current in the same direction. The Hall coefficient R is then defined by R=Ey/HzJc. Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 DejJartnzent of Physics, University of Tokyo, Tokyo Theory of Hall Effect. I 495 When the magnetic field 1s weak enough, R is given by 5> (1·1) rJ f'V 1s the conductivity tensor which satisfies the relation Jf' = .z= (J f'VEv • v diagonal so far. 6> transport with the magnetic Here v is the velocity of the carriers. The fields are assumed to be weak and the relaxation time is introduced in order to consider the effect of collision term in an approximate way. The induced current Jx is thus determined and the Hall coefficient has turned out to be R= 1/nqc, (1·2) . where n is the number density of the carriers. This result is remarkable at the · following two points. First it directly tells us the nature of the carriers, since it has the same sign as their electric charge q. Furthermore we can easily find their density n. Although the carriers are usually electrons, we can sometimes discuss the conduction processes in some solids introducing the concept of "holes" with positive charge. Thus the sign of the Hall coefiicient indicates which of the two types of carriers is more effective in the processes. In these arguments, the energy of each carrier is assumed to have a definite relationship with its momentum. In other words, the system is well represented by an assembly of quasiparticles. When the interactions become essential, the above assumptions may no longer hold and we may expect a modification to the simple formula for the Hall coefficient (I· 2). Let us refer to two typical examples to which the simple theory is not applicable. One is the impurity conduction processes. The other is the cases where many-body correlations are important. In order to discuss these cases quantitatively, we consider how the quantum mechanical density matrix varies owing to the weak electric and magnetic fields. The density matrix may be developed in a power series of these fields. When the magnetic field is uniform, the vector potential becomes large in the regions far from the relevant area. Therefore it is necessary to take into account carefully the contributions from these regions. It is rather a clumsy procedure. Kubo7) Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 We shall confine our discussion in this limit of the weak field. The elements of the tensor r5.11 x and rJ YY have been extensively discussed Therefore, our main concern is in the off-diagonal element (J xy· The simple theory for the Hall effect makes use of the Boltzmann equation. 5> The velocity distribution in a system of charge carriers electric charge q is modified by the force F due to the electric and fields, E and I-I, 496 H. Fukuyama, H. Ebisawa and Y. W ada Using these results, we take the limit of long wave length for the vector potential in the expression for the off-diagonal clement of the conductivity tensor r5xy· Finally, the frequency of the oscillating electric field is set to be zero. The Hall coefficient R turns out to be modified from the expression (1· 2) by the square of a ratio between the unrenormalized and renormalized density of states at the Fermi energy. This renormalization is not the same with the mass renormalization in the electronic specific heat. 15 ) The latter comes from the energy dependence of the self-energy part whereas the former comes from the momentum dependence. This result agrees with one of Ziman's conjectures 16 ) Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 pointed out a possibility to circumvent this problem by using the technique of Wigner representations for the density matrix and the dynamical variables. His result is characteristic in classifying the contributions to the "classical" terms and the "quantum-mechanical" corrections. However, this classification turns out to be not very convenient to discuss the correlation effects. 8l Meanwhile Evans 9l and Springer10 ) investigated the Hall effect in a system with a static perturbing potential. Their treatments depend strongly on the choice of the gauge of vector potential, and the systematic treatment of the correlation effects looks rather difficult. In our formulation we first assume for the vector potential to have a form of a plane wave in order to avoid unphysical contributions from distant regions. An expression for the current density is given by the linear response theory when the uniform electric field is weak enough. The electric field is first assumed to oscillate with a frequency w. That is the so-called Kubo formula. 11 l This expression is expanded as a power series of the magnetic field and we keep only the linear term. The obtained result is rewritten in terms of the thermal Green functions and the vertex parts. In this article we shall consider a simple case, that is, a system composed of nearly free electrons. The effects of the lattice periodicity will be neglected. We know the electron self-energy parts fairly well for some particular cases. For instance, in discussing the residual resistances, it is considered that the impurity potential is of short range and that the electron mean free path is long in comparison with the Fermi wave length. 6l Then the electron self-energy part is obtained by the self-consistent treatments of the second order self-energy part. The same conclusion holds for the electron-phonon system because of the large difference betvveen electron velocity at the Fermi level and the velocity of sound. 12 ) Ziman's 13 ) treatment of liquid metals leads to the same situation. Therefore, it is quite worthwhile investigating these simple cases first. Since the vector potential can have an arbitrary gauge, our discussions have to be performed in a gauge-invariant way. This condition requires that the approximations for the current vertex part have to be consistent with those for the self-energy part. 14l It is easy to find the consistent approximations for the vertex parts. Theory of Hall Effect. I 497 for the Hall effect in liquid metals. The possibility that the Hall coefficient should depend on the density of state has been pointed out by Mott. 17> In § 2 the general expression for (J xy will be derived. It is estimated in the static limit and the Hall coefficient R is given in § 3. Some discussions will be given in § 4. § 2. Hall conductivity A (r) = Aqeiqr (2 ·1) Is given by 11 > where and (J)A-=2n'AT (A: integer, T: temperature). Tin the bracket is the time-ordering operator. The operator fu(k) is defined by where (2 ·2) and (2 ·3) The time evolution and the thermal average are determined by the Hamiltonian 1 /'. !}{II= .!J( - - c J ( - q) Aq . (2·4) Equation (2 · 4) is sufficient as we are concerned with a magnetic field only up to the linear order and H in this equation denotes all the energy operators m the absence of a magnetic field. Expanding the expression for (J p,v in terms of Aq, we have the following formula for off-diagonal component (!1 = x, v = y): (2. 5) where Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 The conductivity tensor in the presence of a vector potential H. Fukuyama, H. Ebisawa and Y. liVada 498 2 f{fi~(q, w) =--r:_--o"aCLfo(q, w+io) -Lfo(q, O+io)) me + l_(Lfi~(q, w+io) -Lfi~(q, O+io)), (2·6) c r~dr i' dr' exp [iw).. (r- r')] <T Jfo (q, r) p(- q, r')) , 8 Lfo (q, iw)..) = _l_ (3 iw)..) = l_ (3 (2 · 7) Jo 1;3dr s(3 d r' ~~ dr" exp [iw).. (r- r'")] Jo o Jo (2 ·8) Hereafter the thermal average and time evolution of the operators are defined by the Hamiltonian !J(. Equations (2 · 6), (2 · 7) and (2 · 8) are exact but we can calculate these correlation function, LP and ~LJI~, only approximately making use of a particular nature of the system. The self-consistency of such approximations for L,J, and Lfi~ is necessary to ensure the gauge invariance of the results which we now discuss. For the case of nearly free electron system it is convenient to take the plane wave function as the basis. We introduce a one-particle thermal Green function as g (p, 8n) = X ---~-- {3V s drdr' r~dr r~dr' exp [ -ip (r- r') + ien(r -r') J Jo Jo <T exp [ (!J(- pi\!) (r- r') J¢ (r) exp [ (!J(- 11N) (r'- r) J¢t (r')) , where Bn = (2n + 1) nT, J1 is the chemical potential and N the total number of electrons. A self-consistent treatment of a second order perturbation diagram for the self-energy of the one-particle Green function gives*) (2·9) and the Green function turns out to be g (p, 8n) =[iBn- E p -1,' (p, 8n) ]- 1, where Bv = p2/2m- Jl. To be specific we discuss explicitly the case of scattering by a static potential. Then V(p-p',8n-8n') =V(p-p')On,n'. (2 ·10) The arguments are, however, applicable to the cases of dynamical interactions, too. Equations (2 · 9) and (2 ·10) lead, through gauge iuvariance arguments, to the ladder correction for the vertex function of the current operator: 14 ) *) agator. In the case of electron-phonon interaction, V(p- p', En -En') is essentially the phonon propIn the case of static potential it is in second order of the perturbing potential. Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 Lfi~ (q, Jo 499 Theory of Hall Effect. I X J( p I+ ,en; p 1- , en- ) f? ( ::d p 1- , Cn- ) , (2 ·11) where XJa ( p - , Sn- ; p + , Bn- ) acp 5d +, en- )Jv ( p + , en- ; p + , en) (2 ·12) which are shown in Fig. 3. It can be proved that the gauge invariance is not broken for a finite q (Appendix A). However, as we are concerned with a uniform magnetic field, we first expand the contributions in Fig. 3 in terms of q and ~(P-P~) Z(P,cnl= ~ P', En Fig. 1. Self-energy diagram for one-particle propagator. A line with p' and En is il(p', En). 1 c = ·#;~),+· ,_ ~ lAp'+ P,cn.Q ,en Fig. 2. Integral equation for current vertex function,Jf'(p+, En; p-, En-). A dot with epfbi m is a bare matrix element of current operator. Fig. 3. • En.~P' p-~t'n J. (J-c J"' " n . Contributions to K~v (q, iwA.). Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 Equations (2 · 9), (2 ·10) and (2 ·11) are shown graphically In Figs. 1 and 2. Under the present approximation, contributions to KfJ.~' Eq. (2 · 6), can be given in the form 500 H. Fukuyama, H. Ebisawa and Y. W ada 2 -21 · me -e · q. '.! (a l (b) Fig. 4. Contributions from the expansion of propagators of the first diagram in Fig. 3. In the remammg half of this section, we represent graphically the procedures to obtain such an expression, while an analytic derivation is given in detail in Appendix B. First, we consider the contributions coming from the expansion of the momentum arguments of one-particle propagators. Those from L11~ just cancel out (Appendix C) and there remain those from L"' which are shown in Fis. 4. The line of propagator with a cross X p means (8 j8kP) g (k, en) =8 Pg (k, en), and the small circle OJ"' denotes the vertex function with q = 0 in Eq. (2 ·11), (2 ·13) Next we evaluate the contributions from the q-linear term of the current vertex functions. One of them, which couples with the magnetic field, Jcn satisfies Eq. (2 ·11) with W>... = 0. In this case, it has the symmetry under the interchange between p+ and p-, so that Ja (p-, en; p+, en) = Ja (p, en)+ 0 (q 2) ' (2 ·14) and moreover we can write (2 ·15) The identity (2 ·15) is discussed in Appendix A. electric field, Jv, can be expanded as The vertex coupled with the (2 ·16) We consider the quantity J/ defined by J"'(p+, en;p-, en_) =J"'(p, em (J)A.) +J/, (2 ·17) which satisfies an integral equation derived by the expansion of Eq. (2 ·11) in terms of q, and is shown in Fig. 5, where J/ is represented by a square o. By Eqs. (2 ·15), (2 ·16) and (2 ·17) the total contributions to K11~ are shown in Fig. 6. In this figure, the current vertex with a cross X p means (8/8kp) J(k, em(!)>...). The diagrams (d) and (e) in Fig. 6 can be rewritten as in Figs. 7 and 8 respectively in virtue of the integral equation for J/. The contributions Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 retain only the linear term. In this case the gauge invariance can be ascertained if we get the following q-dependence of K11~, 501 Theory of Hall Effect. I of (a) in Fig. 4, (h) m Fig. 7 and (k) in Fig. 8. are gathered together to be (I) in Fig. 9. Here Eq. (2 ·11) with q = 0 and the relation e2 me' OJ; Integral equation for + g. [ 8110(. J~. a(j oa + (e) (d) (c) e +-· 2C qp·l oa j a(j fJX j)X J'/1 ( 9) (f ) Fig. 6. J Expansion of current vertices of the triangular diagrams in Fig. 3. = (d) :c . ~- [ i!f :0] +!!_ c Jv (h) atJ (j ) ( i) Fig. 7. (e l 2~ • qf' ·[ (j: -p() ] Jv ( k) (l) Fig. 8. + e c e: (m) Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 Fig. 5. H. Fukuyama, H. Ebisawa and Y. vVada 502 (I) = e 2C qp . [ 8a (~ V(p- p') _q (p', en) p' X x Jv Jv (p', em W;..) g (p', en_)) (2 ·18) are used. Similarly from (b), (i) and (1) and from (c), (j) and (m) we obtain (2) and (3) in Fig. 9 respectively. Diagrams (o), (q) and (s), as a whole, cancel with (r) under the relation of Fig. 5 and we now have only four; (f), (g), (n) and (p). From the symmetry of the isotropic system qP·oP can be expressed as (2} e 2C .qp·[-? a Xa ( n} (o) + Jl) Xa ~ (q) a 0 . [ qp·op=o"aqp,op,+op,aq"o", Jv so that the sum of the diagrams (f) and (p) yields the desired gauge-invariant result. It is also the case for (g) and (n). Finally we obtain, q, J Xa (P} (31 J Xa Xa ( r) (S} j Fig. 9. 111 the limit of small wave number (2 ·19) where g=g(p, en), g (-) = g (p, en_), and each Oa operates only on the function next to this symbol. We have neglected any effects of electron spin except a multiplicity factor 2 in Eq. (2 ·19). In an isotropic system, J is proportional to (e/ m) p, so that it takes a form (2. 20) Using this expressiOn for J, we obtain Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 ~ ~y (j ?0 503 Theory of Hall Effect. I 2 ____, "L....J X2 ( p, ZSm • • ) P.'lJ e 7 , ,L....J rJ xy (W) -_ -WeZW"A w n m p (2. 21) § 3. Explicit evaluations As far as we are concerned with a static response of a weakly perturbed electron system which is in normal state, the electromagnetic properties of a metal are characterized by the behavior of quasiparticles near the Fermi surface. For such a system, the perturbational approach can be used, and the results of the preceding section are applicable. The diagonal element of the conductivity tensor rJ.7Jx IS giVen by 2 P . ) -- - 2 e 2'T" . ZSn. ) :dC( p, Sn)g( p, Sn- ) . (/) xx ( tw"A L....J "''.X L....J ---2-X ( p, ZSm n p m (3 ·1) Equations (2 · 21) and (3 ·1) determine the Hall coefficient within the framework of the present approximation. Representing the summands in Eqs. (2 · 21) and (3 ·1) by 9! (isn, isn_) we. perform n-summation over all integers by transforming it into an integral along the contour C in Fig. 10. 18 ) (3·2) c where f(z) Fig. 10. Contours of integration in z-plane. Crosses are on iEn = i (2n + 1) reT. = [e.Sz + 1]-I, (3. 3) and F(z) is a function of a complex argument z defined by the analytic continuation from F(isn). As the Green function G (p, z) has a cut along Imz = 0 and the vertex correction X (z, z- iw"A) has cuts where the imaginary part of each energy argument is zero, 18 ) the singularities of 9! (z, z- iuh) are located along Im z = 0 and Im z = w"A. The contour C is transformed to Cr + C 2 + C 3 + C4 along these cuts as is shown in Fig. 10, though C 1 + C 4 give a negligibly small contribution in the present case. For Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 where we= lellljmc is a cyclotron frequency. Although Eq. (2·21) is derived in the case of static perturbing potential, this is a quite general expression as far as the second order perturbation diagrams are self-consistently treated. H. Fukuyama, H. Ebisawa and Y. W ada 504 C2 + Cs we make suitable transformations for integral variables and perform the analytic continuation, iw>- ~w + io, then the RHS of Eq. (3 · 2) turns out to be - ~ Joo dxf(x) [F(x + io, 2nz x- w- io) - F(x + w + io, x- io)]. (3·4) -oo Confining ourselves to the static response, we need only w-linear term in the bracket of Eq. (3 · 4), and a partial integration leads to (3· 5) Some words should be added about this result: Not only the diagonal but also off-diagonal components of the conductivity tensor have the main contribution from the regions near the Fermi energy. The diagonal part is dissipative and, correspondingly, it can easily be verified from Eq. (3 ·1) that it has a factor - df/ dx in any case even if the contribution from the path cl + c4 is included. But the off-diagonal one is dispersive and then the expression for oxv has a factor f(x) if we consider C1 + C4. This is the characteristics of the effect of the magnetic field. The contributions from the terms that include f(x) come from the deviation of the distribution function of the system by the influence of the magnetic field. Thus, in the degenerate case the static conductivity tensor 1s g1ven by Oxy=Wc~ ~ 2m P PxX 2 (p) {GR(p, O)axGA(p, 0) -axGR(p, O)GA(p, 0)}, m (3·7) where GR and GA are retarded and advanced Green functions respectively (e.g. GR(p, ien) =g (p, en)' en>O)' GR(p, x) = [x-sp-l'' (p, x) +il'" (p, x)]- 1 • (3·8) Here 2' and .I;" are real and imaginary parts of the self-energy function respectively (l'">O). X (p) is defined by (3·9) If 2" is much smaller than the chemical potential, the Green function may be considered as a function of Lorentzian type regarding cp or x. Expanding .I;' (p, x) in terms of cp and x and neglecting the cp and x dependence of .I:", we obtain (3 ·10) where (3 ·11) Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 - iw JC<J dx(- df(x)_)FCx+io, x-io). 2rr -oo dx Theory of Hall Effect. I 505 (3 ·12) and Po is the Fermi momentum. EP is a solution of The velocity v (p) is defined by dEp/dp and N(O) = _ _!__ TC ~ Im GR(p, 0) =N(O)b, (3 ·13) P where N(O) is the density of states at the Fermi energy of a free electron system. Inserting Eq. (3 ·10) into Eqs. (3 · 6) and (3 · 7) and considering that the function X de_r:;ends weakly on the momentum variable, we obtain (3 ·14) (3 ·15) where n is the number density of electrons n = p 0 3 /3rc 2 • The transport relaxation time !"tr is X(Po) /21:", which coincides with the usual definition. The reason why b does not appear in (J xy is that the current vertex Ja coupled with a magnetic field has a character different from other vertices, so that it is expressed, owing to a "generalized Ward's identity" ,1 4> as a derivative of the Green function with respect to momentum variable. Then we get the Hall coefficient in nearly free electron systems as R- (jxy _ Hz(J;:x- 1 (N(0)) nee Nco) 2 (3 ·16) The mass renormalization, which is important for an electronic specific heat, appear neither in (J xx 19> nor in (J xy, so that if the self-energy does not have a momentum dependence as in the case of electron-phonon interactions, we obtain the same results for (J xJ; and rJ xy (and also R) as those given by the Boltzmann transport equation. The momentum dependence of self-energy, however, affects only (J xx, so that the Hall coefficient is inversely proportional to the square of the density of states N(O) at the Fermi energy. Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 The quantities a and b are energy renormalization factors reflecting the energyand momentum-dependent interactions between electrons or electrons and external systems. For example the electron-phonon interactions enhance the electronic specific heat at low temperatures by a factor a- 1 • 15 > On the other hand b is the renormalization factor of the density of states in the sense that 506 H. Fukuyama, I-I. Ebisawa and Y. lVada § 4. Conclusion Acknowledgements The authors wish to express their hearty thanks to Professor R. Kubo for some useful advice. Thanks are also due to Mr. K. Kawamura for helpful discussions and to other colleagues. Comments by Professor M. Tanaka are gratefully acknowledged. The authors thank to Professor T. Matsubara for sending a manuscript prior to publication. Appendix A The gauge invariance is required by the fact that Jf' should not vary by the gauge transformation of the vector potential as (A·1) What we are to show 1s that KfJ.~ in the present approximation satisfies Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 We have derived an expression for the off-diagonal component of the conductivity tensor as Eq. (2 · 21) in the presence of a magnetic field to its linear order by use of the Green function. The derivation has been performed for the free electron system with weak perturbations. The explicit calculation shows that even in such cases the Hall coefficient differs from the value given by the Boltzmann transport theory, when the interactions are momentum-dependent. The present result, Eq. (3 ·16), applies to the liquid metals if we follow Ziman. 16 ) In liquid metals this dependence of the self-energy function on the momentum variable comes from that of both the pseudopotential and the structure factor. Ziman has argued that the Hall coefficient should depend on the density of states, and that some evidences exist as regards this point. Liquid mercury shows the free electron value for the Hall coefficient in spite of the fact that other properties indicate a strong modification in the density of states. 20 ) This may mean that Ziman's approach might not be sufficient for Hg and that the current vertex part might be varied from ep/m. On the other hand, the experiments on the Knight shife 1) and on the Hall coefficiene 2) of liquid Hg-In alloys can consistently be interpreted, if we are allowed to treat these as nearly free electron systems. The qualitative feature that R is larger in the system with smaller density of states at the Fermi energy is manifested in liquid semiconductors, too. 23 ) Matsubara and Kaneyoshi 24) discussed the Hall effect in impurity conduction processes under the tight-binding approximation. They obtained a result different from ours. It is due to the different definition of density of states. The temperature dependence of R in the noble metals cannot be understood within the present discussions. However, it looks fairly straightforward to take into account the possible effects of phonon drags along the line developed in this work. 507 Theory of Hall Effect. I ~ K11~qa=O, (A·2) a=.J;,y,z so that the results are gauge-invariant. We no\v treat this problem similarly as the arguments of gauge invariance in the many-body theory of superconductivity by Nambu/ 4) and first introduce a "generalized Ward's identity" (GWI) in the special case of zero external frequency (A·3) From (A·3) we obtain which leads immediately to the identity (~ ·15). Using the GWI, (A· 3), we obtain from Fig. 3 where abbreviations J"'(p) and Jv(p+) represent J"(p+, en;p-, en_) and Jv(p+, en-; p+, en). Substituting Eq. (2 ·11) for Jv (p+, en-; p+, en) into the second term of (A· 5), we obtain !!__y~ ~ Jl'(p)fl(p+, en) r~fYv++ L: V(p-p')fl(p'+, en)Jv(p'+) np C p' 111- (A·7) and into the first term of (A· 6), - _!!__ T C ~ ~ J" (p) _q (p+, n en) [_!!__ Pv- + ~ V (p- p') f) (p'-, en) Jv (p'-) P 111- P' X fJ (p'-, J en_) fJ (p-, en_) . (A· 8) The first terms of (A· 7) and (A· 8) are cancelled by (A· 4), because e + e _ e -p - - p =-q. m m m (A·9) By the similar procedures, the first term of (A· 5) and the second of (A· 6) lead to Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 which IS valid for Eqs. (2·9)and (2·11) with (J)~=O. in the limit q->0 H. Fukuyama, H. Ebisawa and Y. W ada 508 X g (p+, en) J" (p+) g (p+, en_) +£TL: ~[£p'"'+ L: V(p-p')g(p'-, c np?n (A ·10) en_)J'"'(p')Q(p'+, en)] p' (A ·11) Appendix B The procedures of deriving Eq. (2 ·19) from Eq. (2 ·12) are as follows. First the contributions coming from the expansion of propagators is given by 1 e2 - --O"aT~ 2 ?nc n ~ qp ~{f)pg(p, en)J#(p, em {J)")g(p, en_) p (a) p as is shown in Fig. 4. Those from the q-linear term of matrix elements of current operator, J/, are (c) and (d) (e) The expansion of current vertex J" yields J/ satisfies the following integral equation, Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 We can see that the second terms of (A ·10) and (A ·11) cancel with the second terms of (A· 7) and (A· 8) respectively, and that the first terms of (A ·10) and (A ·11) together lead to the one which vanishes by the isotropy of the system. Thus all the terms vanish. Theory of Hall Effect. I 509 (B·l) which is shown in Fig. 5. 2:: V (p- p') g (p', en) J/ g (p', en_) } , p' (j) and (e) can be written as follows, (m) The sum of the diagrams (h) and (k) includes Oa [Q (p, Cn-) J" (jJ, em W>c) g (p, en) J - g (p, en_) OaJ" (p, em W>c) g (p, en). Partial integration over p and the equation transform the sum of the contribution (a), (h) and (k) as follows: Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 X By this equation, the term (d) can be rewritten as H. Fuhuyama, H. Ebisawa and Y. 1Vada 510 Similarly, from (b), (i) and (1) and from (c), (j) and (m) we get _l_ !!_____ C T ~ ~ qP ~ g n P (p, en) J'" (p, en, ()),J aPg (p, en_) aaJv (p, em uh) (p) P and (r) (s) respectively. The expressions from (n) to (s) are sho,vn in Fig. 9. Among these contributions, (o), (q), (s) cancel with (r) as is easily verified by use of Eq. (B ·1). Remaining four terms (£), (g), (n) and (p), gives the final expression, Eq. (2·19). Appendix C We show here that we have no q-linear contribution to L11~ from the expansion of the Green functions in Fig. 3. There are apparently three pairs of contributions. (1) Expanding g (p+, en) of the second and g (p-, en_) of the third diagrams in Fig. 3 and using (2 ·14), we obtain the contribution as shown in Fig. 11, which turns out to vanish by the symmetry of the isotropic system. (2) Expansion of the remaining two Green functions in the second diagram jn Fig. 3 just cancel out. (3) Similarly we obtain no contribution from the two Green function of the last diagram in Fig. 3. 2~. qp" [ aVp _pOaJ Jll Fig. 11. Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 2 Theory of 1-Iall Effect. I 511 References l) 2) 3) 4) 7) 8) 9) 10) 11) 12) 13) 14) 15) 16) 17) 18) 19) 20) 21) 22) 23) 24) Downloaded from https://academic.oup.com/ptp/article/42/3/494/1942624 by guest on 30 November 2021 5) 6) G. Busch and H. Labhart, Helv. Phys. Acta 19 (1946), 463. C. S. Hung and ]. R. Gliessman, Phys. Rev. 79 (1950), 726. H. Fritzche, ]. Phys. Chern. Solids 6 (1959), 69. A. J. Greenfield, Phys. l{ev. 135 (1964), A1589. 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