Stoichiometry - deals with mole, mass and volume relationships in chemical reactions Limiting reactant - controls the amount of product formed There is no more at the end of the reaction From the balanced equation, we can predict the amount of product if given the amount of reactant From the balanced equation, we can predict the amount of reactant needed if given the desired amount of product Mole Ratio – will help convert moles of one compound in a balanced chemical equation into moles of another compound. Example: Reaction between magnesium and oxygen to form magnesium oxide. ( fireworks) 2 Mg + O2 2 MgO Mole Ratios: 2 mole : 1 mole : 2 mole Stoichiometry is used in chemical engineering in order to understand/predict chemical reactions. Production of items include: soap, tires, fertilizer, gasoline, deodorant, and chocolate bars Real-life applications in chemical engineering as well as research Therefore, stoichiometry is one of the most important and fundamental topics in chemistry. Write the balanced equation Determine which is the starting chemical (A) and which is chemical we want to end up with (B) Use coefficients of balanced equation to convert moles of chemical A to moles of chemical B ▪ Mole ratio! How many moles of water can be obtained from the reaction of 4 moles of O2? 2 H2 + 4 mol O2 1 x 1 O2 → 2 mol H2O 1 mol O2 2 H2O = 8 mol H2O Mole Ratio In order to produce 15 moles of water, how many moles of oxygen must be reacted? 2 H 2 + 1 O2 → 2 H 2O Allows you to calculate the mass of product produced or the mass of reactant needed. Write the balanced equation Determine which is the starting chemical (A) and which is chemical we want to end up with (B) Steps : Convert gA to molA ▪ Use Molar Mass (GFW = Gram Formula Weight) Convert molA to molB ▪ Use stoichiometry rules Convert molB to gB ▪ Use Molar Mass (GFW = Gram Formula Weight) Moles of “A” Grams of “A” Mole Ratio Moles of “B” Grams of “B” How many grams of SnF2 can be produced from the reaction of 30.00 g of HF with Sn? Sn + 2 HF → SnF2 + H2 30.00 g HF 1 mole HF 1 x 20.01 g HF x 1 molSnF2 2 mol HF x 156.71 g SnF2 1 mol SnF2 Ratio =Mole 117.5 g SnF2GFWSnF2 GFWAnswer HF The combustion of a sample of butane, C4H10 (lighter fluid), produced 2.46 grams of water. 2 C4H10 + 13 O2 -------> 8 CO2 + 10 H2O How many grams of butane were used? Iodine chloride, ICl, can be made by the following reaction between iodine, I2, potassium iodate, KIO3, and hydrochloric acid. 2 I2 + KIO3 + 6 HCl -> 5 ICl + KCl + 3 H2O Calculate how many grams of iodine are needed to prepare 10.3 grams of ICl by this reaction.