Science 10 Science – Grade 10 Quarter 4 – Self-Learning Module 15: Chemical Reactions and Its Equations First Edition, 2020 Republic Act 8293, Section 176 states that no copyright shall subsist in any work of the Government of the Philippines. However, prior approval of the government agency or office wherein the work is created shall be necessary for exploitation of such work for profit. Such agency or office may, among other things, impose as a condition the payment of royalties. Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand names, trademarks, etc.) included in this module are owned by their respective copyright holders. Every effort has been exerted to locate and seek permission to use these materials from their respective copyright owners. The publisher and authors do not represent nor claim ownership over them. Published by the Department of Education - Schools Division of Pasig City Development Team of the Self-Learning Module Writer: Jefrey M. Nual Editor: Jeric N. Estaco Reviewers (Content / Language): Liza A Alvarez Illustrator: Layout Artist: Jean Rean M. Laurente Management Team: Ma. Evalou Concepcion A. Agustin OIC-Schools Division Superintendent Carolina T. Rivera OIC-Assistant Schools Division Superintendent Manuel A. Laguerta, EdD OIC-Chief, Curriculum Implementation Division Education Program Supervisors Librada L. Agon EdD (EPP/TLE/TVL/TVE) Liza A. Alvarez (Science/STEM/SSP) Bernard R. Balitao (AP/HUMSS) Joselito E. Calios (English/SPFL/GAS) Norlyn D. Conde EdD (MAPEH/SPA/SPS/HOPE/A&D/Sports) Wilma Q. Del Rosario (LRMS/ADM) Ma. Teresita E. Herrera EdD (Filipino/GAS/Piling Larang) Perlita M. Ignacio PhD (EsP) Dulce O. Santos PhD (Kindergarten/MTB-MLE) Teresita P. Tagulao EdD (Mathematics/ABM) Printed in the Philippines by Department of Education – Schools Division of Pasig City Science 10 Quarter 4 Self-Learning Module 15 Chemical Reactions and Its Equations Introductory Message For the Facilitator: Welcome to the Science 10 Self-Learning Module on Chemical Reactions and Its Equations This Self-Learning Module was collaboratively designed, developed and reviewed by educators from the Schools Division Office of Pasig City headed by its Officer-in-Charge Schools Division Superintendent, Ma. Evalou Concepcion A. Agustin, in partnership with the City Government of Pasig through its mayor, Honorable Victor Ma. Regis N. Sotto. The writers utilized the standards set by the K to 12 Curriculum using the Most Essential Learning Competencies (MELC) in developing this instructional resource. This learning material hopes to engage the learners in guided and independent learning activities at their own pace and time. Further, this also aims to help learners acquire the needed 21st century skills especially the 5 Cs, namely: Communication, Collaboration, Creativity, Critical Thinking, and Character while taking into consideration their needs and circumstances. In addition to the material in the main text, you will also see this box in the body of the module: Notes to the Teacher This contains helpful tips or strategies that will help you in guiding the learners. As a facilitator you are expected to orient the learners on how to use this module. You also need to keep track of the learners' progress while allowing them to manage their own learning. Moreover, you are expected to encourage and assist the learners as they do the tasks included in the module. For the Learner: Welcome to the Science 10 Self-Learning Module on Chemical reactions and Its Equations! This module was designed to provide you with fun and meaningful opportunities for guided and independent learning at your own pace and time. You will be enabled to process the contents of the learning material while being an active learner. This module has the following parts and corresponding icons: Expectations - This points to the set of knowledge and skills that you will learn after completing the module. Pretest - This measures your prior knowledge about the lesson at hand. Recap - This part of the module provides a review of concepts and skills that you already know about a previous lesson. Lesson - This section discusses the topic in the module. Activities - This is a set of activities that you need to perform. Wrap-Up - This section summarizes the concepts and application of the lesson. Valuing - This part integrates a desirable moral value in the lesson. Posttest - These measures how much you have learned from the entire module. EXPECTATIONS This module is conceptualized for you to gain knowledge and understanding on chemical reactions and its corresponding chemical equations. This will lead you to a better grasp on how chemical reactions produce new products and how the law of mass conservation is being represented in a balanced equation. After going through this self-learning module, you are expected to: 1. classify the chemical reactions as: a) decomposition reaction b) single replacement reaction c) double replacement reaction; 2. Predict for the product of decomposition reaction, single replacement reaction, and double replacement reaction; 3. Write the balanced chemical equation to represent the chemical reaction; 4. Cite at least one (1) observable situation for each type of chemical reaction. PRETEST Read and write the letter of the correct answer. 1. Which of the following hypothetical equations represents a decomposition reaction? A. A + B AB B. AB A + B C. AB + C AC + B D. AB + CD AD + CB 2. Mely used hydrochloric acid to remove rust stain on the white tiles. The brownish stain is composed of iron (III) oxide. What chemical equation best represents the chemical reaction? A. 6HCl (aq) + 2Fe (s) 2FeCl3 (s) + 3H2 (g) B. HCl (ℓ) + Fe(s) FeClO (aq) + H2 (g) C. 6HCl(aq) + Fe2O3 (s) 2FeCl3 (aq) + 3H2O (l) D. H2SO4 (aq) + Fe2O3 (s) FeSO4 (aq) + H2O (l) 3. What kind of chemical reaction took place when Mely cleaned the tiles? A. combination reaction B. decomposition reaction C. singe replacement reaction D. double replacement reaction 4. In performing a laboratory procedure, Kenneth put the small pieces of zinc metals in sulfuric acid solution. He observed production of gas in the form of bubbles. Predict what kind of gas is produced due to the chemical reaction. A. carbon dioxide B. hydrogen C. oxygen D. sulfur dioxide 5. Baking soda or sodium bicarbonate (NaHCO3) is mainly used for baking; it is added to the mixture to make the cake fluffy since when the baking soda is heated it releases gas. Predict the products of the decomposition of baking soda. A. sodium carbonate, water, and carbon dioxide B. sodium carbonate and carbon dioxide C. sodium oxide, water, carbon dioxide D. sodium oxide and water RECAP In the previous Self-Learning Modules, you learned about the Law of Conservation of Mass and the types of chemical reaction. Before you start studying this module, answer this lesson pass. Lesson Pass 3 Things I learned from the previous self-learning modules. 2 Things I found interesting. 1 Question I still have in mind. LESSON Chemical reactions have a wide impact in our daily lives. These reactions are needed to produce new products that we need. Therefore, it is vital to understand chemical reactions to our advantage. There are different kinds of chemical reaction. The reactions we are going to discuss in this module are: a) decomposition reaction; b) single replacement reaction; and c) double replacement reaction. Let us first have the decomposition reaction. When a compound decomposes, it means it will be broken down into simpler substance. This reaction happens in the presence of heat, electricity, or catalyst. Let’s look closer on the types of decomposition reaction. A. Metal Oxide – in this type of decomposition, the product will be metal and oxygen gas. Example 2 Na2O Sodium Oxide ∆ 4Na + O2(g) Sodium Oxygen gas B. Metal Carbonate – the product will be metal oxide and carbon dioxide gas. Example ∆ CaCO3 Calcium carbonate CaO + Calcium oxide CO2(g) Carbon dioxide C. Metal Bicarbonate – the product will be metal oxide, water, and carbon dioxide Example ∆ 2 LiHCO3 Lithium bicarbonate Li2O + Lithium oxide CO2(g) + H2O Carbon dioxide Water D. Metal Chlorate – the product will be metal chloride and oxygen gas. Example ∆ Mg(ClO3)2 MgCl2 + Magnesium Chlorate Magnesium chloride 3O2(g) Oxygen gas E. Metal Nitrate – the product will be metal oxide, nitrogen dioxide gas and oxygen gas. Example ∆ 2 Al(NO3)3 Aluminum nitrate Al2O3 + Aluminum oxide 3NO2(g) + Nitrogen dioxide F. Base – the product will be metal oxide and water Example ∆ Pb(OH)4 Lead(IV) hydroxide PbO2 + Lead(IV) oxide H2O Water G. Acid – the product will be non-metal oxide and water Example HSO4 Sulfuric acid ∆ SO3 + Sulfur trioxide H2O Water 4.5O2(g) Oxygen gas Another type of chemical reaction is single replacement/displacement. In this type of reaction, an ion or an atom in a compound is replaced by a more reactive ion or atom of another element. Single displacement can be represented by this formula: AB + C CA + B or AB + C AC + B In the first formula atom B and C are both metal while in the second formula atom B and C are both non-metals. When single replacement occurs, the product will always be aqueous solution and pure element at the bottom. Most displacement reactions fit into one of the three types: hydrogen displacement, metal displacement and halogen displacement. Hydrogen Displacement – All alkali metal and alkaline earth metals which are the most reactive of the metallic elements, will displace hydrogen from cold water. Example: Na(s) + Sodium Ca(s) H2O(ℓ) NaOH(aq) + Sodium hydroxide Water + Sodium H2O(ℓ) Water Ca(OH)2(aq) + Calcium hydroxide H2(g) Hydrogen gas H2(g) Hydrogen gas Some of the less reactive elements can be react to the steam to produces hydrogen gas. These elements are Magnesium (Mg), Aluminum (Al), Zinc (Zn), Chromium (Cr), Iron (Fe), and Cadmium (Cd). In this reaction it will produce metal oxide and hydrogen gas. Example: Cd + Cadmium H 2O Water CdO + H 2(g) Cadmium oxide Hydrogen gas There are element that is not reactive to water but it can displaced the Hydrogen in the acid. Example: Ni Nickel + HCl Hydrochloric acid NiCl 2 + Nickel chloride H2(g) Hydrogen gas Metal Displacement – In this type of displacement, the metal in a compound can be displaced by another more reactive metal. To predict wether the reaction can be actually occur or not is to refer in the activity series of metal. Activity series is a covenient summary of the result of many possible displacement reactions. In this series, any metal above hydrogen will displace it from water or from an acid but metals below hydrogen will not reacts with either water or an acid. Example: 3FeO + 2Al Iron(II) oxide Aluminum Al2O3 + Aluminum oxide 3Fe Iron Halogen Displacement – A non-metal in a compound can be displaced by another reactive non-metal. Halogens are the atoms in the VII A family namely Fluorine (F 2), Chlorine (Cl2), Bromine (Br2) and Iodine (I2). The activity series of non-metal is: F2 > Cl2 Br2 > > I2 This activity series shows that Fluorine is the most reactive non-metal while Iodine is the least non-metal element. It means that Fluorine can displace all the other halogens while Iodine can be displaced by all non-metals. And last type of chemical reaction is Double Replacement/Displacement. In this reaction, the two positive ions (cations) in the compound found in the reactant will exchange places to form two new compounds. Typically, after in this reaction, the product is precipitate. The general formula in this reaction is: AB + CD Example: AgNO3 Silver nitrate AD + + NaCl Sodium chloride CB AgCl + Silver chloride NaNO3 Sodium nitrate ACTIVITIES Activity 1: Describing Chemical Equations Direction: Classify the following balanced chemical equations according to the types of chemical reactions. Write your answer to the blank provided before the item number. A – Decomposition B – Single Replacement C – Double Replacement _____ 1. NaOH + KNO3 NaNO3 + KOH _____ 2. CH4 + 2O2 CO2 + 2H2O _____ 3. Fe + 3NaBr FeBr3 + 3Na _____ 4. CaSO4 + Mg(OH)2 Ca(OH)2 + MgSO4 _____ 5. NH4OH + HBr _____ 6. 2NaNO3 _____ 7. 2KClO3 _____ 8. H2SO4 + Na H2O + NH4Br 2NaNO2 + O2 2KCl + 3O2 NaSO4 + H2 _____ 9. 2NaHCO3 Na2O + H2O + 2CO2 _____ 10. 2Al(OH)3 Al2O3 + 3H2O Activity 2: Predicting Products of Chemical Reaction Direction: Predict the product of the following chemical reaction and balance them. 1. ____ Na2CO3 + ____ H2O 2. ____ Mg(HCO3)2 3. ____ Ca(NO3)2 + ____ H2O 4. ____ Au2S3 + ____ H2 5. ____ KOH + ____H3PO4 6. ____ Ca(ClO3)2 7. ____ Zn(OH)2 + ____ K 8. ____ H2CO3 + ____ Ca(NO3)2 9. ____ F2 + ____ HI 10. ____Fe(OH)3 Activity 3: Writing Balance Equation Directions: Read carefully the following worded chemical reaction. Write the chemical equation. Classify the following reactions whether: A – Decomposition B – Single Replacement C – Double Replacement _____ 1. Solid iron (Fe) reacts with solid cadmium nitrate (Cd(NO3)2) to produce solid ferric nitrate (Fe(NO3)3) and cadmium (Cd). _____ 2. Solid Manganese (II) carbonate (MnCO3) decomposes to solid manganese oxide (MnO) and carbon dioxide (CO2) gas. _____ 3. Solid Silver (I)chlorate (AgClO3) decomposes to solid silver (I) chloride (AgCl) and release of oxygen (O2) gas. _____ 4. Magnesium (Mg) ribbon is added to liquid carbonic acid (H2CO3) yielding solid magnesium carbonate (MgCO3) and hydrogen (H2) gas. ____ 5. Aqueous aluminum nitrate (Al(NO3)3) reacts with aqueous magnesium sulfide (MgS) to produce aqueous magnesium nitrate (Mg(NO3)2) and solid aluminum sulfide(Al2S3). WRAP-UP Modified TRUE OR FALSE Direction: Write TRUE if the statement is correct and write FALSE if the statement is incorrect, then correct the underlined word to make the statement correct. _____ 1. AB + C CB + A is the general formula for single displacement. _____ 2. Single displacement is the type of reaction where the compound will be broken to simple substance. _____ 3. The ions will be exchange places to form new substance is called double displacement. _____ 4. Alkali metals are the most reactive metals. _____ 5. Precipitate is always the product of single displacement. VALUING Law of conservation of mass states that matter cannot either be created or destroyed. This law was discovered by Antoine Laurent Lavoisier in 1789. The number of atoms on the reactants should be equal to the number of atoms in the product. With this, we need to balance the chemical equation. In balancing the chemical equation, just add coefficient before the compound. In life, we should also balance all the factors that may affect our daily lives. Time management is the main problem that needs to be taken into consideration. Many times, our workload becomes stressful. This is the time that we should know how to manage our time properly to have a balance life. First, we need to take good care of our body. Enough sleep, exercise and eat healthy food such as vegetable and fruits are very essential to maintain healthy body. Having healthy body will allow us to accomplish our task and to function our mind properly. Second, we need to set our priorities. List all the things we need to accomplish in a day or in a week, then, categorize them as very urgent, urgent and less priority. Third, plan. Make a to-do list. Strictly follow your list. You do not have to cram because you already set your goal. Fourth, expect the unexpected. There are times that things did not happen the way we expect. Do not stress yourself to things beyond your control. Lastly, have a positive mindset. The moment you wake up, after praying, tell yourself that you are going to make the best and the most of it. Remember, once you have done everything you can within your control, let your life unfold. Be prepared for the future, but do not worry about it. POSTTEST Read and write the letter of the correct answer. 1. Calcium oxide is used as a drying agent. Potassium oxide formed, when potassium introduced to it. What type of reaction is this? A. single replacement B. combination C. combustion D. double replacement 2. If an iron nail is placed into an aqueous solution of copper (II) sulfate solution, the iron displaces the copper ions in solution, and a copper metal forms on the nail. Which is the correct word equation for this reaction? A. iron + copper (II) sulfate iron copper + sulfate B. iron + copper (II) sulfate copper (II) iron + sulfate C. iron + copper (II) sulfate copper + iron (IV) sulfate D. iron + copper (II) sulfate copper (II) + iron sulfate 3. Liquid bleaches, containing sodium hypochlorite, are often sold in opaque, plastic containers, because sunlight causes the compound to decompose to produce oxygen gas and sodium chloride. Which is the correct formula equation for this equation? A. NaClO O + NaCl B. NaClO O2 + NaCl C. NaClO2 O + NaCl D. NaClO2 O2 + NaCl 4. What are the products in the equation below? Zn + CuSO4 A. Zn and Cu C. ZnSO4 and Cu B. Zn and CuSO4 D. Zn only 5. Which of the following is the correct balanced equation? A. C3H8 + 5O2 3CO2 + 4H2O B. C3H8 + O2 3CO2 + 2H2O C. 2C3H8 + 10O2 6CO2 + 8H2O D. C3H8 + O2 CO2 + H2O KEY TO CORRECTION ACTIVITY NO. 1 1. C 6. A ACTIVITY NO. 2 3. B 8. B 2. B 7. A 3. D 2. D POST TEST 1. A 3. C 2. D PRE-TEST 1. B 4. C 9. A 4. C 4. B 5. C 10. A 5. A 5. A 1. 2. 3. 4. 5. True False – decomposition True True True WRAP – UP ACTIVITY NO. 3 References ▪ Book 1.R. Chang. (8th Edition 2005). Chemistry. McGraw – Hill Education (Asia). 1221 Avenue of the Americas, New York. Page 126 2.E. Madriaga et. al. (Revised Edition 2017). The Particle Nature of Matter. Science Links 8. Rex Book Store Science and Technology Series. 856 Nicanor Reyes Sr. St., Sampaloc, Manila. Page 235 3. P. Campo et. al. (Reprint Edition 2016). The Particle Nature of Matter. Science Learner’s Module. DepEd-BLR. Meralco Avenue, Pasig City. Pages 171-173 ▪ Online Sources Single Replacement Reaction 1. https://www.khanacademy.org/science/ap-chemistry/chemical-reactionsap/types-of-chemical-reactions-ap/a/single-replacement-reactions .Accessed as of February 22, 2021.