minsung kim 2021-09-13 9/30p I. MULTIPLE CHOICE: Tick the box of the letter of your correct choice. 1. What is the molar mass, in gmol−1, of a compound if 0.200mol of the compound has a mass of 13.2g? a. 66.0 b. 66 c. 26.4 d. 26 Correct answer. 0/1p Molar Mass = mass/mole = 13.2 g/0.200 mol = 66.0 g/mol = 66.0 gmol-1 Note: 13.2 = 3 sf, 0.200 = 3 sf Rule: When dividing or multiplying numbers, the number of sf should equal to the least sf of the two numbers 2. What is the number of carbon atoms in 12g of ethanoic acid CH3COOH, Molar Mass=60? a. 0.20 b. 2.0 c. 1.2×10^23 d. 2.4×10^23 Correct answer. 1/1p Moles ethanoic acid = 12 g / 60 g/mol = 0.20 mol Note: 1 molecule of CH3COOH = 2 molecules of C 1 mole CH3COOH = 2 mol CH3COOH Moles of Carbon = (0.20 mol ethanoic acid) x 2 mol C/1 mol ethanoic acid = 0.40 mol C Number C atoms = 0.40 mol x 6.022 x 1023 = 2.4088 x 1023 = 2.4 x 1023 3. Which is correct? a. Mixtures are either homogeneous or heterogeneous and their chemical properties are an average of the individual component properties. b. Mixtures are never heterogeneous and their chemical properties are an average of the individual component properties. c. Mixtures are either homogeneous or heterogeneous and the components retain their individual chemical properties. d. Mixtures are never homogeneous and the components retain their individual 1/7 chemical properties. Correct answer. Answer: C because mixtures can be either homo or heterogeneous but without changing the chemical properties of the individual components Mixture = Asol + Bliq + Cliq (heterogeneous) Mixture = Dliq + Fliq (Homogeneous) 0/1p 4. What is the sum of the coefficients when the equation is balanced with whole numbers? 1 MnO2 (s) + 4 HCl (aq) → 1 MnCl2 (aq) + 2 H2O (l) + 1 Cl2 (g) a. 6 b. 7 c. 8 d. 9 Sum of coefficients = 1 + 4 + 1 + 2 + 1 = 9 5. Which formula is correct? a. NH4PO4 b. (NH4)2PO4 c. (NH4)3PO4 d. (NH4)3(PO4)2 Correct answer. NH41+ Ammonium Cation (positively charged ion) 1/1p PO43Phosphate Anion (negatively charged ion) + The -3 becomes the coefficient of NH4 and +1 becomes the coefficient of PO4 (NH4)3(PO4)1 = (NH4)3PO4 2/7 Example: Aluminum Sulfate Al3+ + SO42- Al2(SO4)3 6. Which diagram represents a heterogeneous mixture? A. B. C. D. Heterogeneous Mixture = have at least 2 different components AND at least 2 different phases (solid, liquid, gas) 3/7 Example: liquid water with ice = 1 component, 2 phases (liquid and solid) = heterogeneous Example: liquid water = 1 component, 1 phase = homogenous 7. Which is not true about sublimation? I. It is an Endothermic process II. A new product is formed III. Kinetic energy of particles is increasing a. I only b. II only c. I and III only d. I, II and III Example. Dry Ice (solid carbon dioxide) gas (carbon dioxide) (sublimation) Sublimation is a physical change, no new product is formed 8. The deposition of gaseous water particles can be represented by which equation? a. H2O(l) ---> H2O(s) b. H2O(l) ---> H2O(g) c. H2O(g) ---> H2O(s) d. H2O(s) ---> H2O(s) Deposition = opposite of sublimation = gas to solid, physical change 9. Which contains the greatest number of moles of oxygen atoms? a. 0.05 mol Mg(NO3)2 b. 0.05 mol C6H4(NO2)2 c. 0.1 mol H2O d. 0.1 mol NO2 0.05 x 6 = 0.3 mol O (answer) 0.05 x 4 = 0.2 mol O 0.1 x 1 = 0.1 mol O 0.1 x 2 = 0.2 mol O 10. What is the sum of the integer coefficients when propene undergoes complete combustion? 2 C3H6 (g) + 9 O2 (g) → 6 CO2 (g) + 6 H2O (l) Hydrocarbon Oxygen (combustion Reaction) a. 11 b. 17 c. 21 d. 23 4/7 Correct answer. 2C3H6 + 9O2 → 6CO2 + 6H2O Sum of coefficients = 2 + 9 + 6 + 6 = 23 1/1p 11. Which changes of state are exothermic processes? I. condensation II. freezing III. deposition a. I and II only b. II and III only c. I and III only d. I, II, and III 12. What is the formula of magnesium nitride? a. MgN b. Mg2N3 c. Mg3N d. Mg3N2 5/7 From the table above, Magnesium is Mg2+ and Nitride is N3Mg2+ + N3- Mg3N2 13. Which is not a pure substance? a. NaCl(aq) aq = aqueous (mixed with water) b. H2O(l) c. C4H10(l) d. Cl2(g) 14. What is the sum of the coefficients when the following equation is balanced using the smallest whole numbers? 1 C6H12O6 (aq) → 2 C2H5OH (aq) + 2 CO2 (g) a. 4 b. 5 c. 9 d. 10 15. Which statements about mixtures are correct? I. The components may be elements or compounds. True II. All components must be in the same phase. False because Heterogenous Mixtures can have different phases III. The components retain their individual properties. True 6/7 a. I and II only b. I and III only c. II and III only d. I, II and III II. SHORT ANSWERS: Use only the space provided for your answers. 16. State the balanced equation (including state symbols) for the following reactions. a. The addition of aqueous hydrochloric acid (HCl) to solid calcium carbonate to give aqueous calcium chloride, carbon dioxide and water. 2HCl (aq) + CaCO3 (s) = CaCl2 (aq) + H2O (l) + CO2 (g) b. The reaction between ammonia gas and oxygen gas to give nitrogen(II) oxide gas and water. 2NH3 (g) + 5/2O2 (g) = 2NO (g) + 3H2O (l) Multiplying the chemical equation by a factor of 2 (where 2 is the denominator of the coefficient of O2), 4NH3 (g) + 5O2 (g) = 4NO (g) + 6H2O (l) Note: nitrogen (II) oxide means nitrogen(II) ion forms a compound with oxide ion, that is, N2+ + O2- N2O2 NO 7/7 17. Stearic acid is a waxy solid and a useful type of saturated fatty acids that comes from many animal and vegetable fats and oils. The diagram below shows the cooling curve of stearic acid. Melting 70 oC Point Phase Change Solid i. Determine the melting point of stearic acid. The melting point of stearic acid is about 70 oC ii. Explain why the temperature remains constant between B and C. The temperature remains constant between B and C because it takes longer time for the solid stearic acid to be completely melted. Moreover, melting is an endothermic process meaning energy is absorbed to but this amount of energy is used up during the phase change and not to increase the temperature of the stearic acid. The phase change stops until such time that all solid stearic acid is converted completely into its liquid state. 18. Methane, (CH4) is a colourless, odourless gas that occurs abundantly in nature and as a product of certain human activities. Deduce the: i. total number of atoms in one molecule of methane. In 1 molecule of methane, there are 1 C atom and 4 H atoms so there are a total of 5 atoms. ii. total number of atoms in one mole of methane. Calculate the number of methane molecules molecules 6.022 1023 molecules mole Calculate the number of atoms. Using the result in part (i) above, there are 5 atoms in a molecule of methane, 5 atoms 6.022 1023 molecules 30.11 1023 atoms 3.011 1024 atoms molecule 1 mole 6.022 1023 8/7 iii. amount in moles of 1.605 g of methane. Calculate the molar mass of methane CH4. Molar Mass (1)(12.01) (4)(1.01) 16.05 g mol Calculate the moles of 1.605 g CH4 Moles 1.605 g 1 g 16.05 mol 0.1000 mol Remarks: Mole to Mass (g): Multiply the given moles by molar mass Mass (g) to Mole: Divide the given mass (g) by the molar mass iv. write the complete and balanced equation for the incomplete combustion of methane. Incomplete combustion (where there is not enough oxygen present) can lead to the formation of carbon or carbon monoxide. With little oxygen CH4 + O2 = C + 2H2O With some oxygen 2CH4 + 3O2 = 2CO + 4H2O Note that there is not only one equation for incomplete combustion, whereas there can only be one equation for complete combustion. Complete Combustion CH4 + 2O2 = CO2 + 2H2O 19. List 3 laboratory safety measures you need to observe when measuring volume of acid using a graduated cylinder. 1. Wear laboratory gown, goggles or face shield, and latex gloves (personal protective equipment or PPE) to avoid direct contact in case of accidental spill. 2. If the acid is from a big container, transfer a sufficient amount into a beaker first before transferring into the graduated cylinder. This way accidental spillage can be prevented 3. Some concentrated acids emit fumes so transferring to graduated cylinder should be done 9/7 inside a fume hood. Fume Hood 4. In case the graduated cylinder breaks causing spillage of the acid, the acid should be neutralized using a base solution (such as caustic solution) to convert the acid to salt and water (which relatively safer than the acid). Then use rag to wipe the spillage and the broken glass can be swept using broom and pan. 20. A student needs to measure 4.00g of CaCO3 (calcium carbonate). However, the substance inside the bottle are in big lumps (granules) of solids. Name 2 apparatus (laboratory instrument) the student will need to be able to correctly measure the mass of CaCO3. First, the student needs to pulverize or grind the CaCO3 lumps into powder using a clean mortar and pestle. Then place a weighing paper on an analytical balance or a top-load balance whose smallest scale is 0.01 g. Using a laboratory spatula or spoon, measure 4.00 g of the CaCO3 powder. Apparatus/Instrument: 1. Mortar and pestle 2. Analytical balance or top-loading balance 10/ 7 Top loading balance Readability 1 g Example 1 g 2 g 3 g Readability 0.1 g 2.1 g 4.5 g 10.5g Readability 0.01 g 4.00g 5.05 g 6.14g 11/ 7