Section 2.1 2.1 Classifying Matter 1 FOCUS Objectives 2.1.1 2.1.2 2.1.3 2.1.4 2.1.5 2.1.6 Classify pure substances as elements or compounds. Describe the characteristics of an element and the symbols used to identify elements. Describe the characteristics of a compound. Distinguish pure substances from mixtures. Classify mixtures as heterogeneous or homogeneous. Classify mixtures as solutions, suspensions, or colloids. Key Concepts Why are elements and compounds classified as pure substances? How do mixtures differ from pure substances? What is the main difference among solutions, suspensions, and colloids? Vocabulary ◆ ◆ ◆ ◆ ◆ ◆ ◆ ◆ ◆ pure substance element atom compound heterogeneous mixture homogeneous mixture solution suspension colloid Reading Strategy Summarizing Copy the diagram below. As you read, complete the classification of matter. Matter a. ? Element Mixture b. ? c. ? d. ? E ach piece of clothing sold has a care label, which lists recommended cleaning methods for the clothing. For a sweater, the instructions might say to machine wash the sweater using a gentle cycle, and then tumble dry at a low temperature. They might say to hand wash the sweater in cold water and lay the sweater flat to dry. The label might even say, “Dry clean only.” Why is it necessary to put care instructions on a label? The same cleaning method will not work for all materials. For example, a shirt made from 100 percent cotton may need to be ironed after washing. But a shirt made from a cotton and polyester blend may come out of the dryer wrinkle free. A wool jacket often needs to be dry cleaned because wool can shrink when washed in water. The tendency to wrinkle when washed is a property of cotton. The tendency not to wrinkle when washed is a property of polyester. The tendency to shrink when washed is a property of wool. Cotton, wool, and polyester have different properties because they have different compositions. The word composition comes from a Latin word meaning “a putting together,” or the combining of parts into a whole. Based on their compositions, materials can be divided into pure substances and mixtures. Reading Focus Build Vocabulary L2 Paraphrasing To help students understand the definitions of vocabulary terms, you may replace less familiar words in a definition with a more familiar word or phrase. For example, you can replace distributed in the definition of a homogeneous mixture with “spread out,” or shattering in the definition of malleability with “breaking into pieces.” Reading Strategy L2 a. Substance b. Compound c. and d. Homogeneous mixture or heterogeneous mixture 2 INSTRUCT Figure 1 You can use the care labels on clothing to sort laundry into batches for cleaning. The care label shown is for a wool sweater that needs to be dry cleaned or washed by hand. L2 Some students may associate the term material exclusively with solids because they can see and hold solid materials. They may have difficulty recognizing that liquids and gases are also matter. Challenge this misconception by pointing to the Materials list for the lab on p. 60 and asking students to identify the liquids. Verbal 38 Chapter 2 38 Chapter 2 Section Resources Print • Guided Reading and Study Workbook With Math Support, Section 2.1 • Transparencies, Chapter Pretest and Section 2.1 Technology • iText, Section 2.1 • Presentation Pro CD-ROM, Chapter Pretest and Section 2.1 • Go Online, NSTA SciLinks, Mixtures Pure Substances Pure Substances FYI Matter that always has exactly the same composition is classified as a pure substance, or simply a substance. Table salt and table sugar are two examples of pure substances. Every pinch of salt tastes equally salty. Every spoonful of sugar tastes equally sweet. Every sample of a given substance has the same properties because a substance has a fixed, uniform composition. Substances can be classified into two categories—elements and compounds. Samples of pure substances almost always contain impurities, some that are unintentional, some intentional. For example, table salt is not pure sodium chloride. It contains between 0.006% and 0.01% potassium iodide. Elements Elements Although there are millions of known substances, there are only about 100 elements. An element is a substance that cannot be broken down into simpler substances. Imagine cutting a copper wire into smaller and smaller pieces. Eventually you would end up with extremely tiny particles called copper atoms. An atom is the smallest particle of an element. An element has a fixed composition because it contains only one type of atom. No two elements contain the same type of atom. In Chapter 4, you will find out more about atoms, including how the atoms of one element differ from the atoms of every other element. Figure 2 Aluminum, carbon, and gold are elements that you can see in common objects, such as cans, pencils, and rings. Mixtures containing iodine are used to prevent and treat infections. Analyzing Data Which of these elements has a symbol that is not related to its name in English? FYI Sometimes an atom is defined as “the smallest particle of an element that has the properties of the element.” However, an atom of copper has none of the properties associated with bulk copper, such as malleability, ductility, or density. Build Science Skills Examples of Elements At room temperature (20°C, or 68°F), most elements are solids, including the elements aluminum and carbon. You have seen aluminum foil used to wrap food. Most soft drink cans are made from aluminum. Carbon is the main element in the marks you make with a pencil on a piece of paper. Some elements are gases at room temperature. The elements oxygen and nitrogen are the main gases in the air you breathe. Only two elements are liquids at room temperature, bromine and mercury, both of which are extremely poisonous. Figure 2 shows four elements and their symbols. Iodine (I) L2 Observing Have students look at the elements in Figure 2. Ask, What are some characteristics of the elements in Figure 2? (Gold is yellow and shiny. Aluminum is gray and shiny. Carbon is dull and black. Iodine is a dark purple solid.) Follow up on their observations by asking students to hypothesize about why the iodine sample is in a closed container. (At room temperature, iodine evaporates and forms a purple gas, which is visible in the container. The gas is poisonous.) Visual Aluminum (Al) Gold (Au) Carbon (C) Properties of Matter 39 Customize for English Language Learners Sharing Experiences Encourage multilingual students to describe what a particular element is called in their native language. This exercise will be most useful for those elements that have been known for centuries or millennia. (Examples include carbon, mercury, sulfur, iron, copper, tin, zinc, silver, gold, and lead.) Use this information as a springboard for discussing the element names given in the text. Answer to . . . Figure 2 Gold Properties of Matter 39 Section 2.1 (continued) Integrate Language Arts Symbols for Elements In 1813, Jöns Berzelius, a Swedish L2 Silicon Have students research and explain the origin of element symbols (other than Au) that are not abbreviations for element names in English. Examples include silver (Ag), lead (Pb), tin (Sn), antimony (Sb), and mercury (Hg). Verbal, Portfolio Compounds FYI When the terms element, atom, compound, and molecule are defined in an introductory section, the definition of a molecule is often both too broad and too narrow. Molecules are not the smallest particle of all compounds, and many elements exist in nature as molecules. For this reason, in this text, the formal definition of molecule does not appear until Chapter 6, the chapter on bonding, where it can be defined accurately. (The term molecule is introduced informally in Section 3.3 when water molecules are described.) chemist, suggested that chemists use symbols to represent elements. Many of the symbols he assigned to elements are still used. Each symbol has either one or two letters. The first letter is always capitalized. If there is a second letter, it is not capitalized. It is easy to see why C and Al are used to represent carbon and aluminum. But why does gold have the symbol Au? The symbols that Berzelius chose were based on the Latin names of the elements. The Latin name for gold is aurum. The symbols allow scientists who speak different languages to communicate without confusion. For example, nitrogen is known as azote in France, as stickstoff in Germany, and as nitrógeno in Mexico. But scientists who speak English, French, German, and Spanish all agree that the symbol for the element nitrogen is N. Sometimes an element’s name contains a clue to its properties. For example, the name hydrogen comes from the Greek words hydro and genes, meaning “water” and “forming.” Compounds Oxygen Figure 3 Elements have different properties than their compounds. Silicon is a gray solid and oxygen is a colorless gas, which can be stored in a metal tank. Silicon and oxygen combine to form silicon dioxide—a colorless, transparent solid found in most grains of sand. Silicon dioxide Water is composed of the elements hydrogen and oxygen. When electricity passes through water, bubbles of oxygen and hydrogen gas form and rise to the surface of the water. If the gases are collected in a container and a flame is brought near the mixture, the hydrogen and oxygen react and form water. Water is classified as a compound. A compound is a substance that is made from two or more simpler substances and can be broken down into those simpler substances. The simpler substances are either elements or other compounds. The properties of a compound differ from those of the substances from which it is made. For example, oxygen and hydrogen are gases at room temperature, but water is a liquid. Hydrogen can fuel a fire, and oxygen can keep a fire burning, but water does not burn or help other substances to burn. In fact, water is one of the substances commonly used to put out fires. Figure 3 shows another example of how properties change when elements join and form compounds. Silicon dioxide is a compound found in most light-colored grains of sand. It is a colorless, transparent solid. Yet, silicon dioxide is made from a colorless gas (oxygen) and a gray solid (silicon). Silicon is used to make chips for computers. A compound always contains two or more elements joined in a fixed proportion. For example, in silicon dioxide, there are always two oxygen atoms for each silicon atom. (Di- means “two.”) In water, there are always two hydrogen atoms for each oxygen atom. What happens if electricity passes through water? 40 Chapter 2 Facts and Figures Electrolysis of Water Early chemists were able to use heat to break down many compounds into their constituent elements. Because water cannot be decomposed by this method, water was classified as an element until chemists were able to use electric current 40 Chapter 2 to break down water into hydrogen and oxygen. (The decomposition of water into hydrogen and oxygen will not occur unless ions are added to the water because there are not enough ions in pure water to conduct an electric current.) Mixtures Figure 4 The ingredients shown are used to make one kind of salsa, which is an example of a heterogeneous mixture. Salsa oes um tomat • 4 or 5 pl Serrano sh fre 5 • 3– s chili pepper of cilantro s rig sp 12 • c clove • large garli ite onion • small wh 1 teaspoons •1 2 juice fresh lime • teaspoon salt 3 4 Figure 5 Sand is a heterogeneous mixture. The spoon is stainless steel, which is a homogeneous mixture. Interpreting Photographs Explain how viewing sand through a hand lens helps show that sand is a heterogeneous mixture. L1 Compare and Contrast Refer to page 226D in Chapter 8, which provides the guidelines for comparing and contrasting. Have students read pp. 41–44 and gather information on different classifications of mixtures. Then, have students create a chart that compares and contrasts each type of mixture. Visual Integrating Language Arts Mixtures Suppose you are making salsa using the ingredients shown in Figure 4. You have a choice. You can use exactly the amounts listed in the recipe, or you can adjust the ingredients according to your own taste. You might have to prepare the recipe a few times before deciding if you have just the right amount of each ingredient. Mixtures tend to retain some of the properties of their individual substances. But the properties of a mixture are less constant than the properties of a substance. The properties of a mixture can vary because the composition of a mixture is not fixed. The type of pepper and the quantity of pepper used in a salsa recipe determine the “hotness” of a batch of salsa. Chili peppers contain a compound called capsaicin (kap SAY uh sin) that can cause a burning sensation in your mouth. The amount of capsaicin varies among types of peppers. Cayenne peppers, for example, contain more capsaicin than do jalapeño peppers. No matter how well you stir a batch of salsa, the ingredients will not be evenly distributed. There may, for example, be more onion in one portion of the salsa than another. Mixtures can be classified by how well the parts of the mixture are distributed throughout the mixture. Build Reading Literacy L2 Have students consider the difference between hot food (as in warm versus cold) and hot food (as in spicy versus mild). Encourage students to suggest examples of dishes other than salsa that are hot in the second, spicy sense. Some students may want to record a family recipe for a “hot” dish. Have them identify the ingredient(s) that can be varied to control the “hotness” of the mixture. Logical Build Science Skills L2 Observing Have students look at samples of sand with a hand lens. Explain that the composition of sand can vary from beach to beach because the rocks and shells from which sand forms have different compositions. Ask, How can you tell that sand is a heterogeneous mixture? (The grains of sand vary in color and size.) (A sample of sand that contains only ground-up shells would probably be classified as homogeneous.) Visual Heterogeneous Mixtures If you look at a handful of sand from a beach, the sand appears to be all the same material. However, if you use a hand lens, you will notice that the sample of sand is not the same throughout. Figure 5 shows that grains of sand vary in size. Also, some grains are light in color and some are dark. Sand is an example of a heterogeneous mixture. Heterogeneous (het uh roh GEE nee us) comes from the Greek words hetero and genus, meaning “different” and “kind.” In a heterogeneous mixture, the parts of the mixture are noticeably different from one another. Properties of Matter 41 Facts and Figures Capsaicinoid Content Capsaicin (8-methylN-vanillyl-6-nonenamide) is the most abundant of a group of compounds called capsaicinoids. These compounds are found in the seeds and membranes of chili peppers. When they are ingested, they affect pain receptors in the mouth and throat. Because capsaicin is an oil, and oil and water do not mix, drinking water spreads the oil to more parts of the mouth and increases the burning sensation. The capsaicinoid content of a pepper is measured in Scoville units. Wilbur Scoville developed the method for measuring the “hotness” of chili peppers in 1912. He mixed ground chilies with a sugar and water solution and diluted the mixture until tasters no longer reported a burning sensation. The greater the dilution needed, the higher the assigned number of Scoville units. Fifteen Scoville units is equivalent to one part per million. Answer to . . . Figure 5 More details are visible in the magnified sand, making it easier to observe the different parts of the mixture. Bubbles of oxygen and hydrogen form and rise to the surface of the water. Properties of Matter 41 Section 2.1 (continued) Do the Contents of Two Cans of Mixed Nuts Meet FDA Regulations? Contents of Two Cans of Mixed Nuts Do the Contents of Two Cans of Mixed Nuts Meet FDA Regulations? L2 Answers 1. Both brands contain the same six types of nuts, but the amount of each type of nut varies. 2. There are 344.79 g in Brand A and 350.32 g in Brand B. The percents by mass in Brand A are: 44.2% peanuts, 13.64% almonds, 16.79% Brazil nuts, 13.4% cashews, 5.77% hazelnuts, and 6.21% pecans. The percents by mass in Brand B are: 54.8% peanuts, 8.90% almonds, 5.59% Brazil nuts, 21.06% cashews, 4.82% hazelnuts, and 4.82% pecans. 3. Yes. Both brands contain more than four types of nuts other than peanuts. The percent of each nut by mass is within the 2% to 80% range. 4. The ingredients are listed in order by total mass. The ingredient with the largest total mass is listed first. For Extra Help The Food and Drug Administration (FDA) has two main areas of concern about food. First, and most important, the FDA ensures that food sold in the United States is safe to eat. Second, the FDA ensures that the information on a food label accurately describes a food product. What can you assume when you see the label “mixed nuts” on a can of nuts? According to the FDA regulations, a can labeled mixed nuts must contain at least four types of shelled nuts other than peanuts. The mass of each type of nut must be not less than 2 percent of the total mass and not more than 80 percent of the total mass. Mass in Brand A Mass in Brand B Peanut 152.39 g 191.96 g Almond 47.02 g 31.18 g Brazil nut 57.88 g 19.60 g Cashew 46.20 g 73.78 g Hazelnut 19.90 g 16.90 g Pecan 21.40 g 16.90 g 1. Comparing and Contrasting How are the two brands of mixed nuts alike? How are they different? 2. Calculating What is the percent by mass of each type of nut in each can? 3. Drawing Conclusions Do the contents of each can meet the FDA regulations? Explain. 4. Inferring On the Brand A label, the nuts are listed in this order: peanuts, Brazil nuts, almonds, cashews, pecans, and hazelnuts. What do you think determines the order? Homogeneous Mixtures If you collect water from both the shallow end and the deep end of a swimming pool, the water samples will appear the same. The water in a swimming pool is a homogeneous (hoh moh GEE nee us) mixture of water and substances that dissolve in water. In a homogeneous mixture, the substances are so evenly distributed that it is difficult to distinguish one substance in the mixture from another. A homogeneous mixture appears to contain only one substance. The serving spoon in Figure 5 is made of stainless steel—a homogeneous mixture of iron, chromium, and nickel. L1 Have students answer Question 3 by calculating 2% and 80% of each total mass and checking to see if any of the masses fall outside that range. Logical Solutions, Suspensions, and Colloids It isn’t always easy to tell a homogeneous mixture from a heterogeneous mixture. You may need to observe the properties of a mixture before you decide. The size of the particles in a mixture has an effect on the properties of the mixture. Based on the size of its largest particles, a mixture can be classified as a solution, a suspension, or a colloid. Solutions, Suspensions, and Colloids FYI Many alloys are not true solutions. Sterling silver, a mixture of silver and copper, is an example. Silver and copper are completely soluble in all proportions when molten. However, solid sterling silver is a two-phase alloy with pockets of almost pure silver and pockets of a 71.9% and 28.1% copper mixture. Type of Nut For: Links on mixtures Visit: www.SciLinks.org Web Code: ccn-1021 Solutions If you place a spoonful of sugar in a glass of hot water and stir, the sugar dissolves in the water. The result is a homogeneous mixture of sugar and water. When substances dissolve and form a homogeneous mixture, the mixture that forms is called a solution. The windshield wiper fluid in Figure 6 is a solution. So is tap water. 42 Chapter 2 Facts and Figures Download a worksheet on mixtures for students to complete, and find additional teacher support from NSTA SciLinks. 42 Chapter 2 Regulatory Agencies Responsibility for protecting the food supply is shared among the FDA, the Department of Agriculture, and the EPA, which regulates pesticides. Food that is adulterated or mislabeled may be voluntarily destroyed or recalled, or seized by court order. The FDA is responsible for establishing standards for identity, quality, and fill of container. If standards have been set for a product, such as mixed nuts, the product must comply with those standards. Food labels must include a statement of identity (usual or common name), the net quantity of the contents, the name and place of business of the supplier, and a list of ingredients in descending order by mass. The goal is to have honest and informative labels. A Figure 6 The liquids shown represent three categories of mixtures. A Windshield wiper fluid is a solution. B Muddy water collected from a swamp is a suspension. C Milk is a colloid. Comparing and Contrasting Based on appearance, how are a solution and a colloid similar? Transmission Versus Scattering L2 Purpose Students observe light pass through different mixtures. B C Materials 2 beakers, water, iodine solution, table salt, stirring rods, milk, fish tank, flashlight, white paper Procedure Demonstrate that a solution can have color and still transmit light. Fill two beakers halfway with water. Add a small amount of iodine solution to one beaker and stir. Add table salt to the second beaker. Ask students to describe the color of each mixture and state whether it is clear. Demonstrate transmission of light versus scattering. Fill the tank with water. Turn off the lights. Shine a flashlight through the tank so that it lights up the white paper placed behind the tank. Add some milk to the water and stir. Shine the light through the tank again. (These behaviors of light are discussed in detail in Section 18.3.) Liquid solutions are easy to recognize. They do not separate into distinct layers over time. If you pour a liquid solution through a filter, none of the substances in the solution are trapped in the filter. You can see through solutions that are liquids because light passes through them without being scattered in all directions. These three properties of liquid solutions can be traced to the size of the particles in a solution. The particles in a solution are too small to settle out of the solution, be trapped by a filter, or scatter light. Suspensions Have you ever seen the instruction “Shake well before using” on a bottle? This instruction is a clue that the material in the bottle is a suspension. A suspension is a heterogeneous mixture that separates into layers over time. For example, if you shake up a container of sand and water, the sand mixes with the water and forms a suspension. Over time, the suspended particles of sand settle to the bottom of the container. You could use a filter to separate the sand from the water. The water would pass through the filter, but the sand would remain in the filter paper. Suspended particles settle out of a mixture or are trapped by a filter because they are larger than the particles in a solution. The worker in Figure 7 is using a mask to filter out particles of plastic foam that are suspended in air. Because larger particles can scatter light in all directions, suspensions are cloudy. Expected Outcome Although the salt solution is colorless and the iodine solution is colored, both transmit light. Light passes through the water in the tank and makes a bright spot on the paper. With milk added, the light is scattered so that the spot is much less distinct. Visual What happens to suspended particles over time? Figure 7 When a surfboard is sanded, particles of plastic become suspended in air. The worker wears a mask to keep from breathing in the particles. Properties of Matter 43 L1 Use Visuals Figure 7 To emphasize that suspended particles settle out over time, ask, What will happen to the particles of plastic suspended in the air? (The plastic particles will eventually settle out.) Discuss with students the dangers of inhaling suspended particles. Ask, How does a mask prevent the worker from inhaling particles of plastic? (The particles in suspensions can be separated by filtration. The mask is a filter.) Visual Answer to . . . Figure 6 The solution and the colloid both appear homogeneous. Suspended particles settle out of a mixture. Properties of Matter 43 Section 2.1 (continued) Build Science Skills L3 High beam Classifying Have interested students research categories of colloids such as gels, foams, aerosols, and emulsions. Have students find out how scientists distinguish different types of colloids. Have them identify household examples of each type. Visual, Portfolio 3 ASSESS Evaluate Understanding L2 Have students make a game of concentration using the terms in the chapter and their definitions. Have groups of students write each term on separate index cards and the definition of each term on a second set of index cards. To play the game, students should shuffle all the cards together and then lay them face down in a grid. Each student takes turns flipping over two index cards. If the cards match, the student can remove the cards from the grid. If the cards do not match, the student places the cards face down. After all of the cards are gone, the student who has removed the most cards wins the match. Reteach Low beam Colloids Milk is a mixture of substances including water, sugar, pro- Figure 8 The photograph shows how water droplets in fog scatter the light from high beams. The drawing compares the areas lit by high beams and low beams. Interpreting Diagrams Which beams normally make a larger area of a road visible? teins, and fats. When fresh cow’s milk is allowed to stand, a layer of cream rises to the top. This layer contains much of the fat in the milk. In the milk you buy at the store, the cream does not form a separate layer. The milk has been processed so that the fat remains dispersed throughout the milk. The result is homogenized milk, which is a colloid. A colloid contains some particles that are intermediate in size between the small particles in a solution and the larger particles in a suspension. Like solutions, colloids do not separate into layers. You cannot use a filter to separate the parts of a colloid. Fog is a colloid of water droplets in air. Figure 8 shows how fog affects which headlights a driver uses. Automobiles have headlights with low beams for normal driving conditions and high beams for roads that are poorly lit. With the high beams, a driver can see a bend in the road or an obstacle sooner. But the high beams are not useful on a foggy night because the water droplets scatter light back toward the driver and reduce visibility. With the low beams, much less light is scattered. The scattering of light is a property that can be used to distinguish colloids and suspensions from solutions. Section 2.1 Assessment Reviewing Concepts L1 1. Use Figure 6 as a visual aid to summarize the key differences among different types of mixtures. 2. 3. 4. 5. Students should specify which ingredients are required for the cereal to qualify for a particular label and suggest a range for ingredients such as dried fruit or nuts. (Students could choose another edible mixture, such as canned vegetable soup.) Why does every sample of a given substance have the same properties? Explain why the composition of an element is fixed. Describe the composition of a compound. Why can the properties of a mixture vary? On what basis can mixtures be classified as solutions, suspensions, or colloids? Critical Thinking 6. Predicting If you added salt instead of sugar to a pitcher of lemonade, how would this change the properties of the lemonade? 44 7. Interpreting Visuals Explain why silicon dioxide cannot be the only compound in the sample of sand shown in Figure 5. 8. Inferring Fresh milk is a suspension. After fresh milk is homogenized, it is a colloid. What happens to the size of the drops of fat in milk when milk is homogenized? Writing Instructions Pick a cereal that is an obvious mixture. Write rules that could be used to control the cereal’s composition. Use the FDA rules for mixed nuts as a model. Chapter 2 If your class subscribes to iText, use it to review key concepts in Section 2.1. Section 2.1 Answer to . . . Figure 8 High beams 44 Chapter 2 Assessment 1. A pure substance has a fixed composition. 2. An element contains only one kind of atom. 3. Compounds contain two or more elements joined in a fixed proportion. 4. Because the composition of a mixture is not fixed 5. Mixtures can be classified as solutions, suspensions, or colloids based on the size of their largest particles. 6. The lemonade would taste salty instead of sweet. 7. Silicon dioxide is colorless. There must be at least one other compound in the sample to account for the dark-colored grains. 8. Large drops are broken down into smaller drops, which can remain dispersed throughout the milk. Section 2.2 2.2 Physical Properties 1 FOCUS Objectives Key Concepts Vocabulary What are some examples of physical properties? ◆ How can knowing the physical properties of matter be useful? ◆ What processes are used to separate mixtures? When does a physical change occur? ◆ ◆ ◆ ◆ ◆ ◆ ◆ physical property viscosity conductivity malleability melting point boiling point filtration distillation physical change Reading Strategy 2.2.1 Building Vocabulary Copy the table. As you read, write a definition for each property. Physical Property Definition Viscosity a. ? Malleability b. ? Melting point c. ? 2.2.3 2.2.4 2.2.5 I f there are pitchers of ice water and lemonade on a picnic table, how do you know which liquid is in each pitcher? It’s easy! The lemonade is yellow. Lemonade also has a tart taste that is hard to miss. A yellow color and a tart taste are two properties of lemonade. Examples of Physical Properties A physical property is any characteristic of a material that can be observed or measured without changing the composition of the substances in the material. Viscosity, conductivity, malleability, hardness, melting point, boiling point, and density are examples of physical properties. Reading Focus Build Vocabulary Figure 9 The object in the photograph is called a honey dipper. Honey is an example of a liquid with a high viscosity. Viscosity Suppose you knock over an open bottle of vinegar and an open jar of honey at exactly the same time. In the time it takes for the vinegar bottle to empty, the honey will scarcely start to flow. The tendency of a liquid to keep from flowing—its resistance to flowing— is called its viscosity. The greater the viscosity, the slower the liquid moves. Thick liquids, such as corn syrup and the honey in Figure 9, have a high viscosity. Thin liquids, such as vinegar, have a low viscosity. The viscosity of a liquid usually decreases when it is heated. For example, a spoonful of cooking oil will spread more quickly across the bottom of a heated frying pan than across the bottom of a cold pan. Why is the viscosity of a liquid important? Consider the motor oil used to keep the parts of an automobile engine from wearing away as they move past one another. The motor oil must not be too thick in cold weather or too thin in hot weather. L2 LINCS Have students use the LINCS strategy to learn and review the terms viscosity, conductivity, and malleability. In LINCS exercises, the students List what they know about each term, Imagine a picture that describes the word or phrase, Note a reminding “sound-alike” word (such as visible, train conductor, and mallet), Connect the terms to the soundalike word by making up a short story, and then perform a brief Self-test. Reading Strategy L2 a. The tendency of a liquid to resist flowing b. The ability of a solid to be hammered without shattering c. The temperature at which a substance changes from a solid to liquid 2 INSTRUCT Examples of Physical Properties Properties of Matter 45 Section Resources Print • Laboratory Manual, Investigation 2B • Guided Reading and Study Workbook With Math Support, Section 2.2 and Math Skill: Melting and Boiling Points • Transparencies, Section 2.2 2.2.2 Describe physical properties of matter. Identify substances based on their physical properties. Describe how properties are used to choose materials. Describe methods used to separate mixtures. Describe evidence that indicates a physical change is taking place. Technology • iText, Section 2.2 • Presentation Pro CD-ROM, Section 2.2 • Go Online, Science News, Properties of matter FYI The text mentions that lemonade can be identified by its taste. Remind students that taste should never be used to identify an unknown substance and that no substances, known or unknown, should ever be ingested in a lab. Properties of Matter 45 Section 2.2 (continued) Liquid crystal thermometer Metal rod Wooden rod Comparing Heat Conductors Foam cups Comparing Heat Conductors Materials L2 2 plastic foam cups, scissors, metric ruler, metal rod, wooden rod, 2 liquid crystal thermometers, hot water, clock or watch with second hand Objective After completing this activity, students will be able to • distinguish a material that is a good conductor of heat from a material that is a poor conductor of heat. Procedure 1. Make a data table with a column for time and a column to record the temperature of each rod. 2. Cut 3 cm off the top of one cup. Turn the cup upside down. Use the metal rod to make two holes about 3 cm apart in the bottom. Skills Focus Observing, Inferring Prep Time 10 minutes 3. Attach a thermometer to each rod as shown. 4. Insert both rods so they will just touch the bottom of the second cup. Lay the cup with the rods on the table. Do not touch the rods and thermometers during the experiment. Advance Prep Acquire wood and metal rods of similar length from the metal or woodworking classroom, a crafts shop, or a home repair shop. Liquid crystal thermometers may be purchased at a pet or aquarium supply store. You may want to cut the cups and attach the thermometers to the rods in advance to save class time. Thermometers can be attached to the rods with their own adhesive backing or taped on. Heat enough water to fill each foam cup about 3/4 full. 5. Ask your teacher to add hot water to the intact cup until it is about three fourths full. Class Time 20 minutes Safety Remind students to handle the setup carefully to prevent burns after the hot water is added. Teaching Tips • You may need to provide tape to attach thermometers to the rods. • Construct a blank data table on the board, an overhead transparency, or a computer and have each group enter its data in this table. All data can then be pooled and averaged for greater accuracy. Figure 10 Because gold is both malleable and beautiful, it is often used to make jewelry. These ancient gold medallions were made to form a necklace. 6. Hold the cup with the hot water firmly as you place the cup with the rods on top of it. CAUTION Be careful not to overturn the cup. 7. Observe and record the temperatures every minute for five minutes. Analyze and Conclude 1. Comparing and Contrasting Is metal or wood a better conductor of heat? Explain. 2. Applying Concepts Is a metal cup a good container for keeping a drink hot for as long as possible? Give a reason for your answer. 3. Evaluating Describe any variables, other than the type of material, that were not controlled in this lab. Conductivity Which spoon should you choose for stirring a pot of soup heating on the stove—a metal spoon or a wooden spoon? If one end of a metal object is heated, the other end will soon feel hot. A material’s ability to allow heat to flow is called conductivity. Materials that have a high conductivity, such as metals, are called conductors. If a material is a good conductor of heat, it is usually also a good conductor of electricity. Wood is not a good conductor of heat. You can stir hot soup with a wooden spoon without worrying about burning your hand because the wooden spoon stays cool to the touch. Malleability The ancient gold objects in Figure 10 were found in a tomb in Greece. A goldsmith made the medallions by tapping gold with a small hammer and punch. Gold can be shaped in this way because it is malleable. Malleability (mal ee uh BIL uh tee) is the ability of a solid to be hammered without shattering. Most metals are malleable. By contrast, an ice cube breaks into small pieces when struck with a hammer. So does ordinary glass when hit by a fast-moving object such as a baseball. Solids that shatter when struck are brittle. Why would a cook use a wooden spoon to stir hot soup? Expected Outcome Metal will conduct heat faster than wood. Analyze and Conclude 1. Metal is a better conductor. Students should cite the differences in temperature over time as evidence. 2. Metal is not the best choice for this purpose. Because metals are good conductors, the contents of the cup will cool quickly as heat is transferred to the surroundings. 3. Depending on what rods are used, possible sources of error are different lengths, different diameters, and different densities of the materials. Kinesthetic, Logical 46 Chapter 2 46 Chapter 2 Customize for Inclusion Students Visually Impaired Provide students who have visual impairments with samples of two different nontoxic solids that have approximately the same mass. By handling the samples, students can infer their relative densities from their volumes. Provide samples of materials with a range of hardness. Have students do scratch tests to determine an order of hardness. Students should be able to feel any indentations on the surfaces of the softer materials. see which of the materials can scratch the other. The blade of a typical kitchen knife, for example, can scratch a copper sheet because stainless steel is harder than copper. The stainless steel in a knife blade is a hard solid that can be shaped into a sharp cutting edge. The material used to sharpen the blade must be harder than stainless steel. Diamond is the hardest known material. Some of the grinding wheels used to sharpen steel contain small grains of diamond. The man in Figure 11 is carving a canoe from a soft wood—Western red cedar. Melting and Boiling Points If you leave a tray of ice cubes on your kitchen counter, the ice cubes will melt. The temperature at which a substance changes from solid to liquid is its melting point. For water, this change normally occurs at 0°C. If you heat water to cook pasta, the water will normally start to boil at 100°C. The temperature at which a substance boils is its boiling point. Figure 12 shows the melting point and the boiling point for some substances. Figure 11 This Tlingit carver is using an adze to carve a canoe from Western red cedar. Red cedar is a relatively soft wood. Melting and Boiling Points of Some Substances Boiling Point Hydrogen ⴚ259.3ⴗC ⴚ252.9ⴗC Nitrogen ⴚ210.0ⴗC ⴚ195.8ⴗC Ammonia ⴚ77.7ⴗC ⴚ33.3ⴗC Octane (found in gasoline) ⴚ56.8ⴗC 125.6ⴗC 0.0ⴗC 100.0ⴗC 16.6ⴗC 117.9ⴗC Water Acetic acid (found in vinegar) Table salt Gold 800.7ⴗC 1465ⴗC 1064.2ⴗC 2856ⴗC L2 There are different scales for describing hardness. The Brinell and Rockwell scales are based on the indentation made by an object. The Brinell hardness number is based on indentation depth. The Rockwell hardness number is based on indentation area. On a scale that measures resistance to abrasion, only two substances are rated above 10: cubic boron nitride (cBN), 19, and diamond, 42.5. Have students find out about hardness scales and describe how they are used to characterize rocks and minerals. Logical, Portfolio that density is the ratio of the mass of a substance to its volume. At room temperature, silver has a density of 10.5 g/cm3. If a coin has a density of 9.9 g/cm3 at room temperature, either the coin is not made from silver or the coin contains substances in addition to silver. Density can be used to test the purity of methanol. Methanol is a fuel burned in some racing motorcycles. The American Motorcycle Association (AMA) requires racers to use fuel that is at least 99.65 percent pure. Race officials may collect a sample of fuel and measure its temperature and density. Then they compare the measured density to the expected density of methanol at that temperature. These spot checks keep racers from adding substances to the fuel that will give them an unfair advantage in a race. Melting Point Figure 10 Gold is the most malleable metal. Ancient Greek jewelry was often hammered to a thickness of 0.1 to 0.15 mm. Ask, What properties of gold can you identify from Figure 10? (Gold is a shiny, yellow solid that can be shaped into small, detailed pieces.) The medallions shown in Figure 10 were found in the Lazlo region of central Italy and were likely made between the eighth and sixth centuries B.C. Ask, Given the age of this jewelry, what other property could you say gold exhibits? (Gold is durable.) Visual Integrate Earth Science Density Density can be used to test the purity of a substance. Recall Substance L1 Use Visuals Hardness One way to compare the hardness of two materials is to FYI Boiling points depend on both temperature and pressure. In Chapter 3, students will study the effect of pressure on boiling points. Figure 12 The table lists the melting points and boiling points for several substances. Analyzing Data Which of these substances are liquids at room temperature (20oC, or 68oF)? Properties of Matter 47 Facts and Figures Specific Gravity The AMA race officials described in the text are using a hygrometer to test specific gravity. Specific gravity is the ratio of the mass of a solid or liquid to the mass of an equal volume of distilled water at 4°C. Because specific gravity is a ratio of values that have identical units, it does not have units. (Density is discussed in greater detail in Chapter 1.) Answer to . . . Figure 12 Octane, water, and acetic acid A wooden spoon is a poor conductor of heat. Properties of Matter 47 Section 2.2 (continued) Using Physical Properties Using Physical Properties People use data about physical properties to solve many different types of problems. Physical properties are used to identify a material, to choose a material for a specific purpose, or to separate the substances in a mixture. Build Reading Literacy L1 Outline Refer to page 156D in Chapter 6, which provides the guidelines for an outline. Using Properties to Identify Materials The steps used to identify a material are similar to the steps used to test for purity. The first step is to decide which properties to test. The second step is to do tests on a sample of the unknown. The final step is to compare the results with the data reported for known materials. The identification of a material can be a crucial step in solving a crime. A detective collects red paint chips from the scene of a hit-andrun accident. He asks a chemist at the crime lab to use the chips to identify the model of the missing vehicle. Because paint is a mixture of substances, the chemist can do tests that distinguish one type of red paint from another. The technician compares the data she collects to an FBI database. The database contains information about the paints used on different makes and models of cars. Once the detective knows the make and model, he uses a database of registered owners to create a list of possible suspects. Have students read pp. 48–50 and gather information on identifying, choosing, and separating substances based on their physical properties. Then, have students use the headings as major divisions in an outline. Have students refer to their outlines when answering the questions in the Section 2.2 Assessment. Visual Using Properties to Choose Materials Properties deter- Comparing Melting Points L2 Purpose Students observe the differences in melting points of two substances. Materials water, ethanol, foam cups, freezer, large beaker, thermometer Procedure Tell students that you will demonstrate that the melting points of two substances differ. The night before, place a foam cup filled with water and a second foam cup filled with ethanol in the freezer. During class, pull both cups out of the freezer. Have students note that the water is frozen, but the ethanol is not. Remove the ice from the cup and add it to the large beaker. Add a small amount of water and allow the ice to begin melting. While the temperature of the ice water is leveling off, have a volunteer measure the temperature of the ethanol. Compare that temperature to the temperature of the ice water. Expected Outcome Because most freezers do not cool to temperatures below the melting point of ethanol, –114.7°C, the ethanol will remain a liquid. After some of the ice has melted, the temperature of the solid-liquid system will stop decreasing and level off. This is the melting point of water, 0°C. The temperature of the chilled ethanol is below 0°C. Visual 48 Chapter 2 Figure 13 Shoelaces for hiking boots are sometimes made from leather. So are some belts and shoes. Making Generalizations What properties of leather would make it a suitable material for all three types of objects? 48 mine which materials are chosen for which uses. For example, you wouldn’t want shoelaces made from wood. Shoelaces must be flexible, that is, they must be able to bend without breaking. They must also be durable, that is, they must be able to withstand repeated use. Laces in hiking boots like those in Figure 13 are usually nylon or leather. People don’t consider just one property when choosing a material for a particular application. They look at a set of properties. For example, the How It Works box on page 49 explains how the properties of wax are used when clay molds are made for casting metal sculptures. Chapter 2 Facts and Figures Identifying Substances Sometimes a single property is not sufficient to positively identify a substance. Iron, nickel, and cobalt, which are often found together in nature, look quite similar. The density of iron is 7.87 g/cm3. The density of nickel is 8.90 g/cm3. The density of cobalt is 8.86 g/cm3. Measurements of mass made on the type of balance found in most school labs would be precise enough to distinguish iron from cobalt or nickel, but not precise enough to distinguish cobalt from nickel. Making a Sculpture Making a Sculpture A process called lost-wax casting is used to make metal sculptures. Different stages of the process depend on physical properties of wax, clay, and metal. Wax can be carved and molded. Clay becomes brittle when baked at a high temperature. When melted, most metals form homogeneous mixtures, which can be poured into molds. Interpreting Diagrams Why is it important that wax has a low melting point? Wax model A wax model of the sculpture is built up around a clay core. Wax is used because it is soft enough for carving fine details, but hard enough to retain its shape at room temperature. Wax model Preparing clay molds This artist from Nepal in southern Asia is preparing molds for lost-wax casting. She is applying layers of clay to a wax model. Cast metal sculpture Molten metal poured into mold Clay core Clay mold Clay is applied to the wax model in layers of increasing coarseness, and left to dry. The inner, finer layers capture every detail of the sculpture in a smooth mold. The outer, coarser layers (clay mixed with sand) provide strength. There are a number of variations to the method described in the text. For example, sometimes there is no clay core. The lost-wax method of casting can also be used to make replicas of existing sculptures. Many other molding and casting techniques also take advantage of the physical properties of different substances to maximize the quality of the final product. For example, the properties of some types of rubber make them ideal materials for molds. Rubber molds are flexible enough that the cast can be pulled out without breaking the mold, yet strong enough to preserve fine details in the final product. Because of their durability, rubber molds can be reused many times. Interpreting Diagrams The wax must melt away when the model is heated in a kiln. Logical Layers of clay applied to the wax model Wax model For Enrichment Melting wax Melting wax The clay-covered wax model is then baked in a kiln. Because wax has a low melting point, the wax model melts away inside the clay, leaving a hardened shell mold. This clay mold is then used to make the final sculpture. Molten metal Molten (liquid) metal is poured into the clay mold and left to cool and harden. For this sculpture of an African head, a mixture of copper, zinc, and lead was used. L2 Broken clay Metal sculpture When the metal has cooled, the clay shell is broken open to reveal the finished metal sculpture. Properties of Matter 49 L3 Because an imprint made in wet sand will hold its shape, filling the imprint with melted wax or wet plaster will produce a cast of the object pressed into the sand. This sculpting technique is called a sand mold. Have students find out about sand molds and use them to make candles or plaster casts of their footprints or handprints. Visual, Portfolio Use Community Resources L2 Arrange for a sculptor or jewelry maker to visit the class. Have the artist describe the molding and casting techniques he or she uses. Before the visit, have students prepare questions about how the artist chooses materials based on their physical properties. Interpersonal Answer to . . . Figure 13 Flexibility and durability Properties of Matter 49 Section 2.2 (continued) Using Properties to Separate Mixtures Build Science Skills L2 Applying Concepts Purpose In this activity, students use properties to separate the components of a mixture. Figure 14 These Americorps students are looking for artifacts at the San Diego Presidio—a fort that was built in 1769. As the students sift dirt through a screen, small objects buried in the dirt collect on the screen. Applying Concepts How could changing the size of the holes in a screen change the number of objects found? Materials a mixture of table salt, sand, and iron filings; beaker; magnet; plastic bag; water; funnel; filter paper Using Properties to Separate Mixtures Some properties can be used to separate mixtures. distillation are two common separation methods. Class Time 20 minutes Procedure Encourage students to consider properties that can be used to separate each material from the other two materials in the mixture. Then, have students design a procedure to complete the separation. Filtration One way to make a pot of tea is to pour hot water over loose tea leaves. Some compounds in the tea leaves, such as caffeine, dissolve in the water. You can separate the hot tea from the loose leaves by pouring the mixture through a strainer. Using a strainer is a type of filtration. Filtration is a process that separates materials based on the size of their particles. Particles of the compounds that dissolve are small enough to pass through the strainer, but the tea leaves themselves are too large to pass through the strainer. The drip method of brewing coffee also uses a filter to separate the brewed coffee from the coffee grounds. The students in Figure 14 are using a wire screen to locate small objects buried in the sand at an archaeological site. Particles of dirt are small enough to pass through the holes in the screen, but objects such as broken bits of pottery are too large to pass through the screen. Expected Outcome Students can collect the iron filings using a magnet covered with a plastic bag. They can add water to the mixture to dissolve the salt. They can use a filter to collect the sand. Students can collect the salt by letting the water evaporate for a few days. Visual, Portfolio L2 Students may think that all the particles in mixtures are similar in size. This is true for solutions and colloids, but not for suspensions. Challenge this misconception by displaying common devices used to filter mixtures (such as a sieve, a colander, and a coffee filter) and discussing the mixtures these devices are used to separate. The size of the holes in a filter determines whether filtration can be used to separate a suspension. Hole size also determines whether all the particles in a colloid pass through the filter or all the particles are trapped in the filter. Either way, the end result is that the colloid is not separated by filtration. Verbal Science News provides students with current information on properties of matter. 50 Chapter 2 Filtration and For: Articles on properties of matter Visit: PHSchool.com Web Code: cce-1022 50 Distillation How can you separate the parts of a solution when all the particles in a solution are small enough to pass through a filter? Sometimes distillation can work. Distillation is a process that separates the substances in a solution based on their boiling points. One practical use of distillation is to provide fresh water for submarines. Most submarines can store only enough fresh water to last about ten days. Each submarine has equipment that can convert seawater into fresh water. The water is heated until it changes from a liquid to a gas. The gas is cooled until it changes back to a liquid, which is collected in a separate container. Boiling can separate fresh water from seawater because water has a much lower boiling point than the compounds dissolved in seawater. These compounds are left behind in the original container. How can loose tea leaves be removed from a pot of brewed tea? Chapter 2 Facts and Figures Tea Tea contains compounds called polyphenols, which are often referred to as tannins. There are health claims made for both black and green tea. The health claims made for green tea are related to the concentration of polyphenols. During the processing of black tea, most of the polyphenols are oxidized. Oxidation of polyphenols is limited during the processing of green tea. (The tea dumped into Boston harbor on December 16, 1773, was green tea, which outsold black tea in the Colonies.) Recognizing Physical Changes Recognizing Physical Changes The change of water from a liquid to a gas during boiling is a physical change. A physical change occurs when some of the properties of a material change, but the substances in the material remain the same. For example, if you slowly heat butter in a pan, it changes from a solid to a liquid, but the substances in the butter do not change. Two other examples of physical changes are crumpling a piece of paper and slicing a tomato. Crumpling and slicing are actions that change the size and shape of a material, but not its composition. Some physical changes can be reversed. You can freeze water, melt the ice that forms, and then freeze the water again. You can use an iron to remove the wrinkles from a cotton shirt. You can braid hair, unbraid the hair, and then braid it again. Some physical changes cannot be reversed. You would not expect to reconstruct a whole tomato from tomato slices or to replace the peel on a peeled orange. Figure 15 shows one physical change that can be reversed and one that cannot be reversed. FYI If butter heated in a pan begins to brown, this is a sign that a chemical change is starting to occur. Students are asked to compare the possible changes to heated butter in Question 5 of the Section 2.3 Assessment. 3 ASSESS Figure 15 Braiding hair and cutting hair are examples of physical changes. Braiding is a reversible change. Cutting cannot be reversed. 1. 2. 3. List seven examples of physical properties. Describe three uses of physical properties. Name two processes that are used to separate mixtures. 4. When you describe a liquid as thick, are you saying that it has a high or a low viscosity? 5. Explain why sharpening a pencil is an example of a physical change. 6. What allows a mixture to be separated by distillation? Critical Thinking 7. Designing Experiments How could you find out whether copper is harder or softer than the plastic used in a plastic cup? L2 Tell students that a layer of fat rises to the top in a pot of chicken soup. Ask, How can the cook remove the fat? (Skim the fat from the surface or freeze the soup and remove the solid fat layer.) L1 Reteach Use the How It Works feature on p. 49 to review with students the importance of examining physical properties when choosing a material. Discuss why the physical properties of wax, clay, and metal determine what roles they play in the making of a sculpture. Section 2.2 Assessment Reviewing Concepts Evaluate Understanding 8. Inferring Why would you expect the materials used to make pot holders to be poor conductors of heat? 9. Applying Concepts Silicon dioxide is a solid at room temperature and methanol is a liquid. Which substance has the higher melting point? Organizing Data In what order are the substances arranged in Figure 12? Use what you studied about organizing data in Section 1.4 to explain why this order is useful. Explain why you might choose a different order if you had similar data for 500 substances. The substances are ordered from lowest to highest melting point, which groups them into gases, liquids, and solids at room temperature. With a larger database, alphabetical order would be more useful for retrieving the data. If your class subscribes to iText, use it to review key concepts in Section 2.2. Properties of Matter 51 Section 2.2 Assessment 1. Students may list hardness, viscosity, conductivity, density, malleability, melting point, and boiling point. Students may also list color, taste, flexibility, and durability. 2. Identify materials, choose a material for a specific purpose, or separate the substances in a mixture 3. Filtration and distillation 4. A thick liquid has a high viscosity. 5. The shape and size of the pencil change, but the composition of the pencil remains the same. 6. A difference in boiling points allows mixtures to be separated by distillation. 7. By scratching the cup with an object made of copper 8. Pot holders are designed to prevent the transfer of heat from a cooking utensil. 9. Silicon dioxide Answer to . . . Figure 14 With smaller holes, more objects would collect on the screen. Loose tea leaves can be removed by filtration. Properties of Matter 51 Getting a Fresh Start Getting a Fresh Start L2 Background Water found in nature is never 100 percent pure. There are always substances dissolved in the water. Some of these substances, as well as bacteria and particles of dirt, must be removed before the water is fit to drink. Aeration is of great importance during waste-water treatment because of the organic compounds in sewage. Aeration is also important when the water source is groundwater because of the likely concentration of dissolved carbonates. Water that contains dissolved calcium and magnesium compounds is called hard water because deposits of these salts can accumulate in water and lessen the effectiveness of soap. Water softeners replace calcium and magnesium compounds with sodium compounds, which do not cause the same problems. Build Science Skills 1 Coarse filter A screen ■ L2 Coarse filter screen Observing Purpose Students observe that water can taste different depending on its source and on its purity. Procedure Have students taste samples of tap water, bottled water, and distilled water. Have them describe any differences or similarities they taste. Layer of lumps Cleaned water spills over into a trough. Mixing tank 3 Forming a colloid Alum ■ Safety Use only water that is intended for consumption. 52 Chapter 2 2 Aeration During aeration, air ■ Colloid forms. Alum (aluminum sulfate) added Class Time 10 minutes Reservoir Aeration tank may be bubbled into the water or water may be sprayed into the air. Aeration removes substances from water, such as iron compounds, that give water an unpleasant taste. Outlet tower Materials tap water, bottled water, distilled water Expected Outcome Students will be able to observe that the taste that they associate with water is due to substances dissolved in the water, and not to the water itself. Kinesthetic, Visual prevents large items such as leaves from entering the water treatment plant. is added to the mixing tank. Alum causes small particles in the water to form a type of colloid called a gel. Most of the bacteria in the water are trapped in the gel. 52 Chapter 2 4 Sedimentation In ■ the sedimentation tank, large lumps slowly settle to the bottom of the tank from where they can be removed. Lumps drained off Sedimentation tank Going Further Water from the ground About half of the drinking water in the United States comes from natural underground sources. Although this groundwater is filtered as it passes through rocks and sand, it sometimes contains high levels of dissolved minerals or chemical pollutants. So groundwater is purified using a modified version of surface water filtration. 6 Carbon filter The water is ■ 5 Sand and gravel filter ■ Next, the water trickles through sand and gravel filter beds, which trap the remaining suspended particles. Because the filter beds can become clogged, they are washed every 24 hours. sometimes passed through a carbon filter. This filter removes tiny amounts of dissolved impurities, and improves the water’s taste and color. Water storage tank Water Fluorine softener added compound added Chlorine added Carbon filter 7 Additives ■ The fluorine compound prevents tooth decay and the chlorine kills bacteria. The water softener removes some magnesium and calcium compounds. 8 Storage Finally, ■ the water is held in storage tanks before passing into the public water supply. Most home water purification systems use activated charcoal (AC) filters or reverse osmosis (RO). Neither system removes all contaminants. Activated charcoal is an extremely porous solid with a large surface area on which substances are absorbed. Activated charcoal is effective for removing volatile organic compounds, pesticides, some metals, and chlorine. Sometimes bacteria grow on the filter. The surface of the activated charcoal may become saturated and ineffective before the consumer replaces the filter. During reverse osmosis, normal household water pressure forces water through a semipermeable membrane. Reverse osmosis is useful for removing lead and other transition metals, asbestos, and many dissolved organic compounds. Reverse osmosis is a slow, wasteful process that uses three to nine gallons per gallon of purified water. (Some people use RO systems in their fish tanks.) In parts of the world without municipal treatment plants, UV light is used to kill waterborne pathogens. Verbal Going Further Gravel layer ■ Some people use a system to purify water at home. Research and write about one of these systems. What is the system designed to do? Compare the method used to the processes that occur at a water purification plant. ■ Take a Discovery Channel Video Field Trip by watching “Fresh-Squeezed Water.” Filtered water Sand layer Video Field Trip Properties of Matter 53 Video Field Trip Fresh-Squeezed Water After students have viewed the Video Field Trip, ask them the following questions: Why did the people on Catalina Island need to convert seawater to fresh water? (They were running out of drinkable water.) What is a semipermeable membrane? (A semipermeable membrane is a material that has microscopic holes to allow water to pass through while blocking salts and viruses.) What is reverse osmosis? (During reverse osmosis, water under high pressure passes through a semipermeable membrane, which removes dissolved salts and other unwanted substances.) Why is NASA also interested in desalination methods? (Being able to recycle the water on board a spacecraft reduces the amount and the weight of water that must accompany the astronauts on their voyages.) Properties of Matter 53 Section 2.3 2.3 Chemical Properties 1 FOCUS Objectives 2.3.1 2.3.2 2.3.3 Describe chemical properties of matter. Describe clues that indicate that a chemical change is taking place. Distinguish chemical changes from physical changes. Key Concepts Vocabulary When can chemical properties be observed? ◆ What observations might indicate that a chemical change has occurred? ◆ ◆ ◆ ◆ chemical property flammability reactivity chemical change precipitate What is the difference between chemical and physical changes? Reading Strategy Relating Text and Visuals Copy the table. Find examples of the clues for recognizing chemical changes in Figures 19 and 20. Clue Example Change in color a. ? Production of gas b. ? Formation of precipitate c. ? Reading Focus Build Vocabulary L2 H Word-Part Analysis Have students look up the words flammable, inflammable, and nonflammable. Have them find two meanings of the prefix in- to explain why the terms are confusing. Ask them to consider why it is very important to know what each term means. (Inflammable and flammable are synonyms. The prefix in- can mean “not,” or “into” as in “burst into flames.” It is important to use the correct meanings when writing or interpreting fire safety warnings.) Reading Strategy ow would you describe candles like the ones in Figure 16? You might describe their color or their hardness. Or, you might observe that the candles float on water, and conclude that the density of candle wax is less than that of water. Color, hardness, and density are physical properties. But there is something else about the candles that may seem even more obvious to you: the fact that the candles are burning. The ability to burn is not a physical property because you cannot observe burning without changing the composition of the material that is burning. As a candle burns, new substances form. Observing Chemical Properties L2 a. Copper roof changing color from red to green when exposed to moist air b. Formation of carbon dioxide gas when vinegar is added to baking soda c. Formation of cottage cheese curds when acid is added to milk Figure 16 When candles burn, new substances form. The ability to burn is a chemical property. 2 INSTRUCT Flammability Materials that burn can be used as fuel. Sometimes, people use burning newspapers to start a fire in a fireplace. Gasoline is the fuel burned in most automobiles. The chemical property that paper and gasoline share is their flammability. Flammability is a material’s ability to burn in the presence of oxygen. Observing Chemical Properties Build Reading Literacy L1 Preview Refer to page 36D in this chapter, which provides the guidelines for previewing. Before they read the section, have students skim the headings, visuals, and boldfaced material to preview how the text is organized. Visual FYI If the combustion of paraffin is not complete, carbon monoxide will form. Combustion as a type of reaction is addressed in Chapter 7. Combustion of fossil fuels is discussed in Chapter 9. 54 Chapter 2 Most candles are made from paraffin, which is a mixture of compounds containing carbon and hydrogen. As a candle burns, the compounds combine with oxygen in the air to form water and carbon dioxide. (Carbon dioxide is the gas that gives a carbonated beverage its fizz.) The ability to burn is a chemical property. A chemical property is any ability to produce a change in the composition of matter. Chemical properties can be observed only when the substances in a sample of matter are changing into different substances. Flammability and reactivity are two examples of chemical properties. 54 Chapter 2 Section Resources Print • Laboratory Manual, Investigation 2A • Guided Reading and Study Workbook With Math Support, Section 2.3 • Transparencies, Section 2.3 Technology • iText, Section 2.3 • Presentation Pro CD-ROM, Section 2.3 • Go Online, NSTA SciLinks, Chemical and physical changes Sometimes flammability is not a desirable property. For example, there are laws that regulate the flammability of fabrics. The fabrics used in children’s sleepwear must have a low flammability. These fabrics are described as flame-resistant because they are difficult to ignite. If they do ignite, they burn slowly. Reactivity The property that describes how readily a substance combines chemically with other substances is reactivity. Nitrogen and oxygen are the main gases in air. Oxygen is a highly reactive element. Nitrogen has an extremely low reactivity. Oxygen reacts easily with most other elements. Figure 17 shows the rust that forms when oxygen reacts with iron and water. Rust is a brittle, reddish-brown compound. A rusty chain or bolt is more likely to break than a new chain or bolt because rust is weaker than iron. Because iron is highly reactive, you would not choose iron to make decorative objects, such as jewelry or coins. Many uses of nitrogen depend on its low reactivity. For example, seawater is often stored in steel tanks located below the lowest deck of a ship. The seawater helps to keep the ship stable in the water. Over time, rust forms in the tanks because iron in the steel reacts with oxygen dissolved in the water. Researchers in Japan have developed a way to reduce the amount of rust produced. They pump nitrogen gas into the tanks, and the nitrogen displaces the dissolved oxygen. Which element is more reactive—oxygen or nitrogen? Oxygen Is Needed For: Links on chemical and physical changes Visit: www.SciLinks.org Web Code: ccn-1023 L2 Purpose Students observe that air is needed for a candle to burn. Materials 2 small candles, matches, large beaker Procedure Tell students that the flammability of a material is tested in air. Light two candles with a match. Carefully place a large beaker over one of the candles and have students observe what happens. Remove the beaker and relight the candle to show that it can still burn. Discuss how a scientist might test the hypothesis that oxygen is the gas in air that supports burning. Figure 17 This automobile must have been exposed to air and water for many years. Drawing Conclusions What evidence is there that parts of the automobile contained iron? Expected Outcome After the beaker is placed over the candle, the flame dies out. The other candle continues to burn. To demonstrate that oxygen is the gas that supports burning, the scientist could try burning the candle in pure samples of the gases in air. Visual, Logical Build Science Skills L2 Designing Experiments Challenge students to describe a material that they could test for flammability without changing its composition. (The material would have to be nonflammable.) Help students by asking them how they would test the material for flammability and what the results of the test would be. Explain that the absence of an observed event is useful data. Verbal Properties of Matter 55 Customize for English Language Learners Paired Brainstorming Have students work in pairs to think of other items—besides cars, chains, or bolts—that rust. Examples include bicycle frames, door and gate hinges, and old nails. Strengthen discussion skills by having students share their examples with the class. Encourage them to comment on what these items have in common. Although many items made from iron are coated with paint to prevent rusting, paint does chip and items containing iron will rust if left outdoors unprotected from the elements. Download a worksheet on chemical and physical changes for students to complete, and find additional teacher support from NSTA SciLinks. Answer to . . . Figure 17 The amount of rust is evidence that much of the automobile was made of iron. Oxygen Properties of Matter 55 Section 2.3 (continued) Recognizing Chemical Changes Identifying a Chemical Change Materials 4. Add 5 mL of calcium chloride solution to test tube A. Add 5 mL of sodium chloride solution to test tube B. Add 5 mL of copper sulfate solution to test tube C. 3 test tubes; test-tube rack; glass-marking pencil; 3 10-mL graduated cylinders; solutions of copper sulfate, calcium chloride, and sodium chloride Identifying a Chemical Change 5. Examine the test tubes for evidence of a chemical change. Record your observations. Procedure L2 1. Construct a data table with columns labeled Test Tube, Contents, and Observations. Objective After completing this activity, students will be able to • recognize evidence of a chemical change. 2. Label the test tubes A, B, and C. 3. Pour 5 mL of copper sulfate solution into test tube A. Pour 5 mL of calcium chloride solution into test tube B. Pour 5 mL of sodium chloride solution into test tube C. CAUTION Do not allow the solutions to touch your skin. They may cause irritation. Skills Focus Observing, Drawing Conclusions Analyze and Conclude 1. Inferring In which test tube(s) did a chemical change occur? Explain your answer. 2. Evaluating Can you be sure that a chemical change occurred? Explain your answer. Prep Time 20 minutes Advance Prep To prepare 1-M solutions of calcium chloride, sodium chloride, and copper sulfate, dissolve 1 mole of each salt (111.0 g CaCl2; 58.5 g NaCl; or 249.69 g CuSO4•5H2O) in approximately 800 mL of distilled or deionized water in a 1-L volumetric flask. Once a salt has dissolved, add enough water to make a 1000-mL solution. Stir the solution. Provide each group with 25 mL of each solution in a wash bottle, which is the easiest container for students to handle. Be sure to label each container with its contents. 6. Pour the contents of the test tubes into the sink. Rinse out the test tubes and flush the contents down the drain. CAUTION Wash your hands thoroughly with soap or detergent before leaving the laboratory. Recognizing Chemical Changes Figure 18 As a banana ripens, chemical changes cause the peel to change color from green to yellow. In a banana that is overly ripe, different chemical changes cause the peel to turn brown. Observing Based on your experience, what other properties of a banana change as it ripens? Figure 18 shows what happens to banana peels as bananas ripen. The color change in a banana peel is caused by chemical changes that are taking place in the cells of the banana. A chemical change occurs when a substance reacts and forms one or more new substances. Chemical changes occur when a cake bakes in an oven, leaves on trees change color, and food is digested in your stomach. How can you recognize a chemical change? You have to look for clues. For example, when food spoils, it often gives off an unpleasant odor. Three common types of evidence for a chemical change are a change in color, the production of a gas, and the formation of a precipitate. Class Time 20 minutes Safety Remind students to wash their hands thoroughly at the end of the lab, to be careful when handling glassware, and to dispose properly of chemical wastes. Teaching Tips • Review how to pour a liquid from a graduated cylinder and accurately read the volume. Expected Outcome A precipitate of calcium sulfate will form in test tube A. The other two combinations will show no evidence of a chemical change. Analyze and Conclude 1. Formation of a precipitate indicated that a chemical change occurred in test tube A. 2. No, formation of a precipitate is evidence for a chemical change, but it is not conclusive. Visual, Logical 56 Chapter 2 56 Chapter 2 Facts and Figures Banana Science There are four stages of banana development: growth, maturation, ripening, and senescence. During ripening, bananas produce increased amounts of ethylene gas, which triggers chemical changes. The peel changes color and becomes more permeable, the pulp softens, starches break down into sugar, and compounds responsible for flavor and aroma are produced. Once ripening begins, the process cannot be stopped. Ripening occurs whether the banana is attached or detached from the parent plant. L1 Use Visuals A Change in Color Over time, a shiny silver bracelet that is exposed to air will darken. As a match burns, it shrivels up and turns black. The new copper roof and the old copper roof in Figure 19 have different colors. In each of these examples, a change in color is a clue that a chemical change has produced at least one new substance. Production of a Gas Figure 20A shows what happens when you mix vinegar with baking soda. Bubbles of carbon dioxide form immediately. A similar chemical change happens when you use baking powder as an ingredient in a cake recipe. Baking powder is a mixture of baking soda and one or more acids that react when wet. As the cake bakes, the bubbles of carbon dioxide expand and cause the cake to rise. Figure 19 When copper is exposed to moist air, it forms a thin coating called a patina. A new copper roof has a reddish color. The green patina on an old copper roof is a mixture of copper compounds. Predicting Would a patina form faster in a rainy climate or in a dry climate? Figure 20 Emphasize that the best way to determine if a chemical change is taking place is to compare materials before and after the reaction. Ask, Describe baking soda and vinegar before they are mixed. (Baking soda is a white solid, and vinegar is a clear solution.) What clue indicates that a chemical change is taking place? (There is production of a gas.) When you see no obvious clues to a chemical change, can you be certain that a chemical change has not occurred? (No) Visual Formation of a Precipitate Another chemical change you can observe in the kitchen is the curdling of milk. If you add lemon juice or vinegar to milk, small bits of white solid will separate from the liquid. Any solid that forms and separates from a liquid mixture is called a precipitate. When an acid is added to milk, proteins in the milk undergo a chemical change that alters their structure, causing them to stick together in clumps. They form the precipitate shown in Figure 20B. What happens when you add vinegar to baking soda? A Figure 20 The formation of a gas or a precipitate can be a clue to chemical change. A Carbon dioxide gas forms when vinegar is mixed with baking soda. B The curds in cottage cheese form when an acid is added to milk. B Properties of Matter 57 Facts and Figures Acids in Action When acid is added to milk, one of the proteins in milk (casein) coagulates. The milk may thicken (as in buttermilk or yogurt) or separate into solid curds and liquid whey (as in cottage cheese). This process is called curdling. Acids may be added directly to the milk or produced by bacteria. Adding rennin (a coagulating enzyme) produces larger curds. Single-action baking powder contains three dry ingredients: an acid (e.g., cream of tartar), a base (e.g., baking soda), and filler (e.g., cornstarch). When water is added, the acid and base react. Double-action baking powders contain two acids, one that reacts faster than the other. Recipes that use baking soda have another ingredient that provides the acid. Answer to . . . Figure 18 Students may say that the banana becomes softer and that its odor increases. Figure 19 In a rainy climate Bubbles of carbon dioxide form. Properties of Matter 57 Section 2.3 (continued) Figure 21 A blacksmith uses a hammer to shape a horseshoe that has been heated. Although the color of the iron horseshoe changes, no chemical change is occurring. Inferring Other than color, what physical property of iron is affected by heating? Is a Change Chemical or Physical? L2 Students often have trouble distinguishing chemical from physical changes. Explain that the composition of some substances must change during a chemical change, but the composition of all substances must remain the same during a physical change. Verbal Is a Change Chemical or Physical? It is not always easy to distinguish a chemical change from a physical change. Even if you observe a color change, a gas, or a precipitate, you cannot be sure that a chemical change has taken place. When the iron horseshoe in Figure 21 is heated, its color changes from gray to red. Despite this change in color, the iron is still iron. When water boils on a stove, the bubbles of gas that rise to the surface are still water. Before you decide whether or not a chemical change has occurred, ask yourself this question: Are different substances present after the change takes place? If not, then the change is physical, not chemical. When matter undergoes a chemical change, the composition of the matter changes. When matter undergoes a physical change, the composition of the matter remains the same. FYI The release of heat or light is sometimes listed as a clue for a chemical change, but energy changes occur with both physical and chemical changes. Exothermic and endothermic changes are discussed in Sections 3.3 (Phase Changes) and 7.3 (Energy Changes in Reactions). 3 ASSESS Evaluate Understanding Section 2.3 Assessment L2 Reviewing Concepts Have students list three clues that indicate that a chemical change is taking place and give an example of each. Then, have them exchange their work with a partner and discuss examples of physical changes that also exhibit these clues. Reteach 1. 2. 3. 4. L1 5. Use Figures 18, 19, and 20 to review the clues that indicate that a chemical change is taking place. Under what conditions can chemical properties be observed? List three common types of evidence for a chemical change. How do chemical changes differ from physical changes? Explain why the rusting of an iron bar decreases the strength of the bar. A pat of butter melts and then burns in a hot frying pan. Which of these changes is physical and which is chemical? Critical Thinking 6. Comparing and Contrasting Compare the properties of a raw egg to those of a hard-boiled egg. Students might argue that observation and experimentation are the key steps in a scientific method for determining whether a change is physical or chemical. If your class subscribes to iText, use it to review key concepts in Section 2.3. Answer to . . . Figure 21 Malleability increases. 58 Chapter 2 58 7. Classifying If you spill household bleach on denim jeans, you will observe that the area of the spill no longer has a blue color. Is this change chemical or physical? Give a reason for your answer. 8. Inferring Gold and platinum are often used to make jewelry. What can you infer about the reactivity of these elements? Scientific Methods Section 1.2 listed typical steps scientists use. Which steps might you use to decide whether a change is physical or chemical? Explain. Chapter 2 Section 2.3 Assessment 1. When the substances in a sample of matter are changing into different substances 2. A change in color, the production of a gas, or the formation of a precipitate 3. A chemical change produces new substances. A physical change produces no new substances. 4. When iron rusts, the compound that forms is brittle. 5. Melting is a physical change. Burning is a chemical change. 6. The raw egg is a viscous liquid. The egg white is cloudy and the yolk is orange. The hard-boiled egg is a soft solid. The egg white is opaque and the yolk is yellow. 7. Because the bleach has caused the denim to change color, the change is likely to be a chemical change. 8. Because jewelry is designed to last a long time, the reactivity of gold and platinum must be relatively low. What Should Be Done With Arsenic-Treated Wood? Termites are among the organisms that attack untreated wood. In 1950, United States suppliers of lumber began to treat wood with a mixture of copper, chromium, and arsenic (CCA). The mixture slows the damage to wood by poisoning the attacking organisms. Outdoor structures such as decks and porches were made from CCA-treated wood. By 2002, more than 95 percent of treated lumber sold for use outdoors contained CCA. Arsenic is a poison that has been linked with certain types of cancer. Arsenic can be absorbed through the skin or ingested in water or food. Consumers were especially concerned about children touching CCA-treated wood and then placing their unwashed fingers in their mouths. Some consumers asked the Environmental Protection Agency (EPA) to ban the use of CCA. In 2002, the chemical and home-improvement industries agreed to stop producing CCA-treated wood for home use. The Viewpoints Old CCA-Treated Wood Does Not Need to Be Removed Old CCA-Treated Wood Needs to Be Removed The EPA did not recommend tearing down existing structures made from CCA-treated wood. A panel of Florida doctors reported that they found no studies linking cancer in children and exposure to CCA-treated wood. They concluded that the amount of arsenic that children could absorb from treated wood is small compared to the amount of arsenic that occurs naturally in soil. A report produced by one state’s Department of Environmental Protection concluded that there is a serious risk for children exposed to arsenic from treated wood. The level of arsenic remains high for 20 years in CCA-treated wood. The useful life of most treated wood products is about 20 years. An area of CCA-treated wood the size of a four-year-old’s hand contains about 120 times the amount of arsenic allowed in a 6-ounce glass of water. (The EPA limit for arsenic in drinking water is 10 parts per billion.) Rainwater penetrates wood and dissolves arsenic. The arsenic ends up on the surface of the wood or in the soil near the wood. There are risks associated with disposing of treated wood. Burning arsenic-treated wood produces ash with high levels of arsenic. The ash would poison a person who inhaled, ingested, or touched it. The only acceptable method of disposal is in landfills, which are rapidly filling. Also, arsenic from landfills can end up in groundwater. What Should Be Done With L2 Arsenic-Treated Wood? Background Woods that are naturally resistant to attack, such as cedar and redwood, tend to be more expensive than timber treated with CCA. Alternatives to waterborne preservatives such as CCA included creosote and pentachlorophenol, or penta. Creosote is a smelly mixture of chemicals distilled from coal tar. Railroads began to treat railroad ties with creosote in 1889. Penta was generally applied in a 5% solution of petroleum solvents. Its use became limited after the price of oil rose in the 1970s. Because there are health risks associated with both penta and creosote, their use has been restricted since 1986. After students answer Question 3, ask, What evidence did the opponents and supporters of CCA removal have that you do not have? Explain how that evidence might have influenced your opinion. (The viewpoints as presented were based on opposing interpretations of scientific studies. Being able to see the actual data might have influenced their opinions.) Research and Decide 1. Defining the Issue In your own words, describe the issue that needs to be resolved about existing structures made from CCA-treated wood. 3. Forming Your Opinion Should existing structures built from CCA-treated wood be removed? Which argument did you find most convincing? 2. Analyzing the Viewpoints List three arguments of those who don’t think that existing structures made from CCA-treated wood need to be removed. List three arguments of those who want to remove existing structures made from CCA-treated wood. Have students further research the issues related to this topic. For: More on this issue Visit: PHSchool.com Web Code: cch-1020 Properties of Matter 59 Answers 1. Are structures built from CCA-treated wood enough of a health hazard for children that the structures should be removed? 2. Old CCA-Treated Wood Does Not Need to Be Removed: The EPA has not recommended removal of the structures. No studies link cancer in children and exposure to CCA-treated wood. There are serious risks associated with disposal of the wood. Old CCA-Treated Wood Needs to Be Removed: The level of arsenic remains high over the lifetime of the wood. The level of arsenic in the wood is much higher than the level allowed in water. Rain causes arsenic to collect on the surface of the wood or in soil. 3. Students should provide a reason for their decision. Properties of Matter 59