Physical Science Module 1 Week 1: Formation of Elements Week 2: Polarity of Molecules 1 Lesson Formation of Heavier Elements 1 At the end of this lesson, I should be able to: 1. Give evidence for and describe the formation of heavier elements during star formation and evolution; 2. Understand the basic concept of star formation; 3. Know that the chemical elements from Hydrogen to Iron can be formed in the stars through stellar fusion; 4. Counteract misconceptions about the formation of heavy elements; 5. Understand the importance and necessity to keep updated the progress of scientific concepts. ACTIVITY 1.1.1 The Galaxy’s Puzzle Instructions: A. Read the short story provided below and find the 5 words related to physics and chemistry. Use items 1-5 as a guide to find the words. Once, there was a spy named Hydrogen (nicknamed Hy) with massive issues on trusting Angela, his agency partner. There was always the possibility that their opinions crash against each other rather than end in a peaceful fusion like when Hy suggests the suspect of the crime they were investigating could be in the East Coast but Angela argues that the place should be in the West Coast. They were almost fired from the job for being too unprofessional, almost becoming the ‘big bang’ to their careers. The gravity of the situation made Hy and Angela rethink their attitude and agree to be more understandable of each other’s differences on opinions. B. Chemistry and Physics words found in the story: ______________________1. This is the lightest element in the periodic table. 2 ______________________2. This is what happens when elements combine together, usually resulting to new elements. ______________________3. This is the theory which proposes the universe is still in the process of inflation. ______________________4. This is the term for stars bigger than our own Sun. ______________________5. This is what pulls atoms together and what causes the Earth to orbit the Sun. VOCABULARY Big Bang Theory: this is the currently accepted theory of the origin of the universe which proposes that everything started from a singularity which in time inflated—and continues to do so—until the world we know of today started existing approximately 14 billion years ago. Stellar Nucleosynthesis: this is the birth of elements through nuclear fusion that takes place within stars. Supernova: this is the explosion in the event of a death of a star. Neutron-Star Mergers: this is when stars merge to form a more massive star, generating more energy than normal stars. Light Elements: these are elements from Hydrogen to Iron which form in less massive stars. Heavy Elements: these are elements heavier than Iron which form from massive stars, supernovae, or neutron-star mergers. Among the proposed explanations on how the universe began, the Big Bang Theory is the one currently accepted, theoretically. It describes that the universe started with a singularity defined simply as a point where all matter, time, space, laws of the universe and reality itself are condensed—ultimately inflating (not exploding) since approximately 14 billion years ago until now, according to NASA (National Aeronautics and Space Administration). Before the planet we live in right now came to existence as all the other planets and solar systems and galaxies, the earliest elements were formed first. 3 Let us explore why the elements needed to exist first: all matter that makes up most of the universe—including us—are made up of elements. These elements are what we study about in the Periodic Table such as Hydrogen (H), Oxygen (O), and Gold (Au). Now we need to understand the foundations and formations of elements. This lesson primarily focuses on the formation of the heavier elements but in order to understand that, we must first understand how the lighter elements were formed. The steps below summarize the formation of the earliest and lighter elements in the heart of massive stars, stars that are nine (9) times the size of our Sun: 1. There is first a huge cloud of Hydrogen (H) atoms. As per the law of the universe, gravity will pull these atoms together. 2. The core (center) of this cloud will get dense and hot, like when more things rub together they get hotter and more compressed. This dense and hot core will start to ignite. 3. This ignition is the start of fusion and since the atoms that are fusing (clumping together) are Hydrogen atoms, this is called Hydrogen Fusion happening in the core of the cloud. *KEEP IN MIND: When the Hydrogen fusion takes place, this doesn’t mean that ALL the Hydrogen atoms are already fusing. The rest of the Hydrogen atoms that are farther from the core remains outside the core. This trend happens not only with Hydrogen but also with other elements when they start to fuse at a later stage of element formation. 4. The heated core eventually becomes plasma: a soup of electrons and nucleuses that are not as well-formed, explaining why they aren’t atoms yet. 5. Hydrogen atoms will eventually fuse into Helium (He) and this (He) is now the new core. The surroundings of this (He) core is the previous (H) now called H-shell or H fusion shell. 4 Figure 1.1 Shows the fusion of the isotopes of Hydrogen atoms to form a Helium atom. 6. Since the remaining H-shell are also constantly fusing into the (He) core, more (He) is formed building up. With this (He) buildup, where gravity pulls atoms inward, there is also pressure which pushes the H-shell outward causing the size of the star to get bigger. 7. Steps 1-6 are going to continue until other fusions starts to happen: a.He fuses with H into a Carbon (C) core with a He-shell outside it; b.C fuses with He into Oxygen (O) core with a C-shell outside of it; and so on until Iron (Fe). 8. Why do we stop at Fe? It’s because in order to produce another element after Fe, more energy is needed than what the existing fusion can supply. That does not mean only the elements from H to Fe are real elements. Heavier elements continue to form where there is enough energy: during supernovae (plural of supernova—when stars explode and die) and neutron-star mergers (when stars merges). Now that we have cleared the basics of how the lighter elements are formed, we go in-depth on how the heavier elements get formed—one concept still unknown to science but supported by theories. 5 Stellar Nucleosynthesis is one of the ways heavier elements are formed. Nucleosynthesis explains how new atomic nucleus are formed from nucleons preceding from the new ones. There is also Nuclear Fusion, a process where neutrons and protons combine to new atoms. Nuclear fusion is how elements Hydrogen, Helium and small amounts of Lithium and Beryllium were formed. *REMEMBER: The number of protons (+) is the identity of an element, not the number of neutron (+) nor the number of electrons (-). 6 ACTIVITY 1.1.2 A Comprehensive Reading Instructions: Read the given passages and answer the questions that follow. This activity aims to practice your analysis on scientific articles, specifically about the basic formation of elements. “Heaviest Elements Did Not Form from Supernovae” Source: Physics Today (Frebel and Beers 2018) Unitil now it is accepted that heaviest elements formed from a supernova.However, scientists Anna Frebel from the Massachussets Institute of Technology (MIT) in Cambridge and Timothy C. Beers from the University of Notre Dame in Indiana have found evidence contrary to that belief. A supernova explosion happens when a star dies. This explosion, like any other explosion, would generate enough heat but in this case, such heat would aid the formation of elements. Since the lighter elements up until Iron can take form from normal stars, there are still questions about how the elements after Iron have taken form to which most studies proposed to be from supernovae. From the study of Anna Frebel and Timothy Beers, heaviest elements tend to form in an environment filled with free neutrons. This is vital because these free neutrons would be captured eventually into an existing nucleus making it heavier. The new element will not be this heavier nucleus but the one formed after this nucleus decays. Such decay would become stable and thus becomes this new, heavier element with a very short lifespan of a millisecond. The big revelation was that such an event with enough energy can only happen during a neutron-star merging. Neutronstar merger is when two stars collide due to gravitational pull and results in a much bigger explosion than a standard supernova. 7 Questions: 1. What is the major finding of Anna Frebel and Timothy Beers’ 2018 study? 2. Why do you think their finding is important to the field of scientific education? 3. What could have happened if the new evidence about the formation of the heaviest elements had not been discovered? ACTIVITY 1.1.2B Formation of Elements: An Analogy Instructions: Read the the procedure carefully. Make sure before doing this activity that your materials are complete. Objective: Understand how the formation of elements works through an analogy. Materials: Colored clays (3 separate colors, at least 1-inch ball each) Permanent marker any smooth paper to serve as a surface 1 whole sheet of paper Procedure: 1. Assign each color as 1A, 2B, and 3C. This will be the information you will put on your paper as reference. 1A, 2B, and 3C will serve as element examples. Make sure to take a picture with the procedures as evidence. 2. Now, make little balls out of one of the colored clays. Make the balls equal in size. This wil be your 1A element atoms. Make as many as your clay would allow while setting aside the other 2 colored clays. 3. Now, merge 2 of the 1A atoms and keep merging two balls of the 1A atoms. 8 4. When merged, cover the merged 1A atoms with a new colored clay. This now becomes an analogy of the birth of a new element, 2B. 5. Continue covering the merged 1A atoms with the 2B atom color. 6. Notice that while the new atom 2B has been formed, the atom also becomes heavier. 7. This time, merge two 2B atoms together until all of them are merged by two. 8. The merged 2B atoms should now be covered with your last colored clay for it to become the atom 3C. Set your merged clays aside and follow through step 9. 9. On your paper, answer the following questions: a.In all honesty, did this activity aided your learning about the formation of elements? Please justify your answer. b.What did the colored clays represent? c. What did the merging of the clay balls represent? 10. End of activity PARTS POINTS Materials 10 (with pictures) Questions 10 (with 1 picture per procedure, total of 8) TOTAL POINTS: 20/20 Activity 1.1.4: Origin of Elements Instructions: In your household, choose one member of your family to be your partner. The purpose of this activity is to strengthen your acquired knowledge through sharing the topic verbally. This method helps improve memory retention and confidence in the lesson. What you will do is to tell your partner about what you have learned today about the formation of the stars and elements. After this, make sure to ask your partner the following questions and write her/his answer on a sheet of 1 whole paper. 9 1. What was the process of the formation of lighter elements? 2. Is this lesson new to you? 3. Are you satisfied knowing the origins of the elements? Please justify your answer. Make sure that you take a picture of you and your partner’s mini discussion about the formation of elements at home. This picture must be sent to your teacher as part of the overall score. Happy learning! Activity 1.1.5: In the News Instructions: To broaden your understanding that this lesson can be applied in real life, research and read about the elements that can be found in our blood and bones. Use the following table below and copy the format on a 1 whole piece of paper. Title of the Article: Date of the Article’s Publication: Reference/s: Score: /10 1. What did you learn from the article? 2. Which elements can be found in a human’s blood and bones? 3. What was the connection of the article you read to the lesson about the formation of elements? 10 Lesson Synthesis of New Elements in the Laboratory 2 ACTIVITY 1.2.1. Hidden Words Instructions: Find the hidden words inside the box of letters and encircle them. Use the words you found to match them with the guide sentences that follow. A G B Y H N E D T E A F T D E V O H E N R Y F R O S D E J B P Q A S I I M C G G L B L A N G U N I J F D A A O S S K K G C U A O S I Y D U U T T W G O S D T Y U R T O D E L E M E N T B A O S E I Y T A W L I B N M A F G K Y G C J R G I P E C H K G A S K A T U N D L T S D O Q R L R M I G O Y D N P A E O E H A T K N V B L A F P S R D R J F D O T V U Y H T W G H 11 Guide Sentences: DOWN 1. This is the term for the combined number of protons and neutrons. ANS: _________________________________ 2. This is what the heaviest elements are called. ANS: _________________________________ 3. This means that one part of a molecule is either more positivelycharged or negatively-charged, to be discussed in Lesson 3. ANS: _________________________________ ACROSS 4. He was the one to fix Mendeleev’s periodic table of elements. ANS: _________________________________ 5. This is formed during the Big Bang, with Hydrogen as an example. ANS: _________________________________ VOCABULARY Synthetic Elements: refers to the chemical elements formed in a laboratory through certain, man-controlled processes. Transuranium Elements: these are elements heavier than Uranium. Isotopes: these are the same atoms with different number of neutrons. Atomic Number: this is the number of protons in an atom, pertaining to its identity. Atomic Weight: this is the number of protons and neutrons together of an atom. Periodic Trends: the chemical properties exhibited by the elements, reflected in the periodic table through groups or families. 12 The heaviest elements in the universe can be recreated in a laboratory. This type of element creation is called the synthesis of elements which is the focus for this lesson. It is important to note that these heavy elements, although created in a laboratory, do exist in space. The main reason why these heavy elements are needed to be created here in our planet is because traces of them in space cannot be harvested. The reason for this is becuase their life spans are too short to be captured for evidence—microseconds short to be exact. Let us take the following scenario for example: the element Gold (Au) is too heavy that whenever it takes form in spcae, it dissipates almost as soon as it was formed. Back on 1913, a scientist named Henry Moseley sought to fix Dmitri Mendeleev’s arrangement of the periodic table of elements. There was a discovery that arranging the elements based on their weight didn’t reflect the element’s chemical properties properly. Henry Moseley experimented by shooting electrons at varying elements. The result was that the elements released x-rays at a certain frequency that increases as the protons increases. Based on Henry Moseley’s x-ray spectroscopy experiment, he opted to arrange the elements in the periodic table according to the square root of their unique frequency emission resulting in a more organized table which shows periodic trends more clearly. Moseley’s x-ray spectroscopy is vital in the synthesis of the heaviest elements in a laboratory because it serves as a foundation of discovering that manipulating an element’s number of protons can be done. SYNTHESIS OF ELEMENTS An element is identified by its number of protons because no two elements can have the same number of protons. So in order to make a new, heavier element, protons must be added to an existing atomic nuclei of an element. A cyclotron—a type of particle accelerator—is a device invented and used to form and accelerate protons to hit a target nuclei, causing an addition of a proton to the target element. 13 Figure 2.1 Shows the simple mechanism and model of a cyclotron. Figure 2.2 Shows the simple mechanism and model of a particle accelerator. What are the elements synthesized here on Earth? These elements are those termed as transuranic elements and those written at the bottom of the periodic table of elements which are the heaviest in terms of atomic number, considered when heavier than Uranium (U) with an atomic number of 92. 14 TRANSURANIC ELEMENTS There are 26 transuranic elements in total, as follows: Atomic Number : 93 94 95 96 97 98 99 100 101 Element Symbol : Np Pu Am Cm Bk Cf Es Fm Md Element Name: Neptuniu m Plutoniu m Americiu m Curiu m Berkeliu m Californiu m Einsteiniu m Fermiu m Mendeleviu m Atomic Number: 102 103 104 105 106 107 108 109 110 Element Symbol: No Lr Rf Db Sg Bh Hs Mt Ds Element Name: Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Atomic Number: Element Symbol: Element Name: 111 112 113 114 115 116 117 118 Rg Cn Nh Fl Mc Lv Ts Og Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson ACTIVITY 1.2.2 Evolution of an Atom’s Representation Instructions: Answer accordingly. Ask your teacher for clarifications. Objectives: 1. Analyze how the model of an atom changed over time; 1. How the different models help us better understand th concept of the atomic number. Procedure: 15 1. Research about the following models of the atom in order: a.John Dalton’s model b.J.J Thomson’s model c. Ernest Rutherford’s model d.Neils Bohr’s model e. Erwin Schrodinger’s model 2. On a piece of 1 whole paper, draw the simple versions of their models (in order) and add notes on the bottom about the highlights of their model. 3. Answer the question: What made the scientists change the atomic models so much? Activity 1.2.3: Bomb Leftovers Remember that during star explosions, heavier elements are created? That same concept happens here on Earth when a nuclear bomb explodes. When a nuke explodes, traces of radioactive elements such as Uranium and those heavier than it are left in the wake of the explosion. These radioactivity can be hazardous to the health of the people near the area. Instructions: To broaden your understanding that this lesson can be applied in real life, research and read about the Chernobyl Nuclear Incident focusing on the topics of radiation and its effects. Use the following table below and copy the format on a 1 whole piece of paper. Title of the Article: Date of the Article’s Publication: Reference/s: Score: /10 1. What did you learn from the article? 16 2. What heavy element was the Chernobyl nuclear accelerators supposed to make? 3. What was the connection of the article you read to the concept of atomic number led to the synthesis of new elements in the laboratory? Lesson Polarities of Molecules 3 At the end of this lesson, I should be able to: 1. Determine if a molecule is polar or non-polar given its structure; 2. Give the scientific definition of polarity; 3. Identify a molecule’s polarity; ACTIVITY 1.3.1 Opposites Instructions: To ready you for the next lesson, this activity will give you an idea on the general concept of polarity. Use a one whole piece of paper to make a simple sketch of the given situations below, following the criteria: 17 Area Creativity Neatness Definition Percentage % Points This is the creative use of the story format as a medium to communicate knowledge of a topic. 60 6 This is the readability of your written output and its neatness. 40 4 100 % 10 per item Situations: 1. Tony and Steve playing on a seesaw, with Steve the heavier one on the left. 2. An infinity sign with the left side bigger than the right. 3. A Yin-Yang VOCABULARY • Polarity: refers to the overall charge of a molecule • Molecule: a group of elements bonded together • Positive charge: refers to an atom or a molecule with an excess proton • Negative charge: refers to an atom or a molecule with an excess, unpaired electron • Electronegativity (EN): the tendency of an atom/element to attract an electron, resulting in a negative charge, hence the name. Before anything else, it is important to note that a molecule is held together by bonds. These bonds are like the ropes which holds together a makeshift roof outside your house except in a subatomic level, these bonds are either polar or nonpolar. 18 A polar bond is generally an unfair bond: one is more tight while the other is rather loose. In chemistry, this bond refers to an ionic bond—a result of an unequal and big difference in electronegativities of elements involved in the bond. On the other hand, a nonpolar bond is a fair bond: the electronegativities of the elements concerned are equal, as well as the sharing of electrons (this usually occurs in covalent bonds). In analogy to the rope, visualize this bond as something with both ends of the rope equally tied tight. DETERMINING THE POLARITY OF A MOLECULE The easier and more basic way in determining the polarity of a given structure is through the Lewis structure and some solving, given the following steps and examples: 1. First, recall how to draw the Lewis structure and apply it to an example. In this case, let’s have the molecule CO2 (more commonly known as carbon dioxide. *IF UNFAMILIAR, kindly ask your teacher to review about how to draw Lewis structures. Lewis structure of C𝑂2: O C O 2. Find the electronegativity (EN) difference of each bond. Use a periodic table of elements for this. If the EN difference of the bond is greater than 0.4, it is polar but if it is lesser than 0.4, it is nonpolar. If ALL of the bonds in the molecule is nonpolar, the molecule is automatically nonpolar. However, if one bond is polar, continue with the steps. In the case of C𝑂2, the EN difference is 0.89 which is greater than 0.4. In this stage we can assume that C𝑂2 is polar. 3. If the central atom has no lone pairs (unpaired electrons) with all of the other atoms around it the same, the molecule is considered to be nonpolar. If the 19 central atom has lone pairs (unpaired electrons) with all of the other atoms around it different, the molecule is possibly polar. ACTIVITY 1.3.2A Creative Approach to Polarity Instructions: On a ½ crosswise sheet of paper, make a creative story about the lesson of polarity of molecules. You can use your own characters and analogy but make sure they are in-line with the main concepts of the lesson. It could be sci-fi, humor, drama, or in a script format—you decide. Your short story will be graded according to the following criteria: Area Significance Creativity Grammar Punctuation Neatness Definition This is the connection of the story to the scientific concept discussed (polarity of molecules) This is the creative use of the story format as a medium to communicate knowledge of a topic. & This is the proper use of the English (American) language in terms of grammar and punctuation. This is the readability of your written output and its neatness. Percentage % Points 30 6 30 6 20 4 20 4 100 % 20 ACTIVITY 1.3.3 Polarities At Home After this lesson, try to look at the common objects you can see in your house and even those outside school with new eyes: how polarity plays a role on their overall figure and look. From the water to the air around you: their polarity at work! 20 Instructions: To broaden your understanding that this lesson can be applied in real life, research and read about the polarity of the following chemicals: isopropyl alcohol, ammonia, vegetable oil, candle wax, acetone, and hydrogen peroxide. Use the following table below and copy the format on a 1 whole piece of paper. Title of the Article/s: Date of the Article’s Publication: Reference/s: Score: /7 1. Which chemicals from the list are polar? 2. Which chemicals from the list are non-polar? 21