Grou p 1 IA 1 1 H Hydro gen 3 4 2 The services we provide include dopant and impurity depth profiling, thin film and coating analysis, bulk composition and impurity analysis, materials characterization, failure analysis, characterization of particles, defects and residues, crystal structure determination, roughness measurement and the investigation of thermal properties. Lithiu Na M g Sodiu m 19 Magn esium 20 4 3 IIIB 13 IIIA 4 IVB 18 VIIIA 14 IVA 2 5 15 5 K C 21 22 6 VB VA 16 6 a Sc 7 23 VIB VIA H 17 7 B e 8 V 2 V 37 4 I I I 8 I B A Ti V C 9 25 38 9 N 5 10 1 2 V 3 3 1 6 III 0 Cr M Rb S 9 40 O 14 27 11 F n Fe r Y 1 28 5 41 IB 12 N A e l 1 2 IIB 6 42 55 9 C S Z o i r 17 30 43 56 N N P 6 b Mo i Cu 18 31 44 S Cs B 32 45 72 C Z T n c l a 33 46 73 A G R r a u 3 47 7 4 87 G 4 R Hf T e h 35 48 75 88 A P s d a 36 49 76 S A W Fr R e g Cd 50 77 104 B R r e a 5 7 105 1 8 K O I r n s 5 7 1 2 9 0 S 6 Rf D n Sb Ir P 53 80 107 b Sg t Au 54 81 108 T e 82 Hg Bh H 109 110 I 83 X T e s M l 8 111 4 P b B t Uu 85 112 i Po 86 nUu 114 uUu At R b n 116 Uu The other divisions of EAG provide additional services, allowing us to meet a larger range of customer needs across many industries. Potas sium Chemir: Providing in-depth analytical investigations and litigation support for a wide variety of industries, including paints, coatings, plastics and consumer products. Calci um Release to Production: Providing electronic testing services to the electronics and communications industries. agrosciences: Providing analytical chemistry, environmental fate and metabolism services for agrochemicals. Rubid ium Life Sciences: Providing regulated analytical and research/development services to the pharmaceutical and medical device industries. Cesiu m 7 lium 12 3 Our analytical staff is highly qualified, knowledgeable and very experienced. Over half of our scientists have advanced degrees in a variety of disciplines, from universities across the globe. The diversity of disciplines (e.g. chemistry, physics, materials science and engineering) enables us to skillfully address materials issues from a wide variety of industries. Beryl Stron tium Scan dium Yttriu m m nium Vana d ium Niobi um Tanta lu m Tung st en Radiu m Ruthe rfordi um Dubn ium ium M anga nese denu m Seab orgiu m Heliu m Carbo n Nitrog en Chrom Molyb Bariu um ium Titan iu Zirco Hafni Franc Boron m Te Coba lt ium R uthen ium Rhod ium ium um inum Nicke l Copp er chnet Rhen Bohri Iron Alum Osmi Hass um ium Meitn Iridium erium Palla dium Platin Unun um nilium Silver Unun Gold unium Zinc Galliu m Cadm ium Merc ury Indium Thalli um Lead bium Unun q quad n anium Tin Unun Silico Germ ium Phos phoru Arsen ic Antim ony Bism uth s Oxyg en Sulfu r Selen ium Tellur iu m Polon ium Uuh Unun hexiu Typical Analysis Depths for Techniques Evans Analytical Group m 11 We characterize materials directly for you; we don’t make or sell instruments! Our scientists use our instruments to the limits of their performance to directly help you solve your problems. Our People Li B e plasma Our Services 2 IIA m ine ine Chlor ine Brom Iodine Astat Fluor ine on n Rado n Argon Krypt Xeno Neon N Who We Are 18 r A Cl S P eon n Argo rine o l h C 36 r K 34 r B 33 e S 54 s A 53 e e G X 2 5 I 51 e T 0 86 b S 85 n n S R 4 8 t A 83 o P 82 i B b P 116 l T h us phor m m leniu ic rsen A Lead ne romi What We Do B rium u l l e T Antim Tin ton Kryp Se ony allium m 35 Phos iu man b r Sulfu muth Bis 114 q u U dium enon X e Iodin ne ti Asta m loniu Po Uu Unu n um hexi on Rad The Materials Characterization division of Evans Analytical Group (EAG) is the world’s largest independent provider of materials characterization and surface analysis services. EAG is the leading global source of microanalytical and surface characterization services to multiple industries and for many applications, ranging from semiconductors to medical devices; from solid state lighting to photovoltaic materials; and from starting/raw materials to finished products. Founded in 1978 in California as Charles Evans & Associates, EAG has grown into a global network of laboratories and sales offices, offering services worldwide. With over 34 years of experience, we provide our customers with information that is essential to the development of new materials and processes. Our customers rely on our data and services to improve product performance; solve materials-related problems and to integrate novel materials into their new products and manufacturing processes. EAG is committed to excellence in our professional practices, offering world-class analytical services with fast turnaround and exceptional quality. We are also committed to continual improvement through our quality management systems. Our ISO 9001 and 17025 certifications provide a strong foundation, enabling us to duplicate procedures and provide excellent consistency among the various EAG sites around the world. Our labs are an extension of your own facilities and we provide you direct access to our analytical staff. The primary analytical techniques used within EAG involve the use of ions, electrons, or photons (e.g. X-rays or infrared light) to probe materials, in order to investigate their composition, structure and chemistry. These analyses can: determine the chemical composition; detect the presence (or absence) of contaminants or dopants; and can investigate the physical structure or appearance of samples of interest. This detailed information is highly useful to our customers as they develop materials for their products, or optimize a new manufacturing process. EBSD Electron Backscatter Diffraction FIB/SEM Imaging Dual Beam and Single Beam FTIR Fourier Transform Infrared Spectroscopy GC-MS Gas Chromatography-Mass Spectrometry 0.1 – 1at% submonolayer Junction location, electrically active crystal defects, depletion layer widths, minority carrier diffusion length n/aYes Yes ≥10nm (Field Emission) In-situ cross section preparation and imaging n/a n/a Yes 1nm Identification of polymers and organics; contamination identification, particles Molecular functional groups 0.1 – 1wt% No ≥15µm Identification and quantification of volatile organic compounds in mixtures, outgassing, residual solvents, liquid or gas injection Molecular ions up to m/z ~500 400ng (full scan) 10ng (outgassing) n/a n/a LA-ICPMS and ICPMS Laser Ablation Inductively Coupled Bulk composition, trace and ultra-trace Li - U elemental analysis, impurity distribution Plasma Mass Spectrometry mapping LEXES Low Energy X-ray Emission Spectrometry Dosimetry/mapping of ion implants, B-U thin film characterization 10ppt wt - 100% 10ppb wt - 100% No n/a n/a Yes 5x1013 at/cm2 Yes 30µm Non-contact 3-dimensional imaging of surface topography n/a n/a Yes 435nm Identification of organics and inorganics; particle identification, stress measurement, carbon phase identification Chemical and molecular information ≥1wt% Yes ≥1µm 1nm imaging 0.5µm EDS Imaging, Z-contrast, elemental mapping elemental identification, EELS line scans, lattice imaging, Bright Field and Dark Field imaging B-U 1% Yes 0.25nm Imaging, elemental identification, crystallographic information, lattice imaging B-U 0.5% Yes 0.19nm Thermal stability and composition of organic/ n/a inorganic composite materials; glass transition, crystallization, melting, clustering, curing, chemisorption, and etc. 0.01 – 200°C/min; 20 - 1100°C; ±0.1mg – ±200mg; ±2.5µV – ±2500µV n/a n/a TOF-SIMS Time-Of-Flight Secondary Ion Mass Spectrometry Surface microanalysis of organic and inorganic materials, chemical mapping H-U Molecular species 107 – 1010 at/cm2 submonolayer Yes ≥0.20µm TXRF Total Reflection X-ray Fluorescence Spectroscopy Metallic surface contamination on semiconductor wafers, non-destructive S-U 109 – 1012 at/cm2 Yes ~10mm XPS/ESCA X-ray Photoelectron Spectroscopy/ Electron Spectroscopy for Chemical Analysis Surface analysis of organic and inorganic materials, depth profiling Li - U Chemical bonding 0.01 – 1at% submonolayer Yes 10µm – 2mm XRD X-ray Diffraction Identification of crystal phases, crystal H-U orientation and crystal quality, % crystallinity 1at% No 50µm XRR X-ray Reflectivity Determination of film density, roughness n/a and thickness n/a Yes 5mm 10ppm Yes 75µm Composition and impurities in thick films and bulk materials, wafer mapping SEM/ EDS Raman XRD XPS/ ESCA Be - U 10 at% 1 at% XRF RBS LEXES 100 ppm TOF-SIMS 1E18 1E17 1E16 10 ppm LA-ICPMS TXRF 1 ppm 100 ppb 10 ppb 1E15 Chemical bonding/ molecular information Elemental information 1E14 Imaging information 1 ppb 1E13 Thickness and Density information only (no composition information) Physical Properties 100 ppt n/a ≥20µm (Depth profiling) 1 - 5µm (Imaging mode) XRF X-ray Fluorescence Auger 0.1 at% 1E19 n/a Dopant and impurity depth profiling, H-U 1012 – 1016 at/cm3 Yes surface, bulk and microanalysis, insulating films, ultra low energy/ultra shallow depth profiling TGA/DTA/DSC Thermogravimetric Analysis Differential Thermal Analysis Differential Scanning Calorimetry STEM/ EDS 1E20 5 - 15mm 5µm 100 at% XRR 1E21 1E12 Dynamic SIMS The EAGLABSSM Bubble Chart ©2013 Evans Analytical Group 0.1 nm SEM (with EDS) Scanning Electron Microscopy Imaging, elemental identification B-U 0.1 % Yes Energy Dispersive X-ray Spectroscopy TEM (with EDS and EELS) Transmission Electron Microscopy Energy Dispersive X-ray Spectroscopy Electron Energy Loss Spectroscopy STEM/ EELS 1E22 50nm to 1µm 1nm imaging; ~80nm minimum grain size 0.1ppm - 50% STEM (with EDS and EELS) Scanning Transmission Electron Microscopy Energy Dispersive X-ray Spectroscopy Electron Energy Loss Spectroscopy OP RTX SEM 1.5 – 5nm Grain size, grain orientation, grain n/a n/aYes misalignment, % crystallinity IGA Bulk analysis of H, C, N, O and S, H, C, N, O, S Instrumental Gas Analysis (Combustion and fusion gas analysis) fractional gas analysis SIMS Secondary Ion Mass Spectrometry EBIC FTIR 1ppm wt - 100% ua nunq U Surface, particle, defect analysis, and large Li - U and small area depth profiling n/a Imaging Techniques AFM FIB n/aYes ICP-OES Inductively Coupled Plasma Bulk composition analysis Li - U Optical Emission Spectroscopy Raman Raman Spectroscopy TEM/STEM 5E22 GDMS Bulk analysis: trace and ultra-trace elemental Li - U Glow Discharge Mass Spectrometry survey analysis, depth profiling OP Optical Profilometry ≥1mm TGA/DTA/DSC 16 EBIC Electron Beam Induced Current n/a No Analytical Resolution versus Detection Limit 1 nm 10 nm 100 nm 1 μm IGA Auger Auger Electron Spectroscopy Roughness, 3-dimensional imaging of surfaces, magnetic field, grain size RBS 0.001 – 10at% (Z dependent) NRA > 1 x 1015 at/cm2 HFS 0.1at% Lateral Resolution/ Probe size ICP techniques 10 Thin film composition/thickness, quantitative B - U (RBS) dose measurement, quantitation without B, N, O, C (NRA) 1 standards, hydrogen in thin films, defects H, 2H (HFS) and lattice locations Imaging/ Mapping GC-MS 5 AFM Atomic Force Microscopy H 17 Detection Limits 10 μm Analytical Spot Size 100 μm 1 mm 10 ppt 1 cm Bulk Techniques GDMS Ox n roge elium rine o u l F ygen Elements Detected th ep D g in th pl ep m th D g Sa ep in D pl nm g .3 m in pl Sa r0 m fo nm Sa it 3 m lim or f 0n al it ic r3 lim ys fo al it Ph c i lim ys al Ph ic ys Ph N Accelerator Techniques Rutherford Backscattering Spectrometry Nuclear Reaction Analysis Hydrogen Forward Scattering Spectrometry Channeling e N F O Typical Applications He 17 VIIA 9 16 VIA 8 Analytical Technique Detection Range Atoms/cm3 18 A VIII 2 Grou p 1 IA 1 H 1 Hydro gen 3 The services we provide include dopant and impurity depth profiling, thin film and coating analysis, bulk composition and impurity analysis, materials characterization, failure analysis, characterization of particles, defects and residues, crystal structure determination, roughness measurement and the investigation of thermal properties. Lithiu 3 19 Na M g m Magn esium 20 3 IIIB 13 IIIA 4 IVB 18 VIIIA 14 IVA 2 5 15 5 K C 21 22 6 VB VA 16 6 a Sc 7 23 VIB VIA H 17 7 B e 8 V 2 V 37 4 I I I 8 I B A Ti V C 9 25 38 9 N 5 10 1 2 V 3 3 1 6 III 0 Cr M Rb S 9 40 O 14 27 11 F n Fe r Y 1 28 5 41 IB 12 N A e l 1 2 IIB 6 42 55 9 C S Z o i r 17 30 43 56 N N P 6 b Mo i Cu 18 31 44 S Cs B 32 45 72 C Z T n c l a 33 46 73 A G R r a u 3 47 7 4 87 G 4 R Hf T e h 35 48 75 88 A P s d a 36 49 76 S A W Fr R e g Cd 50 77 104 B R r e a 5 7 105 1 8 K O I r n s 5 7 1 2 9 0 S 6 Rf D n Sb Ir P 53 80 107 b Sg t Au 54 81 108 T e 82 Hg Bh H 109 110 I 83 X T e s M l 8 111 4 P b B t Uu 85 112 i Po 86 nUu 114 uUu At R b n 116 Uu Potas sium Chemir: Providing in-depth analytical investigations and litigation support for a wide variety of industries, including paints, coatings, plastics and consumer products. Calci um Release to Production: Providing electronic testing services to the electronics and communications industries. agrosciences: Providing analytical chemistry, environmental fate and metabolism services for agrochemicals. Rubid ium Life Sciences: Providing regulated analytical and research/development services to the pharmaceutical and medical device industries. Cesiu m Stron tium Scan dium Yttriu m m nium Vana d ium Niobi um Tanta lu m Tung st en Radiu m Ruthe rfordi um Dubn ium ium M anga nese denu m Seab orgiu m Heliu m Carbo n Nitrog en Chrom Molyb Bariu um ium Titan iu Zirco Hafni Franc Boron m Te Coba lt ium R uthen ium Rhod ium ium um inum Nicke l Copp er chnet Rhen Bohri Iron Alum Osmi Hass um ium Meitn Iridium erium Palla dium Platin Unun um nilium Silver Unun Gold unium Zinc Galliu m Cadm ium Merc ury Indium Thalli um Lead bium Unun quad n anium Tin Unun Silico Germ q ium Phos phoru Arsen ic Antim ony Bism uth s Oxyg en Sulfu r Selen ium Tellur iu m Polon ium Uuh Unun hexiu Typical Analysis Depths for Techniques 4 The other divisions of EAG provide additional services, allowing us to meet a larger range of customer needs across many industries. 7 lium 12 Sodiu Our analytical staff is highly qualified, knowledgeable and very experienced. Over half of our scientists have advanced degrees in a variety of disciplines, from universities across the globe. The diversity of disciplines (e.g. chemistry, physics, materials science and engineering) enables us to skillfully address materials issues from a wide variety of industries. Beryl plasma Evans Analytical Group m 11 We characterize materials directly for you; we don’t make or sell instruments! Our scientists use our instruments to the limits of their performance to directly help you solve your problems. Our People 4 Li B e 2 Our Services 2 IIA m ine ine Chlor ine Brom Iodine Astat Fluor ine on n Rado n Argon Krypt Xeno Neon N Who We Are 18 r A Cl S P eon n Argo rine o l h C 36 r K 34 r B 33 e S 54 s A 53 e e G X 2 5 I 51 e T 0 86 b S 85 n n S R 4 8 t A 83 o P 82 i B b P 116 l T h us phor m m leniu ic rsen A Lead ne romi What We Do B rium u l l e T Antim Tin ton Kryp Se ony allium m 35 Phos iu man b r Sulfu muth Bis 114 q u U dium enon X e Iodin ne ti Asta m loniu Po Uu Unu n um hexi on Rad The Materials Characterization division of Evans Analytical Group (EAG) is the world’s largest independent provider of materials characterization and surface analysis services. EAG is the leading global source of microanalytical and surface characterization services to multiple industries and for many applications, ranging from semiconductors to medical devices; from solid state lighting to photovoltaic materials; and from starting/raw materials to finished products. Founded in 1978 in California as Charles Evans & Associates, EAG has grown into a global network of laboratories and sales offices, offering services worldwide. With over 34 years of experience, we provide our customers with information that is essential to the development of new materials and processes. Our customers rely on our data and services to improve product performance; solve materials-related problems and to integrate novel materials into their new products and manufacturing processes. EAG is committed to excellence in our professional practices, offering world-class analytical services with fast turnaround and exceptional quality. We are also committed to continual improvement through our quality management systems. Our ISO 9001 and 17025 certifications provide a strong foundation, enabling us to duplicate procedures and provide excellent consistency among the various EAG sites around the world. Our labs are an extension of your own facilities and we provide you direct access to our analytical staff. The primary analytical techniques used within EAG involve the use of ions, electrons, or photons (e.g. X-rays or infrared light) to probe materials, in order to investigate their composition, structure and chemistry. These analyses can: determine the chemical composition; detect the presence (or absence) of contaminants or dopants; and can investigate the physical structure or appearance of samples of interest. This detailed information is highly useful to our customers as they develop materials for their products, or optimize a new manufacturing process. EBSD Electron Backscatter Diffraction FIB/SEM Imaging Dual Beam and Single Beam FTIR Fourier Transform Infrared Spectroscopy GC-MS Gas Chromatography-Mass Spectrometry 0.1 – 1at% submonolayer Junction location, electrically active crystal defects, depletion layer widths, minority carrier diffusion length n/aYes Yes ≥10nm (Field Emission) In-situ cross section preparation and imaging n/a n/a Yes 1nm Identification of polymers and organics; contamination identification, particles Molecular functional groups 0.1 – 1wt% No ≥15µm Identification and quantification of volatile organic compounds in mixtures, outgassing, residual solvents, liquid or gas injection Molecular ions up to m/z ~500 400ng (full scan) 10ng (outgassing) n/a n/a LA-ICPMS and ICPMS Laser Ablation Inductively Coupled Bulk composition, trace and ultra-trace Li - U elemental analysis, impurity distribution Plasma Mass Spectrometry mapping LEXES Low Energy X-ray Emission Spectrometry Dosimetry/mapping of ion implants, B-U thin film characterization 10ppt wt - 100% 10ppb wt - 100% No n/a n/a Yes 5x1013 at/cm2 Yes 30µm Non-contact 3-dimensional imaging of surface topography n/a n/a Yes 435nm Identification of organics and inorganics; particle identification, stress measurement, carbon phase identification Chemical and molecular information ≥1wt% Yes ≥1µm 1nm imaging 0.5µm EDS Imaging, Z-contrast, elemental mapping elemental identification, EELS line scans, lattice imaging, Bright Field and Dark Field imaging B-U 1% Yes 0.25nm Imaging, elemental identification, crystallographic information, lattice imaging B-U 0.5% Yes 0.19nm Thermal stability and composition of organic/ n/a inorganic composite materials; glass transition, crystallization, melting, clustering, curing, chemisorption, and etc. 0.01 – 200°C/min; 20 - 1100°C; ±0.1mg – ±200mg; ±2.5µV – ±2500µV n/a n/a TOF-SIMS Time-Of-Flight Secondary Ion Mass Spectrometry Surface microanalysis of organic and inorganic materials, chemical mapping H-U Molecular species 107 – 1010 at/cm2 submonolayer Yes ≥0.20µm TXRF Total Reflection X-ray Fluorescence Spectroscopy Metallic surface contamination on semiconductor wafers, non-destructive S-U 109 – 1012 at/cm2 Yes ~10mm XPS/ESCA X-ray Photoelectron Spectroscopy/ Electron Spectroscopy for Chemical Analysis Surface analysis of organic and inorganic materials, depth profiling Li - U Chemical bonding 0.01 – 1at% submonolayer Yes 10µm – 2mm XRD X-ray Diffraction Identification of crystal phases, crystal H-U orientation and crystal quality, % crystallinity 1at% No 50µm XRR X-ray Reflectivity Determination of film density, roughness n/a and thickness n/a Yes 5mm 10ppm Yes 75µm Composition and impurities in thick films and bulk materials, wafer mapping SEM/ EDS Raman XRD XPS/ ESCA Be - U 10 at% 1 at% XRF RBS LEXES 100 ppm TOF-SIMS 1E18 1E17 1E16 10 ppm LA-ICPMS TXRF 1 ppm 100 ppb 10 ppb 1E15 Chemical bonding/ molecular information Elemental information 1E14 Imaging information 1 ppb 1E13 Thickness and Density information only (no composition information) Physical Properties 100 ppt n/a ≥20µm (Depth profiling) 1 - 5µm (Imaging mode) XRF X-ray Fluorescence Auger 0.1 at% 1E19 n/a Dopant and impurity depth profiling, H-U 1012 – 1016 at/cm3 Yes surface, bulk and microanalysis, insulating films, ultra low energy/ultra shallow depth profiling TGA/DTA/DSC Thermogravimetric Analysis Differential Thermal Analysis Differential Scanning Calorimetry STEM/ EDS 1E20 5 - 15mm 5µm 100 at% XRR 1E21 1E12 Dynamic SIMS The EAGLABSSM Bubble Chart ©2013 Evans Analytical Group 0.1 nm SEM (with EDS) Scanning Electron Microscopy Imaging, elemental identification B-U 0.1 % Yes Energy Dispersive X-ray Spectroscopy TEM (with EDS and EELS) Transmission Electron Microscopy Energy Dispersive X-ray Spectroscopy Electron Energy Loss Spectroscopy STEM/ EELS 1E22 50nm to 1µm 1nm imaging; ~80nm minimum grain size 0.1ppm - 50% STEM (with EDS and EELS) Scanning Transmission Electron Microscopy Energy Dispersive X-ray Spectroscopy Electron Energy Loss Spectroscopy OP RTX SEM 1.5 – 5nm Grain size, grain orientation, grain n/a n/aYes misalignment, % crystallinity IGA Bulk analysis of H, C, N, O and S, H, C, N, O, S Instrumental Gas Analysis (Combustion and fusion gas analysis) fractional gas analysis SIMS Secondary Ion Mass Spectrometry EBIC FTIR 1ppm wt - 100% ua nunq U Surface, particle, defect analysis, and large Li - U and small area depth profiling n/a Imaging Techniques AFM FIB n/aYes ICP-OES Inductively Coupled Plasma Bulk composition analysis Li - U Optical Emission Spectroscopy Raman Raman Spectroscopy TEM/STEM 5E22 GDMS Bulk analysis: trace and ultra-trace elemental Li - U Glow Discharge Mass Spectrometry survey analysis, depth profiling OP Optical Profilometry ≥1mm TGA/DTA/DSC 16 EBIC Electron Beam Induced Current n/a No Analytical Resolution versus Detection Limit 1 nm 10 nm 100 nm 1 μm IGA Auger Auger Electron Spectroscopy Roughness, 3-dimensional imaging of surfaces, magnetic field, grain size RBS 0.001 – 10at% (Z dependent) NRA > 1 x 1015 at/cm2 HFS 0.1at% Lateral Resolution/ Probe size ICP techniques 10 Thin film composition/thickness, quantitative B - U (RBS) dose measurement, quantitation without B, N, O, C (NRA) 1 standards, hydrogen in thin films, defects H, 2H (HFS) and lattice locations Imaging/ Mapping GC-MS 5 AFM Atomic Force Microscopy H 17 Detection Limits 10 μm Analytical Spot Size 100 μm 1 mm 10 ppt 1 cm Bulk Techniques GDMS Ox n roge elium rine o u l F ygen Elements Detected th ep D g in th pl ep m th D g Sa ep in D pl nm g .3 m in pl Sa r0 m fo nm Sa it 3 m lim or f 0n al it ic r3 lim ys fo al it Ph c i lim ys al Ph ic ys Ph N Accelerator Techniques Rutherford Backscattering Spectrometry Nuclear Reaction Analysis Hydrogen Forward Scattering Spectrometry Channeling e N F O Typical Applications He 17 VIIA 9 16 VIA 8 Analytical Technique Detection Range Atoms/cm3 18 A VIII 2 Our Services The services we provide include dopant and impurity depth profiling, thin film and coating analysis, bulk composition and impurity analysis, materials characterization, failure analysis, characterization of particles, defects and residues, crystal structure determination, roughness measurement and the investigation of thermal properties. We characterize materials directly for you; we don’t make or sell instruments! Our scientists use our instruments to the limits of their performance to directly help you solve your problems. The other divisions of EAG provide additional services, allowing us to meet a larger range of customer needs across many industries. Evans Analytical Group Our analytical staff is highly qualified, knowledgeable and very experienced. Over half of our scientists have advanced degrees in a variety of disciplines, from universities across the globe. The diversity of disciplines (e.g. chemistry, physics, materials science and engineering) enables us to skillfully address materials issues from a wide variety of industries. Our People 2 1 1 Grou p 1 IA H Hydro 3 gen 4 2 IIA Li B e Lithiu 11 m Beryl liu 12 3 N a M g Sodiu m m Magn e 19 3 IIIB sium 20 4 13 IIIA 14 18 VIIIA 4 2 5 2 IVB IVA 15 1 5 K 6 22 VB VA 16 6 C a H S B e c T C i V N C Rb O r M S F n r N A F Y e e l C S Z o i r N N P b i C M S Cs u o C Z T B n c l a A G R r a u G R H e h f A P T s d a S A W Fr e g B C R R r d e a K O I r n s S Rf n I r S D P b b t T A S e u g H B I g h X H T e s l P M b t U B u i n P U o u u A t R n P o 7 t a 23 VIB s VIA sium 17 7 Chemir: Providing in-depth analytical investigations and litigation support for a wide C 8 alcium variety of industries, including paints, coatings, plastics and consumer products. VIIB 24 VIIA 37 8 H Scan Boron elium 9 Release to Production: Providing electronic testing services to the electronics 25 3 d 9 8 i u m and communications industries. 5 C T i arbon 10 t 13 a 2 V nium 3 10 6 III 9 agrosciences: Providing analytical chemistry, environmental fate and metabolism N V itroge a 14 nadiu 27 40 11 services for agrochemicals. n m C O Rubid h xygen r 15 o 28 41 m IB 12 Life Sciences: Providing regulated analytical and research/development services to ium ium M F S the pharmaceutical and medical device industries. anga l uorin tronti 16 29 IIB 42 55 ne e u s m e A Neon l u Yttriu minum 17 Iron 30 43 56 m 6 Z S C i r i 18 l o c 3 i c o b 4 o 1 nium alt 4 n P h o Nicke Niobi s phoru 32 45 72 um l s M Copp S o Cesiu l ulfur y 33 b 46 73 d enum er m T C e h Z c Bariu lorine 34 hnetiu inc 47 74 87 m m R G A u rgon allium then 35 48 75 88 i u m G 7 e R Hafni r hodiu m 36 49 anium 76 um m P Arsen Tanta a l l 50 a 77 104 dium ic lum S e T Franc Silver lenium ungst 51 78 105 ium en C B R a r Radiu omine heniu dmium 52 79 106 m m K Indium Osmi rypto 53 80 107 um n Ru Iridium t h Tin 54 e 81 108 r fordiu m A P n D latinu timon ubniu 82 109 m y m T S e eabo llurium Gold 83 110 rgiu m M Iodine B ercur ohriu 84 111 y m T X Hass halliu enon 85 112 iu m m M e Lead 86 i t n erium U B n i smuth u 114 n nilium U P n o u lonium n unium A U statin nu 116 e plasma U u b nbium Uuq Unun quad ium Uuh Unun h Rado n exium Typical Analysis Depths for Techniques N Who We Are 18 r A Cl S P eon n Argo rine o l h C 36 r K 34 r B 33 e S 54 s A 53 e e G X 2 5 I 51 e T 0 86 b S 85 n n S R 4 8 t A 83 o P 82 i B b P 116 l T h us phor m m leniu ic rsen A Lead ne romi What We Do B rium u l l e T Antim Tin ton Kryp Se ony allium m 35 Phos iu man b r Sulfu muth Bis 114 q u U dium enon X e Iodin ne ti Asta m loniu Po Uu Unu n um hexi on Rad The Materials Characterization division of Evans Analytical Group (EAG) is the world’s largest independent provider of materials characterization and surface analysis services. EAG is the leading global source of microanalytical and surface characterization services to multiple industries and for many applications, ranging from semiconductors to medical devices; from solid state lighting to photovoltaic materials; and from starting/raw materials to finished products. Founded in 1978 in California as Charles Evans & Associates, EAG has grown into a global network of laboratories and sales offices, offering services worldwide. With over 34 years of experience, we provide our customers with information that is essential to the development of new materials and processes. Our customers rely on our data and services to improve product performance; solve materials-related problems and to integrate novel materials into their new products and manufacturing processes. EAG is committed to excellence in our professional practices, offering world-class analytical services with fast turnaround and exceptional quality. We are also committed to continual improvement through our quality management systems. Our ISO 9001 and 17025 certifications provide a strong foundation, enabling us to duplicate procedures and provide excellent consistency among the various EAG sites around the world. Our labs are an extension of your own facilities and we provide you direct access to our analytical staff. The primary analytical techniques used within EAG involve the use of ions, electrons, or photons (e.g. X-rays or infrared light) to probe materials, in order to investigate their composition, structure and chemistry. These analyses can: determine the chemical composition; detect the presence (or absence) of contaminants or dopants; and can investigate the physical structure or appearance of samples of interest. This detailed information is highly useful to our customers as they develop materials for their products, or optimize a new manufacturing process. EBSD Electron Backscatter Diffraction FIB/SEM Imaging Dual Beam and Single Beam FTIR Fourier Transform Infrared Spectroscopy GC-MS Gas Chromatography-Mass Spectrometry 0.1 – 1at% submonolayer Junction location, electrically active crystal defects, depletion layer widths, minority carrier diffusion length n/aYes Yes ≥10nm (Field Emission) In-situ cross section preparation and imaging n/a n/a Yes 1nm Identification of polymers and organics; contamination identification, particles Molecular functional groups 0.1 – 1wt% No ≥15µm Identification and quantification of volatile organic compounds in mixtures, outgassing, residual solvents, liquid or gas injection Molecular ions up to m/z ~500 400ng (full scan) 10ng (outgassing) n/a n/a LA-ICPMS and ICPMS Laser Ablation Inductively Coupled Bulk composition, trace and ultra-trace Li - U elemental analysis, impurity distribution Plasma Mass Spectrometry mapping LEXES Low Energy X-ray Emission Spectrometry Dosimetry/mapping of ion implants, B-U thin film characterization 10ppt wt - 100% 10ppb wt - 100% No n/a n/a Yes 5x1013 at/cm2 Yes 30µm Non-contact 3-dimensional imaging of surface topography n/a n/a Yes 435nm Identification of organics and inorganics; particle identification, stress measurement, carbon phase identification Chemical and molecular information ≥1wt% Yes ≥1µm 1nm imaging 0.5µm EDS Imaging, Z-contrast, elemental mapping elemental identification, EELS line scans, lattice imaging, Bright Field and Dark Field imaging B-U 1% Yes 0.25nm Imaging, elemental identification, crystallographic information, lattice imaging B-U 0.5% Yes 0.19nm Thermal stability and composition of organic/ n/a inorganic composite materials; glass transition, crystallization, melting, clustering, curing, chemisorption, and etc. 0.01 – 200°C/min; 20 - 1100°C; ±0.1mg – ±200mg; ±2.5µV – ±2500µV n/a n/a TOF-SIMS Time-Of-Flight Secondary Ion Mass Spectrometry Surface microanalysis of organic and inorganic materials, chemical mapping H-U Molecular species 107 – 1010 at/cm2 submonolayer Yes ≥0.20µm TXRF Total Reflection X-ray Fluorescence Spectroscopy Metallic surface contamination on semiconductor wafers, non-destructive S-U 109 – 1012 at/cm2 Yes ~10mm XPS/ESCA X-ray Photoelectron Spectroscopy/ Electron Spectroscopy for Chemical Analysis Surface analysis of organic and inorganic materials, depth profiling Li - U Chemical bonding 0.01 – 1at% submonolayer Yes 10µm – 2mm XRD X-ray Diffraction Identification of crystal phases, crystal H-U orientation and crystal quality, % crystallinity 1at% No 50µm XRR X-ray Reflectivity Determination of film density, roughness n/a and thickness n/a Yes 5mm 10ppm Yes 75µm Composition and impurities in thick films and bulk materials, wafer mapping SEM/ EDS Raman XRD XPS/ ESCA Be - U 10 at% 1 at% XRF RBS LEXES 100 ppm TOF-SIMS 1E18 1E17 1E16 10 ppm LA-ICPMS TXRF 1 ppm 100 ppb 10 ppb 1E15 Chemical bonding/ molecular information Elemental information 1E14 Imaging information 1 ppb 1E13 Thickness and Density information only (no composition information) Physical Properties 100 ppt n/a ≥20µm (Depth profiling) 1 - 5µm (Imaging mode) XRF X-ray Fluorescence Auger 0.1 at% 1E19 n/a Dopant and impurity depth profiling, H-U 1012 – 1016 at/cm3 Yes surface, bulk and microanalysis, insulating films, ultra low energy/ultra shallow depth profiling TGA/DTA/DSC Thermogravimetric Analysis Differential Thermal Analysis Differential Scanning Calorimetry STEM/ EDS 1E20 5 - 15mm 5µm 100 at% XRR 1E21 1E12 Dynamic SIMS The EAGLABSSM Bubble Chart ©2013 Evans Analytical Group 0.1 nm SEM (with EDS) Scanning Electron Microscopy Imaging, elemental identification B-U 0.1 % Yes Energy Dispersive X-ray Spectroscopy TEM (with EDS and EELS) Transmission Electron Microscopy Energy Dispersive X-ray Spectroscopy Electron Energy Loss Spectroscopy STEM/ EELS 1E22 50nm to 1µm 1nm imaging; ~80nm minimum grain size 0.1ppm - 50% STEM (with EDS and EELS) Scanning Transmission Electron Microscopy Energy Dispersive X-ray Spectroscopy Electron Energy Loss Spectroscopy OP RTX SEM 1.5 – 5nm Grain size, grain orientation, grain n/a n/aYes misalignment, % crystallinity IGA Bulk analysis of H, C, N, O and S, H, C, N, O, S Instrumental Gas Analysis (Combustion and fusion gas analysis) fractional gas analysis SIMS Secondary Ion Mass Spectrometry EBIC FTIR 1ppm wt - 100% ua nunq U Surface, particle, defect analysis, and large Li - U and small area depth profiling n/a Imaging Techniques AFM FIB n/aYes ICP-OES Inductively Coupled Plasma Bulk composition analysis Li - U Optical Emission Spectroscopy Raman Raman Spectroscopy TEM/STEM 5E22 GDMS Bulk analysis: trace and ultra-trace elemental Li - U Glow Discharge Mass Spectrometry survey analysis, depth profiling OP Optical Profilometry ≥1mm TGA/DTA/DSC 16 EBIC Electron Beam Induced Current n/a No Analytical Resolution versus Detection Limit 1 nm 10 nm 100 nm 1 μm IGA Auger Auger Electron Spectroscopy Roughness, 3-dimensional imaging of surfaces, magnetic field, grain size RBS 0.001 – 10at% (Z dependent) NRA > 1 x 1015 at/cm2 HFS 0.1at% Lateral Resolution/ Probe size ICP techniques 10 Thin film composition/thickness, quantitative B - U (RBS) dose measurement, quantitation without B, N, O, C (NRA) 1 standards, hydrogen in thin films, defects H, 2H (HFS) and lattice locations Imaging/ Mapping GC-MS 5 AFM Atomic Force Microscopy H 17 Detection Limits 10 μm Analytical Spot Size 100 μm 1 mm 10 ppt 1 cm Bulk Techniques GDMS Ox n roge elium rine o u l F ygen Elements Detected th ep D g in th pl ep m th D g Sa ep in D pl nm g .3 m in pl Sa r0 m fo nm Sa it 3 m lim or f 0n al it ic r3 lim ys fo al it Ph c i lim ys al Ph ic ys Ph N Accelerator Techniques Rutherford Backscattering Spectrometry Nuclear Reaction Analysis Hydrogen Forward Scattering Spectrometry Channeling e N F O Typical Applications He 17 VIIA 9 16 VIA 8 Analytical Technique Detection Range Atoms/cm3 18 A VIII 2 Grou p 1 IA 1 H 1 Hydro gen 3 The services we provide include dopant and impurity depth profiling, thin film and coating analysis, bulk composition and impurity analysis, materials characterization, failure analysis, characterization of particles, defects and residues, crystal structure determination, roughness measurement and the investigation of thermal properties. Lithiu 3 19 Na M g m Magn esium 20 3 IIIB 13 IIIA 4 IVB 18 VIIIA 14 IVA 2 5 15 5 K C 21 22 6 VB VA 16 6 a Sc 7 23 VIB VIA H 17 7 B e 8 V 2 V 37 4 I I I 8 I B A Ti V C 9 25 38 9 N 5 10 1 2 V 3 3 1 6 III 0 Cr M Rb S 9 40 O 14 27 11 F n Fe r Y 1 28 5 41 IB 12 N A e l 1 2 IIB 6 42 55 9 C S Z o i r 17 30 43 56 N N P 6 b Mo i Cu 18 31 44 S Cs B 32 45 72 C Z T n c l a 33 46 73 A G R r a u 3 47 7 4 87 G 4 R Hf T e h 35 48 75 88 A P s d a 36 49 76 S A W Fr R e g Cd 50 77 104 B R r e a 5 7 105 1 8 K O I r n s 5 7 1 2 9 0 S 6 Rf D n Sb Ir P 53 80 107 b Sg t Au 54 81 108 T e 82 Hg Bh H 109 110 I 83 X T e s M l 8 111 4 P b B t Uu 85 112 i Po 86 nUu 114 uUu At R b n 116 Uu Potas sium Chemir: Providing in-depth analytical investigations and litigation support for a wide variety of industries, including paints, coatings, plastics and consumer products. Calci um Release to Production: Providing electronic testing services to the electronics and communications industries. agrosciences: Providing analytical chemistry, environmental fate and metabolism services for agrochemicals. Rubid ium Life Sciences: Providing regulated analytical and research/development services to the pharmaceutical and medical device industries. Cesiu m Stron tium Scan dium Yttriu m m nium Vana d ium Niobi um Tanta lu m Tung st en Radiu m Ruthe rfordi um Dubn ium ium M anga nese denu m Seab orgiu m Heliu m Carbo n Nitrog en Chrom Molyb Bariu um ium Titan iu Zirco Hafni Franc Boron m Te Coba lt ium R uthen ium Rhod ium ium um inum Nicke l Copp er chnet Rhen Bohri Iron Alum Osmi Hass um ium Meitn Iridium erium Palla dium Platin Unun um nilium Silver Unun Gold unium Zinc Galliu m Cadm ium Merc ury Indium Thalli um Lead bium Unun quad n anium Tin Unun Silico Germ q ium Phos phoru Arsen ic Antim ony Bism uth s Oxyg en Sulfu r Selen ium Tellur iu m Polon ium Uuh Unun hexiu Typical Analysis Depths for Techniques 4 The other divisions of EAG provide additional services, allowing us to meet a larger range of customer needs across many industries. 7 lium 12 Sodiu Our analytical staff is highly qualified, knowledgeable and very experienced. Over half of our scientists have advanced degrees in a variety of disciplines, from universities across the globe. The diversity of disciplines (e.g. chemistry, physics, materials science and engineering) enables us to skillfully address materials issues from a wide variety of industries. Beryl plasma Evans Analytical Group m 11 We characterize materials directly for you; we don’t make or sell instruments! Our scientists use our instruments to the limits of their performance to directly help you solve your problems. Our People 4 Li B e 2 Our Services 2 IIA m ine ine Chlor ine Brom Iodine Astat Fluor ine on n Rado n Argon Krypt Xeno Neon