Test 1 Practice Problems Fill in the blank for the phase changes below: Describe the properties of each of Solid __________________________ Gas the states of matter. Liquid __________________________ Solid Gas Solid: __________________________ Solid Liquid __________________________ Gas Liquid: Solid __________________________ Liquid Gas __________________________ Liquid Gas: Label each as a heterogeneous or homogeneous mixture. Salt water ___________________________ Brewed tea/coffee ___________________________ Oil and water ___________________________ Dilute HCl solution ___________________________ Carbonated beverage ___________________________ Sandy water ___________________________ Blood ___________________________ Name three examples of pure substances. 1. _____________________________ 2. _____________________________ 3. _____________________________ Label each as a compound, a molecule, or an atom (put two if applicable). H2O _____________________________ Au _____________________________ CO2 _____________________________ H2 _____________________________ Ne _____________________________ Name all 7 diatomic molecules. Name three physical properties and three chemical properties Label each property below as intensive or extensive. Density ____________________________ Color ____________________________ Mass ____________________________ Boiling point ____________________________ Volume ____________________________ Enthalpy ____________________________ Define physical and chemical changes providing one example of each. Name the three methods of separation from lecture and what they separate (Ex. homogeneous mixtures). 1. ______________________________________________ 2. ______________________________________________ 3. ______________________________________________ Convert the following temperatures: 32˚F _________________˚C 42˚C _________________K 376 K _________________˚C 200 K _________________˚F Calculate the values for the density problems below: Mass = 24.5 g Volume = 4.67 mL Density = 12.10 g/mL Mass = 46.07 g Density = ? Volume = 2.3 mL Density = 3.08 g/mL Mass = ? Volume = ? Convert the following: 25 kilometers ________________________ nanometers 3.74 millimeters ________________________ gigameters 400 petagrams __________________________ grams 0.078 femtometers ________________________ millimeters 16.2 liters ____________________________ microliters Write the number of significant figures in each example below: 0.0032 _____________ 1.0462 _____________ 203 _____________ 402,000 _____________ 6,000. _____________ 0.000005 _____________ Reduce the following examples to the specified number of significant figures. 1.067 to 2 sig figs ________________________ 670,000. to 2 sig figs ________________________ 0.034 to 1 sig fig ________________________ 22.3 to 2 sig figs ________________________ 56.45 to 3 sig figs ________________________ 7.35752 to 4 sig figs ________________________ Complete the following calculations with the correct number of significant figures. 20.42 – 18.3 + 2.36 = _________________________ 5.78 x 11.4 x 3.2 = _________________________ (4.31 + 6.88) / 2.5 = _________________________ 12.02 x (7.0 – 4.33) = _________________________ Convert the following values using dimensional analysis. 17 miles inches (5280 ft = 1 mi) 1200 m/s km/hr 1 year seconds Complete the table below: Protons Neutrons Electrons Ne Fe2+ 37 Cl 35 Cl O2Complete the following average atomic mass problems. Rubidium is a soft, silvery-white metal that has two common isotopes, 85Rb and 87Rb. If the abundance of 85Rb is 72.2% and the abundance of 87Rb is 27.8%, what is the average atomic mass of rubidium? Uranium is used in nuclear reactors and is a rare element on earth. Uranium has three common isotopes. If the abundance of 234U is 0.01%, the abundance of 235U is 0.71%, and the abundance of 238U is 99.28%, what is the average atomic mass of uranium? Titanium has five common isotopes: 46Ti (8.0%), 47Ti (7.8%), 48Ti (73.4%), 49Ti (5.5%), 50 Ti (5.3%). What is the average atomic mass of titanium? Label each of the following as ionic or molecular. H2O _______________________ NaCl _______________________ CO2 _______________________ Fe2O3 _______________________ C6H12O6 ______________________ Reduce the following molecular formulas to empirical formulas. C6H12O6 ___________________ C5H5 ___________________ C2H6 ___________________ Determine the charges of the following ions: Cl ________________ O ________________ Na ________________ Ca ________________ N ________________ PO4 ________________ Al ________________ Write the chemical formulas for the compounds made from the ions below: Mg2+ + N3- ______________________ Ca2+ + Cl- ______________________ NH4+ + SO42- _____________________ Na+ + Cl- ______________________ Al3+ + O2- ______________________ Fe2+ + O2- ______________________ Write the two ions that compose each of the following compounds: Mg(OH)2 ______________________ CaCO3 ______________________ Li2O ______________________ Name the following compounds, or write the formula from the given name: Sodium chloride _________________________ KOH _________________________ CaCO3 _________________________ Fe2O3 _________________________ Calcium sulfite _________________________ CO2 __________________________ Mg3N2 __________________________ Carbon tetrachloride __________________________ CuSO4 __________________________ CO __________________________ Dinitrogen pentoxide __________________________ HBr __________________________ Ammonium chloride __________________________ Iron (II) oxide __________________________ Pb(NO3)2 ______________________________ Ba(OH)2 ______________________________ Sodium sulfate ______________________________ (NH4)3PO4 ______________________________ Lithium carbonate ______________________________ Iron (II) oxide ______________________________ Balance the following reactions. _____CH4 + _____O2 _____CO2 + _____H2O _____Ca + _____N2 _____Ca3N2 _____NH3 _____N2 + _____H2 _____Al + _____O2 _____Al2O3 _____Na + _____H2O _____NaOH + _____H2 _____NaHCO3 _____Na2CO3 + _____CO2 + _____H2O _____KIO3 _____KI + _____O2 _____Fe + _____O2 _____Fe2O3 _____Fe2O3 + _____Al _____Al2O3 + _____Fe _____P4 + _____Cl2 _____PCl3 _____H2 + _____O2 _____H2O _____P4 + _____O2 _____P2O5 _____P2O5 + _____H2O _____H3PO4 _____NaH + _____BF3 _____B2H6 + _____NaF _____Fe3O4 + _____CO _____Fe + _____CO2 Classify the following reactions as combination, decomposition, or combustion reactions. 2H2O2 2H2O + O2 __________________________________ 2Na + Cl2 2NaCl __________________________________ Mg + F2 MgF2 __________________________________ 2C2H6 + 7O2 4CO2 + 6H2O __________________________________ 2NI3 N2 + 3I2 __________________________________ 2C8H18 + 25O2 16CO2 + 18H2O __________________________________ Write the balanced chemical reaction for the following examples. Methanol (CH3OH) burns in excess oxygen gas. Solid sodium is added to iodine vapor. Magnesium metal is burned in oxygen gas. Molten aluminum chloride is electrolyzed (decomposed). Solid calcium carbonate is heated to decomposition. Propane (C3H8) combusts in air. Find the formula/molecular weight of the following compounds. LiF __________________________ CaCO3 __________________________ Na2SO4 __________________________ NH4NO3 __________________________ C6H12O6 __________________________ C2H5OH __________________________ HClO3 __________________________ Sr(OH)2 __________________________ Find the percent composition of each of the elements in the following compounds. NaCl Na: __________________________ Cl: __________________________ C4H10 C: __________________________ H: __________________________ K2CO3 K: __________________________ C: __________________________ O: __________________________ Ag2SO4 Ag: __________________________ S: __________________________ O: __________________________ C12H22O11 C: __________________________ H: __________________________ O: __________________________ HBr H: __________________________ Br: __________________________ Solve the following problems using stoichiometric calculations. Convert 3.5 grams of NaCl to molecules of NaCl. How many atoms of hydrogen are in 4.28 grams of (NH4)2SO4? How many grams of CaCO3 are in 0.784 moles of CaCO3? How many grams of phosphorus are in 22.3 grams of P2O5? How many grams of water can be made with 3.17 grams of hydrogen gas in excess oxygen gas? 2H2 + O2 2H2O Solve the following problems for the specified empirical and/or molecular formula. Find the empirical formula for a compound which contains 32.8% chromium and 67.2% chlorine. What is the empirical formula for a compound which contains 67.1% zinc and the rest is oxygen? The empirical formula of a substance is CH2O. The molar mass is 180g/mol, what is the molecular formula? A compound containing 5.9265% H and 94.0735% O has a molar mass of 34.01468 g/mol. Determine the empirical and molecular formula of this compound. What is the empirical formula for a compound which contains 0.0134g of iron, 0.00769g of sulfur, and 0.0115g of oxygen? What is the molecular formula if the molar mass is 407.55g/mol? Solve the following limiting reactant problems. If 13.2 grams of nitrogen and 17.0 grams of hydrogen are used, how many grams of ammonia can be made? N2 + 3H2 2NH3 How much carbon dioxide in grams can be produced by combusting 14.5 grams of octane (C8H18) in a controlled 25 gram amount of oxygen gas? 2C8H18 + 25O2 16CO2 + 18H2O How much of the excess reactant in grams is left over when reacting 4.96 grams of nitric acid with 7.28 grams of barium hydroxide? 2HNO3 + Ba(OH)2 Ba(NO3)2 + 2H2O How many moles of salt can be produced by reacting 42 moles each of solid sodium and chlorine gas? 2Na + Cl2 2NaCl Calculate the percent yield for each of the following problems. *Be aware that you may need to find the limiting reactant first if not otherwise specified. If 25 grams of iron (III) phosphate reacts with excess sodium sulfate, how many grams of iron (III) sulfate can be produced? If 18.5 grams are actually produced, what is the percent yield? 2FePO4 + 3Na2SO4 Fe2(SO4)3 + 2Na3PO4 If 30 grams of ammonium nitrate reacts with 50 grams of sodium phosphate, how many grams of sodium nitrate will form? If 28.3 grams is synthesized in lab, what is the percent yield? 3NH4NO3 + Na3PO4 (NH4)3PO4 + 3NaNO3 If 100 grams of calcium carbonate reacts with 45 grams of iron (II) phosphate, how many grams of calcium phosphate can be made? If we obtain 78% yield, how much was the actual yield? 3CaCO3 + Fe3(PO4)2 Ca3(PO4)2 + 3FeCO3