BIOGEOCHEMICAL CYCLES - The cycle wherein the elements and compounds that make up nutrients move continually through air, water, soil, rocks and living organisms within ecosystems. - Life-earth-chemical cycles or nutrient cycles. WATER CYCLE Water is an amazing substance that is necessary for life on the earth and there is a fixed supply of it in our planet. The hydrologic or water cycle, collects, purifies, and distributes this supply of water. The water cycle is a continuous movement of water from the atmosphere to the earth and from the earth back to the atmosphere. Four major processes: 1. Evaporation – changes liquid water into water vapor in the atmosphere. 2. Condensation – the process by which water vapour in air cools and condenses into droplets of water forming clouds. 3. Precipitation – movement of water from the atmosphere to the earth. 4. Transpiration – the loss of water from plants due to evaporation. Human beings alter the water cycle by withdrawing large quantities of freshwater faster than it can be replaced and by clearing the vegetation. We also cover land with buildings and pavement, which reduces the recharge of aquifers by holding water above ground and increase runoff, which in turns increases flooding and soil erosion. CARBON CYCLE Role of Carbon 1. Carbon is a major building block in organisms as it is a component of carbohydrates, fats, proteins, ATP, and nucleic acids. 2. Carbon forms carbon dioxide (CO2), a component of the atmosphere which acts as a major storage “bank” for the recycles carbon in the biosphere. 3. Carbon dioxide enters the plant body as a raw material for photosynthesis. 4. Carbon is stored in the earth’s crust, in the limestone shells of marine organisms, and as fossil fuels or deposits of coal, oil, and natural gas. Role of Oxygen 1. Oxygen is one of life’s building blocks. About every fourth atom in the body of an organism is an oxygen atom. 2. Oxygen serves as an acceptor of hydrogen atoms in the respiration process. 3. Together with hydrogen atoms, oxygen forms water molecules during respiration. 4. Oxygen enables heterotrophic cells to transform energy through oxidation of food materials. Processes involved: - Photosynthesis – use of CO2 along with water and the sun’s energy to produce glucose and release O2. - Respiration – both plants and animals use O2 to breakdown glucose. The by products are carbon dioxide and water. - Decomposition – process by which organisms like bacteria break down the tissues and excretions of other organisms to simple substances. This process of decay releases carbon dioxide from the compounds retained in the bodies of organisms when they die. Human beings are altering the carbon cycle mostly by adding large amounts of carbon dioxide to the atmosphere when we burn carbon-containing fossil fuels and clear carbon-absorbing vegetation forests (especially tropical forests) faster than it can grow back. NITROGEN CYCLE - Involves green plants and several kinds of bacteria, and may or may not involve animals. - the major reservoir for nitrogen is the atmosphere. Chemically unreactive nitrogen makes up 78% of the volume of the atmosphere. Nitrogen is crucial component of proteins, many vitamins, and nucleic acids such as DNA (deoxyribonucleic acid ). However, N2 cannot be absorbed and used directly as a nutrient by plants and animals. - Two natural processes convert or fix N2 into compounds that can be used as nutrients – electrical discharges or lightning taking place in the atmosphere and nitrogen-fixing bacteria. Processes involved: 1. Ammonification. The process of releasing ammonia (NH3) from decaying protein by means of bacterial action. 2. Nitrification. The action of a group of bacteria on ammonia, producing nitrates (NO3). 3. Denitrification. This process is carried out by denitrifying or anaerobic bacteria which breaks down ammonia, nitrates, and nitrites (NO2), liberating free nitrogen. 4. Nitrogen Fixation. This refers to the process by which bacteria in the soil or in the roots or leguminous plants converts free N2 into compounds that the plants can use. Human beings have more than doubled the annual release of nitrogen from the land into the rest of the environment. Most of this is from the greatly increased use of inorganic fertilizer to grow crops. A problem brought about by human input is eutrophication – a process by which lakes or any freshwater ecosystems slowly become shallow by the accumulation of dead plant materials. In such a process, as contaminants are dumped into the body of water, there is an increased quantity of nitrate or phosphate ions causing a rapid multiplication of algae population. The condition in which the algae either cover the water of color it with their presence is called algal bloom. Algal bloom increases the number of decomposers which use up the oxygen needed by other animals as well as other decomposers. As an effect, the water animals and the decomposers die, accumulating at the bottom of the body of water. PHOSPHORUS CYCLE The major reservoir for phosphorus is phosphate salts containing phosphate ions (PO4-3) in terrestrial rock formation and ocean bottom sediments. The phosphorus cycle is slow as compared to to other cycles and does not include the atmosphere. As water runs over exposed phosphorus-containing rocks, it slowly erodes away inorganic compounds that contain phosphate ions. The dissolved phosphate can be absorbed by the roots of plants and by other producers. Phosphorus is transferred by food webs from producers to consumers, eventually including detritus feeders and decomposers. Phosphorus can be lost from the cycle for long periods when it washes from the land into streams and rivers and is carried to the ocean. There it can be deposited as marine sediments and remain trapped for millions of years. Someday, geological processes may uplift and expose these seafloor deposits from which phospahet cn be eroded to start the cycle again. Human activities are affecting the phosphorus cycle which includes removing large amounts of phosphate from the earth to make fertilizer and reducing phosphorus in tropical soils by clearing forests. Soil that is eroded from fertilized crop fields, lawns, and golf courses carries large quantities of phosphates into streams, lakes and oceans where it stimulates the growth of producers. Phosphorus-rich run-off from the land can produce huge populations of algae, which can upset chemical cycling and other processes in lakes. SULFUR CYCLE Sulfur enters the atmosphere - as hydrogen sulfide, a colorless gas, highly poisonous gas with a rotten-egg smell and as sulfur dioxide, a colorless and suffocating gas. Both gases are released by volcano. Particles of sulphate enters the atmosphere from sea spray, dust storms and forest fires. Plant roots absorb sulphate ions and incorporate sulphur as an essential component of proteins. Specialized bacteria converts sulphate ions to sulphide ions. Sulfide ions can react with metal ions to form insoluble metallic sulfides which are deposited as rocks or metal ores and the cycle continues. Human activities have affected the sulfur cycle primarily by releasing large amounts of sulfur dioxide into the atmosphere. Ways of adding sulfur dioxide into the atmosphere: Burning of sulphur-containing coal and oil to produce electric power. Refining sulfur-containing petroleum to make gasoline. Conversion of sulfur-containing metallic mineral ores into free metals such as copper, lead and zinc.