Revising Unit 1 Chemistry Atomic Structure Learning Objectives Answer 1.1: Describe how the Dalton model of the atom has changed over time because of the discovery of subatomic particles ● Dalton thought that atoms were _________ ● described atoms as______ ________, ● modern ideas about atoms suggest atoms are made up of ________ particles such as protons _______ and _________. Protons solid spheres smaller indestructible neutrons 1.2 Draw the structure of the atom as nucleus containing protons and neutrons, surrounded by electrons in shells. 1.3 Recall the relative charge and relative mass of a: a proton, b: a neutron & c: an electron Particle Mass ChargeRelative mass Relative crge Proton Neutron Electron 1.4 Explain why atoms contain equal numbers of protons and electrons. Atoms are _______ - they have no charge overall The charge on electrons is the same size as the charge on the ______- these charges cancel out. This is why atoms contain the ______ number of protons as electrons. Same 1.5 Describe the nucleus of an atom as very small compared to the overall size of the atom 1.6 Recall that most of the mass of an atom is concentrated in the nucleus. protons neutral The nucleus: is in the _________of the atom. It contains _______ and _______. It has a _______ charge because of the _______. It has almost the whole _______ (of the atom) concentrated in the nucleus (1.6) It is _______ compared to the overall size of the atom Tiny mass protons positive neutrons centre 1.7 Recall the meaning of the term mass number of an atom 1.8 Describe atoms of a given element as having the same number of protons in the nucleus and that this number is unique to that element The atomic number tells you how many protons/neutrons an atom has. Every atom of an element has the same number of protons/neutrons. 1.9 Describe isotopes as different atoms of the same element containing the same number of protons but different numbers of neutrons in their nuclei Isotopes are different forms of the same element which have: the same atomic number (number of neutrons /protons) different mass numbers (different numbers of protons /neutrons) 1.10 Calculate the numbers of protons, neutrons and electrons in atoms given the atomic number and mass number Number of protons (same as atomic number) =___ In any atom: No. of protons =No. of electrons Hence, no. of electrons = ____ No. of neutrons = mass no. – atomic no. = 1.11 Explain how the existence of isotopes results in relative atomic masses of some elements not being whole numbers 1.12 Calculate the relative atomic mass of an element from the relative masses and abundances of its isotopes [Higher only] If an element has more than one isotope, its mass no. is the average of the mass numbers of all the different isotopes, taking into account how much there is of each one. So, it might not be a whole number. Eg., chlorine has two stable isotopes, chlorine-35 and chlorine-37. There’s quite a lot of chlorine-35 around and not so much chlorine-37 — so chlorine’s mass no. works out as 35.5. Chlorine naturally exists as two isotopes, and (chlorine-35) (chlorine-37). The abundance of chlorine-35 is 75% and the abundance of chlorine-37 is 25%. To calculate the relative atomic mass, Ar, of chlorine: (to 1 decimal place) Note. The answer is closer to 35 than it is to 37. This is because the chlorine-35 isotope is much more abundant than the chlorine-37 isotope. 1.13 Describe how Mendeleev arranged the elements, known at that time, in a periodic table by using properties of these elements and their compounds Sorted elements (and their compounds) with similar ________ properties into groups, In order of atomic______, this showed a _________ mass chemical pattern 1.14 Describe how Mendeleev used his table to predict the existence and properties of some elements not then discovered 1.15 Explain that Mendeleev thought he had arranged elements in order of increasing relative atomic mass but this was not always true because of the relative abundance of isotopes of some pairs of elements in the periodic table Mendeleev ______ the chemical and physical properties of an element he called_______, which we know today as germanium. Ekasilicon predicted Mendeleev ordered elements by decreasing /increasing atomic mass but he was wrong (due to the presence of_________ ) which he did not know about some elements just didn’t quite fit the pattern he ________ the order of the elements to keep those with the ______ properties in the same columns switched isotopes same Eg., Iodine has a lower relative atomic mass than tellurium. So iodine should be placed before tellurium in Mendeleev's table. However, iodine has similar chemical properties to chlorine and bromine. To make iodine line up with chlorine and bromine in his table, Mendeleev swapped the positions of iodine and tellurium. iodine and tellurium were reversed in Mendeleev's table because: iodine has one naturally occurring isotope, iodine-127 the most abundant tellurium isotopes are tellurium-128 and tellurium-130 The high relative abundance of these tellurium isotopes gives tellurium the greater relative atomic mass. The atomic number of tellurium is 52 and the atomic number of iodine is 53, so these elements are in the correct order in the modern periodic table. 1.16 Explain the meaning of atomic number of an element in terms of position in the periodic table and number of protons in the nucleus atomic number of an atom is the number of _______ it contains All the atoms of a particular element have the _____ atomic number (number of protons) atoms of different elements have _____ numbers of protons. Different protons same 1.17 Describe that in the periodic table a. elements are arranged in order of increasing atomic number, in rows called periods b. elements with similar properties are placed in the same vertical columns called groups In the periodic table the elements are arranged into: a. Rows, called _____, are organised in order of increasing atomic _____ - the period to which the element belongs corresponds to the number of _____ of electrons it has. b. Vertical columns, called _______, where the elements have _______ properties Shells 1.18 Identify elements as metals or nonmetals according to their position in the periodic table, explaining this division in terms of the atomic structures of the elements similar periods number group In the modern periodic table, the elements are arranged according to their atomic number - not their relative atomic _____. The metal elements are found on the _____ hand side of the periodic table, and the non-metal elements are found on the _____. Right 1.19 Predict the electronic configurations of the first 20 elements in the periodic table as diagrams and in th e form, for examp le 2.8.1 mass left Predicting an electronic configuration The electronic configuration of an atom can be predicted from its atomic number. For example, the atomic number of sodium is 11. Sodium atoms have 11 protons and so 11 electrons: The electronic configuration of sodium (2.8.1) shows that sodium, Na: is in period __ is in group __ has an atomic number of ___ 1 1.20 Explain how the electronic configuration of an element is related to its position in the periodic table 3 11 An electronic configuration is the way in which electrons are _____ in an atom. Electrons in shells Different shells can hold ________ numbers of electrons. Electrons occupy shells starting with the __________one. They begin to occupy the next shell when a shell becomes______. Full innermost different arranged