MEASURING RATES DURING A REACTION Background Magnesium reacts with hydrochloric acid and gives off hydrogen gas. A graph of volume of hydrogen produced against time can be used to measure the rate at different points of the reaction. Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g) Aim You are going to react magnesium with hydrochloric acid in order to see how the rate changes during the reaction. Safety Hydrochloric acid is an irritant. Hydrogen and magnesium are flammable. There should be no naked flames in the laboratory. Method 3 1) Measure out 10 cm of hydrochloric acid using a measuring cylinder and place into a boiling tube in a rack. 2) Set up a syringe using a clamp and a stand. 100 cm3 syringe 3) Cut a 4 cm length of magnesium ribbon. Rub the surface down with emery / sandpaper. Fold it loosely in half. reaction in boiling tube hydrochloric acid 4) Add the magnesium ribbon to the hydrochloric acid, attaching the delivery tube straight away and starting the timer magnesium 5) Record the volume of gas every 10 seconds for 2 minutes in the table. Results Time (s) 0 10 20 30 40 50 60 70 80 90 100 110 120 Volume (cm3) 140 1) Plot a graph of the gas volume against time. 2) Draw tangent to the line at 0 and 30 seconds to find the gradient and so rate of reaction at each point. Remember how to find the gradient: For example, at 30 seconds: 3 Change in y = 140 – 52 = 88 = 1.5 cm /s Change in x 60 – 0 60 120 100 Volume (cm3) Analysis 140 – 52 3 = 88 cm + 80 60 60 – 0 = 60 s 40 20 0 0 20 40 60 80 100 Time (s) © www.CHEMSHEETS.co.uk 20-February-2017 Chemsheets GCSE 1165 rate at 0 seconds rate at 30 seconds Describe how the rate changes during the reaction. Explain, using collision theory, why the rate changes ………………………………………..…………………………………………………………………………………………………………………….... …………………………………………..………………………………………………………………………………………………………………….... ………………………………………..…………………………………………………………………………………………………………………….... Explain, using collision theory, why the reaction eventually stops. ………………………………………..…………………………………………………………………………………………………………………….... …………………………………………..………………………………………………………………………………………………………………….... © www.CHEMSHEETS.co.uk 20-February-2017 Chemsheets GCSE 1165