Stoich Practice Test Multiple Choice Identify the choice that best completes the statement or answers the question. ____ 1. Which branch of chemistry deals with the mass relationships of elements in compounds and the mass relationships among reactants and products in chemical reactions? a. qualitative analysis c. chemical kinetics b. entropy d. stoichiometry ____ 2. Which of the following would not be studied in the branch of chemistry called stoichiometry? a. the mole ratio of aluminum and chlorine in aluminum chloride b. the amount of energy required to break the ionic bonds in calcium fluoride c. the mass of carbon produced when a known mass of sucrose decomposes d. the number of moles of hydrogen that reacts completely with a known quantity of oxygen ____ 3. The coefficients in a chemical equation represent the a. masses, in grams, of all reactants and products. b. relative numbers of moles of reactants and products. c. number of atoms in each compound in a reaction. d. number of valence electrons involved in the reaction. ____ 4. Each of the four types of reaction stoichiometry problems requires using a a. table of bond energies. c. Lewis structure. b. chart of electron configurations. d. mole ratio. ____ 5. Which equation is not balanced? a. b. ____ 6. Given the equation , the starting mass of A, and its molar mass, and you are asked to determine the moles of C produced, your first step in solving the problem is the multiply the given mass of A by a. c. b. ____ c. d. 7. The units of molar mass are a. g/mol. b. mol/g. d. c. amu/mol. d. amu/g. ____ 8. In the reaction represented by the equation N2 + 3H2 2NH3, what is the mole ratio of nitrogen to ammonia? a. 1:1 c. 1:3 b. 1:2 d. 2:3 ____ 9. In the equation 2KClO3 2KCl + 3O2, how many moles of oxygen are produced when 3.0 mol of KClO3 decompose completely? a. 1.0 mol c. 3.0 mol b. 2.5 mol d. 4.5 mol ____ 10. For the reaction represented by the equation 2H2 + O2 2H2O, how many moles of water can be produced from 6.0 mol of oxygen? a. 2.0 mol c. 12 mol b. 6.0 mol d. 18 mol ____ 11. For the reaction represented by the equation AgNO3 + NaCl NaNO3 + AgCl, how many moles of silver chloride, AgCl, are produced from 7.0 mol of silver nitrate AgNO3? a. 1.0 mol c. 7.0 mol b. 2.3 mol d. 21 mol Use the table below to answer the following questions. Element Bromine Calcium Carbon Chlorine Cobalt Copper Fluorine Hydrogen Iodine Iron Lead Magnesium Mercury Nitrogen Oxygen Potassium Sodium Sulfur Symbol Br Ca C Cl Co Cu F H I Fe Pb Mg Hg N O K Na S Atomic Mass 79.90 40.08 12.01 35.45 58.93 63.55 19.00 1.01 126.90 55.85 207.2 24.30 200.59 14.01 15.00 39.10 22.99 32.01 ____ 12. For the reaction represented by the equation 2Na + 2H2O 2NaOH + H2, how many grams of sodium hydroxide are produced from 3.0 mol of sodium with an excess of water? a. 40. g c. 120 g b. 80. g d. 240 g ____ 13. For the reaction represented by the equation 2Fe + O2 2FeO, how many grams of iron(II) oxide are produced from 8.00 mol of iron in an excess of oxygen? a. 71.8 g c. 712 g b. 575 g d. 1310 g ____ 14. For the reaction represented by the equation 2HNO3 + Mg(OH)2 Mg(NO3)2 + 2H2O, how many grams of magnesium nitrate are produced from 8.00 mol of nitric acid, HNO3, and an excess of Mg(OH)2? a. 148 g c. 593 g b. 445 g d. 818 g ____ 15. For the reaction represented by the equation Pb(NO3)2 + 2KI PbI2 + 2KNO3, how many moles of lead(II) iodide are produced from 300. g of potassium iodide and an excess of Pb(NO3)2? a. 0.904 mol c. 3.61 mol b. 1.81 mol d. 11.0 mol ____ 16. For the reaction represented by the equation 3Fe + 4H2O Fe3O4 + 4H2, how many moles of iron(III) oxide are produced from 500. g of iron in an excess of H2O? a. 1.04 mol c. 8.95 mol b. 2.98 mol d. 12.98 mol ____ 17. For the reaction represented by the equation Cl2 + 2KBr 2KCl + Br2, how many grams of potassium chloride can be produced from 300. g each of chlorine and potassium bromide? a. 98.7 g c. 188 g b. 111 g d. 451 g ____ 18. For the reaction represented by the equation 2Na + Cl2 2NaCl, how many grams of sodium chloride can be produced from 500. g each of sodium and chlorine? a. 112 g c. 409 g b. 319 g d. 824 g ____ 19. Which reactant controls the amount of product formed in a chemical reaction? a. excess reactant c. composition reactant b. mole ratio d. limiting reactant ____ 20. To determine the limiting reactant in a chemical reaction, one must know the a. available amount of one of the reactants. b. amount of product formed. c. available amount of each reactant. d. speed of the reaction. ____ 21. To determine the limiting reactant in a chemical reaction involving known masses of A and B, one could first calculate a. the mass of 100 mol of A and B. b. the masses of all products. c. the bond energies of A and B. d. the number of moles of B and the number of moles of A available. ____ 22. What is the measured amount of a product obtained from a chemical reaction? a. mole ratio c. theoretical yield b. percentage yield d. actual yield ____ 23. For the reaction represented by the equation SO3 + H2O H2SO4, calculate the percentage yield if 500. g of sulfur trioxide react with excess water to produce 575 g of sulfuric acid. a. 82.7% c. 91.2% b. 88.3% d. 93.9% ____ 24. For the reaction represented by the equation CH4 + 2O2 2H2O + CO2, calculate the percentage yield of carbon dioxide if 1000. g of methane react with excess oxygen to produce 2300. g of carbon dioxide. a. 83.88% c. 92.76% b. 89.14% d. 96.78% Completion Complete each statement. 1. If four moles of each reactant are available for the reaction described by the following equation, ____________________ is the substance that is the excess reactant. Short Answer 1. How does the actual yield of a chemical reaction compare to the theoretical yield? 2. Give at least three reasons why the actual yield of a chemical reaction could be less than the theoretical yield. Problem 1. Sulfur in gasoline can produce sulfuric acid, H2SO4, according to the two-step process shown below. For each 125 g of sulfur in gasoline, how many moles of H2SO4 will be produced? 2. Given the reaction represented by the equation Mg + 2HCl H2 + MgCl2, determine to two decimal places the molar masses of all substances involved. Then write the molar masses as conversion factors. 3. What mass is grams of potassium chloride is produced if 100. g of potassium chlorate decompose according to the following equation? 4. What mass of PCl3 forms in the reaction of 75.0 g P4 with 275 g Cl2 ? 5. What mass in grams of sodium hydroxide is produced if 20.0 g of sodium metal react with excess water according to the chemical equation 2Na(s) + 2H2O(l) 2NaOH(aq) + H2(g)? 6. What mass in grams of 1-chloropropane (C3H7Cl) is produced if 400. g of propane react with excess chlorine gas according to the equation C3H8 + Cl2 C3H7Cl + HCl? 7. What mass in grams of hydrogen gas is produced if 20.0 mol of Zn are added to excess hydrochloric acid according to the equation Zn(s) +2HCl(aq) ZnCl2(aq) + H2(g)? 8. How many grams of ammonium sulfate can be produced if 30.0 mol of H2SO4 react with excess NH3 according to the equation 2NH3(aq) + H2SO4(aq) (NH4)2SO4(aq)? 9. How many moles of Ag can be produced if 350. g of Cu are reacted with excess AgNO3 according to the equation Cu(s) + 2AgNO3(aq) 2Ag(s) + Cu(NO3)2(aq)? 10. The reaction of 100. g of salicylic acid, C7H6O3, with excess acetic anhydride produces 50.0 g of aspirin, C9H8O4, according to the equation below. What is the percentage yield for this reaction? 11. In the decomposition of hydrogen peroxide, the percentage yield of oxygen is 93.0%. What is the actual yield in grams of oxygen if you start with 100. g of H2O2? The reaction proceeds according to the equation . 12. In the reaction represented by the equation 2NH3 + CO2 CO(NH2)2 + H20, 30.7 g of CO(NH2)2 forms per 1.00 mol of CO2 that reacts when NH3 is in excess. What is the percentage yield? Essay 1. List the four types of reaction stoichiometry problems and briefly describe how to solve each one. 2. Explain the effect of limiting and excess reactants in an automobile engine that stalls. Stoich Practice Test Answer Section MULTIPLE CHOICE 1. ANS: D PTS: 1 DIF: REF: cde4a936-f97e-11de-9c72-001185f0d2ea 2. ANS: B PTS: 1 DIF: REF: cdebf75d-f97e-11de-9c72-001185f0d2ea 3. ANS: B PTS: 1 DIF: REF: cdee32aa-f97e-11de-9c72-001185f0d2ea 4. ANS: D PTS: 1 DIF: REF: cdf0bc17-f97e-11de-9c72-001185f0d2ea 5. ANS: D PTS: 1 DIF: REF: cdf559c1-f97e-11de-9c72-001185f0d2ea 6. ANS: C PTS: 1 DIF: REF: cdfc80d8-f97e-11de-9c72-001185f0d2ea 7. ANS: A PTS: 1 DIF: REF: ce016ca2-f97e-11de-9c72-001185f0d2ea 8. ANS: B PTS: 1 DIF: REF: ce060a4c-f97e-11de-9c72-001185f0d2ea 9. ANS: D PTS: 1 DIF: REF: ce0d3163-f97e-11de-9c72-001185f0d2ea 10. ANS: C PTS: 1 DIF: REF: ce0f93c0-f97e-11de-9c72-001185f0d2ea 11. ANS: C PTS: 1 DIF: REF: ce121d2d-f97e-11de-9c72-001185f0d2ea 12. ANS: C Solution: I OBJ: 1 II OBJ: 1 I OBJ: 1 I OBJ: 2 II OBJ: 2 I OBJ: 2 I OBJ: 3 III OBJ: 3 III OBJ: 3 III OBJ: 3 III OBJ: 1 PTS: 1 OBJ: 2 13. ANS: B Solution: DIF: III REF: ce16bad7-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 14. ANS: C Solution: DIF: III REF: ce191d34-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 15. ANS: A Solution: DIF: III REF: ce1b7f91-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 3 16. ANS: B Solution: DIF: III REF: ce1e08fe-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 3 17. ANS: C Solution: DIF: III REF: ce22a6a8-f97e-11de-9c72-001185f0d2ea Since Cl2 would produce the most KCl, KBr is the limiting reactant, thus 188 G KCl is produced. PTS: 1 OBJ: 4 18. ANS: D Solution: DIF: III REF: ce276b62-f97e-11de-9c72-001185f0d2ea Since Na would produce the most NaCl, Cl2 is the limiting reactant, thus 824 g NaCl is produced. 19. 20. 21. 22. 23. PTS: 1 DIF: III REF: OBJ: 4 ANS: D PTS: 1 DIF: REF: ce2c572c-f97e-11de-9c72-001185f0d2ea ANS: C PTS: 1 DIF: REF: ce30f4d6-f97e-11de-9c72-001185f0d2ea ANS: D PTS: 1 DIF: REF: ce335733-f97e-11de-9c72-001185f0d2ea ANS: D PTS: 1 DIF: REF: ce381bed-f97e-11de-9c72-001185f0d2ea ANS: D Solution: ce29cdbf-f97e-11de-9c72-001185f0d2ea I OBJ: 1 II OBJ: 1 I OBJ: 1 I OBJ: 3 PTS: 1 OBJ: 4 24. ANS: A Solution: DIF: III REF: ce3f4304-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 4 DIF: III REF: ce41cc71-f97e-11de-9c72-001185f0d2ea DIF: I REF: ce4db842-f97e-11de-9c72-001185f0d2ea COMPLETION 1. ANS: silicon dioxide (SiO2) silicon dioxide SiO2 PTS: 1 OBJ: 1 SHORT ANSWER 1. ANS: The actual yield is always less than the theoretical yield. PTS: 1 DIF: II REF: ce658fe4-f97e-11de-9c72-001185f0d2ea OBJ: 3 2. ANS: The actual yield could be less than a theoretical yield for these reasons: reactants may form by-products in competing side reactions, reactants may contain impurities, and reactions may not go to completion. PTS: 1 OBJ: 3 DIF: II REF: ce6a2d8e-f97e-11de-9c72-001185f0d2ea PROBLEM 1. ANS: 3.90 mol H2SO4 PTS: 1 DIF: III REF: ce6a549e-f97e-11de-9c72-001185f0d2ea OBJ: 2 2. ANS: Mg: 24.30 g/mol; HCl: 36.46 g/mol; H2 : 2.02 g/mol; MgCl2. 95.20 g/mol. Conversion factors: PTS: 1 OBJ: 4 3. ANS: 60.8 g KCl DIF: II PTS: 1 DIF: III OBJ: 4 4. ANS: Assuming that P4 is the limiting reagent: REF: ce6c8feb-f97e-11de-9c72-001185f0d2ea REF: ce6ef248-f97e-11de-9c72-001185f0d2ea Assuming that Cl2 is the limiting reagent: Since the smaller amount of product is formed from P4, it is the limiting reagent. The mass of product formed is: PTS: 1 OBJ: 1 5. ANS: 34.8 g NaOH DIF: III REF: ce6f1958-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 6. ANS: 712 g C3H7Cl DIF: III REF: ce7154a5-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 7. ANS: 40.4 g H2 DIF: III REF: ce717bb5-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 8. ANS: 3960 g (NH4)2SO4 DIF: III REF: ce73b702-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 9. ANS: 11.0 mol Ag DIF: III REF: ce76195f-f97e-11de-9c72-001185f0d2ea DIF: III REF: ce76406f-f97e-11de-9c72-001185f0d2ea DIF: II REF: ce787bbc-f97e-11de-9c72-001185f0d2ea PTS: 1 OBJ: 2 10. ANS: PTS: 1 OBJ: 4 11. ANS: PTS: 1 DIF: II OBJ: 4 12. ANS: First find the theoretical yield: PTS: 1 OBJ: 4 DIF: III REF: ce7ade19-f97e-11de-9c72-001185f0d2ea REF: ce7b0529-f97e-11de-9c72-001185f0d2ea ESSAY 1. ANS: For all types, start with a balanced chemical equation. In the first type, both given and unknown quantities are expressed in moles. There is one conversion factor used to solve it. In the second type, the given quantity is expressed in moles and the unknown is in grams. Two conversion factors are needed. The third type has a given quantity in grams and an unknown amount in moles. This type of problem also requires two conversion factors. The last type has both the given and the unknown as masses. Three conversion factors are needed. PTS: 1 DIF: II REF: ce7d4076-f97e-11de-9c72-001185f0d2ea OBJ: 2 2. ANS: In a properly running engine, air and gasoline are mixed in correct proportions. When air is the limiting reactant, the engine floods with gas and will not run. When gas is the limiting reactant, the engine stalls because the amount of fuel burned is not sufficient to run the engine. PTS: 1 OBJ: 2 DIF: III REF: ce7fc9e3-f97e-11de-9c72-001185f0d2ea