International Journal of Civil Engineering and Technology (IJCIET) Volume 10, Issue 04, April 2019, pp. 626–634, Article ID: IJCIET_10_04_065 Available online at http://www.iaeme.com/ijmet/issues.asp?JType=IJCIET&VType=10&IType=4 ISSN Print: 0976-6308 and ISSN Online: 0976-6316 © IAEME Publication Scopus Indexed CHARACTERISTICS OF THE REINFORCED CONCRETE CONSTRUCTIONS AND STRUCTURES OPERATED IN THE COASTAL ZONE OF THE BLACK SEA COAST Kazakov Sergey Dmitrievich, Bryl Julya Sergeevna, Kuznetsov Vladimir Aleksandrovich, Smolinskiy Nikolay Yakovlevich, Kharchenko Maria Sergeyevna, Kovalenko Tatyana Anatolyevna, Bormotina Anastasia Mikhailovna, Khalitova Anzira Rustamovna Moscow State University of Civil Engineering (MGSU) National Research University, 26, Yaroslavskoye Shosse, Moscow, Russia ABSTRACT Concrete and reinforced concrete are used for the construction of buildings and structures with long-term operation. The use of structures made of these building materials is massive, and more than 4.5 billion m3 per year of concrete and reinforced concrete are produced in the world to meet the requirements in the building industry. During operation, structures are often exposed to adverse environmental effects (aggressive chemicals in the form of gases, salt solutions and aerosols, microorganisms) and turn out to be in difficult working conditions. These effects contribute to the destruction of materials and reduce the durability of structures, which in some cases may fail within a year or even months after the start of operation. When building objects are located near industrial enterprises and on the coast, the impact of adverse factors may increase. The article presents the results of a study of the content of inorganic salts and the species composition of microorganisms in the surface layer of concrete in reinforced concrete structures operated on the Black Sea coast. The authors presented the results of the study of samples of concrete taken from the structures of the pier, which was in direct contact with sea water, depending on elevations relative to sea level and orientation to the cardinal points. The results of the study of samples taken from the structures of the fence, located at a distance of about 50 m from the coastal edge, depending on the orientation of the fence on the cardinal points and its parallel or perpendicular position relative to the coastline were also obtained. A correlation was found between the levels of salt content and the types of microorganisms inhabiting the surface layer of concrete in coastal structures. It has been established that under the influence of the sea climate, a simultaneous impact on building structures of high air temperature, solar radiation, wind, biological environment, moisture and impurities of hygroscopic sea salts in the air occurs. http://www.iaeme.com/IJCIET/index.asp 626 editor@iaeme.com Characteristics of the Reinforced Concrete Constructions and Structures Operated in the Coastal Zone of the Black Sea Coast The intensity of the impact of negative factors depends on the elevations of the location of the structures relative to the surface of the water and their orientation relative to the coast and to the cardinal points. Key words: aggressive environmental impact; salt sprays; concrete and reinforced concrete; biodegradation; concrete destruction; structures and facilities; corrosion; microorganisms; salt content. Cite this Article: Kazakov Sergey Dmitrievich, Bryl Julya Sergeevna, Kuznetsov Vladimir Aleksandrovich, Smolinskiy Nikolay Yakovlevich, Kharchenko Maria Sergeyevna, Kovalenko Tatyana Anatolyevna, Bormotina Anastasia Mikhailovna, Khalitova Anzira Rustamovna, Characteristics of the Reinforced Concrete Constructions and Structures Operated in the Coastal Zone of the Black Sea Coast, International Journal of Civil Engineering and Technology 10(4), 2019, pp. 626–634. http://www.iaeme.com/IJCIET/issues.asp?JType=IJCIET&VType=10&IType=4 1. INTRODUCTION Concrete and reinforced concrete are one of the main types of building materials, which are widely used for the erection of buildings and structures with planned long-term operation - up to 100 years or more. To meet the needs of construction, more than 4.5 billion m3 per year of concrete and reinforced concrete are produced worldwide. Due to the difficult working conditions in some cases, the construction of these materials may be short-lived and fail after a year or months of operation. Substances added to the material during its production, as well as the environment with admixtures of aggressive components, influence the durability of concrete. For example, ambiguous effects on concrete and reinforced concrete structures have chemical additives introduced into the building material to improve the technological properties of the concrete mix. In study [1] it is noted that ―for the majority of groups of additives in general and specific types of additives, in particular, side effects are characteristic. They can be no less strong and no less significant than the main effect as they can be both positive and negative. " Basically the negative effect of the use of additives is detected during overdose [2], then the appearance of efflorescence, the occurrence of corrosion and wet spots on the surface of structures, the cracking of reinforcement, etc., is possible. According to research by a number of authors [3, 4, 5], it has been established that up to 75% of concrete and reinforced concrete building structures are exposed to the damaging effects of the environment with constantly deteriorating indicators. The speed and scale of damage to such structures are associated with corrosion caused by the aggressive influence of the external environment, which ―is capable of weakening concrete strength over time, thereby reducing the safety and durability of buildings and structures‖ [6]. It has been established that the less aggressive environmental impact is taken into account in the design calculations during design, the more pronounced the corrosion becomes during the operation of buildings and structures [7] throughout the entire life cycle. Corrosive damage of the reinforced concrete structures is caused by exposure of the surrounding air environment, groundwater with aggressive substances [8]. Also, environmental factors that adversely affect the initial properties of concrete include: the action of elevated and lowered temperatures, ultraviolet radiation, temperature conditions that cause alternate freezing and thawing of building materials. Such impacts are specific to the http://www.iaeme.com/IJCIET/index.asp 627 editor@iaeme.com Kazakov Sergey Dmitrievich, Bryl Julya Sergeevna, Kuznetsov Vladimir Aleksandrovich, Smolinskiy Nikolay Yakovlevich, Kharchenko Maria Sergeyevna, Kovalenko Tatyana Anatolyevna, Bormotina Anastasia Mikhailovna, Khalitova Anzira Rustamovna operating conditions of the structures of buildings and structures located on the coasts of the seas. To these adverse effects, the effect on the structure of seawater and salt fog with chloridecontaining environment [9, 10, 11, 12] in the form of an aerosol of hygroscopic salts is added. Along with inorganic substances, microorganisms affect the corrosion damage of concrete. According to a number of researchers, ―more than 40% of the total biodegradation is associated with the activity of microorganisms — bacteria and fungi‖ [13, 14, 15]. The processes of bio deterioration of reinforced concrete structures in the warm and humid climatic conditions of the construction area are intensified [16], which is caused by the presence of factors that ―stimulate reproduction: high humidity, relatively high temperatures, various kinds of pollution, as well as potential differences and a pH shift of the environment‖ [17]. The development, reproduction and change of species of bacteria is caused by a change in the characteristics of the environment over time [18]. Biodeteriorations are also typical for polymer composite materials, in particular, polymer concrete [16, 19, 20, 21]. 2. STATEMENT OF THE PROBLEM AND RESEARCH METHODS The task was to establish the species composition of microorganisms and the content of inorganic salts in the surface layer of concrete structures used on the Black Sea coast. The species composition of microorganisms was established in the National Research Mordovia State University. N.P. Ogareva ‖ Saransk city, using the standard method in accordance with the identification of micromycetes on the basis of their morphological and cultural characteristics using determinants: K.B. Raper, S.A. Tom (Raper, Nhom, 1949); K.B. Raper, D.I. Fennel (Raper, Fennell, 1965); N.M. Pidoplichko (1971); M.A. Litvinov (1967); A.A. Milko (1974); TS Kirilenko (1977); C. Donsch, V. Gams (Donch, Gams, 1980); A.Yu. Lugauskas, A.N. Mikulskene, D.Yu. Shliauzeni (1987); V.I. Bilay, E.Z. Koval (1988) [16]. The chemical analysis of material samples on the quantitative content of inorganic salts was carried out according to the standard methods adopted in analytical chemistry in the analytical laboratory of Pigment PJSC, Tambov city. The determination of chlorides was made by the universal ion-meter EV-74, and the determination of sulfates was made by a photoelectric photometer KFK-3- "ZOMZ". 3. THE RESULTS OF RESEARCH During this period its structural elements have not been repaired. Samples were taken at two characteristic vertical portions of the pier, oriented along the cardinal points, respectively, to the east and to the west (Pic. 1). One altitude mark for material sampling was assigned at a level below 1 m from the level of a smooth surface of water, the other one was assigned at the level of a surface of water; the third one was assigned at a height of 2 m above the water level. The first stage of the study consisted in determining the salt content and the presence of microorganisms in the surface layer of concrete in a reinforced concrete pier and comparing the values obtained for different elevation marks of sampling points. http://www.iaeme.com/IJCIET/index.asp 628 editor@iaeme.com Characteristics of the Reinforced Concrete Constructions and Structures Operated in the Coastal Zone of the Black Sea Coast N Figure 1 Sampling site (highlighted by authors with red color) of pier concrete structures on the map The source of the presence of salts in the surface layer of concrete piers, as structures that are in direct contact with the sea, is sea water and salt fog. It is known that the salt content in seawater averages 3.5% (mass.), chlorides, sodium and sulfates constitute the largest part of it: Cl - 55%, Na - 30.6%, SO4 - 7.7%. The remaining substances are magnesium, calcium and potassium: Mg - 3.7%, Ca - 1.2%, K - 1.1% 2. Table 1 Results of microbiological and chemical analysis of samples of concrete of the coastal pier in Gelendzhik Therefore, in the samples of concrete, the presence of salts, such as chlorides and sulfates, are represented massively [22]. http://www.iaeme.com/IJCIET/index.asp 629 editor@iaeme.com Kazakov Sergey Dmitrievich, Bryl Julya Sergeevna, Kuznetsov Vladimir Aleksandrovich, Smolinskiy Nikolay Yakovlevich, Kharchenko Maria Sergeyevna, Kovalenko Tatyana Anatolyevna, Bormotina Anastasia Mikhailovna, Khalitova Anzira Rustamovna Data on the microbiological and chemical analysis of samples of the surface layer of concrete of the coastal pier in the city of Gelendzhik on the Black Sea coast are presented in Table 1. In accordance with the data presented in Table 1, the smallest composition of microorganisms is observed in concrete below the surface of seawater. So at a depth of 1 m, three types of microorganisms such as: Aspergillus niger, Fusarium moniliforme, Cladosporium elatum were identified. At the level of the water surface in the pier material, six species of microorganisms were identified, to the above mentioned: Alternaria brassicae, Cladosporium herbarum and Aspergillus oryzae were added. In samples taken at a height of 2 m above sea level, five types of microorganisms were identified. At the same time, Cladosporium elatum, Aspergillus oryzae and Cladosporium herbarum are absent from those identified at the water level. Additionally, the following species: Chaetomium dolichortrichum and Penicillium chrysogenum have been identified. The average and total salt content was, respectively, in concrete below the surface of seawater at a depth of 1 m - 0.78 and 1.56 w. %, at the level of the water surface - 1.40 and 2.80 w. %, and at an altitude of 2 m above sea level - 1.35 and 2.69 w. %. It was revealed that the salt content values are correlated with the species composition of microorganisms in the samples of the pier material. Analysis of salt content in samples of the material depending on the orientation of sampling points along the cardinal points showed that the total salt content was higher at all elevations relative to sea level. When the vertical pier wall was oriented to the west compared to the east-oriented wall and there were: at points on 1 m below sea level - 1.09 against 0.47 w. %, at the level of the surface of the water - 2.04 against 0.76 w. %, at the level of 2 m above sea level - 1.61 against 1.07 w. % The greatest difference in salinity levels for sampling point No. 2 of western orientation compared to point No.1 of eastern orientation was observed for samples taken at the water surface level - by 63 rel. % For samples below sea surface 1 m, the difference was 57rel. %, and for samples at a height of 2 m above the water level was 34 rel. % Thus, for these conditions, the highest salt content was revealed with the western orientation of the pier wall as compared with the eastern one. At the second stage, studies of a reinforced concrete fence (Pic. 2), made of fence panels of 3.00 × 0.08 × 2.00 (h) m, were carried out. The indicators of reinforced concrete products at a distance of about 50 m to the seawater edge were compared, because it is known that the greatest number of microorganisms is detected on samples taken from reinforced concrete structures 50 meters and more from the sea [16]. The lifetime of the fence is more than 30 years, repair work on its restoration has not been carried out. Material samples were taken from structures that were arranged parallel and perpendicular to the seawater edge at the same time from 2 sides of the structures - facing the sea and on the reverse side. The orientation of the fence to the cardinal points was also established: at the location of the structure parallel to the edge of the sea, it had the orientation of the front side - to the northeast (C-B), and the back side - to the south-west (SW). For the fence, located perpendicular to the coastal edge, the front side was oriented to the south-east (SE), and the rear side - to the north-west (North-west). http://www.iaeme.com/IJCIET/index.asp 630 editor@iaeme.com Characteristics of the Reinforced Concrete Constructions and Structures Operated in the Coastal Zone of the Black Sea Coast N Figure 2 Sampling site (highlighted by the authors with red color) of the reinforced concrete fence structures on the map A visual inspection of the reinforced concrete structures of the fence revealed that the face layer of structures located parallel to the sea and facing the sea, i.e., N-E orientation, underwent the greatest damage (Pic. 3). The armature of intake elements has traces of corrosion. Figure 3 The samples of the reinforced concrete structures of the fence at their location: a, b - parallel to the sea coast with orientation: a - to the sea (N-E), b - from the sea (S-W); c, d - perpendicular to the sea coast with orientation: c - to the sea (SE), d - from the sea (NW) The species composition of microorganisms on the surface of structures is established. It is more widely expressed on surfaces facing seaward, at N-E and S-E orientation 9 types of http://www.iaeme.com/IJCIET/index.asp 631 editor@iaeme.com Kazakov Sergey Dmitrievich, Bryl Julya Sergeevna, Kuznetsov Vladimir Aleksandrovich, Smolinskiy Nikolay Yakovlevich, Kharchenko Maria Sergeyevna, Kovalenko Tatyana Anatolyevna, Bormotina Anastasia Mikhailovna, Khalitova Anzira Rustamovna microorganisms were found, compared with surfaces facing "from the sea", at C-W and SW orientation 6 types of microorganisms are found. Out of six species of microorganisms listed in Table 2, identified on the side facing "from the sea", in the samples of fence designs facing the sea, 2 species such as Penicillium chrysogenum and Penicillium nigricans were missing. 5 species such as - Aspergillus clavatus, Fusarium moniliforme , Fusarium avenaceum, Aspergillus niger and Aspergillus oryzae were additionally found , i.e., nine species of microorganisms were present. The level of salt content in structures located parallel to the coast and facing ―seawards‖ (orientation to N-E) was 16 rel. % higher than in structures located to the side "from the sea" with a focus on S-W (Table 2). Table 2 Species composition of microorganisms in the samples of structural elements of the reinforced concrete fence in the coastal zone of the Black Sea coast At the third stage of the study, an analysis was made of the wind rose in Gelendzhik (Pic. 4), which showed that the NE direction of the wind (17.8% repeatability) compared with the SW direction (8.2% repeatability) prevails 2.2 times. Therefore, it is obvious that the accumulation of salts in the structures of the fence parallel to the coast and seawards, having a NE orientation, is due to the introduction of salt aerosol structures from the sea to the surface of the building material. At the same time, the back side of the fence structure, oriented to SW, undergoes wind impact of lesser intensity and is more protected by that part of the fence, which has a direction perpendicular to the seashore. Analysis of the data in Table 2 allowed to establish that on the obverse (orientation to the SE) and the rear sides (orientation to the NW) of the fence located perpendicular to the sea shore, the salinity is at the same level as the salinity in the structures parallel to the seashore. And it converts "from the sea" with a focus on SW, as well as 16 rel. % lower than in constructions located in the direction ―seawards‖ with orientation to NE. When the fence is oriented perpendicular to the seashore, its front side facing the sea and to the SE is exposed to less aerosol of sea salt due to its perpendicular orientation, as well as http://www.iaeme.com/IJCIET/index.asp 632 editor@iaeme.com Characteristics of the Reinforced Concrete Constructions and Structures Operated in the Coastal Zone of the Black Sea Coast the smaller impact of the SE wind, the frequency of which is 13% against the NE wind repeatability 17.8% for the fence parallel orientation relative to the coast in the direction NE. Figure 4. Wind rose in Gelendzhik Solar radiation also affects the destruction of the surface layer of a concrete fence. At the same time, its impact is complex, since with the existing location of the fence, its mutually perpendicular sides, turned "from the sea" during the daylight hours cast a shadow on each other. The analysis of the amount of total solar radiation (direct and diffuse) on the vertical surface of the fence structures with a cloudless sky is carried out without taking into account that the surface under study is in the shadow of a perpendicular structure. Total solar radiation was determined in accordance with the data of the Code of Practice for the location: Gelendzhik, height above sea level is 22 m, geographical coordinates are 44 ° 33′43 ″ north latitude and 38 ° 05′05 ″ east longitude. The results of the sample are shown in Table 3. With the NE and NW orientation of the fence, the magnitude of the total solar radiation is 575 kWh / m2. With SE and SE orientations are 1594 kWh / m2. It is known that when exposed to solar radiation, significant stresses occur in the body of structures due to the radiation amplitude and inhomogeneous composition of the material. Therefore, when exposed to solar radiation, it is possible to destroy the material by the action of the salt and microbiological environment more intensively. Table 3. The value of the total solar radiation (direct and diffuse) on a vertical surface with a cloudless sky, kWh / m2 http://www.iaeme.com/IJCIET/index.asp 633 editor@iaeme.com Kazakov Sergey Dmitrievich, Bryl Julya Sergeevna, Kuznetsov Vladimir Aleksandrovich, Smolinskiy Nikolay Yakovlevich, Kharchenko Maria Sergeyevna, Kovalenko Tatyana Anatolyevna, Bormotina Anastasia Mikhailovna, Khalitova Anzira Rustamovna 4. CONCLUSIONS The study showed that under the influence of the Black Sea climate, simultaneous exposure of building structures to variable positive temperatures, solar radiation, wind, biological environment, moisture and impurities of hygroscopic sea salts in the air occurs. The intensity of the impact of negative factors depends on the elevations of the location of the structures relative to the surface of the water, as well as their orientation relative to the coastal edge and to the cardinal points. At the same time, orientation to the cardinal points is the determining factor for taking into account the influence of wind and solar radiation. REFERENCES [1] Kuderskaya, O.O. Study of the effect of HSTN additive on the development of corrosion and the formation of efflorescence on the concrete surface // Vestnik of Kuzbass, State Technical University. - Publishing house of the Kuzbass State Technical University. named after T.F. Gorbachev (Kemerovo). - 2017. - №4. - p. 141-143. [2] Bazhenov, Yu.M. Concrete technology. - M .: Publishing House ASV, 2015. - 500 p. [3] Alekseev, S.N, Ivanov, F.M., Modry, S., Schissl, P., Durability of Reinforced Concrete in Aggressive Environments. - M., 2016. - 316 p. [4] Alekseev S.N., Rosenthal N.K. Corrosion resistance of reinforced concrete structures in an aggressive industrial environment. - M.: Stroiizdat, 2016. - 205 p. [5] Mathematical models of concrete corrosion processes / B.V. Gusev, A.S. Faivusovich, V.F. Stepanova et al. - M .: Institute of Information and Information Center "TIMR", 2016. - 103 p. [6] Fedosov S.V., Rumyantseva V.E., Khrunov V.A. Mathematical modeling of mass transfer in the processes of corrosion of concrete to ensure the safety and durability of buildings and structures // Actual problems of drying and thermo-moisture treatment of materials in various industries and agro-industrial complex: a collection of scientific articles of the First International Lykovsky scientific readings dedicated to the 105th anniversary of academician A.V. Lykov. - 2015. - p. 260-262. [7] Karpenko N.I., Karpenko S.N., Yarmakovsky V.N., Erofeev V.T. Modern methods of ensuring the durability of reinforced concrete structures // ACADEMIA. RAAC - M., 2015. - № 1. - p. 93-102. [8] Elchishcheva, T.F. Dynamics of the content of impurities in the air of the Central Black Earth region for the design of external enclosing structures of buildings // Housing construction. - 2016. - №6. - pp. 48-51. [9] Erofeev V.T., Smirnov V.F., Morozov E.A. and others. Microbiological destruction of materials. - M .: DIA, 2018. - 128 p. http://www.iaeme.com/IJCIET/index.asp 634 editor@iaeme.com