-- Lizensiert für DVS Media GmbH, -- SPECIALIST ARTICLES Occupational health and safety regulations with regard to welding and assessment of the exposure to welding fumes and of their effect This article presents a model for the assessment of the exposure to welding fumes and of their effect. The model and the hazard figure calculated with it should not be understood as an assessment in relation to occupational medicine and toxicology but are instead intended to be described with technical tools and, from a technical viewpoint, comparisons between processes, materials and workplace-specific factors and, while doing so, try to explain why a residual risk remains in the case of some welding technology work. The use of personal protective equipment (here, wearing breathing apparatus) should be recognised as a necessary supplementary protective measure (see TRGS 528 [1], particularly the sections with regard to the evaluation of the hazards and to the protective measures). 1 Introduction It is known from literature sources that soldering processes were already used for the joining of noble metals in the ancient world. The industrial revolution in the 19th century was the starting point for a systematic development of welding technologies. It is the time when the generation of energy transfer media and their use for the manufacturing of certain products become possible. Keywords in this context are: electrical energy (arcing processes) and chemical energy (in the form of acetylene). Some examples In 1885, the carbon arc was used by the Russian Benardos for the fusion of metals and alloys, missing material being replaced by currentless filler wire. In 1889, Zerener registered a process for patent where the arc burns between two carbon electrodes. In 1890, the Russian Slawjanow registered a patent; he used the filler wire itself as the arc transfer medium and thus combined electrode and filler wire. In 1889, the pressure-reducing regulator was patented by Dräger. In 1892, the large-scale industrial production of calcium carbide was started. The time needed for the development of the arc technology was significantly longer. We know of first „welding trials“ as early as in 1792 but the possibility to develop welding processes only arose with the generation of electric current on a large scale (end of the 19th century). Since the middle of the 20th century, an increase in the number of welding processes and materials can be observed. In the eighties, the automated use of processes was increased and laser welding established in industry. In 2004, about 70% of the fusion welding processes used were metal gas welding processes, as related to the deposited weld metal. With progressing development of welding current sources, the welding arc could increasingly be influenced by electronic control. Firstly, high-power types of gasshielded metal arc welding are developed, the wire feed rates of which are up to three times higher than those commonly used. Different gas mixtures of argon, carbon 60 THE AUTHOR Dr.-Ing. Vilia Elena Spiegel-Ciobanu is Chairman of the Section „Hazardous Substances in Welding and Allied Processes“ in the BG Expert Committee „Metal and Surface Treatment“ (FAMO) of the German Social Accident Insurance (DGUV), German Social Accident Insurance Institution for the Woodworking and Metalworking Industries (BGHM). dioxide, helium and oxygen support the new processes and process types. Latest developments model the arc individually for the relevant welding task or position. The prospect for further development of welding technology seems to be that conventional welding processes, especially gas-shielded arc welding and resistance welding, will continue to be the dominant types of application but that special welding processes will increasingly become important. Parallel to the development of the processes, the materials to be treated are developed further and refined. BGI 616 contains more information in this context. Mechanisation and automation are promoted in order to achieve higher productivity, higher capacities and higher quality. In accordance with EN 14610, the most widespread metal welding processes can be roughly divided with respect to the type of energy transfer medium into autogenous processes (gas fusion welding, energy transfer medium: gas), arc processes (gas-shielded metal arc welding, tungsten inert gas and plasma welding, energy transfer medium: electric gas discharge), resistance processes (resistance pressure welding and resistance fusion welding, energy transfer medium: electric current) and beam processes (laser beam welding and electron beam welding, energy transfer medium: radiation). Additional processes used are friction welding (energy transfer medium: mass which is moved), fusion welding with liquid heat transfer (energy transfer medium: liquid) and a range of pressure welding processes (energy transfer medium: mass which is moved and undefined energy transfer medium). There are also great differences between the process groups of welding, thermal cutting, thermal spraying and soldering/brazing due to process conditions. These two different categorisations must also be considered when considering the connected hazards. Different hazards occur, e.g. optical radiation, electric current, hazardous substances etc., and the effects of these are different as a function of the process and the material, from both qualitative and quantitative points of view. Welding and Cutting 11 (2012) No. 1 -- Lizensiert für DVS Media GmbH, 2 Hazard assessment Fig. 1 • Welding – Development of occupational health and safety (example Germany). [2...4] Mandatory limit values serving as the upper limit for the relevant exposures to hazardous substances are of special importance for hazard evaluation [6]. Concerning hazardous substances in welding and allied processes, there is no special welding fume limit value at present. For the assessment of the exposure to welding fumes (particulate substances), the A fraction of dust of 3 mg/m³ as the upper limit is of assistance. In addition, the substancespecific limit values for key and main components shall be considered, e.g. AGW (workplace exposure limits, OEL) for Mn and Cu (as MnO and CuO). Carcinogenic substances are excluded from this (risk-related values in preparation). For these substances, the minimisation order according to GefStoffV (German Hazardous Substances Ordinance) is prevalent. The main objective is the hazard-oriented specification of protective measures on the basis of information collection and knowledge about workplace exposure limits (OEL) and the classification of hazardous substances. The level of exposure of the welder to hazardous substances mainly depends on the process used (e.g. gasshielded metal arc welding) and its parameters (e.g. current, voltage etc.), the process types (e.g. pulsed arc) and the materials (e.g. high-alloyed steels), the auxiliary materials/consumables used (e.g. shielding gases) and the surface condition of the materials (e.g. oiled or coated). These factors directly influence the level of the emission rate (in mg/s) and thus also the level of concentration (in mg/m³) at the workplace (in the breathing zone of the welder or stationary in the room). In addition, workplace-specific factors like the ventilation situation, the head/body position of the welder and the room volume influence the level of hazardous substance concentration in the breathing zone of the welder and partially also the room pollution. The chemical composition of the utilised materials and consumables (e.g. rod wire/filler wire and shielding gases) is responsible for the chemical composition of the welding fumes and gases generated. The toxicity of the individual components and also their synergetic effect must be considered in the hazard evaluation by effect-specific factors. For medium, high and very high emission rates without ventilation measures, hazardous substance concentrations occur in the breathing zone of the welder exceed -- the limit values many times over. For low emission rates, it is known by experience that the hazardous substance concentrations in the breathing zone of the welders are in the range of the limit values or slightly below. Therefore, priority shall be given to: • selection of low-emission processes (as far as technically feasible); • selection of low-emission materials (as far as technically feasible); • optimum solutions for ventilation technology. Other hazards during welding are e.g.: Electrical hazard For an increased electrical hazard, especially in confined spaces, dangers result from electric current. Protection of the arc welder against electrical hazards caused by welding equipment (current sources, torches, electrode holders and other work equipment) covers their construction, installation and use (safe operating state, correct installation and safe use). Thermal hazard The heat of the arc also creates metal and slag spilling, hot electrodes and hot torches. This gives rise to the hazard of burning. Fire-resistant protective clothing and appropriate hearing protection are required for protection. Physical hazards by optical radiation and noise There is also a hazard due to e.g. optical radiation like arc radiation or – less intensive by far but nevertheless hazardous – light radiation from the oxyacetylene flame and the welding bath and to noise. Personal protective equipment is required: Eye protection with the appropriate protection class, work and protective clothing, respiratory protective equipment, hearing protectors and skin protection. Fire and explosion hazards Ignition sources (arc, thermal conduction and sparks/flying sparks during welding) often cause fires and explosions. Recommended preventive measures are: Covering, sealing, fire watchers, provision of fire extinguishers etc.). These dangers and related hazards shall be taken into account appropriately. Suitable protective measures shall be selected and effected [7;8]. 3 Assessment of exposure to welding fumes and their effect on the welder During welding, cutting and allied processes, different amounts of gaseous or particulate substances are generated as a function of the processes and materials used. The particulate substances mainly have a particle size (aerodynamic diameter) of below 1 µm, are respirable and are called „welding fumes“ in practice. The chemical composition of the particulate substances primarily depends on the chemical composition of the materials used (filler/parent metals). The quantity and composition of gaseous substances, in contrast, are mainly based on surface impurities (oil and Welding and Cutting 11 (2012) No. 1 61 -- Lizensiert für DVS Media GmbH, -- SPECIALIST ARTICLES Table 1 • Process-specific hazard figures (GZ)E. Table 2 • Effect-specific hazard figures (GZ)W. Table 3 • Correlation between the process-specific and effect-specific hazard figures (GZ)E and (GZ)W (the figures – the result of the multiplication E x W – refer to a percentage of 100% of toxic or carcinogenic substances in the welding fume). Table 4 • Factors for ventilation and spatial conditions (for particulate substances; with capture: with technical ventilation measures; without capture: without technical ventilation measures; confined space*: spatial volume smaller than 100 m³). grease) and coatings. As the welding fumes have very complex and varying compositions, workplace monitoring is mostly based on key components. The complexity of the welding fumes also entails the difficulty to evaluate diseases in welders from an occupational medical point of view. Thus, e.g. the causes of diseases of welders are not sufficiently clear. The causal connection between exposure to welding fumes and a disease of e.g. the respiratory tract/lung often can only be found with great difficulties. The reason lies in the difficulties occurring, on the one hand, during technical identification of the data and, on the other hand, during occupational medical assessment – due to insufficient data about toxicological effects. Experience showed that the collection of occupational anamnesis data which occurred during assessments within the German framework of the BK (occupational disease) procedures often presented difficulties, as the general 62 conditions – materials used, auxiliary means etc. – are in most cases difficult to identify in retrospect. For an improvement of the prevention and the identification of causes of diseases in welders, the following procedure is suggested: • Data identification within the framework of a wellfounded occupational anamnesis is supported by an occupational anamnesis sheet encompassing several pages („Informationsermittlung für die Gefährdungsbeurteilung/Arbeitsanamnesebogen“, http://www.bghm.de/arbeitsschutz/fachausschuesse/metal-undoberflaechenbehandlung/sachgebiete/schadstoffe-in-der-schweisstechnik.html) which was specially developed for this purpose. In the future, there will be the possibility to record the process-specific, material-specific and workplace-specific general conditions by means of this sheet. • For the evaluation of the hazards caused by different types of welding fumes, an empirical model has been developed. It is based on measuring results from the lab and the workplace as well as on occupational medical findings and experience with regard to the effects of hazardous substances. The exposure of the welder to welding fumes at the workplace depends on a series of different factors. They include the process/material combinations used which are responsible for the amount of the relevant gaseous and particulate substances, the emissions (see below under I) and the workplace conditions, e.g. ventilation situation, spatial conditions and head/body position of the welder (see below under II). The effect of the different welding fume types on persons has been considered in a differentiated way, namely with respect to exposure of the respiratory tract, exposure of the lung and carcinogenic hazard. Additional hazardous effects on other organs in the human body were not included in the model. The model may be used for the calculation of welding fume hazard years (Schweißrauchgefährdungs-Jahre, SchwRGJ) on the basis of a calculated hazard figure (Gefährdungszahl GZ) on the one hand and identified welding years on the other hand as follows: SchwRGJ = GZ x welding years GZ = [Ep x Wp + EGx WG] x (1/10) x L x R x Kp The first term of this equation contains the process-specific and effect-specific factors (E factors and W factors) and the second the workplace-specific factors (L, R and Kp factors): I) Ep EG Wp WG emission rates – factor for particulate substances emission rates – factor for gaseous substances effect factor for particulate substances effect factor for gaseous substances II) L ventilation situation – factor R spatial conditions – factor Kp head/body position – factor Welding and Cutting 11 (2012) No. 1 -- Lizensiert für The welding years are calculated from the estimation of the arcing time or the duty cycle (ED) of the torch and the working hours of the welder as follows (the total welding time (years, months or weeks) is considered)): III) Exposure time (shift-related; per shift x 220 per year [hours/year (h/a)]; for 1 shift and ED ≈ 40 to 50 %) 1 shift (8 h/shift) ED 4h exposure time 880 h/a ¾ shift (6 h/shift) ED 3h exposure time 660 h/a ½ shift (4 h/shift) ED 2h exposure time 440 h/a ¼ shift (2 h/shift) ED 1h exposure time 220 h/a With regard to the process-specific and effect-specific factors (I) For the first step, the emission factors during welding (EP and EG) were established. The welding processes were divided into four groups according to emission rates and correlation factors between the processes (process-specific hazard figure (GZ)E) were specified, Table 1. The hazard figures related to emission groups and emission rates were presented as follows: nE : mE : hE : shE = 1 : 3 : 9 : 5 The process-related hazard figure (GZ)E for the relevant emission category thus results as follows: nE: mE: hE: shE: factor 1 = 1 factor 1 x 3 = 3 factor 1 x 3 x 9 = 27 = 27 factor 1 x 3 x 9 x 5 = 135 = 135 The effect factors (WP and WG) were much more difficult to specify than the technical factors. A differentiated consideration of the specific effect intensity of the relevant key components in welding fume was carried out in a first step. Experience gained within the framework of workplace-related provocation tests, anamnesis findings and course observations were used for key components which could not be classified in this way according to literature data. A simplified procedure is suggested for practice: Limit values and ranges of limit values are used and, similar to the emission rates, effect-specific hazard figures are defined. Here, a distinction is made between the three effects lung-stressing, toxic and carcinogenic , Table 2. As the hazard depends on the process-specific and effect-specific factors, the process-specific hazard figures are then multiplied by the effect-specific hazard figures and shown in Table 3. The figures in Table 3 (the result of the multiplication: E x W) refer to a percentage of 100% toxic or carcinogenic substances in the welding fume. Since the composition of the welding fumes is very complex and the hazard assessment is carried out on the basis of specified key components (occupational medically and toxicologically and also as quantity of the relevant substances in the welding fume) (see as well [9…11]), the relevant figures from Table 3 are corrected, i.e. multiplied, by the percentage of the relevant key component in the Welding and Cutting 11 (2012) No. 1 DVS Media GmbH, -- welding fume (for carcinogenic substances with the sum of the percentages of these substances in the welding fume) in the following calculation (see examples). With regard to the workplace-specific factors (II) Here, the three workplace-specific factors according to BGI 616 were taken into account: • ventilation (L), • spatial conditions (R), • working position, body posture and head position (Kp). They were defined by factors as explained in the following. In relation to the workplace conditions, the parameter „ventilation“ was subdivided into the categories “with capture” (with technical ventilation measures) and “without capture” (without technical ventilation measures) and the factor L was elaborated accordingly, Table 4. For spatial conditions, the factor R distinguishes between a non-confined space/room (with V > 100 m³) and a confined space (with V < 100 m³). In relation to working position, body posture and head position, a distinction was made between „head within the plume“ and „head outside the plume“ and the factor KP was elaborated accordingly, Table 5. The factors for spatial conditions (R), for ventilation (L) and for working position, body posture and head position (KP) are combined in Table 6 and the workplace-specific factors are multiplied (see formula). The application of this model was tested on the premises of the Norddeutsche Metall-Berufsgenossenschaft in cooperation with the then occupational physician of the BG, Dr. Englitz, in order to evaluate the relevance of the welding fumes to diseases. Especially for the effect factors, it was found that the presently available data material does not suffice to clearly describe the viability and limits of this model. Therefore, it is suggested to critically check the organ-related effect factors by a competent working group in order to have them scientifically substantiated. Table 5 • Factors for working position, body posture and head position (for particulate substances). Table 6 • Correlation between workplace-specific factors. 63 -- Lizensiert für DVS Media GmbH, -- SPECIALIST ARTICLES (0.1% + 0.1%) = 4 and L x R x KP = 1 x 1 x 1 = 1. The hazard figure is: GZ = 4 x 1/10 x 1 x 1 = 0.4. b) Welding is done in a confined space without extraction (capture) and the head of the welder is above the plume, E x W = 2,000 x [(% Cr(VI) compound + % Ni in the welding fume)] = 2,000 x (0.1 % + 0.1 %) = 4 and L x R x KP = 4 x 4 x 4 = 64. This results in the hazard figure: GZ = 4 x 1/10 x 64 = 25.6. The hazard figure for the TIG welder is between 0.1 and 25.6, as a function of the boundary conditions. Figure 2 shows an overview of the hazard figures (GZ) for different welding processes. 5 Conclusions Fig. 2 • Hazard figures (GZ) for different welding processes. In addition, the model may be used in prevention work for the assessment of the future risk of a disease or for the selection of the preventive measures. 4 Examples TIG welding with unalloyed and low-alloyed filler metal The welding fumes are lung-stressing, E x W = 1. a) Welding is done in a normal space (no confined space) with extraction (capture) and the head of the welder is outside the plume; L x R x KP = 1. From the tables above and the formula, the hazard figure for this activity results as follows: GZ = 1 x 1/10 x 1 x 1 = 0.1. b) Welding is done in a confined space with extraction (capture) and the head of the welder is above the plume, E x W = 1 and L x R x KP = 16. The hazard figure is: GZ = 1 x 1/10 x 16 = 1.6. c) Welding is done in a confined space without extraction (capture) and the head of the welder is above the plume, E x W = 1 and L x R x KP = 4 x 4 x 4 = 64. This results in the hazard figure: GZ = 1 x 1/10 x 64 = 6.4. TIG welding with high-alloyed filler metal The welding fumes contain carcinogenic substances. a) Welding is done in a normal space (no confined space) with extraction (capture) and the head of the welder is outside the plume; E x W = 2,000 x [(% Cr(VI) compound + % Ni in the welding fume)] = 2,000 x 64 The presented model which focuses on the hazard figure for the exposure assessment and the examples given are intended to show that • Practically no hazard due to welding fumes (= particulate substances) arises from low-emission processes like TIG welding (GZ = 0.1 to 0.4). Even during working on high-alloyed steels (Cr/Ni steels), no hazard is to be expected – with the exception of welding work in “confined spaces“ with an unfavourable position of the head above the plume. • even high-emission processes like manual metal arc welding with low-alloyed filler metals may lead to very low hazard figures (e.g. GZ = 2.7), i.e. to a low hazard, provided that the following optimised general technical conditions are given: - efficient extraction is used, - the welding work in not done in a “confined space“ and - the head of the welder is outside the plume. • the hazard figure (GZ) under the optimised general technical conditions described above – compared to contrary conditions (unfavourable conditions like “confined space“, “no extraction“ and “head of the welder above the plume“) - may be lower by a factor of nearly 100. • the level of the emission rate and the percentage of toxic and especially of carcinogenic substances in the welding fume is important for the size of the hazard figure (quasi-linear). Therefore, it is the more important to provide for an influence of at least the three workplace-specific factors: L x R x KP which is as low as possible, best = 1. This is especially important for processes with high fusion capacities, e.g. during surfacing/hardfacing where high welding fume emission rates at the same time contain high percentages (e.g. 23 %) of carcinogenic substances and thus result in a high hazard figure (hazard). This can only be reached by the optimised general technical conditions mentioned. Welding and Cutting 11 (2012) No. 1 -- Lizensiert für • low-emission/low-hazard processes when carried out in “confined spaces“ also have a hazard figure which cannot be neglected (see TIG welding with high-alloyed filler metal, GZ = 25.6). TIG welding without filler metal is excluded from this. Literature [1] TRGS 528 „Technische Regeln für Gefahrstoff; Schweißtechnische Arbeiten“ (Ausgabe Februar 2009). [2] N. N.: Virtuelles Museum der Schweißtechnik. DVS, Düsseldorf, http://www.dvs-aft.de/M/. [3] Flemming, D., u. H. Sossenheimer: Schweißen heute und Morgen – 1897 bis 1972. Festschrift „75 Jahre Schweißtechnische Gemeinschaftsarbeit – 25 Jahre Deutscher Verband für Schweißtechnik e. V.“. DVS Media, Düsseldorf 1972. [4] Kleinöder, N.: Die Geschichte des Arbeitsschutzes in der Bundesrepublik am Beispiel des Werkes Huckingen nach 1945. Magisterarbeit, Universität, Düsseldorf, Februar 2009, Fassung 10/2010). [5] ArbSchG „Gesetz über die Durchführung von Maßnahmen des Arbeitsschutzes zur Verbesserung der Sicherheit und des Gesundheitsschutzes der Beschäftigten bei der Arbeit“ Arbeitsschutzgesetz vom 7. August 1996 (BGBl. I S. 1246), das zuletzt durch Artikel 15 Absatz 89 des Gesetzes vom 5. DVS Media GmbH, -- Februar 2009 (BGBl. I S. 160) geändert worden ist“. Stand: Zuletzt geändert durch Art. 15 Abs. 89 G v. 5.2.2009 I 160. Hrsg.: Bundesministeriums der Justiz. [6] Spiegel-Ciobanu, V. E.: Arbeitsschutzregelungen beim Schweißen, Schwerpunkt Schadstoffe. Tagungsbd. Fachausschuss-Symposium „Schadstoffe beim Schweißen und bei verwandten Verfahren“ (Mai 2011, Hannover). http:// www.bghm.de/fileadmin/downloads/FA_MO/Schadstoffe/Tagungsband_2011Internetseite_Exemplar_Kurzfassung_kopie.pdf?PHPSESSID=7287a3ba3b23cf22e20f32fe06 e14915. [7] BGI 553 „Lichtbogenschweißer“ (Ausgabe 2008). Hrg.: VMBG. Carl-Heymanns-Verlag, Köln 2008. [8] BGI 554 „Gasschweißer“ (Ausgabe 2009). Hrsg.: VMBG. Carl Heymanns Verlag, Köln 2009. [9] Spiegel-Ciobanu, V. E.: Schadstoffe beim Schweißen und bei verwandten Verfahren. BGI 593, Ausgabe 2008. Hrsg.: VMBG. Carl-Heymanns-Verlag, Köln 2008. [10] Spiegel-Ciobanu, V. E.: Beurteilung der Gefährdung durch Schweißrauche. BGI 616, Ausgabe 2005. Hrsg.: VMBG. CarlHeymanns-Verlag, Köln 2005. [11] Spiegel-Ciobanu, V. E.: Matrix zur Beurteilung der Schadstoffbelastung durch Schweißrauche. Diss., TH-Aachen 2009. Aachener Berichte Fügetechnik, Bd. 3 2009 (Hrsg. 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