Specialty additives and solvents for coatings formulations Europe, Middle East, and Africa Contents Introduction........................................... 03 Market segments .................................... 04 Specialty products Cellulose acetate..................................... 05 Cellulose acetate butyrate......................... 06 Performance additives.............................. 07 Cellulose acetate propionate...................... 08 Adhesion promoters................................. 09 Plasticizers............................................. 11 Sulfopolyester dispersions......................... 12. Eastman coalescing aids.. .......................... 13 Eastman Optifilm™ additive.. ...................... 14 High-performance solvents Eastman high-performance solvents............ 15 Find out more about Eastman and its products at www.eastmancoatings.com. Introduction Introduction Eastman coatings: a unique portfolio of world-class specialty additives for Europe, Middle East, and Africa Eastman Coatings: a unique portfolio of world-class specialty additives for Europe, Middle East and Africa. Eastman Coatings is committed to delivering innovation and solutions for . coatings applications. For more than 70 years, we have been a leading provider of high-quality raw materials and services for the global paint and coatings industry. With an in-depth understanding of the coatings market, technology-based innovation, and world-class technical service, Eastman helps its customers deliver value-creating solutions to meet the challenging performance and environmental requirements in today’s marketplace. Today, we offer a unique portfolio of specialty additives such as cellulose esters . and adhesion promoters; VOC-compliant coalescents such as Eastman Texanol™ ester alcohol and Eastman Optifilm™ enhancer 300 and 400; sulfopolyester dispersions specialty solvents such as Eastman ketones and EEP; and Eastman . resin intermediates, the building blocks for better resins. Eastman Coatings is a business group of Eastman Chemical Company headquartered in Kingsport, Tennessee (U.S.A.), with regional headquarters, including a customer service center, in Capelle aan den IJssel (the Netherlands) . and European Technical Centre in Liverpool (UK). We work with our customers to meet the ever-changing regulatory climate, . toward a greener tomorrow, helping them make good paint based on sound chemistry. These products are suitable for use in conventional, high solid and waterborne coatings in architectural, automotive, and industrial applications. 3 Market segments Architectural trim Architectural trim is classified as all interior and exterior architectural components, i.e., window frames and sills, door frames and doors, . barge and soffit boards, cladding, skirting boards, and staircases. Architectural flat Architectural flat is classified as all large interior and exterior flat surfaces, i.e., walls and ceilings. General industrial General industrial is classified as factory-applied coatings normally dried by forced evaporation of solvents in curing ovens. Most ­products are coated . postmanufacture and include household appliances, metal furniture, shelving, automotive components, drums, and plastic components. Factory- and field-applied wood Coating solutions, specifically designed for factory- and field-applied wood applications, serving the industrial and decorative wood markets for . applications such as furniture, flooring, fixtures, and window frames. Transport Transport finishes include automotive OEM, automotive refinish, trucks, agricultural and construction equipment, railroads, and aircraft. Maintenance and marine Maintenance and marine includes all high-performance protective coatings vital for protecting corrosion in steel structures of all kinds. Applications embrace . ships, oil rigs, and tank linings as well as basic steel structures including bridges, chemical plants, electrical power stations, pylons, and warehouses. Can and coil Can and coil includes all factory-applied coatings onto metal, normally steel, aluminum, and tin, generally prior to the manufacture of the final component. Consumer electronics Consumer electronics includes plastic coatings, water-based or solvent-based, applied onto various electronic devices. Coatings can have special effects, . such as metallic look and can be monocoats, 2K, UV, or basecoat/clearcoat systems. 4 Eastman CA 394-60S Eastman CA-398-3 Eastman CA-398-6 60/228 3/11.4 6/22.8 39.5 39.8 39.8 55 55.5 55.5 4 3.5 3.5 240–260 230–250 230–250 186 180 182 Eastman CA-398-30 30/114 39.7 55.4 3.5 230–250 189 Eastman CA-436-80S 80/304 43.6 60.8 0.82 269–300 — Consumer electronics Tg (ºC) Can and coil Melting range (ºC) Maintenance & marine Hydroxyl content (%) Transport Combined acetic acid content (%) Wood Acetyl content (%) General industrial Viscosity (seconds/ poise) Architectural flat Cellulose acetate Architectural trim Specialty products Key features and benefits • Very high melting point. Limited solubility and compatibility, low odour. Gives high strength and good resistance to ­ultraviolet light, heat, oils, and greases. Useful in lacquers for glass, plastic, wire, and release coatings. • Very high melting point. Limited solubility and compatibility, low odour. Gives high strength and good resistance to ultraviolet light, heat, oils, and greases. Useful in lacquers for glass, plastic, wire, and release coatings. Lowest viscosity 398 grade. • Very high melting point. Limited solubility and compatibility, low odour. Gives high strength and good resistance to ­ultraviolet light, heat, oils, and greases. Useful in lacquers for glass, plastic, wire, and release coatings. • • Very high melting point. Limited solubility and compatibility, low odour. Gives high strength and good resistance to ultraviolet light, heat, oils, and greases. Useful in lacquers for glass, plastic, wire, and release coatings. Highest viscosity 398 grade. Triacetate grade. Excellent solvent resistance. 5 Eastman CAB 171-15 15.0/57.0 29.5 17.0 1.5 230–240 161 Eastman CAB 321-0.1 0.1/0.38 17.5 32.5 1.3 165–175 127 Eastman CAB 381-0.1 0.1/0.38 13.5 38.0 1.3 155–165 123 Eastman CAB 381-0.5 0.5/1.9 13.5 38.0 1.3 155–165 130 Eastman CAB 381-2 2.0/7.6 13.5 38.0 1.3 171–184 133 Eastman CAB 381-2 BP 2.2/8.4 14.5 35.5 1.8 175–185 130 Eastman CAB 381-20 20.0/76.0 13.5 37.0 1.8 195–205 141 Eastman CAB 381-20 BP 16.0/60.8 15.5 35.5 0.8 185–195 128 Eastman CAB 500-5 5.0/19.0 4.00 51.0 1.0 165–175 96 Eastman CAB 531-1 1.9/7.22 3.00 50.0 1.7 135–150 115 Eastman CAB 551-0.01 0.01/0.038 2.00 53.0 1.5 127–142 85 Eastman CAB 551-0.2 0.2/0.76 2.00 52.0 1.8 130–140 101 Eastman CAB 553-0.4 0.3/1.14 2.00 46.0 4.8 150–160 136 6 • • • • • • • • • • • Consumer electronics Tg (ºC) Can and coil Melting range (ºC) Maintenance & marine Hydroxyl content (%) Transport Butyryl content (%) Factory-applied wood Acetyl content (%) General industrial Viscosity (seconds/ poise) Architectural flat Cellulose acetate butyrate Architectural trim Specialty products Key features and benefits Limited solubility and compatibility. Useful in coatings for wire, leather, plastic, and cloth. • • • • • • • • • • • • • • • • • • • • •• •• • •• ••• ••• •• • Designed for use in automotive basecoats. Resistant to attack and redissolve by solvents typical in clearcoats. Low solution viscosity. Useful in coatings for wood, metal, plastic, paper, leather, and cloth. Reduces cratering, dry to touch time, improves pigment control and intercoat ­adhesion. Higher viscosity, increased toughness. Good balance of compatibility and viscosity. Higher viscosity, increased toughness with excellent surface hardness. Used in automotive basecoats for metallic flake control. Higher hydroxyl content version of CAB 381-2. Highest viscosity, greatest rheological modification. Useful as a blending cellulosic resin in automotive coatings. Lower hydroxyl content version of CAB 381-20. Produces a relatively soft flexible film. Useful in leather ­coatings and as a flow control additive in polyurethanes. Higher butyryl content offers improved compatibility. Excellent compatibility and low viscosity. Solubility in styrene and methyl methacrylate monomers allows use in UV-curing systems. Gives improved hardness, dry-to-touch, and ­application properties to 2K and high-solids systems. Excellent compatibility and low viscosity. Useful in high-solids, thermoset coatings. Modifier for UV-curing systems. Alcohol solubility with excellent compatibility and pigment-wetting characteristics. High hydroxyl content allows a high level of cross-linking. Eastman Solus™ 2100 Eastman Solus™ 2300 Eastman Solus™ 3050 — — — — — — — — 50 1.2–1.9 1.2–1.9 2.80 — — — 70–80 110 130 Consumer electronics Tg (ºC) Can and coil Melting range (ºC) Maintenance & marine Hydroxyl content (%) Transport Acid number Factory-applied wood Acetyl content (%) General industrial Viscosity (seconds/ poise) Architectural flat Performance additives Architectural trim Specialty products Key features and benefits ••• Eastman Solus 2100 performance additive is a dry, free-flowing powder convenient to handle. It is soluble in a wide range of solvents and compatible in most high-solids coatings systems. • • Eastman Solus™ 2300 performance additive is a dry, free-flowing powder convenient to handle. It is soluble in a wide range of solvents and compatible in most high-solids coatings systems. Solus 2300 was developed for higher solids base metallic base coat systems where attributes are good strike-in resistance. ••• Eastman Solus™ 3050 performance additive is a dry, white granular powder. Eastman Solus 3050 can be dissolved in selected solvents . or appropriate blends of solvents, water, and neutralizing agents. Eastman Solus 3050 provides many of the unique contributions . of solventborne cellulosic additives in waterborne coating formulations. ™ 7 Eastman CAP 482-0.5 0.4/1.52 2.5 45 2.6 188–210 142 Eastman CAP 482-20 20.0/76.0 1.3 48 1.7 188–210 147 Eastman CAP 504-0.2 0.2/0.76 0.6 42.5 5.0 188–210 159 8 • • • Consumer electronics Tg (ºC) Can and coil Melting range (ºC) Maintenance & marine Hydroxyl content (%) Transport Combined acetic acid content (%) Factory-applied wood Acetyl content (%) General industrial Viscosity (seconds/ poise) Architectural flat Cellulose acetate propionate Architectural trim Specialty products Key features and benefits Low odour. Excellent grease barrier properties. Excellent solvent release. Higher viscosity, low-odour resin. Low-odour resin with high hydroxyl content for cross-linking systems. Excellent pigment-wetting characteristics. 20.5 — 10 9.5 Eastman CP 347W 25 Water 20.5 — 10 9.5 Eastman CP 349W 26 Water 20.5 — 10 9.5 Eastman CP 153-2 25% xylene 25 Xylene 23.0 15 — — Eastman CP 164-1 100% 100 None 20.5 16 — — Eastman CP 343-1 100% 100 None 20.5 — — — Eastman CP 343-1 25% xylene 25 Xylene 20.5 7 — — Eastman CP 343-1 40% xylene 40 Xylene 20.5 8 — — Eastman CP 343-1 50% xylene 50 Xylene 20.5 8 — — Eastman CP 343-3 25% xylene 25 Xylene 29.0 7 — — • • • • • • • • • • • • • • • • • • • • Consumer electronics Water Can and coil 30 Eastman CP 310W Maintenance & marine Typical pH Transport Viscosity (mPa•s) Wood Colour (Gardner) (max.) General industrial Solvent Typical chlorine content (wt%) Average nonvolatile content (%) Architectural flat Adhesion promoters Architectural trim Specialty products • • • • • • • • • • Key features and benefits Oil in water-type emulsion containing ammonia as ­neutralizing amine. Recommended for adhesion to untreated polypropylenebased substrates. Oil in water-type emulsion. Neutralized with AMP. Recommended for promoting adhesion to untreated polypropylene-based substrates. Oil in water-type emulsion. Neutralized with AMP and ­containing . 5 wt% ethylene glycol. Recommended for ­promoting adhesion to untreated polypropylene (PP)-based substrates. Recommended as an adhesion-promoting primer for untreated polyethylene-based substrates. Designed for improved humidity and gasoline ­resistance when used as an adhesion promoter for TPO- or PP-based substrates. Supplied in powder form. Excellent adhesion to PP-based substrates. Also promotes adhesion to steel, galvanized steel, phosphated steel, wood, and rigid PVC. Excellent adhesion to PP-based substrates. Also promotes adhesion to steel, galvanized steel, phosphated steel, wood, and rigid PVC. Excellent adhesion to PP-based substrates. Also promotes adhesion to steel, galvanized steel, phosphated steel, wood, and rigid PVC. Higher chlorine content than CP343-1, gives improved compatibility with co-resins. Recommended as stir-in additive to promote adhesion to PP-based substrates. 9 29.0 11 — — Eastman CP 515-2 40% aromatic 100 40 Aromatic 100 29.0 7 — — Eastman CP 515-2 40% xylene 40 Xylene 29.0 3 — — Eastman CP 730-1 20% xylene 20 Xylene 22.5 7 — — Eastman CP 730-1 20% aromatic 100 20 Aromatic 100 22.5 7 — — Eastman AP 550-1 25% aromatic 100 25 Xylene N/A 7 — — Eastman AP 550-1 25% xylene 25 Xylene N/A 7 — — Eastman Advantis™ 510W 10 24 Water N/A Off-white milky liquid <75cP 8 • • • • • • • • • • • • Consumer electronics Xylene Can and coil 50 Eastman CP 343-3 50% xylene Maintenance & marine Typical pH Transport Viscosity (mPa•s) Factory-applied wood Colour (Gardner) (max.) General industrial Solvent Typical chlorine content (wt%) Average nonvolatile content (%) Architectural flat Adhesion promoters (Continued) Architectural trim Specialty products Key features and benefits • • • • Higher chlorine content than CP343-1 gives improved compatibility with co-resins. Recommended as stir-in additive . to promote adhesion to PP-based substrates. • Excellent humidity and gasoline resistance. Superior hightemperature performance. Recommended for adhesion onto PP-based substrates. Recommended as stir-in additive to promote adhesion to PP . and other difficult to coat substrates. Recommended as stir-in additive to promote adhesion to PP . and other difficult to coat substrates. Excellent humidity and gasoline resistance. Superior hightemperature performance. Recommended for adhesion onto PP-based substrates. • Nonchlorinated adhesion promoter. Excellent adhesion to TPO- and PP-based substrates. Excellent humidity and gasoline resistance particularly under 1K systems. • Nonchlorinated adhesion promoter. Excellent adhesion to TPO- and PP-based substrates. Excellent humidity and gasoline resistance particularly under 1K systems. • Chlorine-free and APEO-free product, which will be found in primary application as a blend-in resin in waterborne primers and waterborne basecoats for automotive bumper applications. It also can be used as a wash primer and is suitable as an adhesion promoter for applications beyond automotive. Freezing point (ºC) Flash point (ºC) Eastman SAIB-100 — 200 1.146 0.20. (acid no.) 100,000 (30ºC) — — 260 (COC) Eastman SAIB-90 — 200 1.100 0.20. (acid no.) 770. (25ºC) — — 18 (TCC) Eastman SAIB-90 EA — 200 1.110 0.20. (acid no.) 935 (25ºC) — — 91. (COC) •• •• •• Consumer electronics Boiling range (ºC) Can and coil Viscosity (mPa•s) Maintenance & marine Acidity as acetic acid (max. wt%) Transport Specific gravity (25ºC) Factory-applied wood Colour (Pt-Co) (max.) General industrial Evaporation rate nBuOAc = 1 Architectural flat Plasticizers Architectural trim Specialty products Key features and benefits Low volatile plasticizer giving improved adhesion to a variety of substrates. 90% solids in ethanol provides lower viscosity and . improved handling. 90% solids in ethyl acetate provides lower viscosity and improved handling. 11 Consumer electronics Can and coil Maintenance & marine Transport Typical pH Average particle size (nm) Field-applied wood Solvent Viscosity (mPa•s) General industrial Average nonvolatile content (%) Architectural flat Sulfopolyester dispersions Architectural trim Specialty products Key features and benefits • Eastek 1000 polymer dispersion is a film-forming polyester polymer supplied as an aqueous dispersion containing 30% polymer solids. Eastek 1000 provides excellent alcohol resistance, fast drying rates, low odour, low foaming, good adhesion to aluminum, and neutral pH. Eastek 1000 polymer dispersion is amine, surfactant, and cosolvent free. • Eastek™ 1100 polymer dispersion is a film-forming polyester polymer supplied as an aqueous dispersion containing 33% polymer solids. Eastek 1100 provides excellent alcohol resistance, fast drying rates, low odour, low foaming, good adhesion to aluminum, and neutral pH. Eastek 1100 polymer dispersion is amine, surfactant, and cosolvent free. • Eastek™ 1200 polymer dispersion is a film-forming polyester polymer supplied as an aqueous solution containing 2% n-propanol and 30% polymer solids. Eastek 1200 provides excellent water resistance, alcohol resistance, fast drying rates, low odour, and a consistently low coefficient of friction. Eastek 1200 polymer dispersion is amine and surfactant free. ™ Eastek™ 1000 Eastek™ 1100 Eastek™ 1200 Eastek™ 1300 Eastek™ 1400 a Contains 2% n-propanol 12 30 33 30 30 30 Water Water Watera Water Water 60 89 99 14 15 6.0 6.2 6.6 6.0 6.0 27 20 13 54 34 • • Eastek™ 1300 polymer dispersion, alcohol free is a film-forming polyester polymer. Aqueous dispersions of this polymer are characterized by low odour, good storage stability, and reducibility with water or water/alcohol mixtures. This product offers excellent resistance properties and fast drying rates. Eastek 1300 polymer dispersion is amine, surfactant, and cosolvent free. • Eastek™ 1400 polymer dispersion is a 100% sulfopolyester. Aqueous dispersions of this polymer are characterized by low odour, good storage stability, and reducibility with water or water/alcohol mixtures. This product offers excellent resistance properties and fast drying rates. Eastek 1400 has outstanding adhesion to a variety of substrates, including PET film (treated or untreated), paper, SBS board, aluminum foil, and metallized papers/films. Eastek 1400 polymer dispersion is amine, surfactant, and cosolvent free. Eastman Texanol™ ester alcohol Eastman Optifilm™ enhancer 300 Eastman Optifilm™ enhancer 400 Eastman EEH solvent a b 0.002 0.00077 0.000017 0.003 10 30 100 max. 10 0.95 (20ºC) 0.945 (20ºC) 0.967 0.882 0.05 0.05b — 0.01 — — 15.8 cp 7 cP 254a 281a 344 235–275 Freezing point (ºC) –50 –70 –50 <–45 Flash point (ºC) 120 (COC) 143 (COC) 199 102 Consumer electronics Boiling range (ºC) Can and coil Viscosity (mPa•s) Maintenance & marine Acidity as acetic acid (max. wt%) Transport Specific gravity (25ºC) Field-applied wood Colour (Pt-Co) (max.) General industrial Evaporation rate nBuOAc = 1 Architectural flat Eastman coalescing aids Architectural trim Specialty products Key features and benefits ••••••• Excellent coalescing aid, particularly under adverse conditions of high humidity and low temperature. Excellent properties with associative thickeners. Useful as a slow-evaporating solvent in polyester coil coatings and high-bake enamels. Not classified as VOC per EU Directive 2004/42/EC and EU Solvent Emissions Directive. ••••••• Useful for preparing low viscosity weatherable PVC . coil coatings. Coalescing aid with low volatility and excellent application properties. Excellent properties with associative thickeners. Not classified as VOC per EU Directive 2004/42/EC and EU Solvent Emissions Directive. •••• Eastman Optifilm™ enhancer 400, a low-odour coalescent that is compatible with a variety of latex types. It is an efficient coalescent that aids in the development of latex paints that have a good balance of performance properties. Eastman Optifilm enhancer 400 delivers excellent film integrity, touch-up properties, and scrub resistance. Paints prepared . with Eastman Optifilm enhancer 400 have also demonstrated good exterior durability after one year exposure. Not classified as VOC per EU Directive 2004/42/EC and EU Solvent Emissions Directive. ••••• •• Used in performance specialty coatings applications. . It offers an excellent balance of performance properties when used as a coalescent in architectural and industrial maintenance coatings. Eastman EEH solvent has low water miscibility, low surface tension, good hydrolytic stability, and high electrical resistance. . In electrodeposition primers, Eastman EEH reduces volatilization from dip tank and provides good flow . and leveling of the coating in the baking oven. Boiling point Acidity as propionic acid (isobutyric) 13 Eastman Optifilm™ additive OT1200 14 69 1.08 8500 8.3 Hazy 28 VOC (%) <1 •• Consumer electronics Water (%) Can and coil Appearance Maintenance & marine pHa Transport Viscosity (cps) Wood Density (g/cm3) General industrial Active content (%) Architectural flat Eastman Optifilm™ additive Architectural trim Specialty products Key features and benefits Eastman Optifilm™ additive OT1200 uniquely improves the application properties of your paint through improved workability and longer open time over a range of application conditions. OT1200 is a low-VOC additive . and does not negatively affect other key paint properties such as water resistance, wet adhesion, block resistance, and stability. Because the impact of OT1200 is in the . early stages of film formation, it will not affect dry time . or recoat time of the paint. OT1200 can be substituted for volatile glycols, giving a substantial reduction in the . VOC content while improving the application feel and the workability of the paint. Eastman EEP 0.12 15 0.950 0.02 165–172 <–50 58 Eastman EP 0.20 10 0.913 0.01 148.5–153.5 <–90 49 Eastman MAK 0.4 10 0.818 0.02 147–154 –33 39 Eastman MIAK 0.5 10 0.813 0.01 141–148 –74 36 Eastman MPK 2.3 10 0.810 0.01 101–105 –86 8 Eastman n-butylpropionate 0.5 10 0.876 0.01a 145–149 –75 36 Eastman IBIB 0.4 15 0.855 0.01 145–152 –80 40 a ••••• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • Consumer electronics Flash point (ºC) Can and coil Freezing point (ºC) Maintenance & marine Boiling range (ºC) Transport Acidity as acetic acid (max. wt%) Field-applied wood Specific gravity (25ºC) General industrial Colour (Pt-Co) (max.) Architectural flat Evaporation rate nBuOAc = 1 Eastman high-performance solvents Architectural trim High-performance solvents Key features and benefits Retarder solvent with excellent solvency characteristics. High-boiling process solvent for acrylic polymer production. High autoignition temperature makes it suitable for use in . coil coatings. Good coupling solvent for resin/water ­systems. Effective retarder solvent. High solvency combined with low SG. Particularly useful in high-solids coatings. Its high-boiling characteristics make it ­suitable as a process solvent for acrylic resin manufacture. High solvency and low SG. Excellent in high-solids systems. Medium evaporating, active solvent for most resin types. . Excellent in high-solids systems. Good solvency for most coatings resins, useful in paint . stripping applications. Economical ester retarder solvent. Particularly useful in . nitrocellulose systems. Low crazing of plastic substrates. Acidity as propionic acid 15 Europe, Middle East, and Africa Eastman Chemical B.V. Fascinatio Boulevard 602-614 2909 VA Capelle aan den IJssel The Netherlands Telephone: (31) 10 2402 111 Fax: (31) 10 2402 100 Europe, Middle East, and Africa Eastman Chemical B.V. 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You should obtain and review available material safety information before handling our products. If any materials mentioned are not our products, appropriate industrial hygiene and other safety our products. If any materials mentioned are not our products, appropriate industrial hygiene and other safety precautions recommended by their manufacturers should be observed. precautions recommended by their manufacturers should be observed. © 2013 Eastman Chemical Company. Eastman, Advantis, Eastek, Optifilm, Solus, Texanol, and The results of insight are © 2013 Eastman Chemical Company. Eastman, Advantis, Eastek, Optifilm, Solus, Texanol, and The results of insight are www.eastman.com trademarks of Eastman Chemical Company. trademarks of Eastman Chemical Company. GN-446D 7/13 GN-446D 7/13