LiTE STAR

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LiTE STAR
THE SOLID STATE, THIN-FILM, LITHIUM BATTERY
• Taking the next step with thin-film flexible energy storage
• Going where no other battery is able
• Inside the product for life
Product development specialists across many industries are
finding innovative ways to exploit the performance life in the
LiTE*STAR™ Battery. Life cycle testing has exceeded 60,000
full depth of discharge cycles and an end of life limit has yet to
be reached.
As a result, the LiTE*STAR™ Battery can be engineered inside
the product for life as a fully integrated device within the
electronic circuitry. In many applications, a micro-amp-hr
battery is sufficient where an internal or external source (i.e.
RF Energy) is present for recharging the battery.
RFID Tags
Medical Implants
Smart Cards
LiTE*STAR™ is available in flexible or rigid formats and can
be engineered to specific patterns, shapes, and sizes.
Micro-Electromechanical Sensors
Semi-Conductors
Micro-Electronics
Engineered Performance Options:
OPTIONS
APPLICATION CHARACTERISTICS
Substrates
Ceramic Al2 O3
Metal Foil
Thin (5mil) where flexible form not required.
Thin (1mil) where planar flexibility or conformal
packaging required
Cathodes
LiCoO 2
Engineered capacities up to ~.2 mAh/cm2, 0°C ,
4.2-3.0V range
Engineered capacities up to ~.2 mAh/cm2, ~-15°C low
operating limit, 4.5-1.5V range
Engineered capacities up to ~.3mAh/cm2 , 0°C low
operating limit, 4.0-1.0V range
Mn 2O4
V2O5
Dimensions
Patterns/Packaging
Conformal cell patterns and packaging tailored to form,
fit and function requirements
Features:
•
Reversible, High Energy Density Cell Chemistry
•
Superior Cycle Life (Rechargeability)
•
High Voltage Cell Chemistry
•
Thin-Film Flexible Form Factor (<15µm)
•
Intrinsically Stable, All solid state construction
•
No Memory Effects
•
Able to charge from low (<1) to high (>50) C rates
•
In-Situ Compatibility with manufacturing processes
Performance Comparisons:
Battery
System
LiTE*STAR
Anode
Cathode
Voltage
Nominal, V
Li
LiCoO2*
4.0
Lead-acid
Pb
Nickel-Cadmium
Cd
Nickel-M-Hydride
(MH)
Lithium ion
C
Lithium-organic
Li
Lithium-Polymer
Li
Edison
Fe
Silver-zinc
Zn
Nickel-zinc
Zn
Nickel-hydrogen
H2
Silver-Cadmium
Cd
Zinc-air
Zn
Zinc Bromine
Zn
High-Temperature
Li(Al)
High-Temperature
Na
* For a 1 mil titanium foil substrate
PbO2
Ni oxide
Ni oxide
LixCoO2
MnO2
V6O13
Ni Oxide
AgO
Ni oxide
Ni Oxide
AgO
O2 (air)
Br2
FeS2
S
2
1.2
1.2
4
3
3
1.2
1.5
1.6
1.2
1.1
1.5
1.6
1.7
2
Energy Density
Wh/kg
Wh/I
200*
35
35
50
90
120
200
30
90
60
55
55
150
70
180
170
450
70
80
175
200
265
350
55
180
120
60
100
160
60
350
250
Comparative Performance of Typical Secondary Batteries
Cycle
Life
>60,000
200-250
400-500
400-500
>500
500
500
Life Cycles Comparison of Rechargeable Batteries
www.InfinitePowerSolutions.com
PRELIMINARY PERFORMANCE SPECIFICATIONS
BATTERY TYPE
Makeup:
Electrolyte:
Anode
Cathode
Form
Substrate
Encapsulant
VOLTAGE (V) Nominal
Solid State Rechargeable Microbattery
All Solid State (LiPON, Lithium Phosphorus Oxynitride)
Lithium
LiCoO2
Thin Film
Metal Foil or Rigid Ceramic
Fully encapsulated in thin membrane
4.0 V Open Circuit
CAPACITY
Up to: ~0.2mAhr/cm2
Can be increased by surface area or parallel cell stacks
OPERATING RANGE
Survivability -50°C to 180°C
Can be engineered to higher temperatures
Sustained Operation
0°-120°C
CHARGING
>85% Charging efficiency
Capability to charge at C rates greater than 50 at lower efficiencies
SPECIFICATIONS
ENERGY DENSITY
Wh/kg (gravimetric)
Wh/l (volumetric)
LIFE
Cycle Life
Shelf Life
Quiescent Storage Life
200
450
MECHANICAL
Designed to Application Specific Form Factor Requirements
>60,000 charge/discharge cycles
Infinite prior to activation
<1% total energy loss per year after initial activation
1
Fig.1: Typical Thin-Film Battery Discharge Capacity
Fig:2 Typical Internal Resistance
2
650
4.2
4.1
600
100
3.9
Discharge Current µAmps
550
Volts
3.8
500
3.7
3.6
450
3.5
Discharge
Discharge
Current µ A Capacity ( µAhr)
3.4
400
3.3
Resistance (Ohms)
4
20 (74.1)
40 (70.8)
3.2
350
80 (68.0)
3.1
100 (67.0)
0223-10
0223-10
3
300
0
10
20
30
40
50
60
70
80
90
100
4.2
4.1
4.0
3.9
3.8
3.7
Volts
Discharge Capacity (uAhr)
Fig.3: Discharge Performance During Long Term Cycling
Fig.4: Performance after Thermal Cycling & at Temperatures
3
4
4.2
4.2
4.1
4.1
4.0
4
3.9
3.8
3.8
3.7
3.7
Volts
Volts
3.9
3.6
Charge/Discharge Cycles
3.5
3.5
1000
3.4
3.6
Initial Room Temperature Discharge
3.4
Discharge After 5 Thermal Cycles (-50ºC
to 80ºC)
10,000
3.3
3.3
20,000
3.2
Discharge at 80ºC
3.2
30,000
Final Room Temperature Discharge
3.1
40,000
0803-7LT
3
0
10
20
30
40
50
60
70
3.1
0803-8
3.0
0
Capacity (uAhr)
*Note: All tests results are based on a 1.2 µ cathode thickness and 1.0 cm2 area.
Production batteries available in 3.0 µ thicknesses for capacities up to 0.2 mAhr/cm2
1: Discharge Capacity based upon 1.2 µ thick cathode
2: Internal Resistance Measured at Various voltages during discharge cycle
3: Cycling: Charged @ 500µA to 4.2V then discharged @ 500µA to 3.0V
4: Thermal Cycle Testing Using 100µA discharge current
10
20
30
40
50
60
70
80
90
Discharge Capacity (uAhr)
Infinite Power Solutions
8130 Shaffer Parkway
Littleton, Colorado USA 80127
Phone: 303-285-5108, Fax: 303-285-5171
www.InfinitePowerSolutions.com
100
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