LiTE STAR THE SOLID STATE, THIN-FILM, LITHIUM BATTERY • Taking the next step with thin-film flexible energy storage • Going where no other battery is able • Inside the product for life Product development specialists across many industries are finding innovative ways to exploit the performance life in the LiTE*STAR™ Battery. Life cycle testing has exceeded 60,000 full depth of discharge cycles and an end of life limit has yet to be reached. As a result, the LiTE*STAR™ Battery can be engineered inside the product for life as a fully integrated device within the electronic circuitry. In many applications, a micro-amp-hr battery is sufficient where an internal or external source (i.e. RF Energy) is present for recharging the battery. RFID Tags Medical Implants Smart Cards LiTE*STAR™ is available in flexible or rigid formats and can be engineered to specific patterns, shapes, and sizes. Micro-Electromechanical Sensors Semi-Conductors Micro-Electronics Engineered Performance Options: OPTIONS APPLICATION CHARACTERISTICS Substrates Ceramic Al2 O3 Metal Foil Thin (5mil) where flexible form not required. Thin (1mil) where planar flexibility or conformal packaging required Cathodes LiCoO 2 Engineered capacities up to ~.2 mAh/cm2, 0°C , 4.2-3.0V range Engineered capacities up to ~.2 mAh/cm2, ~-15°C low operating limit, 4.5-1.5V range Engineered capacities up to ~.3mAh/cm2 , 0°C low operating limit, 4.0-1.0V range Mn 2O4 V2O5 Dimensions Patterns/Packaging Conformal cell patterns and packaging tailored to form, fit and function requirements Features: • Reversible, High Energy Density Cell Chemistry • Superior Cycle Life (Rechargeability) • High Voltage Cell Chemistry • Thin-Film Flexible Form Factor (<15µm) • Intrinsically Stable, All solid state construction • No Memory Effects • Able to charge from low (<1) to high (>50) C rates • In-Situ Compatibility with manufacturing processes Performance Comparisons: Battery System LiTE*STAR Anode Cathode Voltage Nominal, V Li LiCoO2* 4.0 Lead-acid Pb Nickel-Cadmium Cd Nickel-M-Hydride (MH) Lithium ion C Lithium-organic Li Lithium-Polymer Li Edison Fe Silver-zinc Zn Nickel-zinc Zn Nickel-hydrogen H2 Silver-Cadmium Cd Zinc-air Zn Zinc Bromine Zn High-Temperature Li(Al) High-Temperature Na * For a 1 mil titanium foil substrate PbO2 Ni oxide Ni oxide LixCoO2 MnO2 V6O13 Ni Oxide AgO Ni oxide Ni Oxide AgO O2 (air) Br2 FeS2 S 2 1.2 1.2 4 3 3 1.2 1.5 1.6 1.2 1.1 1.5 1.6 1.7 2 Energy Density Wh/kg Wh/I 200* 35 35 50 90 120 200 30 90 60 55 55 150 70 180 170 450 70 80 175 200 265 350 55 180 120 60 100 160 60 350 250 Comparative Performance of Typical Secondary Batteries Cycle Life >60,000 200-250 400-500 400-500 >500 500 500 Life Cycles Comparison of Rechargeable Batteries www.InfinitePowerSolutions.com PRELIMINARY PERFORMANCE SPECIFICATIONS BATTERY TYPE Makeup: Electrolyte: Anode Cathode Form Substrate Encapsulant VOLTAGE (V) Nominal Solid State Rechargeable Microbattery All Solid State (LiPON, Lithium Phosphorus Oxynitride) Lithium LiCoO2 Thin Film Metal Foil or Rigid Ceramic Fully encapsulated in thin membrane 4.0 V Open Circuit CAPACITY Up to: ~0.2mAhr/cm2 Can be increased by surface area or parallel cell stacks OPERATING RANGE Survivability -50°C to 180°C Can be engineered to higher temperatures Sustained Operation 0°-120°C CHARGING >85% Charging efficiency Capability to charge at C rates greater than 50 at lower efficiencies SPECIFICATIONS ENERGY DENSITY Wh/kg (gravimetric) Wh/l (volumetric) LIFE Cycle Life Shelf Life Quiescent Storage Life 200 450 MECHANICAL Designed to Application Specific Form Factor Requirements >60,000 charge/discharge cycles Infinite prior to activation <1% total energy loss per year after initial activation 1 Fig.1: Typical Thin-Film Battery Discharge Capacity Fig:2 Typical Internal Resistance 2 650 4.2 4.1 600 100 3.9 Discharge Current µAmps 550 Volts 3.8 500 3.7 3.6 450 3.5 Discharge Discharge Current µ A Capacity ( µAhr) 3.4 400 3.3 Resistance (Ohms) 4 20 (74.1) 40 (70.8) 3.2 350 80 (68.0) 3.1 100 (67.0) 0223-10 0223-10 3 300 0 10 20 30 40 50 60 70 80 90 100 4.2 4.1 4.0 3.9 3.8 3.7 Volts Discharge Capacity (uAhr) Fig.3: Discharge Performance During Long Term Cycling Fig.4: Performance after Thermal Cycling & at Temperatures 3 4 4.2 4.2 4.1 4.1 4.0 4 3.9 3.8 3.8 3.7 3.7 Volts Volts 3.9 3.6 Charge/Discharge Cycles 3.5 3.5 1000 3.4 3.6 Initial Room Temperature Discharge 3.4 Discharge After 5 Thermal Cycles (-50ºC to 80ºC) 10,000 3.3 3.3 20,000 3.2 Discharge at 80ºC 3.2 30,000 Final Room Temperature Discharge 3.1 40,000 0803-7LT 3 0 10 20 30 40 50 60 70 3.1 0803-8 3.0 0 Capacity (uAhr) *Note: All tests results are based on a 1.2 µ cathode thickness and 1.0 cm2 area. Production batteries available in 3.0 µ thicknesses for capacities up to 0.2 mAhr/cm2 1: Discharge Capacity based upon 1.2 µ thick cathode 2: Internal Resistance Measured at Various voltages during discharge cycle 3: Cycling: Charged @ 500µA to 4.2V then discharged @ 500µA to 3.0V 4: Thermal Cycle Testing Using 100µA discharge current 10 20 30 40 50 60 70 80 90 Discharge Capacity (uAhr) Infinite Power Solutions 8130 Shaffer Parkway Littleton, Colorado USA 80127 Phone: 303-285-5108, Fax: 303-285-5171 www.InfinitePowerSolutions.com 100