The Multi-Busbar Design: an Overview Stefan Braun1, Giso Hahn1 Robin Nissler2, Christoph Pönisch2, Dirk Habermann2 Universität Konstanz1 www.uni-konstanz.de/photovoltaics Gebr. Schmid GmbH2 4th Metallization Workshop, May 8th 2013, Konstanz S. Braun Motivation Optimized Solar Cell Design for Module Integration* Ag consumption Solar cell optimization Module = + Multi-Busbar Solar Cell *S. Braun et al., “Solar Cell Improvement by Using a Multi-Busbar Design as Front Electrode”, Energy Procedia 21, 227-233 (2012) 4th Metallization Workshop, May 8th 2013, Konstanz 1 S. Braun Outline • Motivation • Cell Concepts - Differences between 3-busbar and multi-busbar solar cell • Simulation - Advantages of multi-busbar design on cell- and module-level • Results of Experiment - Solar cells & one cell modules • Summary 4th Metallization Workshop, May 8th 2013, Konstanz 2 S. Braun Cell Concepts SE Solar Cell (6 inch Cz) Alkaline textured SiNx:H layer Screen printed fingers Full area Al BSF 4th Metallization Workshop, May 8th 2013, Konstanz 3 S. Braun Cell Concepts SE Solar Cell (6 inch Cz) Alkaline textured 3-Busbar SiNx:H layer Multi-Busbar Screen printed fingers Full area Al BSF 3 Busbars 4th Metallization Workshop, May 8th 2013, Konstanz Round Sn coated Cu wires 3 S. Braun Extraction IV Parameters Starting Point 2-diode model simulation 4th Metallization Workshop, May 8th 2013, Konstanz 4 S. Braun Extraction IV Parameters Starting Point 2-diode model simulation Selective Emitter reference cell* Extracted parameters jsc [mA/cm2] Voc [mV] FF [%] 37.63 638.7 79.78 η [%] 19.17 j01 [fA/cm2] j02 [nA/cm2] rp [cm2] rs [cm2] jph [mA/cm2] 538 17 10000 0.433 40.5** **without shading *B. Tjahjono et al.,”Optimizing selective emitter technology in one year of full scale production”, Proc. 26th EUPVSEC Hamburg, p. 901-905 4th Metallization Workshop, May 8th 2013, Konstanz 4 S. Braun Simulation How many busbars do we need? 19.4 Adding busbars to cell structure Busbar width 1.4 mm 19.2 19.0 [%] IV setup IV setup 18.8 18.6 18.4 Cell Stringed Stringed opt. 18.2 18.0 3 4 5 6 7 Busbars 8 9 10 Shading dominates drop 4th Metallization Workshop, May 8th 2013, Konstanz 5 S. Braun Simulation How many busbars do we need? Stringed front side 19.4 Busbar width 1.4 mm Height of rectangular tabbing 200 µm 19.2 [%] 19.0 18.8 18.6 18.4 Cell Stringed Stringed opt. 18.2 18.0 • drop due to stringing • Additional Rs by tabbing • IV measurement does not represent module ..performance 4th Metallization Workshop, May 8th 2013, Konstanz 6 3 4 5 6 7 Busbars 8 9 10 Shading dominates drop S. Braun Simulation How many busbars do we need? Stringed front side 19.4 Busbar width variable Height of rectangular tabbing 200 µm 19.2 [%] 19.0 18.8 18.6 18.4 Cell Stringed Stringed opt. 18.2 18.0 3 4 5 6 7 Busbars 8 9 10 Rs reduction dominates η gain 4th Metallization Workshop, May 8th 2013, Konstanz 7 S. Braun Simulation How many busbars do we need? Stringed front side [%] 1.4 19.2 1.2 19.0 1.0 18.8 0.8 18.6 0.6 18.4 18.2 18.0 0.4 Cell Stringed Stringed opt. 3 4 5 6 7 Busbars 0.2 8 9 Busbar width [mm] 19.4 Busbar width variable Height of rectangular tabbing 200 µm 0.0 10 Rs reduction dominates η gain 4th Metallization Workshop, May 8th 2013, Konstanz 8 S. Braun String Geometry Tabbing Wire Reflection on string Reflection on wire Effectively shaded area: ~100% Effectively shaded area: ~70% 4th Metallization Workshop, May 8th 2013, Konstanz 9 S. Braun String Geometry Tabbing Wire Reflection on string Total reflection on glass Effectively shaded area: ~100% Effectively shaded area: ~36% 4th Metallization Workshop, May 8th 2013, Konstanz 10 S. Braun String Geometry *A.W. Tabbing Wire Reflection on string Partial reflection on glass Effectively shaded area: ~100% Effectively shaded area: 30%* Blakers, "Shading losses of solar-cell metal grids“, Journal of Applied Physics, vol. 71, p. 5237, 1992 4th Metallization Workshop, May 8th 2013, Konstanz 11 S. Braun Finger Design Multi-Busbar (15 wires), 6 inch 3-Busbar, 6 inch L = 25 mm L = 5 mm Series resistance rs of finger grid: rs ~ L2 rs 3BB 25 times higher with same grid structure 4th Metallization Workshop, May 8th 2013, Konstanz 12 S. Braun Finger Design Multi-Busbar (15 wires), 6 inch 3-Busbar, 6 inch L = 25 mm L = 5 mm 1.0 Finger spacing constant (2 mm) 0.8 2 rs [cm ] Aspect ratio height/width = 0.5 Gaussian shaped fingers IV setup 3 Busbars 15 Wires 0.6 0.4 0.2 0.0 10 20 30 40 50 60 70 80 90 Finger width [µm] 4th Metallization Workshop, May 8th 2013, Konstanz 13 S. Braun Finger Design Multi-Busbar (15 wires), 6 inch 3-Busbar, 6 inch L = 5 mm 0.6 Finger spacing variable 2 rs [cm ] Aspect ratio height/width = 0.5 Gaussian shaped fingers IV setup 2.4 0.5 2.0 0.4 1.6 0.3 3 Busbars 15 Wires 1.2 0.2 0.8 0.1 0.4 Finger spacing [mm] L = 25 mm 0.0 0.0 10 20 30 40 50 60 70 80 90 Finger width [µm] 4th Metallization Workshop, May 8th 2013, Konstanz 14 S. Braun Ag Consumption & Efficiency 0.6 IV setup 3 Busbars 15 Wires 0.5 19.8 0.4 19.6 0.3 19.4 0.2 19.2 0.1 19.0 0.0 18.8 10 20 30 40 50 60 70 80 90 Finger width [µm] [%] 2 rs [cm ] 20.0 Finger width η 3 Busbars 50 µm 19.3% 15 Wires 17 µm 19.7% 4th Metallization Workshop, May 8th 2013, Konstanz 15 S. Braun Ag Consumption & Efficiency 0.6 19.8 0.5 0.4 19.6 0.4 120 0.3 19.4 0.3 90 0.2 19.2 0.2 60 0.1 19.0 0.1 30 0.0 18.8 10 20 30 40 50 60 70 80 90 Finger width [µm] [%] 2 2 3 Busbars 15 Wires 0.5 rs [cm ] IV setup 20.0 3 Busbars 15 Wires 150 0.0 0 10 20 30 40 50 60 70 80 90 Finger width [µm] Finger width η 3 Busbars 50 µm 19.3% 108 mg 15 Wires 17 µm 19.7% 6.7 mg 4th Metallization Workshop, May 8th 2013, Konstanz 180 Ag paste [mg] IV setup rs [cm ] 0.6 15 Ag consumption S. Braun Aluminium Rear Side How many Ag Pads on Al Rear Side? • Pad size 4 mm x 0.5 mm continuous 6 • 15 round Cu wires • Rsheet Al = 10 m/sq. ~ 18 µm 5 4 3 2 Pads on unit cell Al rear side ? 4th Metallization Workshop, May 8th 2013, Konstanz 16 S. Braun Aluminium Rear Side How many Ag Pads on Al Rear Side? • Pad size 4 mm x 0.5 mm 0.50 • 15 round Cu wires 0.45 • Rsheet Al = 10 m/sq. ~ 18 µm 2 rs [cm ] 0.40 rs <0.3 cm2 is sufficient 2 Pads 3 Pads 4 Pads 5 Pads 6 Pads Continuous 0.30 0.25 0.20 Number of pads depends on wire diameter 4th Metallization Workshop, May 8th 2013, Konstanz 0.35 Stringed rear side 0.15 220 17 240 260 280 Wire diameter [µm] 300 S. Braun Aluminium Rear Side How many Ag Pads on Al Rear Side? TinPad* 0.50 0.45 2 rs [cm ] 0.40 0.35 Stringed rear side 2 Pads 3 Pads 4 Pads 5 Pads 6 Pads Continuous 0.30 0.25 0.20 0.15 220 Sn pads instead of Ag pads Full area Al BSF *TinPad 240 260 280 Wire diameter [µm] 300 by Schmid Group 4th Metallization Workshop, May 8th 2013, Konstanz 17 S. Braun Aluminium Rear Side How many Ag Pads on Al Rear Side? TinPad* 0.50 0.45 2 rs [cm ] 0.40 0.35 Stringed rear side 2 Pads 3 Pads 4 Pads 5 Pads 6 Pads Continuous 0.30 0.25 0.20 0.15 220 Sn pads instead of Ag pads Full area Al BSF *TinPad 240 260 280 Wire diameter [µm] 300 by Schmid Group 4th Metallization Workshop, May 8th 2013, Konstanz 17 S. Braun Experiment Process Flow Solar Cell Level Cz-Si, 6 inch, 2 Ohmcm Alkaline texture POCl3 emitter diffusion 55 Ohm/sq. 3 busbars + fingers Inkjet masking Front pads + fingers Emitter etch back 110 Ohm/sq. Chemical edge isolation SiNx:H deposition Screen printing full area Al BSF 3 busbars + fingers Screen printing front side Front pads + fingers Finger width 70 µm Spacing 2.1 mm Co-firing Finger width 50 µm Spacing 1.8 mm Pads 500 x 700 µm2 IV measurement 4th Metallization Workshop, May 8th 2013, Konstanz 18 S. Braun Experiment Process Flow Module Level TinPad 3 ribbons Stringing front- / rear side 15 wires Collector ribbons Lamination process IV measurement 4th Metallization Workshop, May 8th 2013, Konstanz 19 S. Braun Experiment Process Flow Module Level TinPad 3 ribbons Stringing front- / rear side 15 wires Collector ribbons V,I Lamination process V,I Aperture area - IV measurement Independently measured @ European Solar Test Installation in Ispra, Italy V,I 4th Metallization Workshop, May 8th 2013, Konstanz V,I 19 S. Braun Experiment: IV Results Average IV Parameters of 3x Solar Cells Design Ag [mg] Voc [mV] jsc [mA/cm²] FF [%] rs [Ωcm2] η [%] 3BB 140 640 38.1 80.0 0.41 19.45 MBB 68 640 37.7 80.2 0.32 19.34 Delta -72 0 -0.4 +0.2 -0.09 -0.11 • Ag paste reduction >50% for multi-busbar cells (72 mg) • jsc loss -0.4 mA/cm² • Efficiency loss -0.11% Similar η on cell level 4th Metallization Workshop, May 8th 2013, Konstanz 20 S. Braun Experiment: IV Results Average IV Parameters of 3x Solar Cells and 3x 1-Cell Modules Design Ag [mg] Voc [mV] jsc [mA/cm²] FF [%] rs [Ωcm2] η [%] 3BB 140 640 38.1 80.0 0.41 19.45 MBB 68 640 37.7 80.2 0.32 19.34 Delta -72 0 -0.4 +0.2 -0.09 -0.11 Design Ag [mg] Voc [mV] jsc [mA/cm²] FF [%] rs [Ωcm2] η [%] 3BB 140 638 37.1 76.7 1.19 18.16* MBB 68 637 37.3 77.9 0.96 18.49* Delta -72 -1 +0.2 +1.2 -0.23 +0.33 *aperture area High module efficiencies with multi-busbar design 4th Metallization Workshop, May 8th 2013, Konstanz 20 S. Braun Conclusion Advantages of Multi-Busbar Solar Cell Design • Multiple busbars can boost module efficiency • Technology has high potential for metal reduction • Ag reduction via fine line printing 72 mg 50%abs • Module efficiencies 18.16% 3BB 18.49% MBB • Best multi-busbar module efficiency 18.57% • Outlook: - Optimized front pad design increased jsc η 18.7% possible (Simulation) 4th Metallization Workshop, May 8th 2013, Konstanz 21 S. Braun Thank you for your attention! Special thanks to: Schmid Group for funding Harald Müllejans, Diego Pavanello, Elena Salis, Roberto Galleano for IV measurements 4th Metallization Workshop, May 8th 2013, Konstanz S. Braun