C I E N C E , T E C H N O L O G Y , S O C I E T Y ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ Fuel-Cell DRIVERS WANTED by Todd Clark and Rick Jones I f you were to ask middle level students what type of car they would like to drive when they get their driver’s license, they would no doubt respond with “a sports car” or an SUV. Although they are years away from being licensed drivers, most have spent considerable time contemplating their dream car. Suggesting that maybe they should consider a fuel-cell car or a hybrid vehicle may generate some laughs, but may also pique their curiosity. Recently, President Bush commented that the greatest environmental progress made in this century will be through technology and innovation (Bush 2003). His administration has committed $1.7 billion over the next five years for research on the use of fuel cells for personal transportation (Abraham 2003). While the political climate seems favorable for the development of fuel-cell vehicles for personal transportation, the market’s demand may not be so favorable. Nonetheless, middle level students will be the next generation of drivers and voters, and they need to be able to make informed decisions regarding the nation’s energy and transportation policies and understand how such decisions impact our environment. PHOTOS COURTESY OF THE AUTHORS S 22 science scope Summer 2004 Todd Clark is a science education advisor in the Office of Science at the U.S. Department of Energy in Washington, D.C. Rick Jones is a high school science teacher and Einstein Fellow from Billings, Montana. ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ FIGURE 1 ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ Chemical equations (1) This is the combination of two other chemical reactions, one at the cathode: O2 + 4H+ + 4e¯ → 2H2O (2) and one at the anode: 2H2 → 4H+ + 4e¯ ○ S C I E N C E , FIGURE 2 The combined chemical reaction for fuel cells is simply: 2H2 + O2 → 2H2O ○ (3) Fuel-cell technology Fuel cells generate electricity by the reverse reaction of electrolysis of water. In the electrolysis, electrical current causes water molecules to separate into their component gases: two-parts hydrogen and one-part oxygen. In a fuel cell, hydrogen combines with oxygen to produce electricity, heat, and water (see Figure 1 for the chemical equations used in a fuel cell). The U.S. Department of Energy (DOE) has committed resources to help teachers and the general public understand the science behind this new technology and the benefits and disadvantages of fuel-cell technology (see critical-thinking questions in Figure 2). Start your engines As an initial introduction, it may be helpful to have the students brainstorm what they know about hydrogen, the sources of hydrogen on Earth, and its potential uses. Ask students if it is possible to race a model car using only distilled water as fuel or how NASA provides safe electrical power aboard the space shuttle. The idea for using hydrogen and oxygen to produce electricity has been around for about 100 years and practical use of fuel cells to provide electrical power for space craft has been a reality for more than 40 years. Students may be provided with the materials necessary to design and carry out several experiments that will allow them to separate hydrogen and oxygen from water. From these explorations, students will have the necessary conceptual understanding of electrolysis. More than just a car race In May of 2003, in conjunction with the DOE’s National Science Bowl, 50 students from around the country participated in the First Annual Fuel-Cell Car Challenge at the National 4-H Center in Chevy Chase, Maryland. Students had approximately 12 hours to design, construct, and race their cars in two events: driving up an inclined T E C H N O L O G Y , S O C I E T Critical-thinking questions • What would be the advantages and disadvantages of hydrogen as an “energy currency” relative to our current use of carbon-based fuels for energy storage? • There was some expectation that battery-storage electric vehicles would be the next generation of personal transportation. Why does that seem unlikely today? How are fuel-cell vehicles different from electric vehicles and how are they similar? Do the same drawbacks that apply to electric cars with batteries apply to fuel-cell vehicles? • Fuel-cell cars will initially be more expensive than gasolinepowered cars. How should consumers decide if the additional expense is warranted? Should the government provide incentives for drivers to purchase alternatively fueled vehicles? Why or why not? • The infrastructure of gasoline stations throughout the country to provide fuel for gasoline-powered cars was built up over many decades. How would an infrastructure to provide hydrogen to fuel-cell cars be different and is there a best method for making this transition, if it occurs? FIGURE 3 Materials list • Thames and Kosmos Hydrogen Fuel-Cell Car Kit (plastic car body with water reservoir removed) • One empty juice box (with 10-cm x 3-mm plastic straw) • One 6-speed gearbox kit (Tamiya) • One bag “OO” gears, shafts, and accessories for 2-mm shaft (Solar World) • Two high-speed, 2.54-cm-diameter racer wheels for 3-mm axle with matching O-ring (Pitsco) • Two 5-cm-diameter pulley wheels for 3-mm axle with matching O-ring (Sargent Welch) • Four brass sleeves (3-mm x 1-cm) • One 30-cm x 3-mm brass axle rod • Four alligator clips • Two 30-cm length pieces of 20-gauge copper wire • One bottle instant bond cement • Four 5-mm cable staples and 4 small wood screws • One roll electrical tape • One utility knife • One set small (jeweler’s) screwdrivers • One 15-cm x 50-cm x .6-cm piece foam core • One 15-cm x 30-cm x .6-cm piece balsa wood • One 7.5-cm x 46-cm x .6-cm piece balsa wood Summer 2004 science scope 23 Y S C I E N C E , T E C H N O L O G Y , S O C I E T Y ○ Racing student-designed fuel-cell cars up an inclined plane. ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ products of the incomplete combustion of hydrocarbons. Students also discover that another advantage of using a fuel cell to generate electricity is that there are no moving parts, making it more efficient than a generator. Like batteries, fuel cells can be connected in series and in parallel to meet different electrical loading requirements. In addition, the output of a fuel cell—water—can be converted back into hydrogen and reused as fuel. Competitions with fuel-cell-powered model cars can help teachers integrate several science areas. Students learn about chemistry when they study the chemical reactions that produce electricity and water in fuel-cell operations. Students apply their knowledge of physics when they study gear ratios, friction, Newton’s laws, and the center of gravity in constructing their model cars. Students engage in engineering when they work as a team to design, modify, redesign, and test their vehicles. Finally, students learn about communication when they work with teammates to develop a division of labor that will allow them to construct their cars in a timely manner. n plane with increasingly steeper angles and a head-to-head, double-elimination speed race. In this competition, students were provided key components, such as a fuel cell, in addition to other materials like balsa wood and juice boxes (for adapting this competition for use in your classroom, see the complete list of materials in Figure 3). Students designed vehicles that were as varied as their personalities, and the time limit was still long enough to allow for multiple designs and redesigns as students explored their understanding of gear ratios, torque, friction, and Newton’s laws of motion. The winning team for the inclined plane test used impressive gear ratios (1,300:1) to climb a 44-degree incline, while the winning team for the speed race used a three-wheel design (to reduce friction) with a long, narrow chassis to help the car align quickly with the guide wire. The competition, while exciting, was secondary to learning about how fuel cells operate, engineering design principles, and cooperative problem-solving skills. Abraham, S. 2003. Remarks prepared for Secretary of Energy Spencer Abraham at International Energy Agency Ministerial Working Dinner, Monday, April 28, 2003, Le Meridian Etoile Hotel Paris, available at www.evworld.com/databases/shownews.cfm? pageid=news290403-06 Bush, G.W. 2003. Comments made by President George W. Bush at the National Building Museum, February 6, 2003 www.white house.gov/news/releases/2003/02/20030206-12.html. Driving is learning Internet resources By building and racing these cars, students learn firsthand two advantages of using fuel-cell technology: (1) the fuel is hydrogen, which is the most abundant element in the universe and (2) the product of the internal reacExplore Fuel cells at www.scilinks.org. tion is water (see Figure 2), which Enter code SS070402 is far more benign than the many DOE fuel cell information—www.eere.energy.gov/hydrogen andfuelcells/education.html How fuel cells work—science.howstuffworks.com/fuel-cell.htm Junior Solar Sprint Rules—www.nrel.gov/education/student/ natjssrules.html Model fuel-cell car kits—www.thamesandkosmos.com/store/ fuelcell1.html and www.heliocentris.com/products/school.html National Middle School Science Bowl—www.scied.science.doe.gov/ nmsb/default.htm 24 science scope Summer 2004 References ○ ○ ○ ○ ○