ieee transactions on ultrasonics, ferroelectrics, and frequency control, vol. 53, no. 3, march 2006 631 Single Crystal PMN-PT/Epoxy 1-3 Composite for Energy-Harvesting Application Kailiang Ren, Yiming Liu, Student Member, IEEE, Xuecang Geng, Heath F. Hofmann, Member, IEEE, and Qiming M. Zhang, Senior Member, IEEE Abstract—One key parameter in using electroactive materials to harvest electric energy from mechanical sources is the energy conversion efficiency. Recently, it was shown that, in the relaxor ferroelectric PMN-PT single crystals, a very high longitudinal electromechanical coupling factor ( 90%) can be obtained. This paper investigates energy harvesting using 1-3 composites of PMN-PT single crystals in a soft epoxy matrix. It is shown that 1-3 composites enable the single crystals operating in the longitudinal mode to achieve high efficiency for energy harvesting, and the soft-polymer, matrix-supported single-crystal rods maintain high mechanical integrity under different external loads. For comparison, 1-3 composites with piezoceramic PZT also are investigated in energy-harvesting applications, and the results show that the high coupling factor of single crystal PMN-PT 1-3 composites leads to much higher electric energy output for similar mechanical energy input. The harvested energy density of 1-3 composite with single crystal (22.1 mW/cm3 under a stress of 40.4 MPa) is about twice of that harvested with PZT ceramic 1-3 composite (12 mW/cm3 under a stress of 39 MPa). At a higher stress level, the harvested-energy density of 1-3 PMN-PT single crystal composite can reach 96 mW/cm3 . > I. Introduction sing electroactive materials to harvest electric energy from various parasitic mechanical sources is attractive for a broad range of applications, especially in view of the fact that some of these materials can be made into flexible forms and in very small volumes. In a typical energyharvesting process, an electroactive material absorbs the external mechanical energy, and through a proper electromechanical conversion process converts that energy into electric form. This converted electric power, through a power electronic interface, is delivered to the electronic load. Therefore, several steps must be taken in designing an energy-harvesting system to effectively convert the mechanical energy available in an external medium into the electric energy to be delivered to an electric load: a mechanical impedance match of the electroactive material system to the environment to realize maximum mechanical energy transfer into the electroactive material system; high electromechanical conversion efficiency of the electroactive material system; a proper power electronics to U Manuscript received July 5, 2005; accepted September 23, 2005. K. Ren, Y. Liu, H. F. Hofmann, and Q. M. Zhang are with the Department of Electrical Engineering, Pennsylvania State University, University Park, PA (e-mail: kxr233@psu.edu). X. Geng is with Blatek, Inc., State College, PA. efficiently transfer converted electric power into the electric load. Here we focus on the electroactive material system, which includes possible modification to the pure material by other mechanical or electrical parts. These additions or modifications may improve the electromechanical conversion efficiency and/or the mechanical impedance match to the external mechanical environment [1]. Recently, it was reported that, in relaxor ferroelectric single crystals of PZN-PT and PMN-PT, a very high longitudinal electromechanical coupling factor (>0.9) can be achieved [2]–[4]. Such a high coupling factor is attractive for energy harvesting using electroactive materials. This paper investigates the energy harvesting using 1-3 composites with relaxor ferroelectric single crystal PMN-PT in a soft epoxy matrix. The single crystal at the composition of 0.67PMN-0.33PT is chosen for this investigation. This composition is in the rhombohedra side near the morphotrophic phase boundary between the tetragonal and rhombohedra phases. When oriented and poled along the 001 direction, a piezoelectric d33 coefficient higher than 2000 pC/N and a longitudinal coupling factor k33 of 0.94 have been reported. In contrast, the thickness coupling factor kt of the same crystals is not very high (in fact, it is nearly the same as that of the piezoelectric PZT ceramics) [2]–[4]. In this investigation, 1-3 single crystal/soft epoxy composites are used to take advantage of the high k33 coefficient and avoid the low kt of the single crystal. As has been shown both theoretically and experimentally for a properly designed 1-3 piezoceramic-polymer composite, the thickness coupling factor can approach the longitudinal coupling factor of the piezoelectric phase [5]–[8]. In addition, the soft polymer matrix also provides support to the single crystals, which improves the mechanical reliability against mechanical loads in energy harvesting experiments. The use of 1-3 composites also reduces the elastic impedance of the electroactive material system (defined as ρ∗ Va , where ρ is the density and Va is the acoustic velocity). When harvesting energy from a person during walking or from many other mechanical sources such as ocean waves, a lower mechanical impedance of the electroactive material system, compared with the piezoceramic and single crystals, is highly desirable. It is noted that, from the engineering perspective, the single crystal PMN-PT is much more expensive than the PZT. Hence, it can be prohibitive for large-scale applications. However, there are applications such as microelectromechanical systems and microsensors for which only a small amount of materials is needed. c 2006 IEEE 0885–3010/$20.00 632 ieee transactions on ultrasonics, ferroelectrics, and frequency control, vol. 53, no. 3, march 2006 (a) (b) Fig. 1. (a) Optical image of 1-3 composite: dark area, PMN-33PT; white area, epoxy. (b) Diphase 1-3 composite arranged in parallel configuration along the z-direction, Hatched area, PMN-PT; white area, epoxy; Z, the direction of spontaneous polarization and the applied electric field). II. 1-3 Composite Fabrication and Characterization Single crystals of 0.67PMN-0.33PT oriented along 001 direction are used in this investigation. The single crystals are poled at room temperature under a field of 10 kV/cm. The poled single crystals exhibit a d33 of 2060 pC/N measured using a d33 meter. In the 1-3 composite fabrication process, extra precaution has to be taken not to damage the single crystals. The poled single crystals of 1-mm thick (001 oriented) are first diced along the 100 direction using the Automatic Dicing Saw K&S 982-6 (supplied by Kulicke & Soffa Industries, Willow Grove, PA) with a kerf width of 100 µm, then diced in the perpendicular direction to produce an array of posts with a rectangular cross section [Fig. 1(a)]. The width (0.1 and 0.3 mm along the two perpendicular directions, respectively) of the single crys- tal rods is much smaller than the thickness of the crystal (or length of the rods, along the z-direction [Fig. 1(b)]), required in order to realize the longitudinal coupling factor of the crystal in the composite. The cutting process is followed by filling of Mereco 1650 series epoxy (Mereco Technology Group Inc., West Warwick, RI) to form a 1-3 composite [Fig. 1(a)]. The Young’s modulus of the epoxy is 14 MPa, much smaller than that of single crystal. The 1-3 composites are polished to a thickness of about 0.7 mm and sputtered Au films of 20-nm thick are used as the electrodes. The finished composites are poled again along the thickness direction in silicone oil for 5 minutes under a direct current (DC) field of 10 kV/cm. We find that this second poling process is necessary to have high piezoelectric coefficient and electromechanical coupling factor of the composites. The dielectric, piezoelectric, and electromechanical properties are characterized for the 1-3 composites. For a 1-3 composite, because the two constituents are electrically in parallel [Fig. 1(b)], the dielectric constant can be expressed as ε = 1 vε1 + 2 vε2 , if the fabrication process does not affect the properties of the single crystals [9]. In this equation, 1 ν and 2 ν denote the volume fraction of phase 1 and phase 2, ε1 and ε2 are the dielectric permittivity of phase 1 and phase 2, respectively. Fig. 2 presents data of the dielectric constant as a function of temperature (measured during cooling) for a 1-3 single crystal composite with 44.4% volume fraction of PMN-PT single crystal. For comparison, the data for the single crystal of the same composition and orientation is shown in Fig. 2(b). The dielectric peak at 130◦ C for the composite is the same as that in the single crystal. At room temperature, the dielectric constant of the crystal is 3390 and the 1-3 composite is 1536, which is close to 44.4% of 3390 (=1505). The result indicates that the 1-3 composite fabrication process used in this investigation does not have a marked effect on the single crystal piezoelectric properties. For 1-3 composites with a small aspect ratio (the width of the crystal rods and width of the polymer phase kerf versus the thickness), the piezoelectric coefficient d33 of 1-3 composites can be expressed as [10]: 1 1 d33 = v d33 2 s33 + 2 v 2 d33 1 s33 , 1 v2 s 2 1 33 + v s33 (1) where 1 d33 and 2 d33 are the piezoelectric coefficient and 1 s33 and 2 s33 are the elastic compliance of phase 1 and phase 2, respectively. For the PMN-PT/epoxy composite, the piezoelectric coefficient of the epoxy 2 d33 is 0 and the elastic compliance of epoxy 2 s33 is much larger than 1 s33 (7.1 × 10−8 1.2 × 10−10 ), which yield d33 ≈ 1 d33 . Directly measuring the d33 coefficient of 1-3 composites using a d33 meter shows that this is indeed the case. As has been shown by earlier works [11], [12] on piezoelectric 1-3 composites, the thickness electromechanical coupling factor kt of 1-3 composites, which is the coefficient related to the energy harvesting experiment in this paper, can be very close to the longitudinal coupling factor k33 of the single crystal. ren et al.: energy harvesting single crystals and soft epoxy material 633 (a) Fig. 3. Electrical impedance Z and phase angle θ for a PMN-33PT/Epoxy composite with 0.56 volume fraction, thickness/width = 1.77. (b) Fig. 2. The dielectric constant as a function of temperature for (a) 1-3 PMN-33PT/Epoxy composite with a 44.4% volume fraction of PMNPT; (b) PMN-33PT single crystal (measured at cooling at 1 kHz). The coupling factor kt of the 1-3 composites is characterized using an HP Impedance Analyzer (HP Model 4284A, Agilent, Palo Alto, CA), and the data is shown in Fig. 3. From the series resonance frequency fs and the parallel resonance frequency fp , kt can be determined from [13]: kt2 π fs = tan 2 fp π fp − fs 2 fp Fig. 4. Thickness coupling coefficient kt versus volume fraction for PMN-33PT/Epoxy composites. Open circles, experimental data and solid curve, a fitting to the data using the relation in [7] and [12]. The elastic stiffness cD 33 of the 1-3 composite can be deduced from the resonance frequency [12]: 2 . (2) The coupling factors of composites with different volume fraction of PMN-PT single crystals are shown in Fig. 4. In the composition with PMN-PT single crystals near 50%, the coupling factor kt reaches 0.855, close to the single crystal k33 value of about 0.9, which is higher than the values reported by others on single crystal-polymer composites [12]. The difference might be due to the polymer matrix used by different groups because the matrix used here possesses a very low elastic modulus. For comparison, the coupling factor kt of the same PMN-PT single crystals also is measured, and it is 0.59. cD 33 = ρ (2tfp ) , (3) where ρ is the density of the composite and t is its thickness. Using the relationship [13]: D 2 cE (4) 33 = 1 − kt c33 , the elastic stiffness under constant electric field also can be E obtained. The elastic stiffness cD 33 and c33 as a function of the volume fraction of PMN-PT single crystals are shown D in Fig. 5. Both cE 33 and c33 increase with the volume content of the single crystal, and the elastic stiffness of 1-3 composites whose composition is about 50% single crystal is much smaller than that of the crystal itself, which are expected. 634 ieee transactions on ultrasonics, ferroelectrics, and frequency control, vol. 53, no. 3, march 2006 (a) Fig. 6. Electrical impedance Z and phase angle θ for a PZT/Epoxy composite with 0.4 volume fraction. Fig. 7. Schematics for the energy-harvesting experiment setup in this study. (b) Fig. 5. (a) Elastic stiffness constant cD 33 versus volume fraction. (b) Elastic compliance constant cE 33 versus volume fractions for 13 PMN-33PT/Epoxy composite. Data points are shown and solid curves are drawn to guide eyes. For comparison, 1-3 composites of piezoceramic PZT in a polymer matrix also are used in an energy-harvesting experiment. The 1-3 piezocomposites are purchased from Smart Material Corp., Osprey, FL. The volume fraction of the PZT ceramic is 40%. The electric impedance curve for the PZT-piezoceramic/polymer composite is shown in Fig. 6. The coupling factor deduced from the resonance D data is 62.8%. The elastic stiffness cE 33 and c33 of the PZT 10 2 composite are 3.32 × 10 N/m and 2.1 × 1010 N/m2 , respectively. III. Energy Harvesting Using 1-3 Composites The schematic of the energy-harvesting experiment setup is shown in Fig. 7 in which the harvested electric energy is delivered to a resistive load. In the experiment, a Universal Test Machine (MTS 810, Supplied by Material Test System Corp., Eden Prairie, MN) is used to provide the mechanical energy input to the electroactive materi- als [an alternating current (AC) compressive stress of 4 to 10 Hz]. The compressive stress is applied along the poling direction (the 3- or z-direction). The energy-harvesting experiment also is intended to evaluate how high of a stress field can be applied to the composites to generate a highelectric, energy-density output without damaging or depoling the composite. For PMN-PT single crystals, it has been shown that a very large strain can be induced by an external applied electric field for the crystals at the composition investigated here when oriented along the 001 direction [2]–[4]. Hence, it is expected that, in poled composites, a high stress can be applied to induce large strain and consequently a large mechanical energy density in the composites. It also has been shown by earlier investigations [14] that a high compressive mechanical stress applied to a piezoelectric material, as in the energy-harvesting experiment presented here, can depole the piezoelectric material. In order to prevent possible depoling at high stress level, a DC electric bias field is applied to the composites to stabilize the polarization against high-compressive stress. A very large resistor R1 is used to isolate the DC power source from the AC energy-harvesting circuit (the R1 Cs time constant is much larger than 1/f , where f is the AC mechanical signal frequency, in the 4 to 10 Hz range in the present experiment, and Cs is the capacitance of the electroactive composites). ren et al.: energy harvesting single crystals and soft epoxy material For the piezo-composites in the energy-harvesting experiment, assuming that the nonzero strain component is S3 (the strain S along the applied stress direction due to the fact that the lateral dimensions are much larger than the thickness of the composites), which is close to the experimental situation, the piezoelectric constitutive relations are: T = cE S − eE, D = eS + εs E, (5) where cE is the elastic stiffness under constant field, e is the piezoelectric constant, and εs is the dielectric permittivity under constant stress, T is the stress component T3 , E is the electric field E3 , and D is the displacement component D3 , respectively. When a sinusoidal mechanical force F = F eiωt is applied on the sample and a sinusoid voltage and strain are generated, the phase of which are determined by: Fe iωt E = c l0 e Q = el0 e i(ωt+α) i(ωt+α) − eV0 e i(ωt+θ) + C0 V0 e , i(ωt+θ) , The generated voltage is given by: V0 eiθ = RI = R iωel0 eiα + iωC0 V0 eiθ , iRωel0 eiα , 1 − iωRC0 V02 Re2 l02 ω 2 = , 2R 2 (1 + ω 2 R2 C02 ) 1 , ωC0 2 2 e2 l02 2ω , 4C0 In addition: cE e2 =1+ E . D c c C0 (14) Substituting (13) and (14) into (10) yields the harvested power in the load resistor: Re2 ω 2 F 2 2 2 cE 1 + (ωRC0 )2 1 1 − kt2 2 . 1 − kt2 , ωC0 (8) (9) (10) (11) (12) S ω or the power density is e 4ε s ; (12) shows that the output power is proportional to the excitation frequency of (15) Hence, the maximum power delivered to the load resistor is achieved when: and the maximum power in this case is given by: F 2 e2 ω 1 − kt2 F 2 kt2 ω Powerpeak = = , E 2 4cE 4 c C0 and the peak power is: Powerpeak = (13) (7) which shows that, when the load resistor is equal to the impedance of the sample voltage source, the maximum power dissipated in the resistor can be reached, i.e., when: R= F . iRωe2 cE − 1 − iωRC0 R= and the power dissipation in the load resistor is: Power = l0 eiα = Power = where R is the total external load resistor (∼ R4 in our experiment). Solving these equations yields the generated voltage: V0 eiθ = the mechanical force, the square of the displacement, and the piezoelectric constant of the material. This means that, if a material with a high-piezoelectric constant and a high-strain capability is used, the harvested-electric energy would improve greatly. For the single crystal PMN-33PT, the strain can be more than 1%, which is much larger than the strain of the piezoceramic [2]–[4]. The relationship between the output power and input mechanical F also can be derived. From (6) and (9), l0 is: (6) where A is the cross section and t0 is the thickness, l0 = St0 is the displacement, F = T A is the applied force, Q = DA is the charge, V = Et0 is the voltage, cE = cE tA0 , s e = e tA0 and C0 = εt0A , respectively. The current generated in an external load, therefore, is: ∂Q I= = iωel0 ei(ωt+α) + iωC0 V0 ei(ωt+θ) . ∂t 635 T 2 k2 ω (16) (17) or the peak power density is 4cEt . The result indicates that the output power density is proportional to the square of the stress, excitation frequency of the mechanical force, and the coupling factor of the material. It is also inversely proportional to the elastic stiffness of the material. Hence, a soft material with a high-electromechanical coupling factor will deliver higher output electrical energy. The 1-3 composites with PMN-PT single crystals meet these conditions. It should be pointed out that the equations derived are based on the assumption that all the coefficients do not change with the applied mechanical stress and electric field. The schematics of the energy-harvesting experiment using a resistive load are shown in Fig. 7. The energy harvested is measured directly from the voltage across R2 . In the experiment, two different types of 1-3 composites are used. One is the 1-3 PMN-33PT/Epoxy composite. Another one is PZT/Epoxy 1-3 composite, which is used for comparison. To determine the maximum output power under a constant stress, a variable resistor is connected to the circuit 636 ieee transactions on ultrasonics, ferroelectrics, and frequency control, vol. 53, no. 3, march 2006 Fig. 8. Harvested power density versus the load resistor in the circuit for the 1-3 PMN-PT/Epoxy composite with volume fraction 56.3%. Applied AC stress amplitude is 88.9 MPa, DC bias field is 4.35 kV/cm, and the sample dimension is 10 mm × 10 mm × 0.69 mm. and an 88.9 MPa AC stress (4 Hz) is applied to the 1-3 composite (56% of PMN-PT crystal). The result is shown in Fig. 8, and the maximum power density is 96 mW/cc when the load resistor is 9.5 Mohm. Under high compressive stress, both the capacitance and the coupling factor will decrease compared with their stress-free values. Hence, the load resistor value at high stress for the maximum power output is higher than for the stress-free case (∼4 MPa). Such a nonlinear material response is a common feature of piezomaterials. In this experiment, a DC bias field of 4.65 kV/cm is applied to prevent depoling due to stress. After energy-harvesting experiments, the coupling factor kt of the 1-3 composite was measured, and the results showed that the coupling factor of the composite did not change after the energy-harvesting experiments, indicating that no depoling occurs under a high-stress level when the composites are subject to the DC bias field. For comparison, the dependence of the power harvested on applied stress level is measured using a 1-3 PZT/Epoxy composite (purchased from Smart Material Corp.) in which soft PZT (PZT-5H) is used. As shown in the data of Fig. 9(a), when no DC bias is applied to the composites, a partial depolarization occurs that results in a much smaller harvested power as the stress amplitude is reduced (reduction of the coupling factor and piezoelectric coefficient). When a high DC bias field is applied, from the data in Fig. 9(b), the harvested energy is enhanced because the DC bias prevents the partial depoling of the 1-3 composite during the measurement. The maximum power density is 12 mW/cc from the 1-3 PZT/Epoxy composite under a 40 MPa AC stress of 4 Hz. The results from these studies are summarized in Table I. Due to a higher coupling factor, the harvested-energy density of 1-3 composite with single crystal (22.1 mW/cc under 40.4 MPa) is about twice of that harvested with (a) (b) Fig. 9. Harvested power density versus applied mechanical stress for a PZT/Epoxy composite with 0.4 volume fraction. Sample diameter, 2 cm and thickness, 1.1 mm. (a) DC bias = 0 V. (b) DC bias = 5.45 kV/cm. The direction of the stress cycle is indicated in the figure. PZT ceramic 1-3 composite (12 mW/cc under 39 MPa). At a higher stress level, the harvested-energy density of 1-3 PMN-PT single crystal composite can be 96 mW/cc. From Table I, when the applied mechanical stress is increased by 88.9/40.4 = 2.2 times, the square dependence of the output power on the applied stress indicates that the harvested-energy density should be increased by a factor of 4.8. The result in Table I shows an increase in the power density of a factor of (96.2/22.1) 4.4, close to 4.8 as predicted. It should be pointed out that, because the composites are insulators, there is very little energy consumption of the DC power source used to provide DC bias voltage. In fact, such a DC voltage source can be provided by the harvested-electric energy through properly designed power electronics. ren et al.: energy harvesting single crystals and soft epoxy material TABLE I Summary of the Experimental Results. Volume fraction E cD 33 c33 (GPa) Stress (MPa) Power density (mW/cc) 1-3 PZT/Epoxy composite 40% 34.8/21 39 12 1-3 single crystal PMN-33PT/ Epoxy composite 37.5% 56% 49/12.8 60/15.6 40.4 88.9 22.1 96.2 Material IV. Conclusions In this paper, 1-3 PMN-PT single-crystal/polymer composites are investigated for energy-harvesting applications. To make use of the high-strain capability, and hence the high-energy density, while maintaining mechanical integrity, 1-3 composites are a preferred form for the single crystals to be utilized for energy harvesting. The single crystal PMN-PT/Epoxy composites with different volume fraction of single crystals are fabricated and characterized. The results show that, for a properly designed and fabricated 1-3 single crystal/polymer composite, the thickness coupling factor kt , which is used in this energy-harvesting experiment, can be very close to the longitudinal coupling factor k33 of the single crystal. For the experiments conducted in this paper, kt of 1-3 single crystal composite is 0.855, close to k33 = 0.9 of the single crystals used in this study. In the energy-harvesting experiments, a resistive load circuit is used to measure the energy harvested. Based on the piezoelectric constitutive equations, the relations between the input mechanical strain, stress and harvested electrical energy density are derived. For comparison, the energy-harvesting experiment using 1-3 PZT/Epoxy composites also is performed. Due to the higher coupling factor, the harvested energy density from 1-3 PMNPT/Epoxy composite is about twice of that from the 1-3 PZT/Epoxy. Under a mechanical stress of 88.9 MPa at 4 Hz, a harvested-energy density of near 0.1 W/cc can be achieved. The experimental results also show that a high stress (more than 40 MPa) can be applied to 1-3 single crystal composites without damaging the composites, and a DC bias field applied to the composites is very effective in preventing the stress depoling in the composites. No degradation is observed after many energy harvesting cycles under high stress using these 1-3 composites. References [1] Y. Liu, K. Ren, H. Hofmann, and Q. M. Zhang, “Investigation of electrostrictive polymers for energy harvesting,” IEEE Trans. Ultrason., Ferroelect., Freq. Contr., vol. 52, pp. 2411– 2417, Dec. 2005. [2] S. Park and T. Shrout, “Characteristics of relaxor-based piezoelectric single crystals for ultrasonic transducers,” IEEE Trans. Ultrason., Ferroelect., Freq. Contr., vol. 44, pp. 1140–1147, Sep. 1997. 637 [3] S.-E. Park and T. R. Shrout, “Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals,” J. Appl. Phys., vol. 82, pp. 1804–1811, Aug. 1997. [4] S. J. Zhang, L. Lebrun, D. Y. Jeong, C. A. Randall, Q. M. Zhang, and T. R. Shrout, “Growth and characterization of Fe-doped Pb(Zn1/3 Nb2/3 )O3 -PbTiO3 single crystals,” J. Appl. Phys., vol. 93, pp. 9257–9262, June 2003. [5] T. R. Gururaja, W. A. Schulze, L. E. Cross, R. E. Newnham, B. A. Auld, and Y. J. Wang, “Piezoelectric composite materials for ultrasonic transducer applications. Part I: Resonant modes of vibration of PZT rod-polymer composites,” IEEE Trans. Sonics Ultrason., vol. SU-32, pp. 481–498, July 1985. [6] T. R. Gururaja, W. A. Schulze, L. E. Cross, and R. E. Newnham, “Piezoelectric composite materials for ultrasonic transducer applications. Part II: Evaluation of ultrasonic medical applications,” IEEE Trans. Sonics Ultrason., vol. SU-32, pp. 499–513, July 1985. [7] W. A. Smith and B. A. Auld, “Modeling 1-3 composite piezoelectrics: Thickness-mode oscillations,” IEEE Trans. Ultrason., Ferroelect., Freq. Contr., vol. 38, pp. 40–47, Jan. 1991. [8] H. L. W. Chan and J. Unsworth, “Mode coupling in modified lead titanate polymer 1-3 composites,” J. Appl. Phys., vol. 65, pp. 1754–1758, 1989. [9] K. Uchino, Ferroelectric Device. New York: Marcel Dekker, Inc., 2000. [10] R. E. Newnham, D. P. Skinner, and L. E. Cross, “Connectivity and piezoelectric-pyroelectric composites,” Mater. Res. Bull., vol. 13, pp. 525–536, 1978. [11] Y. Phermpornsakul, S. Muensit, and I. L. Guy, “Determination of piezoelectric and pyroelectric coefficients and thermal diffusivity of 1-3 PZT/Epoxy composites,” IEEE Trans. Dielect. Elect. Insulation, vol. 11, pp. 280–285, Apr. 2004. [12] K. C. Cheng, H. L. W. Chan, C. L. Choy, Q. Yin, H. Luo, and Z. Yin, “Single crystal PMN-0.33PT/Epoxy 1-3 composites for ultrasonic transducer application,” IEEE Trans. Ultrason., Ferroelect., Freq. Contr., vol. 50, pp. 1177–1183, Sep. 2003. [13] IEEE Standard on Piezoelectricity, ANSI/IEEE, Standard, 176-7987, 1987. [14] Q. M. Zhang and J. Zhao, “Electromechanical properties of lead zirconate titanate piezoceramics under the influence of mechanical stresses,” IEEE Trans. Ultrason., Ferroelect., Freq. Contr., vol. 46, pp. 1518–1526, Nov. 1999. Kailiang Ren was born in Shaanxi, China, in 1974. He received the B.S. degree in electrical engineering from Tianjin University, Tian’jin, China, in 1997 and the M.S. degree in electrical engineering from Pennsylvania State University, University Park, PA, in 2005. He is currently a Ph.D. student in Pennsylvania State University. His research interests are in preparation and characterization of ferroelectric materials (electroactive polymer and composite) and designing some devices for applications, including energy harvesting, transducer, actuator, and microfluidic devices. Yiming Liu (S’03) was born in Lanzhong, China, in 1972. He received his B.S. degree in physics from Nanjing University, Nanjing, China, in 1996. Between 1996 and 1999 he worked in The National Laboratory of Solid State Microstructures, Nanjing, China, as a research assistant on ferroelectric thin films. He was admitted to the Ph.D. program of the Department of Physics at the Pennsylvania State University, University Park, PA, in fall 1999. After finishing core courses and passing candidacy examination, he changed his major 638 ieee transactions on ultrasonics, ferroelectrics, and frequency control, vol. 53, no. 3, march 2006 to electrical engineering and continues his Ph.D. study. He worked as a research assistant for the Material Research Institute at Penn State University on loss mechanism of piezoelectric and ferroelectric materials between 2001 and 2002. At the end of 2002 he joined the Power Electronic Group at Penn State University led by Dr. Heath Hofmann. He has dedicated himself to research on energy harvesting since March 2003. His research interests are power electronics and piezoelectric devices, analytic and numerical modeling of dynamic systems, and control theory of switched mode power electronics. Xuecang Geng received a B.S. degree in physics from Xi’an Jiaotong University, Xi’an, China, in 1983, a M.S. degree in acoustics from the Institute of Acoustics, Chinese Academy of Sciences, Beijing, China, in 1989, and a Ph.D. degree in material engineering from Pennsylvania State University, University Park, PA, in 1997. From 1983 to 1986 he was an engineer at Center of Microelectronics, Chinese Academy of Sciences, Beijing, China. This work focused on the computer-aided design of integrated circuit modeling of the integrated circuit process. From 1990 to 1993 as a research assistant at the ultrasonic lab of the Institute of Acoustics, Beijing, China, he worked on non-destructive testing of materials, acoustic wave logging, design, fabrication, and characterization of 1-3 piezocomposites for ultrasonic transducer applications. Since 1998, he has worked as a senior scientist at Blatek, Inc., State College, PA, focusing on ultrasonic transducer design for medical and industrial applications. Heath F. Hofmann (M’89) is an associate professor at Pennsylvania State University, University Park, PA. Dr. Hofmann’s research area is power electronics, specializing in the design and control of electromechanical systems. Specific interests are sensorless control techniques, low-power electronic design, and finite-element analysis. Ongoing projects include the design of a high-speed motor/generator for flywheel energy storage systems, optimization of ultrahigh power density electric machines, design of an ultra- capacitor energy storage system for hybrid electric vehicles, energyharvesting circuitry for vibrating piezoelectric devices, sensorless control of interior permanent magnet machines, induction machines, and linear machines, design of a unity-power factor bi-directional AC-DC converter, and stability analysis of DC distribution systems. Dr. Hofmann was awarded a Prize Paper Award (First Prize) by the Electric Machines Committee at an IEEE Industry Applications Society Annual Meeting in 1998. Qiming M. Zhang (M’96–SM’00) is a professor of electrical engineering. He obtained a Ph.D. degree in 1986 from Pennsylvania State University, University Park, PA. The research areas in his group include fundamentals and applications of novel electronic and electroactive materials. Research activities in his group include actuators and sensors, transducers, dielectrics and charge storage devices, polymer thin film devices, polymer microelectromechanical systems (MEMS), and electro-optic and photonic devices. He has over 230 publications and 8 patents in these areas. His group has discovered and developed a ferroelectric relaxor polymer that possesses room temperature dielectric constant higher than 50, an electrostrictive strain higher than 7%, and electric energy density near 10 J/cm3 . His group also proposed and developed nano-polymer composites based on delocalized electron systems to raise the nano-polymeric composites dielectric constant near 1,000. He is the recipient of the 1999 Penn State Engineering Society Outstanding Research Award. The research works in his group have been funded by The Defense Advanced Research Projects Agency (DARPA), the Office of Naval Research (ONR), National Institutes of Health (NIH), National Science Foundation (NSF), and many companies.